dolabelide-c has been researched along with allyl-alcohol* in 1 studies
1 other study(ies) available for dolabelide-c and allyl-alcohol
Article | Year |
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Highly demanding cross-metathesis in the synthesis of the C16-C30 fragment of dolabelide C.
A highly demanding cross-metathesis (CM) reaction for the formation of the C24-C25 trisubstituted olefin of dolabelide C has been optimized. A difference in reactivity between the E and Z enone isomers in this reaction was uncovered, and the selection of the Z isomer of the starting enone was critical for the success of the cross-metathesis. Application to the synthesis of the C16-C30 fragment of dolabelide C is reported. Topics: Isomerism; Macrolides; Molecular Structure; Propanols | 2011 |