Page last updated: 2024-09-03

carbene and rhodium

carbene has been researched along with rhodium in 132 studies

Compound Research Comparison

Studies
(carbene)
Trials
(carbene)
Recent Studies (post-2010)
(carbene)
Studies
(rhodium)
Trials
(rhodium)
Recent Studies (post-2010) (rhodium)
2,06701,2653,25511,727

Research

Studies (132)

TimeframeStudies, this research(%)All Research%
pre-19900 (0.00)18.7374
1990's1 (0.76)18.2507
2000's25 (18.94)29.6817
2010's88 (66.67)24.3611
2020's18 (13.64)2.80

Authors

AuthorsStudies
Cetinkaya, B; Cetinkaya, E; Durmaz, R; Küçükbay, H1
Davies, JR; Kane, PD; Moody, CJ; Slawin, AM1
Bertrand, G; Canac, Y; DeHope, A; Donnadieu, B; Lavallo, V1
Choi, SY; Chung, YK; Jung, IG; Lee, BY; Lee, SI; Park, JH; Park, SY1
Fröhlich, R; Hahn, FE; Le Van, D; Paas, M1
Wang, J; Xiao, F1
Ahmed, M; Beller, M; Buch, C; Jackstell, R; Klein, H; Routaboul, L; Spannenberg, A1
Linder, J; Moody, CJ1
Hengge, AC; Wang, J; Wong, FM; Wu, W1
Davies, HM; Hedley, SJ1
Afonso, CA; André, V; Caddick, S; Cloke, FG; Duarte, MT; Gois, PM; Trindade, AF; Veiros, LF1
Miyamoto, K; Ochiai, M; Okada, T; Sota, A; Tada, N1
Allen, DP; Crudden, CM; Grein, F; Kennepohl, P; Praetorius, JM; Wang, R; Webb, JD1
Crudden, CM; Praetorius, JM1
Guzei, IA; Scarborough, CC; Stahl, SS1
Antos, JM; Francis, MB; Iavarone, AT; McFarland, JM1
Li, X; Song, G; Song, Z; Zhang, H; Zhao, J1
Blake, AJ; Campbell, IB; Judkins, BD; Moody, CJ; Shi, B1
Doyle, MP; Duffy, R; Ratnikov, M; Zhou, L1
de Bruin, B; Jellema, E; Reek, JN; Rubio, M; Siegler, MA; Spek, AL1
Padwa, A1
Blake, AJ; Campbell, IB; Judkins, BD; Lewis, W; Moody, CJ; Shi, B1
Fan, B; Liu, B; Liu, Y; Shi, W; Wang, J; Xiao, F; Xu, F; Zhang, B; Zhang, J; Zhang, Z1
Albrecht, M; Krüger, A; Neels, A1
Berthon-Gelloz, G; Markó, IE; Reek, JN; Siegler, MA; Spek, AL; Tinant, B1
Fokin, VV; Grimster, N; Zhang, L1
da Costa, AP; Peris, E; Royo, B; Sanaú, M1
Nechaev, MS; Normand, AT; Tukov, AA1
Messerle, BA; Page, MJ; Wagler, J1
Beetstra, DJ; Binobaid, A; Cavell, KJ; Dervisi, A; Fallis, IA; Iglesias, M; Kariuki, B1
Douthwaite, RE; Dyson, G; Frison, JC; Whitwood, AC1
Cowie, M; Ferguson, MJ; McDonald, R; Zamora, MT1
Bhadbhade, M; Colbran, SB; McSkimming, A1
Boultadakis-Arapinis, M; Lecourt, T; Lemoine, P; Micouin, L; Turcaud, S1
Wee, AG; Zhang, B1
Garner, TP; Linder, J; Moody, CJ; Searle, MS; Williams, HE1
Davies, HM; Morton, D1
Chuprakov, S; Fokin, VV; Malik, JA; Zibinsky, M1
