daphenylline and propionaldehyde

daphenylline has been researched along with propionaldehyde* in 1 studies

Other Studies

1 other study(ies) available for daphenylline and propionaldehyde

Article	Year
Direct and short construction of the ACDE ring system of daphenylline. Chemistry, an Asian journal, 2015, Volume: 10, Issue:2 Daphenylline, a novel daphniphyllum alkaloid, boasts a fused and bridging ring system coupled with six stereogenic centers. Here we present a direct and short construction of the ACDE ring system of daphenylline from the known 3-(2-bromophenyl)propanal in 10 steps and 17 % overall yield. The synthesis features an iron(III)-catalyzed aza-Cope-Mannich reaction, a self-terminating 6-exo-trig aryl radical-alkene cyclization and an intramolecular Friedel-Crafts acylation. Topics: Acylation; Aldehydes; Alkaloids; Alkenes; Catalysis; Crown Compounds; Crystallography, X-Ray; Cyclization; Ferric Compounds; Molecular Conformation	2015

Article

Year

Direct and short construction of the ACDE ring system of daphenylline.

Chemistry, an Asian journal, 2015, Volume: 10, Issue:2

Daphenylline, a novel daphniphyllum alkaloid, boasts a fused and bridging ring system coupled with six stereogenic centers. Here we present a direct and short construction of the ACDE ring system of daphenylline from the known 3-(2-bromophenyl)propanal in 10 steps and 17 % overall yield. The synthesis features an iron(III)-catalyzed aza-Cope-Mannich reaction, a self-terminating 6-exo-trig aryl radical-alkene cyclization and an intramolecular Friedel-Crafts acylation.

Topics: Acylation; Aldehydes; Alkaloids; Alkenes; Catalysis; Crown Compounds; Crystallography, X-Ray; Cyclization; Ferric Compounds; Molecular Conformation

2015