chlorophyll-d and thiophenol

chlorophyll-d has been researched along with thiophenol* in 2 studies

Other Studies

2 other study(ies) available for chlorophyll-d and thiophenol

Article	Year
Non-enzymatic conversion of chlorophyll-a into chlorophyll-d in vitro: a model oxidation pathway for chlorophyll-d biosynthesis. FEBS letters, 2012, Jul-30, Volume: 586, Issue:16 Chlorophyll-a (Chl-a) was readily converted into Chl-d under mild conditions without any enzymes. Treatment of Chl-a dissolved in dry tetrahydrofuran (THF) with thiophenol and acetic acid at room temperature successfully produced Chl-d in 31% yield. During the acidic oxidation, removal of the central magnesium, pheophytinization, was sufficiently suppressed. This mild pathway can give insights into the yet unidentified Chl-d biosynthesis. Topics: Absorption; Acetic Acid; Chlorophyll; Chlorophyll A; Chromatography, High Pressure Liquid; Free Radicals; Furans; In Vitro Techniques; Magnesium; Models, Chemical; Oxidation-Reduction; Oxygen; Phenols; Spinacia oleracea; Sulfhydryl Compounds; Time Factors	2012
A mild conversion from 3-vinyl- to 3-formyl-chlorophyll derivatives. Bioorganic & medicinal chemistry letters, 2011, Apr-15, Volume: 21, Issue:8 The C3-vinyl group of a chlorophyll derivative, methyl pyropheophorbide-a, was converted into the formyl group by a novel one-pot reaction with thiophenol at room temperature. The mild reaction can provide insight into development of 'green' catalysts displacing OsO(4) or O(3), and into elucidation of unknown biosynthetic processes of chlorophyll-d. Topics: Catalysis; Chlorophyll; Chlorophyll A; Osmium Tetroxide; Oxidation-Reduction; Phenols; Sulfhydryl Compounds	2011

Article

Year

Non-enzymatic conversion of chlorophyll-a into chlorophyll-d in vitro: a model oxidation pathway for chlorophyll-d biosynthesis.

FEBS letters, 2012, Jul-30, Volume: 586, Issue:16

Chlorophyll-a (Chl-a) was readily converted into Chl-d under mild conditions without any enzymes. Treatment of Chl-a dissolved in dry tetrahydrofuran (THF) with thiophenol and acetic acid at room temperature successfully produced Chl-d in 31% yield. During the acidic oxidation, removal of the central magnesium, pheophytinization, was sufficiently suppressed. This mild pathway can give insights into the yet unidentified Chl-d biosynthesis.

Topics: Absorption; Acetic Acid; Chlorophyll; Chlorophyll A; Chromatography, High Pressure Liquid; Free Radicals; Furans; In Vitro Techniques; Magnesium; Models, Chemical; Oxidation-Reduction; Oxygen; Phenols; Spinacia oleracea; Sulfhydryl Compounds; Time Factors

2012

A mild conversion from 3-vinyl- to 3-formyl-chlorophyll derivatives.

Bioorganic & medicinal chemistry letters, 2011, Apr-15, Volume: 21, Issue:8

The C3-vinyl group of a chlorophyll derivative, methyl pyropheophorbide-a, was converted into the formyl group by a novel one-pot reaction with thiophenol at room temperature. The mild reaction can provide insight into development of 'green' catalysts displacing OsO(4) or O(3), and into elucidation of unknown biosynthetic processes of chlorophyll-d.

Topics: Catalysis; Chlorophyll; Chlorophyll A; Osmium Tetroxide; Oxidation-Reduction; Phenols; Sulfhydryl Compounds

2011