Fokin, VV; Zibinsky, M1
Shen, JJ; Xie, XL; Xu, B; Zhou, QL; Zhu, SF1
Berry, JF1
Burgin, RN; Doyle, MP; Helper, M; Jaber, DM; Zavalij, PY1
Ge, R; Liu, Z; Qu, P; Wang, J; Xia, Y; Xiao, Q; Zhang, Y1
Castarlenas, R; Crucianelli, M; Di Giuseppe, A; Lahoz, FJ; Oro, LA; Pérez-Torrente, JJ; Polo, V; Sancho, R1
Abrahams, QM; Doyle, MP; Wang, X; Zavalij, PY1
Doyle, MP; Hu, W; Qian, Y; Wang, X; Xu, X; Zavalij, PJ1
Davies, HM; Dick, AR; Ghosh, D; Morton, D1
DeAngelis, A; Dmitrenko, O; Fox, JM1
Alberico, E; Albrecht, M; Gladiali, S; Monney, A; Müller-Bunz, H; Ortin, Y1
Schienebeck, CM; Shu, D; Shu, XZ; Tang, W1
Chuprakov, S; Fokin, VV; Selander, N; Velaparthi, S; Worrell, BT1
Doyle, MP; Xu, X; Zavalij, PY2
Chang, S; Jung, Y; Kwak, J; Ohk, Y1
Albrecht, M; Monney, A1
Dai, L; Park, CM; Qi, X1
Fokin, VV; Selander, N; Worrell, BT1
Gevorgyan, V; Gulevich, AV1
de Bruin, B; Franssen, NM; Reek, JN1
Boultadakis-Arapinis, M; Gandon, V; Lecourt, T; Lemoine, P; Micouin, L; Prost, E; Turcaud, S1
Azpíroz, R; Castarlenas, R; Di Giuseppe, A; Oro, LA; Pérez-Torrente, JJ1
Albrecht, M; Monney, A; Nastri, F1
Chuprakov, S; Fokin, VV; Kwok, SW1
Doyle, MP; Hu, W; Qian, Y; Zavalij, PJ1
Davies, HM; Green, SA; Parr, BT1
Braunschweig, H; Radacki, K; Ye, Q1
Guzei, IA; Liu, R; Song, W; Tang, W; Winston-McPherson, GN; Xu, X; Yang, ZY; Zhou, X1
Andersson, PG; Li, JQ1
Gevorgyan, V; Shi, Y1
Küster, LN; Muñoz-Castro, A; Oehninger, L; Ott, I; Prokop, A; Schmidt, C1
Brunelli, NA; Chepiga, KM; Davies, HM; Feng, Y; Jones, CW1
Chuprakov, S; Fokin, VV; Selander, N; Sit, RK; Worrell, BT1
Funakoshi, Y; Miura, T; Murakami, M1
Gilbertson, SR; Zhao, Y1
Lu, P; Sheng, G; Wang, J; Wang, Y; Xing, Y1
Feng, J; Shang, H; Tang, Y; Tian, Y; Wang, Y1
Goldfogel, MJ; Meek, SJ; Roberts, CC1
Castarlenas, R; Di Giuseppe, A; Lahoz, FJ; Oro, LA; Pérez-Torrente, JJ1
Crudden, CM; Keske, EC; Moore, BD; Schatte, G; Wang, R; Zenkina, OV1
Davies, HM; Parr, BT1
Doyle, MP; Hu, WH; Xu, X; Zavalij, PY1
Chen, W; Ma, X; Pan, S; Wang, H1
Hu, W; Jia, S; Xing, D; Zhang, D1
Ganesh, V; Kumagai, N; Shibasaki, M; Sureshkumar, D1
Hu, W; Jiang, J; Liu, S; Lv, S; Ma, X; Xia, F; Yang, Y; Yao, W1
He, L; Shi, M; Tang, XY; Wei, Y; Zhang, YS1
Jia, ZH; Shen, MH; Xu, HD; Xu, K; Zhou, H1
Fernández-Alvarez, FJ; García-Orduña, P; Iglesias, M; Lahoz, FJ; Lázaro, G; Oro, LA; Pérez-Torrente, JJ; Polo, V1
Jiang, Y; Shi, M; Tang, XY1
Galkina, OS; Giera, DS; Hennig, L; Klinkova, AA; Medvedev, JJ; Nikolaev, VA; Schneider, C1
