fostriecin has been researched along with allyl-alcohol* in 1 studies
1 other study(ies) available for fostriecin and allyl-alcohol
Article | Year |
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Synthesis of homoallylic chiral tertiary alcohols via chelation-controlled diastereoselective nucleophilic addition on alpha-alkoxyketones: application for the synthesis of the C(1)-C(11) subunit of 8-epi-fostriecin.
[reaction: see text] Chiral beta-syn-alkoxyhomoallylic alcohols derived from alkoxyallylboration of aldehydes upon oxidation provided the corresponding chiral ketones. Chelation-controlled nucleophilic addition to these ketones occurred in a highly stereoselective manner to afford anti-homoallylic tertiary alcohols. This methodology has been applied for the synthesis of the C(1)-C(11) subunit of C(8)-epi-fostriecin. Topics: Alkenes; Chelating Agents; Ketones; Polyenes; Propanols; Pyrones; Stereoisomerism | 2003 |