clay and ferric-chloride

Topics: Adsorption; Cadmium; Clay; Hydrogen-Ion Concentration; Iron; Kinetics; Water Pollutants, Chemical

A series of ferric chloride-lignin sulfonate (FCLS) was prepared from ferric chloride and lignin sulfonate to be used as shale inhibitor. The swelling rate of clay with FCLS-2 (

Topics: Bentonite; Chlorides; Clay; Ferric Compounds; Lignin; Microscopy, Electron, Scanning; Minerals; Natural Gas; Oil and Gas Industry; Particle Size; Petroleum; Sulfonic Acids; Thermogravimetry; Viscosity

A huge amount of various oily suspensions that frequently display properties of stable emulsions are produced per day in upstream and downstream petroleum industries. As this waste is considered potentially harmful to the environment, their management and disposal require particular attention. While current treatment processes, such as partial water removal via the separation of phases by centrifuging result in decreased waste volumes for disposal, a significant volume of water and oil remains trapped in the form of water-in-oil emulsion. Therefore, the electrokinetic method for oil-water separation came into consideration for the improvement of the quality and volume of separated products. This paper discusses the impacts of additives, namely, ferric chloride, alum, cationic polymer, clay, and a mixture of clay and cationic polymer on the electrokinetic treatment of suspensions. The tests were conducted at a lab scale using an array of steel electrodes and low voltage. The objective of this study was to observe the impact of voltage gradients on electro-demulsification, in conjunction with employing additives into the separation and recovery of water, light, and heavy oil. An optimal recovery of light oil by 28%-52% in addition to heavy oil and water in the presence of ferric chloride under a constant voltage gradient of 1 V/cm, was achieved. Furthermore, the same system revealed an excellent clarity of extracted water. The results from this study can be implemented at a larger scale in upstream and downstream petroleum industries.

Topics: Alum Compounds; Chlorides; Clay; Emulsions; Ferric Compounds; Oils; Sewage; Suspensions; Water

The use of some novel and efficient crop nutrient-based superabsorbent hydrogel nanocomposites (SHNCs), is currently becoming increasingly important to improve the crop yield and productivity, due to their water retention properties. In the present study a poly(Acrylamide-co-acrylic acid)/AlZnFe2O4 superabsorbent hydrogel nanocomposite was synthesized and its physical properties characterized using Energy Dispersive X-ray (EDX), FE-SEM and FTIR spectroscopic techniques. The effects of different levels of SHNC were studied to evaluate the moisture retention properties of sandy loam soil (sand 59%, silt 21%, clay 19%, pH 7.4, EC 1.92 dS/m). The soil amendment with 0.1, 0.2, 0.3 and 0.4 w/w% of SHNC enhanced the moisture retention significantly at field capacity compared to the untreated soil. Besides, in a separate experiment, seed germination and seedling growth of wheat was found to be notably improved with the application of SHNC. A delay in wilting of seedlings by 5-8 days was observed for SHNC-amended soil, thereby improving wheat plant growth and establishment.

Topics: Absorption; Acrylamides; Agriculture; Alum Compounds; Aluminum Silicates; Chlorides; Clay; Electric Conductivity; Ferric Compounds; Germination; Hydrogels; Hydrogen-Ion Concentration; Metal Nanoparticles; Nanocomposites; Porosity; Seedlings; Silicon Dioxide; Sodium Hydroxide; Soil; Spectrometry, X-Ray Emission; Spectroscopy, Fourier Transform Infrared; Triticum; Water; Wettability; Zinc Sulfate

We demonstrated that water-soluble aminopropyl magnesium functionalized phyllosilicate could be used as a soil-flushing agent for heavy metal contaminated soils. Soil flushing has been an attractive means to remediate heavy metal contamination because it is less disruptive to the soil environment after the treatment was performed. However, development of efficient and non-toxic soil-flushing agents is still required. We have synthesized aminoclays with three different central metal ions such as magnesium, aluminum, and ferric ions and investigated applicability of aminoclays as soil flushing agents. Among them, magnesium (Mg)-centered aminoclay showed the smallest size distribution and superior water solubility, up to 100mg/mL. Mg aminoclay exhibited cadmium and lead binding capacity of 26.50 and 91.31 mg/g of Mg clay, respectively, at near neutral pH, but it showed negligible binding affinity to metals in acidic conditions. For soil flushing with Mg clay at neutral pH showed cadmium and lead were efficiently extracted from soils by Mg clay, suggesting strong binding ability of Mg clay with cadmium and lead. As the organic matter and clay compositions increased in the soil, the removal efficiency by Mg clay decreased and the operation time increased.

Topics: Aluminum Silicates; Chlorides; Clay; Environmental Restoration and Remediation; Ferric Compounds; Hydrophobic and Hydrophilic Interactions; Magnesium Chloride; Metals, Heavy; Microscopy, Electron, Transmission; Porosity; Powder Diffraction; Propylamines; Silanes; Soil; Soil Pollutants; Solubility; Surface Properties; Water; X-Ray Diffraction