cholecalciferol has been researched along with allyl-chloride* in 1 studies
1 other study(ies) available for cholecalciferol and allyl-chloride
Article | Year |
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Fluoride-mediated elimination of allyl sulfones: application to the synthesis of a 2,4-dimethyl-A-ring vitamin D3 analogue.
A coupling strategy for the synthesis of 2,4-dimethyl-1α,25(OH)(2)D(3) is achieved which involves methylation of a pro-A ring vinyl sulfone and in situ traping of the allyl sulfonyl anion with a CD ring allyl chloride. TBAF-promoted 1,2-eliminative desulfonylation and concomitant silyl ether deprotection gives the vitamin D(3) analogue. Topics: Allyl Compounds; Calcitriol; Cholecalciferol; Fluorides; Molecular Structure; Stereoisomerism; Sulfones; Vinyl Compounds | 2012 |