chromomycin-a3 and galactal

chromomycin-a3 has been researched along with galactal* in 1 studies

Other Studies

1 other study(ies) available for chromomycin-a3 and galactal

Article	Year
Totally stereoselective synthesis of 1,3-disaccharides through Diels-Alder reactions. The Journal of organic chemistry, 2003, Oct-31, Volume: 68, Issue:22 A nonclassical, totally stereoselective synthesis of orthogonally protected 1,3-disaccharides is reported. Enantiomerically pure beta-keto-delta-lactones, efficiently obtained from glucal and galactal, are transformed into electron-poor heterodienes and chemo-, regio-, and stereoselectively cycloadded to glycals as electron-rich dienophiles, to directly afford 2-thiodisaccharides. The reductive desulfurization of the latter smoothly gave the corresponding 2,2'-dideoxydisaccharides. Topics: Calcium Gluconate; Carbohydrate Sequence; Chromomycin A3; Cyclization; Disaccharides; Galactose; Ketones; Lactones; Molecular Sequence Data; Pyrans; Quinones; Stereoisomerism; Sulfhydryl Compounds	2003

Article

Year

Totally stereoselective synthesis of 1,3-disaccharides through Diels-Alder reactions.

The Journal of organic chemistry, 2003, Oct-31, Volume: 68, Issue:22

A nonclassical, totally stereoselective synthesis of orthogonally protected 1,3-disaccharides is reported. Enantiomerically pure beta-keto-delta-lactones, efficiently obtained from glucal and galactal, are transformed into electron-poor heterodienes and chemo-, regio-, and stereoselectively cycloadded to glycals as electron-rich dienophiles, to directly afford 2-thiodisaccharides. The reductive desulfurization of the latter smoothly gave the corresponding 2,2'-dideoxydisaccharides.

Topics: Calcium Gluconate; Carbohydrate Sequence; Chromomycin A3; Cyclization; Disaccharides; Galactose; Ketones; Lactones; Molecular Sequence Data; Pyrans; Quinones; Stereoisomerism; Sulfhydryl Compounds

2003