Lei, X; Tang, Y; Wang, Y1
Chen, D; Qi, WY; Xu, B; Xu, MH; Zhang, X1
Basauri-Molina, M; Kleijn, H; Klein Gebbink, RJ; Riemersma, CF; Würdemann, MA1
Jia, ZH; Pan, YP; Ren, XT; Shen, MH; Xu, HD; Zhang, P1
Hayes, CJ; Lewis, W; Moody, CJ; Nicolle, SM1
Cong, X; Rao, B; Wei, Y; Zeng, X1
Fox, JM; Panish, R; Selvaraj, R1
Hu, W; Jing, C; Xing, D1
Lang, B; Lu, P; Ren, A; Wang, C; Wang, Y; Zhang, H1
Moody, CJ; Wada, H; Williams, HE1
Guzei, IA; Li, H; Li, X; Liu, L; Song, W; Tang, W; Tseng, PS1
Joseph, D; Kanchupalli, V; Katukojvala, S1
DeAngelis, A; Fox, JM; Panish, R1
Poater, A1
Abu El Maaty, MA; Karge, B; Muenzner, JK; Ott, I; Schobert, R; Wölfl, S; Zhang, JJ1
Cokoja, M; Drees, M; Herrmann, WA; Jantke, D; Kühn, FE; Pardatscher, L1
Dong, G; Liu, P; Lu, G; Xia, Y1
Frias, C; Jones, PG; Keppler, BK; Misgeld, R; Ott, I; Prokop, A; Streciwilk, W; Terenzi, A1
Bacsa, J; Boyarskikh, V; Davies, HML; Liao, K; Musaev, DG; Pickel, TC1
Davies, HML; Garlets, ZJ1
Besnard, C; Bosmani, A; Goudedranche, S; Guarnieri-Ibáñez, A; Lacour, J1
Cordova, J; Dimirjian, CA; Fettinger, JC; Hodur, BM; Nickerson, LA; Penrod, CN; Shaw, JT; Souza, LW; Squitieri, RA1
Harada, S; Hashimoto, Y; Kono, M; Nemoto, T1
Hammoud, J; Joosten, A; Lecourt, T1
Daubit, IM; Goldstone, DC; Hartinger, CG; John, M; Metzler-Nolte, N; Sullivan, MP1
Lee, YH; Park, CM; Yu, E1
Cullen, W; Jamagne, R; Tilly, DP; Vitórica-Yrezábal, I; Webb, SJ; Zhong, H1
Bacsa, J; Cammarota, RC; Davies, HML; Liu, W; Sigman, MS1
Ganesan, V; Kim, JJ; Park, K; Shin, J; Yoon, S1
Deng, C; Duan, S; Feng, Z; Li, CY; Wang, W; Xu, X; Xu, ZF; Yan, Z1
Dubrawski, ZS; Gelfand, BS; Harrison, A; Pezoulas, ER; Puerta Lombardi, BM; Roesler, R; Suvinen, RA; Tuononen, HM1
Chen, XX; Chung, LW; Wang, TY; Xu, MH; Zhu, DX1
Dong, Z; Ma, MY; Xu, J; Yang, Z1
Bakker, E; Besnard, C; de Aguirre, A; Di Bari, L; Fabri, B; Guarnieri-Ibáñez, A; Guénée, L; Lacour, J; Moneva Lorente, P; Moreau, D; Nikolova, Y; Pescitelli, G; Poblador-Bahamonde, AI; Soda, Y; Zinna, F1
Buchsteiner, M; Decaens, J; Fürstner, A; Singha, S1
Alford, JS; Davies, HML; Kubiak, RW; Tracy, WF1
Clément, S; Devillers, CH; Dumail, X; Gramage-Doria, R; Granier, M; Poyac, L; Richeter, S; Scoditti, S1
Boni, YT; Davies, HML; Vaitla, J1
Furuya, T; Harada, S; Ikeda, K; Nemoto, T1
Boni, YT; Cai, Q; Chen, Z; Davies, HML; Fu, J; Liu, W1
Laconsay, CJ; Tantillo, DJ1
Deng, L; Loman, T; Palmans, ARA; Sathyan, A1

