epohelmin-b and allyl-bromide

epohelmin-b has been researched along with allyl-bromide* in 1 studies

Other Studies

1 other study(ies) available for epohelmin-b and allyl-bromide

Article	Year
Asymmetric syntheses of epohelmins A and B by In-mediated allylation. Organic & biomolecular chemistry, 2016, Dec-07, Volume: 14, Issue:45 A diastereoselective new approach for the synthesis of trans-4-hydroxy-5-allyl-2-pyrrolidinone 9 has been developed through In-mediated allylation of α-chiral aldimine 8 with allyl bromide. The stereochemistry at the C-2 stereogenic center of 9 was controlled by both the α-OTBS substitution and the sulfinamide moiety. The utility of this asymmetric allylation is demonstrated by the asymmetric syntheses of epohelmins A (4) and B (10). Topics: Allyl Compounds; Bridged Bicyclo Compounds, Heterocyclic; Pyrrolidinones; Stereoisomerism; Sulfonium Compounds	2016

Article

Year

Asymmetric syntheses of epohelmins A and B by In-mediated allylation.

Organic & biomolecular chemistry, 2016, Dec-07, Volume: 14, Issue:45

A diastereoselective new approach for the synthesis of trans-4-hydroxy-5-allyl-2-pyrrolidinone 9 has been developed through In-mediated allylation of α-chiral aldimine 8 with allyl bromide. The stereochemistry at the C-2 stereogenic center of 9 was controlled by both the α-OTBS substitution and the sulfinamide moiety. The utility of this asymmetric allylation is demonstrated by the asymmetric syntheses of epohelmins A (4) and B (10).

Topics: Allyl Compounds; Bridged Bicyclo Compounds, Heterocyclic; Pyrrolidinones; Stereoisomerism; Sulfonium Compounds

2016