ferryl-iron and cyclam

ferryl-iron has been researched along with cyclam* in 2 studies

Other Studies

2 other study(ies) available for ferryl-iron and cyclam

Article	Year
Role of "S" Substitution on C-H Activation Reactivity of Iron(IV)-Oxo Cyclam Complexes: a Computational Investigation. Inorganic chemistry, 2022, Sep-19, Volume: 61, Issue:37 A comprehensive density functional theory (DFT) investigation has been presented in this article to address the role of equatorial sulfur ligation in C-H activation. A non-heme iron-oxo compound with four nitrogen atoms constituting the equatorially connected macrocyclic framework (represented as N Topics: Heterocyclic Compounds; Iron; Iron Compounds; Nitrogen; Organometallic Compounds; Oxidants; Oxygen; Sulfur	2022
Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size. Dalton transactions (Cambridge, England : 2003), 2013, Jun-14, Volume: 42, Issue:22 The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe(IV/III) redox potential. Topics: Heterocyclic Compounds; Hydrogen; Iron; Iron Compounds; Ligands; Methylation; Models, Molecular; Oxygen	2013

Article

Year

Role of "S" Substitution on C-H Activation Reactivity of Iron(IV)-Oxo Cyclam Complexes: a Computational Investigation.

Inorganic chemistry, 2022, Sep-19, Volume: 61, Issue:37

A comprehensive density functional theory (DFT) investigation has been presented in this article to address the role of equatorial sulfur ligation in C-H activation. A non-heme iron-oxo compound with four nitrogen atoms constituting the equatorially connected macrocyclic framework (represented as N

Topics: Heterocyclic Compounds; Iron; Iron Compounds; Nitrogen; Organometallic Compounds; Oxidants; Oxygen; Sulfur

2022

Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size.

Dalton transactions (Cambridge, England : 2003), 2013, Jun-14, Volume: 42, Issue:22

The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe(IV/III) redox potential.

Topics: Heterocyclic Compounds; Hydrogen; Iron; Iron Compounds; Ligands; Methylation; Models, Molecular; Oxygen

2013