caryophyllene has been researched along with 1-4-cyclohexadiene* in 1 studies
1 other study(ies) available for caryophyllene and 1-4-cyclohexadiene
| Article | Year |
|---|---|
Selective molecular sequestration with concurrent natural product functionalization and derivatization: from crude natural product extracts to a single natural product derivative in one step.
A resin-bound nitroso compound sequestered a single unexpected component from crude plant seed extracts. Several plants, including Piper nigrum, Eugenia caryophyllata, and Pimenta dioica, were extracted with organic solvent in the presence of a nitroso-containing resin. The nitroso resin selectively sequestered a single compound, β-caryophyllene, via a chemo- and regioselective ene reaction. The ene product was released from the resin, and proper selection of the solid-phase linker and cleavage cocktail allowed concomitant further transformation of the primary ene product to a novel functionalized polycycle. Preliminary studies indicate that the new hydroxylamine-containing natural product derivatives have antibiotic activity. Topics: Acrylic Resins; Anti-Inflammatory Agents, Non-Steroidal; Chromatography, High Pressure Liquid; Complex Mixtures; Cyclohexenes; Hydroxylamines; Magnetic Resonance Spectroscopy; Molecular Structure; Nitroso Compounds; Pimenta; Piper nigrum; Plant Extracts; Polycyclic Sesquiterpenes; Seeds; Sesquiterpenes; Syzygium | 2011 |