cholecalciferol and allyl-chloride

cholecalciferol has been researched along with allyl-chloride* in 1 studies

Other Studies

1 other study(ies) available for cholecalciferol and allyl-chloride

ArticleYear
Fluoride-mediated elimination of allyl sulfones: application to the synthesis of a 2,4-dimethyl-A-ring vitamin D3 analogue.
    The Journal of organic chemistry, 2012, Jun-01, Volume: 77, Issue:11

    A coupling strategy for the synthesis of 2,4-dimethyl-1α,25(OH)(2)D(3) is achieved which involves methylation of a pro-A ring vinyl sulfone and in situ traping of the allyl sulfonyl anion with a CD ring allyl chloride. TBAF-promoted 1,2-eliminative desulfonylation and concomitant silyl ether deprotection gives the vitamin D(3) analogue.

    Topics: Allyl Compounds; Calcitriol; Cholecalciferol; Fluorides; Molecular Structure; Stereoisomerism; Sulfones; Vinyl Compounds

2012