fostriecin and allyl-alcohol

fostriecin has been researched along with allyl-alcohol* in 1 studies

Other Studies

1 other study(ies) available for fostriecin and allyl-alcohol

ArticleYear
Synthesis of homoallylic chiral tertiary alcohols via chelation-controlled diastereoselective nucleophilic addition on alpha-alkoxyketones: application for the synthesis of the C(1)-C(11) subunit of 8-epi-fostriecin.
    Organic letters, 2003, Oct-02, Volume: 5, Issue:20

    [reaction: see text] Chiral beta-syn-alkoxyhomoallylic alcohols derived from alkoxyallylboration of aldehydes upon oxidation provided the corresponding chiral ketones. Chelation-controlled nucleophilic addition to these ketones occurred in a highly stereoselective manner to afford anti-homoallylic tertiary alcohols. This methodology has been applied for the synthesis of the C(1)-C(11) subunit of C(8)-epi-fostriecin.

    Topics: Alkenes; Chelating Agents; Ketones; Polyenes; Propanols; Pyrones; Stereoisomerism

2003