Reviews

6 review(s) available for carbene and rhodium

ArticleYear
Intermolecular reactions of electron-rich heterocycles with copper and rhodium carbenoids.
    Chemical Society reviews, 2007, Volume: 36, Issue:7

    Topics: Copper; Heterocyclic Compounds; Hydrocarbons; Methane; Rhodium

2007
N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivity.
    Dalton transactions (Cambridge, England : 2003), 2008, Aug-21, Issue:31

    Topics: Catalysis; Heterocyclic Compounds; Methane; Organometallic Compounds; Rhodium

2008
Catalytic carbene insertion into C-H bonds.
    Chemical reviews, 2010, Feb-10, Volume: 110, Issue:2

    Topics: Azo Compounds; Carbon; Catalysis; Copper; Isomerism; Methane; Rhodium

2010
Domino reactions of rhodium(II) carbenoids for alkaloid synthesis.
    Chemical Society reviews, 2009, Volume: 38, Issue:11

    Topics: Alkaloids; Cyclization; Diazonium Compounds; Methane; Rhodium

2009
Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.
    Chemical Society reviews, 2011, Volume: 40, Issue:4

    Topics: Azo Compounds; Biological Products; Carbon; Catalysis; Hydrogen; Methane; Rhodium; Stereoisomerism

2011
Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush".
    Chemical Society reviews, 2012, Dec-07, Volume: 41, Issue:23

    Topics: Catalysis; Cycloaddition Reaction; Esters; Methane; Rhodium; Stereoisomerism

2012

Other Studies

126 other study(ies) available for carbene and rhodium

ArticleYear
Antimicrobial activity of carbene complexes of rhodium(I) and ruthenium(II).
    Arzneimittel-Forschung, 1996, Volume: 46, Issue:8

    Topics: Ampicillin; Anti-Bacterial Agents; Benzimidazoles; Enterococcus faecalis; Escherichia coli; Hydrocarbons; Methane; Microbial Sensitivity Tests; Penicillins; Pseudomonas aeruginosa; Rhodium; Ruthenium; Staphylococcus aureus

1996
Control of competing N-H insertion and Wolff rearrangement in dirhodium(II)-catalyzed reactions of 3-indolyl diazoketoesters. synthesis of a potential precursor to the marine 5-(3-indolyl)oxazole martefragin A.
    The Journal of organic chemistry, 2005, Jul-22, Volume: 70, Issue:15

    Topics: Alkaloids; Amides; Amines; Azo Compounds; Catalysis; Cations, Divalent; Esters; Hydrocarbons; Indoles; Methane; Models, Chemical; Oxazoles; Rhodium; Stereoisomerism

2005
A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes.
    Angewandte Chemie (International ed. in English), 2005, Nov-11, Volume: 44, Issue:44

    Topics: Hydrocarbons; Hydrocarbons, Cyclic; Ligands; Methane; Molecular Structure; Organometallic Compounds; Palladium; Rhodium; Transition Elements

2005
Rhodium N-heterocyclic carbene-catalyzed [4 + 2] and [5 + 2] cycloaddition reactions.
    The Journal of organic chemistry, 2006, Jan-06, Volume: 71, Issue:1

    Topics: Catalysis; Cyclization; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Rhodium

2006
Unsymmetrically N,N'-substituted saturated carbenes: synthesis, reactivity and preparation of a rhodium(I) carbene complex.
    Dalton transactions (Cambridge, England : 2003), 2006, Feb-14, Issue:6

    Topics: Amines; Dimerization; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Models, Molecular; Rhodium; Sulfur; X-Ray Diffraction

2006
1,2-migration in rhodium(II) carbene transfer reaction: remarkable steric effect on migratory aptitude.
    The Journal of organic chemistry, 2006, Jul-21, Volume: 71, Issue:15

    Topics: Azo Compounds; Catalysis; Chromatography, Thin Layer; Electronics; Hydrocarbons; Methane; Models, Molecular; Rhodium

2006
Hydroaminomethylation with novel rhodium-carbene complexes: an efficient catalytic approach to pharmaceuticals.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2007, Volume: 13, Issue:5

    Topics: Alkenes; Amines; Catalysis; Hydrocarbons; Imidazoles; Ligands; Methane; Methylation; Models, Chemical; Molecular Structure; Organometallic Compounds; Pharmaceutical Preparations; Piperidines; Propane; Rhodium; Styrenes

2007
The total synthesis of siphonazole, a structurally unusual bis-oxazole natural product.
    Chemical communications (Cambridge, England), 2007, Apr-21, Issue:15

    Topics: Biological Products; Hydrocarbons; Methane; Oxazoles; Rhodium

2007
Mechanism of rhodium-catalyzed carbene formation from diazo compounds.
    Organic letters, 2007, Apr-26, Volume: 9, Issue:9

    Topics: Azo Compounds; Catalysis; Hydrocarbons; Methane; Molecular Structure; Rhodium

2007
Tuning the reactivity of dirhodium(II) complexes with axial N-heterocyclic carbene ligands: the arylation of aldehydes.
    Angewandte Chemie (International ed. in English), 2007, Volume: 46, Issue:30

    Topics: Aldehydes; Heterocyclic Compounds; Hydrocarbons; Ligands; Methane; Models, Molecular; Molecular Structure; Rhodium

2007
Thermal and catalytic transylidations between halonium ylides and synthesis and reaction of stable aliphatic chloronium ylides.
    Journal of the American Chemical Society, 2008, Feb-20, Volume: 130, Issue:7

    Topics: Alkenes; Catalysis; Cyclooctanes; Cyclopropanes; Halogens; Hot Temperature; Hydrocarbons; Hydrocarbons, Halogenated; Methane; Rhodium

2008
N-heterocyclic carbene complexes of Rh: reaction with dioxygen without oxidation.
    Journal of the American Chemical Society, 2008, Mar-26, Volume: 130, Issue:12

