clay and benzobicyclon

Benzobicyclon is a systemic herbicide that was officially registered in China in 2018. The environmental behaviors of benzobicyclon hydrolysate (BH), the main metabolite and active product of benzobicyclon, remain poorly understood in paddy fields. Here, agricultural soil samples were collected from paddy fields in Jiangxi (Ferralsols), Shandong (Alisols), Hebei (Luvisols), Heilongjiang (Phaeozems), Zhejiang (Anthrosols), Sichuan (Gleysols), Hainan (Plinthosols), and Hubei (Lixisols) across China. The equilibrium oscillation method was used to study the adsorption-desorption behaviors of BH in the eight soils. The relationships between BH adsorption and soil physicochemical properties, environmental factors (temperature and initial solution pH), and other external conditions (addition of humic acid, biochar, and metal ions) were quantified. The adsorption-desorption parameters of BH in all soils were well fitted by the Freundlich model. The adsorption constant of BH varied between 0.066 and 4.728. The BH adsorption capacity decreased in the following order: Phaeozems > Alisols > Ferralsols > Lixisols > Plinthosols > Anthrosols > Luvisols > Gleysols. The Freundlich adsorption and desorption constants of BH were linearly positively correlated with soil clay content (R

Topics: Adsorption; Agriculture; Bridged Bicyclo Compounds; China; Clay; Groundwater; Herbicides; Soil; Soil Pollutants; Sulfones