cholecalciferol and allyl-alcohol

cholecalciferol has been researched along with allyl-alcohol* in 1 studies

Other Studies

1 other study(ies) available for cholecalciferol and allyl-alcohol

Article	Year
Asymmetric Synthesis of Vitamin D3 Analogues: Organocatalytic Desymmetrization Approach toward the A-Ring Precursor of Calcifediol. Organic letters, 2015, Nov-06, Volume: 17, Issue:21 A novel asymmetric synthesis has been developed for the construction of the A-ring of a chiral precursor to calcifediol. The highlights of this synthesis include (i) the introduction of the stereochemistry at the C5-position of the A-ring through the organocatalytic enantioselective desymmetrization of a prochiral cyclic anhydride using a bifunctional urea catalyst and (ii) the introduction of the exo-cyclic (Z)-dienol side chain by a tandem Claisen rearrangement/sulfoxide thermolysis of an allylic alcohol. Topics: Anhydrides; Calcifediol; Catalysis; Cholecalciferol; Molecular Structure; Propanols; Stereoisomerism; Urea	2015

Article

Year

Asymmetric Synthesis of Vitamin D3 Analogues: Organocatalytic Desymmetrization Approach toward the A-Ring Precursor of Calcifediol.

Organic letters, 2015, Nov-06, Volume: 17, Issue:21

A novel asymmetric synthesis has been developed for the construction of the A-ring of a chiral precursor to calcifediol. The highlights of this synthesis include (i) the introduction of the stereochemistry at the C5-position of the A-ring through the organocatalytic enantioselective desymmetrization of a prochiral cyclic anhydride using a bifunctional urea catalyst and (ii) the introduction of the exo-cyclic (Z)-dienol side chain by a tandem Claisen rearrangement/sulfoxide thermolysis of an allylic alcohol.

Topics: Anhydrides; Calcifediol; Catalysis; Cholecalciferol; Molecular Structure; Propanols; Stereoisomerism; Urea

2015