    Topics: Heterocyclic Compounds; Methane; Models, Chemical; Models, Molecular; Molecular Structure; Organometallic Compounds; Oxygen; Rhodium; Spectrometry, X-Ray Emission

2008
Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene.
    Dalton transactions (Cambridge, England : 2003), 2009, Apr-07, Issue:13

    Topics: Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism

2009
Chemoselective tryptophan labeling with rhodium carbenoids at mild pH.
    Journal of the American Chemical Society, 2009, May-06, Volume: 131, Issue:17

    Topics: Hydrogen-Ion Concentration; Methane; Models, Molecular; Organometallic Compounds; Rhodium; Solutions; Solvents; Tryptophan; Water

2009
Methyleneimidazoline complexes of iridium, rhodium, and palladium from selective C(sp3)-H bond activation.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2009, Volume: 15, Issue:22

    Topics: Crystallography, X-Ray; Imidazoles; Iridium; Methane; Molecular Conformation; Molecular Structure; Organometallic Compounds; Palladium; Rhodium; Thermodynamics

2009
The rhodium carbene route to oxazoles: a remarkable catalyst effect.
    Chemical communications (Cambridge, England), 2009, Jun-14, Issue:22

    Topics: Amides; Catalysis; Crystallography, X-Ray; Esters; Methane; Oxazoles; Rhodium

2009
Supramolecular NHC ligands: on the influence of Zn(II)-templates on the activity of Rh(I)(cod) complexes in 'carbene polymerization'.
    Dalton transactions (Cambridge, England : 2003), 2009, Nov-07, Issue:41

    Topics: Catalysis; Cations, Divalent; Heterocyclic Compounds; Ligands; Methane; Models, Chemical; Molecular Weight; Organometallic Compounds; Polymers; Rhodium; Zinc

2009
Rhodium carbene routes to oxazoles and thiazoles. Catalyst effects in the synthesis of oxazole and thiazole carboxylates, phosphonates, and sulfones.
    The Journal of organic chemistry, 2010, Jan-01, Volume: 75, Issue:1

    Topics: Carboxylic Acids; Catalysis; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Organophosphonates; Oxazoles; Rhodium; Stereoisomerism; Structure-Activity Relationship; Sulfones; Thiazoles

2010
Rh(II)-catalyzed reaction of alpha-diazocarbonyl compounds bearing beta-trichloroacetylamino substituent: C-H insertion versus 1,2-H shift.
    Chemistry, an Asian journal, 2010, May-03, Volume: 5, Issue:5

    Topics: Amino Acids; Azo Compounds; Catalysis; Crystallography, X-Ray; Methane; Molecular Conformation; Rhodium

2010
Rhodium-mediated activation of an alkane-type C-H bond.
    Chemical communications (Cambridge, England), 2010, Jan-14, Volume: 46, Issue:2

    Topics: Alkanes; Carbon; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Rhodium

2010
IPr* an easily accessible highly hindered N-heterocyclic carbene.
    Dalton transactions (Cambridge, England : 2003), 2010, Feb-14, Volume: 39, Issue:6

    Topics: Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Methane; Molecular Conformation; Rhodium; Silver

2010
Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes.
    Journal of the American Chemical Society, 2010, Mar-03, Volume: 132, Issue:8

    Topics: Methane; Molecular Structure; Rhodium; Stereoisomerism; Triazoles

2010
Easy preparation of Cp*-functionalized N-heterocyclic carbenes and their coordination to rhodium and iridium.
    Dalton transactions (Cambridge, England : 2003), 2009, Sep-21, Issue:35

    Topics: Crystallography, X-Ray; Cyclopentanes; Heterocyclic Compounds; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism

2009
N-heterocyclic carbenes bearing two, one and no nitrogen atoms at the ylidene carbon: insight from theoretical calculations.
    Dalton transactions (Cambridge, England : 2003), 2009, Sep-21, Issue:35

    Topics: Carbon; Computer Simulation; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Nitrogen; Organometallic Compounds; Rhodium; Thermodynamics

2009
Pyrazolyl-N-heterocyclic carbene complexes of rhodium as hydrogenation catalysts: The influence of ligand steric bulk on catalyst activity.
    Dalton transactions (Cambridge, England : 2003), 2009, Sep-21, Issue:35

    Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogenation; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Pyrazolones; Rhodium; Stereoisomerism

2009
Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis.
    Dalton transactions (Cambridge, England : 2003), 2009, Sep-21, Issue:35

    Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism

2009
Synthesis of rhodium(I) and iridium(I) complexes of chiral N-heterocyclic carbenes and their application to asymmetric transfer hydrogenation.
    Dalton transactions (Cambridge, England : 2003), 2009, Sep-21, Issue:35

    Topics: Amines; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogenation; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism

2009
Carbene-anchored/pendent-imidazolium species as precursors to di-N-heterocyclic carbene-bridged mixed-metal complexes.
    Dalton transactions (Cambridge, England : 2003), 2009, Sep-21, Issue:35

    Topics: Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Iridium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Rhodium; Stereoisomerism

2009
Hydride ion-carrier ability in Rh(I) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand.
    Dalton transactions (Cambridge, England : 2003), 2010, Nov-28, Volume: 39, Issue:44

    Topics: Crystallography, X-Ray; Electrochemistry; Heterocyclic Compounds; Hydrogen; Ions; Ligands; Methane; Niacinamide; Organometallic Compounds; Rhodium; Spectrometry, Mass, Electrospray Ionization; Spectrophotometry, Ultraviolet

2010
Rh(II) carbene-promoted activation of the anomeric C-H bond of carbohydrates: a stereospecific entry toward α- and β-ketopyranosides.
    Journal of the American Chemical Society, 2010, Nov-10, Volume: 132, Issue:44

    Topics: Carbohydrate Sequence; Carbohydrates; Ketones; Methane; Molecular Sequence Data; Pyrans; Rhodium; Stereoisomerism

2010
Di- and trisubstituted γ-lactams via Rh(II)-carbenoid reaction of N-Cα-branched, N-bis(trimethylsilyl)methyl α-diazoamides. Synthesis of (±)-α-allokainic acid.
    Organic letters, 2010, Dec-03, Volume: 12, Issue:23

    Topics: Amides; Azo Compounds; Kainic Acid; Lactams; Methane; Molecular Structure; Rhodium; Trimethylsilyl Compounds

2010
Telomestatin: formal total synthesis and cation-mediated interaction of its seco-derivatives with G-quadruplexes.
    Journal of the American Chemical Society, 2011, Feb-02, Volume: 133, Issue:4

    Topics: Base Sequence; Biophysical Phenomena; Cations, Monovalent; G-Quadruplexes; Humans; Ligands; Methane; Models, Molecular; Oxazoles; Rhodium

2011
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
    Journal of the American Chemical Society, 2011, Jul-13, Volume: 133, Issue:27

    Topics: Alkanes; Carbon; Catalysis; Methane; Rhodium; Stereoisomerism; Sulfonamides; Triazoles

2011
Reactivity of N-(1,2,4-triazolyl)-substituted 1,2,3-triazoles.
    Organic letters, 2011, Sep-16, Volume: 13, Issue:18

    Topics: Methane; Molecular Structure; Rhodium; Stereoisomerism; Triazoles

2011
Asymmetric N-H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids.
    Angewandte Chemie (International ed. in English), 2011, Nov-25, Volume: 50, Issue:48

    Topics: Amines; Amino Acids; Catalysis; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Phosphoric Acids; Rhodium; Spiro Compounds; Stereoisomerism

2011
The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates.
    Dalton transactions (Cambridge, England : 2003), 2012, Jan-21, Volume: 41, Issue:3

    Topics: Catalysis; Electrons; Hydrogen; Imines; Methane; Models, Theoretical; Molecular Structure; Rhodium

2012
Competitive [2,3]- and [1,2]-oxonium ylide rearrangements. Concerted or stepwise?
    Organic letters, 2012, Apr-06, Volume: 14, Issue:7

    Topics: Acetoacetates; Catalysis; Crystallography, X-Ray; Methane; Molecular Conformation; Molecular Structure; Onium Compounds; Rhodium; Stereoisomerism

2012
Rhodium(II)-catalyzed cyclization of bis(N-tosylhydrazone)s: an efficient approach towards polycyclic aromatic compounds.
    Angewandte Chemie (International ed. in English), 2012, Jun-04, Volume: 51, Issue:23

    Topics: Azo Compounds; Catalysis; Cyclization; Hydrazones; Methane; Polycyclic Compounds; Rhodium

2012
Ligand-controlled regioselectivity in the hydrothiolation of alkynes by rhodium N-heterocyclic carbene catalysts.
    Journal of the American Chemical Society, 2012, May-16, Volume: 134, Issue:19

    Topics: Alkynes; Catalysis; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Rhodium; Stereoisomerism; Substrate Specificity; Sulfhydryl Compounds; Sulfides

