corrole and porphycene

corrole has been researched along with porphycene* in 2 studies

Other Studies

2 other study(ies) available for corrole and porphycene

ArticleYear
Reconstitution of Heme Enzymes with Artificial Metalloporphyrinoids.
    Methods in enzymology, 2016, Volume: 580

    An important strategy used in engineering of hemoproteins to generate artificial enzymes involves replacement of heme with an artificial cofactor after removal of the native heme cofactor under acidic conditions. Replacement of heme in an enzyme with a nonnatural metalloporphyrinoid can significantly alter the reactivity of the enzyme. This chapter describes the design and synthesis of three types of artificial metalloporphyrinoid cofactors consisting of mono-, di-, and tri-anionic ligands (tetradehydrocorrin, porphycene, and corrole, respectively). In addition, practical procedures for the preparation of apo-hemoproteins, incorporation of artificial cofactors, and characterization techniques are presented. Furthermore, the representative catalytic activities of artificial enzymes generated by reconstitution of hemoproteins are summarized.

    Topics: Corrinoids; Heme; Hemeproteins; Kinetics; Metalloporphyrins; Porphyrins; Protein Engineering

2016
Hemiporphycene from the expansion of a corrole ring.
    Angewandte Chemie (International ed. in English), 2005, May-13, Volume: 44, Issue:20

    Topics: Crystallography, X-Ray; Models, Molecular; Molecular Structure; Porphyrins

2005