flustramine-c and deformylflustrabromine

flustramine-c has been researched along with deformylflustrabromine* in 1 studies

Other Studies

1 other study(ies) available for flustramine-c and deformylflustrabromine

Article	Year
Total synthesis of flustramine C via dimethylallyl rearrangement. Organic letters, 2007, Jan-18, Volume: 9, Issue:2 The marine natural product flustramine C from the bryozoan Flustra foliacea was synthesized in five steps and 38% yield starting from Nb-methyltryptamine. The key step is the biomimetic oxidation of the natural product deformylflustrabromine causing selective 1,2-rearrangement of the inverse prenyl group. By 1H,15N HMBC experiments, it is unambiguously shown that the reaction with t-BuOCl commences with chlorination of the side chain nitrogen. Deformylflustrabromine itself was synthesized via Danishefsky inverse prenylation. [reaction: see text]. Topics: Allyl Compounds; Animals; Bryozoa; Heterocyclic Compounds, 3-Ring; Indole Alkaloids; Indoles; Magnetic Resonance Spectroscopy; Models, Molecular; Molecular Structure; Niobium; Oxidation-Reduction; Sensitivity and Specificity; Tryptamines	2007

Article

Year

Total synthesis of flustramine C via dimethylallyl rearrangement.

Organic letters, 2007, Jan-18, Volume: 9, Issue:2

The marine natural product flustramine C from the bryozoan Flustra foliacea was synthesized in five steps and 38% yield starting from Nb-methyltryptamine. The key step is the biomimetic oxidation of the natural product deformylflustrabromine causing selective 1,2-rearrangement of the inverse prenyl group. By 1H,15N HMBC experiments, it is unambiguously shown that the reaction with t-BuOCl commences with chlorination of the side chain nitrogen. Deformylflustrabromine itself was synthesized via Danishefsky inverse prenylation. [reaction: see text].

Topics: Allyl Compounds; Animals; Bryozoa; Heterocyclic Compounds, 3-Ring; Indole Alkaloids; Indoles; Magnetic Resonance Spectroscopy; Models, Molecular; Molecular Structure; Niobium; Oxidation-Reduction; Sensitivity and Specificity; Tryptamines

2007