chaetominine and selectfluor

chaetominine has been researched along with selectfluor* in 1 studies

Other Studies

1 other study(ies) available for chaetominine and selectfluor

ArticleYear
Double annulative cascade of tryptophan-containing peptides triggered by selectfluor.
    Organic letters, 2014, Jan-03, Volume: 16, Issue:1

    A common dearomative strategy toward the kapakahines B/F and chaetominine natural products is reported. The proposed biomimetic strategy generates the tetracyclic α-carboline core in a single step, featuring a selectfluor-mediated dearomatization of preactivated N-Phth-Trp-Xaa-OR dipeptides at the C-terminus. The pivotal cascade includes a double annulation and the formation of three carbon-heteroatom bonds while gaining, for the first time, some insight on the diastereoselectivity outcome during the formation of the α-carboline fragment.

    Topics: Biological Products; Diazonium Compounds; Indole Alkaloids; Molecular Conformation; Oligopeptides; Peptides, Cyclic; Stereoisomerism; Tryptophan

2014