corrole and hydroxide-ion

corrole has been researched along with hydroxide-ion* in 1 studies

Other Studies

1 other study(ies) available for corrole and hydroxide-ion

Article	Year
Nucleophilic attack of hydroxide on a Mn(V) oxo complex: a model of the O-O bond formation in the oxygen evolving complex of photosystem II. Journal of the American Chemical Society, 2009, Jul-01, Volume: 131, Issue:25 A manganese(III) corrole complex, 1, has been synthesized and used to study a potential mechanism for oxidation of water to molecular oxygen. Oxidation by t-BuOOH gave the Mn(V)=O complex 2. Addition of hydroxide led to release of oxygen via the Mn(IV) complex 4 and regeneration of complex 1. It could be shown that the oxygen from (18)O-labeled water was incorporated in both the formed molecular oxygen and the peroxy intermediate 4. Topics: Hydroxides; Manganese; Models, Biological; Oxidation-Reduction; Oxygen; Photosystem II Protein Complex; Porphyrins; tert-Butylhydroperoxide; Water	2009

Article

Year

Nucleophilic attack of hydroxide on a Mn(V) oxo complex: a model of the O-O bond formation in the oxygen evolving complex of photosystem II.

Journal of the American Chemical Society, 2009, Jul-01, Volume: 131, Issue:25

A manganese(III) corrole complex, 1, has been synthesized and used to study a potential mechanism for oxidation of water to molecular oxygen. Oxidation by t-BuOOH gave the Mn(V)=O complex 2. Addition of hydroxide led to release of oxygen via the Mn(IV) complex 4 and regeneration of complex 1. It could be shown that the oxygen from (18)O-labeled water was incorporated in both the formed molecular oxygen and the peroxy intermediate 4.

Topics: Hydroxides; Manganese; Models, Biological; Oxidation-Reduction; Oxygen; Photosystem II Protein Complex; Porphyrins; tert-Butylhydroperoxide; Water

2009