fumarates and benzeneboronic-acid

fumarates has been researched along with benzeneboronic-acid* in 1 studies

Other Studies

1 other study(ies) available for fumarates and benzeneboronic-acid

Article	Year
Preparation of chiral 3-arylpyrrolidines via the enantioselective 1,4-addition of arylboronic acids to fumaric esters catalyzed by Rh(I)/chiral diene complexes. Organic letters, 2012, Jun-01, Volume: 14, Issue:11 A highly efficient rhodium-catalyzed protocol for the preparation of 2-arylsuccinic esters and 3-arylpyrrolidines of high optical purity has been achieved. In the presence of 1 mol % of a chiral diene/Rh(I) catalyst, asymmetric addition of various arylboronic acids to di-tert-butyl fumarate (3c) provides the corresponding adducts in up to 99% yield and 94→99.5% ee. Excellent enantioselectivities were also observed in the regio- and enantioselective conjugate addition of phenylboronic acid (4a) to compound 3e. Topics: Boronic Acids; Catalysis; Esters; Fumarates; Molecular Structure; Pyrrolidines; Rhodium; Stereoisomerism; Succinates	2012

Article

Year

Preparation of chiral 3-arylpyrrolidines via the enantioselective 1,4-addition of arylboronic acids to fumaric esters catalyzed by Rh(I)/chiral diene complexes.

Organic letters, 2012, Jun-01, Volume: 14, Issue:11

A highly efficient rhodium-catalyzed protocol for the preparation of 2-arylsuccinic esters and 3-arylpyrrolidines of high optical purity has been achieved. In the presence of 1 mol % of a chiral diene/Rh(I) catalyst, asymmetric addition of various arylboronic acids to di-tert-butyl fumarate (3c) provides the corresponding adducts in up to 99% yield and 94→99.5% ee. Excellent enantioselectivities were also observed in the regio- and enantioselective conjugate addition of phenylboronic acid (4a) to compound 3e.

Topics: Boronic Acids; Catalysis; Esters; Fumarates; Molecular Structure; Pyrrolidines; Rhodium; Stereoisomerism; Succinates

2012