cholesterol-acetate has been researched along with picolinic-acid* in 1 studies
1 other study(ies) available for cholesterol-acetate and picolinic-acid
| Article | Year |
|---|---|
A new electrochemical system for stereoselective allylic hydroxylation of cholesteryl acetate with dioxygen induced by iron picolinate complexes.
The oxygenation reaction of cholesteryl acetate 1 was examined with the Fe(III)(PA)(3)/O(2)/MeCN system using an electrochemical method. The constant potential technique gave mainly the 7-hydroxylated product stereoselectively, along with the 7-oxo product. This oxygenation system is mechanistically unique, requiring iron catalyst, dioxygen, and both cathode and anode. Topics: Allyl Compounds; Cholesterol Esters; Electrochemistry; Hydroxylation; Iron; Oxygen; Picolinic Acids; Stereoisomerism | 2004 |