2012
Highly regio- and stereoselective dirhodium vinylcarbene induced nitrone cycloaddition with subsequent cascade carbenoid aromatic cycloaddition/N-O cleavage and rearrangement.
    Angewandte Chemie (International ed. in English), 2012, Jun-11, Volume: 51, Issue:24

    Topics: Methane; Nitrogen; Nitrogen Oxides; Oxygen; Rhodium; Stereoisomerism; Vinyl Compounds

2012
Rhodium(II)- and copper(II)-catalyzed reactions of enol diazoacetates with nitrones: metal carbene versus Lewis acid directed pathways.
    Angewandte Chemie (International ed. in English), 2012, Jun-11, Volume: 51, Issue:24

    Topics: Acetates; Catalysis; Copper; Lewis Acids; Methane; Nitrogen Oxides; Rhodium; Stereoisomerism

2012
Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton.
    Chemical communications (Cambridge, England), 2012, Jun-14, Volume: 48, Issue:47

    Topics: Androgens; Androstadienes; Catalysis; Hydrogen; Methane; Oxygen; Rhodium; Silver

2012
Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration.
    Journal of the American Chemical Society, 2012, Jul-04, Volume: 134, Issue:26

    Topics: Azo Compounds; Catalysis; Computer Simulation; Cyclopropanes; Hydrogen; Methane; Molecular Conformation; Rhodium; Stereoisomerism

2012
Stereospecific synthesis and catalytic activity of L-histidylidene metal complexes.
    Dalton transactions (Cambridge, England : 2003), 2012, Aug-07, Volume: 41, Issue:29

    Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Histidine; Iridium; Ligands; Methane; Molecular Conformation; Phosphines; Rhodium; Stereoisomerism; Temperature

2012
Arylation of rhodium(II) azavinyl carbenes with boronic acids.
    Journal of the American Chemical Society, 2012, Sep-12, Volume: 134, Issue:36

    Topics: Amines; Aza Compounds; Boronic Acids; Catalysis; Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism

2012
Synthesis of tetrahydropyridazines by a metal-carbene-directed enantioselective vinylogous N-H insertion/Lewis acid-catalyzed diastereoselective Mannich addition.
    Angewandte Chemie (International ed. in English), 2012, Sep-24, Volume: 51, Issue:39

    Topics: Catalysis; Cycloaddition Reaction; Lewis Acids; Methane; Pyridazines; Rhodium; Stereoisomerism

2012
Rollover cyclometalation pathway in rhodium catalysis: dramatic NHC effects in the C-H bond functionalization.
    Journal of the American Chemical Society, 2012, Oct-24, Volume: 134, Issue:42

    Topics: 2,2'-Dipyridyl; Catalysis; Cyclization; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Quantum Theory; Quinolines; Rhodium; Stereoisomerism

2012
A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of an NHC-Rh hydrosilylation catalyst.
    Chemical communications (Cambridge, England), 2012, Nov-18, Volume: 48, Issue:89

    Topics: Catalysis; Chelating Agents; Heterocyclic Compounds; Histidine; Methane; Molecular Structure; Rhodium; Silanes

2012
Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines.
    Chemical communications (Cambridge, England), 2012, Nov-25, Volume: 48, Issue:91

    Topics: Coordination Complexes; Ethers; Methane; Nitrogen; Oximes; Oxygen; Pyridines; Rhodium

2012
Ring expansion and rearrangements of rhodium(II) azavinyl carbenes.
    Angewandte Chemie (International ed. in English), 2012, Dec-21, Volume: 51, Issue:52

    Topics: Alkenes; Catalysis; Click Chemistry; Heterocyclic Compounds; Methane; Rhodium; Stereoisomerism; Triazoles

2012
Versatile reactivity of rhodium-iminocarbenes derived from N-sulfonyl triazoles.
    Angewandte Chemie (International ed. in English), 2013, Jan-28, Volume: 52, Issue:5

    Topics: Alcohols; Catalysis; Click Chemistry; Methane; Rhodium; Triazoles

2013
A different route to functional polyolefins: olefin-carbene copolymerisation.
    Dalton transactions (Cambridge, England : 2003), 2013, Jul-07, Volume: 42, Issue:25

    Topics: Alkenes; Catalysis; Methane; Molecular Structure; Organometallic Compounds; Polymerization; Rhodium

2013
Carbene-mediated functionalization of the anomeric C-H bond of carbohydrates: scope and limitations.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2013, May-03, Volume: 19, Issue:19

