cavicularin has been researched along with divinyl-sulfone* in 2 studies
2 other study(ies) available for cavicularin and divinyl-sulfone
| Article | Year |
|---|---|
Enantioselective and regioselective pyrone Diels-Alder reactions of vinyl sulfones: total synthesis of (+)-cavicularin.
The total synthesis of (+)-cavicularin is described. The synthesis features an enantio- and regioselective pyrone Diels-Alder reaction of a vinyl sulfone to construct the cyclophane architecture of the natural product. The Diels-Alder substrate was prepared by a regioselective one-pot three-component Suzuki reaction of a non-symmetric dibromoarene. Topics: Catalysis; Cycloaddition Reaction; Ethers, Cyclic; Pyrones; Stereoisomerism; Sulfones | 2014 |
Total synthesis of (±)-cavicularin: control of pyrone Diels-Alder regiochemistry using isomeric vinyl sulfones.
An intramolecular pyrone Diels-Alder reaction-elimination retro-Diels-Alder cascade of a vinyl sulfone was used in the synthesis of cavicularin, a molecule possessing conformational chirality. The vinyl sulfone substitution pattern allowed for regiocontrol in the Diels-Alder cascade event. Topics: Ethers, Cyclic; Molecular Structure; Pyrones; Stereoisomerism; Sulfones | 2013 |