crinane and sulfoxide
crinane has been researched along with sulfoxide* in 1 studies
Other Studies
1 other study(ies) available for crinane and sulfoxide
| Article | Year |
|---|---|
Synthesis of crinane utilizing an allylic sulfoxide for the construction of a hydroindole ring via vinylogous C-N bond formation.
The synthesis of crinane is disclosed via intramolecular C-N bond formation by the displacement of an allylic sulfoxonium salt. The allylic sulfide precursor was synthesized by a ring-closing metathesis reaction. The quaternary carbon stereocenter was created by alkylation of a benzylic cyanide. The allyl sulfide 14 was prepared by adding vinylmagnesium bromide to an α-chlorosulfide. Topics: Alkenes; Amaryllidaceae Alkaloids; Carbon; Chemistry Techniques, Synthetic; Indoles; Nitrogen; Safrole | 2016 |