ethylenethiourea and 2-mercaptobenzimidazole

ethylenethiourea has been researched along with 2-mercaptobenzimidazole* in 1 studies

Other Studies

1 other study(ies) available for ethylenethiourea and 2-mercaptobenzimidazole

ArticleYear
Halogen, chalcogen, and hydrogen bonding in organoiodine cocrystals of heterocyclic thiones: imidazolidine-2-thione, 2-mercaptobenzimidazole, 2-mercapto-5-methylbenzimidazole, 2-mercaptobenzoxazole, and 2-mercaptobenzothiazole.
    Acta crystallographica. Section C, Structural chemistry, 2022, 12-01, Volume: 78, Issue:Pt 12

    Through the combination of heterocyclic thiones with variation in the identity of the heterocyclic elements, namely, imidazolidine-2-thione, 2-mercaptobenzimidazole, 2-mercapto-5-methylbenzimidazole, 2-mercaptobenzoxazole, and 2-mercaptobenzothiazole with the common halogen-bond donors 1,2-, 1,3-, and 1,4-diiodotetrafluorobenzene, 1,3,5-trifluorotriiodobenzene, and tetraiodoethylene, a series of 18 new crystalline structures were characterized. In most cases, N-H...S hydrogen bonding was observed, with these interactions in imidazole-containing structures typically resulting in two-dimensional motifs (i.e. ribbons). Lacking the second N-H group, the thiazole and oxazole hydrogen bonding resulted in only dimeric pairs. C-I...S and C-I...I halogen bonding, as well as C=S...I chalcogen bonding, served to consolidate the packing by linking the hydrogen-bonding ribbons or dimeric pairs.

    Topics: Benzothiazoles; Chalcogens; Crystallography, X-Ray; Ethylenethiourea; Halogens; Hydrogen Bonding; Polymers; Thiones

2022