colitose and tris(trimethylsilyl)silane

colitose has been researched along with tris(trimethylsilyl)silane* in 1 studies

Other Studies

1 other study(ies) available for colitose and tris(trimethylsilyl)silane

Article	Year
Gram-scale synthesis of an armed colitose thioglycoside. The Journal of organic chemistry, 2014, Oct-17, Volume: 79, Issue:20 A concise gram-scale synthesis of protected colitose thioglycosides for use in bacterial carbohydrate antigen synthesis is described. The synthesis proceeds in six steps and 59-70% overall yield from commercially available l-fucose, making it the most efficient route reported to date. Key steps include regioselective installation of a thiocarbonate using catalytic dioctyltin dichloride (10 mol%) and a tris(trimethylsilyl)silane-mediated radical deoxygenation. Topics: Deoxy Sugars; Fucose; Magnetic Resonance Spectroscopy; Molecular Structure; Silanes; Thioglycosides	2014

Article

Year

Gram-scale synthesis of an armed colitose thioglycoside.

The Journal of organic chemistry, 2014, Oct-17, Volume: 79, Issue:20

A concise gram-scale synthesis of protected colitose thioglycosides for use in bacterial carbohydrate antigen synthesis is described. The synthesis proceeds in six steps and 59-70% overall yield from commercially available l-fucose, making it the most efficient route reported to date. Key steps include regioselective installation of a thiocarbonate using catalytic dioctyltin dichloride (10 mol%) and a tris(trimethylsilyl)silane-mediated radical deoxygenation.

Topics: Deoxy Sugars; Fucose; Magnetic Resonance Spectroscopy; Molecular Structure; Silanes; Thioglycosides

2014