clavosolide-a has been researched along with quinone* in 1 studies
1 other study(ies) available for clavosolide-a and quinone
| Article | Year |
|---|---|
Cyclopropane compatibility with oxidative carbocation formation: total synthesis of clavosolide A.
Cyclopropane-substituted allylic ethers react with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone to form oxocarbenium ions with no competitive ring cleavage. This reaction can be used for the preparation of cyclopropane-substituted tetrahydropyrans. The protocol was used as a key step in the total synthesis of the sponge-derived macrolide clavosolide A. Topics: Animals; Benzoquinones; Cyclopropanes; Macrolides; Molecular Structure; Porifera | 2012 |