crotylsilane and carbene

crotylsilane has been researched along with carbene* in 1 studies

Other Studies

1 other study(ies) available for crotylsilane and carbene

Article	Year
Vinylogous aldol products from chiral crotylsilanes obtained by enantioselective Rh(II) and Cu(I) carbenoid Si-H insertion. Organic letters, 2010, May-07, Volume: 12, Issue:9 Enantioenriched homoallylic ethers containing a alpha,beta-unsaturated ester (syn-vinylogous aldol products) were directly accessed by Lewis acid catalyzed crotylation utilizing chiral silane 2. The reagents were prepared by enantioselective Si-H insertion to an alpha-diazovinylacetates using Davies' Rh(2)(DOSP)(4) catalyst or chiral Cu(I) Schiff base complex. Topics: Aldehydes; Copper; Hydrogen; Methane; Rhenium; Silanes; Silicones; Stereoisomerism	2010

Article

Year

Vinylogous aldol products from chiral crotylsilanes obtained by enantioselective Rh(II) and Cu(I) carbenoid Si-H insertion.

Organic letters, 2010, May-07, Volume: 12, Issue:9

Enantioenriched homoallylic ethers containing a alpha,beta-unsaturated ester (syn-vinylogous aldol products) were directly accessed by Lewis acid catalyzed crotylation utilizing chiral silane 2. The reagents were prepared by enantioselective Si-H insertion to an alpha-diazovinylacetates using Davies' Rh(2)(DOSP)(4) catalyst or chiral Cu(I) Schiff base complex.

Topics: Aldehydes; Copper; Hydrogen; Methane; Rhenium; Silanes; Silicones; Stereoisomerism

2010