dimethyl-maleate and carbazole

dimethyl-maleate has been researched along with carbazole* in 1 studies

Other Studies

1 other study(ies) available for dimethyl-maleate and carbazole

ArticleYear
Diversity oriented convergent access for collective total synthesis of bioactive multifunctional carbazole alkaloids: synthesis of carbazomycin A, carbazomycin B, hyellazole, chlorohyellazole, and clausenaline D.
    Organic letters, 2014, Oct-17, Volume: 16, Issue:20

    Facile syntheses of imperative carbazole alkaloids carbazomycin A, carbazomycin B, hyellazole, chlorohyellazole, and clausenaline D have been demonstrated starting from readily available Boc-protected 3-formylindole and dimethyl maleate. The suitably substituted aromatic rings have been designed comprising three/four significant C-C bond forming reactions. The competent Wittig reaction, selective monoalkylations, one-pot regioselective Weinreb amide formation and Boc-deprotection, well designed Grignard reactions, dehydrative intramolecular cyclizations, and Baeyer-Villiger rearrangement of aromatic aldehydes were the main features.

    Topics: Aldehydes; Carbazoles; Cyclization; Indole Alkaloids; Indoles; Maleates; Molecular Structure

2014