Compounds > dimethyloxosulfonium-methylide

dimethyloxosulfonium-methylide and n-hexane

dimethyloxosulfonium-methylide has been researched along with n-hexane* in 1 studies

Other Studies

1 other study(ies) available for dimethyloxosulfonium-methylide and n-hexane

Article	Year
Novel skeleton transformation reaction of α-pyrone derivatives to spirobicyclo[3.1.0]hexane derivatives using dimethylsulfoxonium methylide. Organic letters, 2012, Dec-07, Volume: 14, Issue:23 By applying a skeleton transformation reaction using dimethylsulfoxonium methylide, a novel reaction was identified by which 5,6,7,8-tetrahydrocoumarin with the electron-withdrawing group at C3 was led to the spirobicyclo[3.1.0]hexane-cyclohexane derivative. Moreover, by establishing the scope of this reaction, it was confirmed that it is possible to apply this reaction to not only ring-fused α-pyrone derivatives but also alkyl-chain-substituted α-pyrone derivatives in moderate to good yields. Topics: Bridged Bicyclo Compounds; Hexanes; Molecular Structure; Pyrones; Spiro Compounds; Stereoisomerism; Sulfonium Compounds	2012

Article

Year

Novel skeleton transformation reaction of α-pyrone derivatives to spirobicyclo[3.1.0]hexane derivatives using dimethylsulfoxonium methylide.

Organic letters, 2012, Dec-07, Volume: 14, Issue:23

By applying a skeleton transformation reaction using dimethylsulfoxonium methylide, a novel reaction was identified by which 5,6,7,8-tetrahydrocoumarin with the electron-withdrawing group at C3 was led to the spirobicyclo[3.1.0]hexane-cyclohexane derivative. Moreover, by establishing the scope of this reaction, it was confirmed that it is possible to apply this reaction to not only ring-fused α-pyrone derivatives but also alkyl-chain-substituted α-pyrone derivatives in moderate to good yields.

Topics: Bridged Bicyclo Compounds; Hexanes; Molecular Structure; Pyrones; Spiro Compounds; Stereoisomerism; Sulfonium Compounds

2012