    Topics: Carbohydrates; Chemistry, Organic; Disaccharides; Glycosides; Glycosylation; Hydrogen Bonding; Methane; Molecular Conformation; Rhodium

2013
A new access to 4 H-quinolizines from 2-vinylpyridine and alkynes promoted by rhodium-N-heterocyclic-carbene catalysts.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2013, Mar-18, Volume: 19, Issue:12

    Topics: Alkynes; Catalysis; Coordination Complexes; Methane; Pyridines; Quinolizines; Rhodium; Stereoisomerism

2013
Peptide-tethered monodentate and chelating histidylidene metal complexes: synthesis and application in catalytic hydrosilylation.
    Dalton transactions (Cambridge, England : 2003), 2013, Apr-28, Volume: 42, Issue:16

    Topics: Amino Acid Sequence; Catalysis; Chelating Agents; Coordination Complexes; Heterocyclic Compounds; Histidine; Iridium; Methane; Oligopeptides; Rhodium; Silicon

2013
Transannulation of 1-sulfonyl-1,2,3-triazoles with heterocumulenes.
    Journal of the American Chemical Society, 2013, Mar-27, Volume: 135, Issue:12

    Topics: Catalysis; Imidazoles; Isocyanates; Isothiocyanates; Methane; Polyenes; Rhodium; Sulfinic Acids; Thiazoles; Triazoles

2013
Bicyclic pyrazolidinone derivatives from diastereoselective catalytic [3 + 3]-cycloaddition reactions of enoldiazoacetates with azomethine imines.
    Organic letters, 2013, Apr-05, Volume: 15, Issue:7

    Topics: Azo Compounds; Bridged Bicyclo Compounds, Heterocyclic; Catalysis; Cyclization; Cycloaddition Reaction; Imines; Methane; Molecular Structure; Pyrazoles; Rhodium; Stereoisomerism; Thiosemicarbazones

2013
Rhodium-catalyzed conversion of furans to highly functionalized pyrroles.
    Journal of the American Chemical Society, 2013, Mar-27, Volume: 135, Issue:12

    Topics: Catalysis; Furans; Imines; Methane; Pyrroles; Rhodium

2013
Synthesis and structure of a carbene-stabilized boraallene coordinated to rhodium.
    Inorganic chemistry, 2013, May-20, Volume: 52, Issue:10

    Topics: Alkadienes; Boron Compounds; Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Quantum Theory; Rhodium

2013
Generation of rhodium(I) carbenes from ynamides and their reactions with alkynes and alkenes.
    Journal of the American Chemical Society, 2013, Jun-05, Volume: 135, Issue:22

    Topics: Alkenes; Alkynes; Amides; Methane; Molecular Structure; Organometallic Compounds; Rhodium

2013
Room temperature and solvent-free iridium-catalyzed selective alkylation of anilines with alcohols.
    Chemical communications (Cambridge, England), 2013, Jul-14, Volume: 49, Issue:55

    Topics: Alcohols; Alkylation; Amines; Catalysis; Iridium; Methane; Phosphines; Rhodium; Temperature

2013
Catalytic asymmetric syntheses of quinolizidines by dirhodium-catalyzed dearomatization of isoquinolinium/pyridinium methylides--the role of catalyst and carbene source.
    Journal of the American Chemical Society, 2013, Aug-21, Volume: 135, Issue:33

    Topics: Catalysis; Methane; Models, Molecular; Molecular Conformation; Pyridines; Quinolizidines; Rhodium; Stereoisomerism

2013
Intramolecular transannulation of alkynyl triazoles via alkyne-carbene metathesis step: access to fused pyrroles.
    Organic letters, 2013, Oct-18, Volume: 15, Issue:20

    Topics: Alkynes; Cyclization; Methane; Molecular Structure; Organometallic Compounds; Pyrroles; Rhodium; Triazoles

2013
A chemical-biological evaluation of rhodium(I) N-heterocyclic carbene complexes as prospective anticancer drugs.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2013, Dec-23, Volume: 19, Issue:52

    Topics: Antineoplastic Agents; Humans; Methane; Rhodium

2013
Silica-immobilized chiral dirhodium(II) catalyst for enantioselective carbenoid reactions.
    Organic letters, 2013, Dec-20, Volume: 15, Issue:24

    Topics: Catalysis; Methane; Molecular Conformation; Organometallic Compounds; Proline; Rhodium; Silicon Dioxide; Stereoisomerism

2013
Stereoselective 1,3-insertions of rhodium(II) azavinyl carbenes.
    Journal of the American Chemical Society, 2014, Jan-08, Volume: 136, Issue:1

    Topics: Amides; Aza Compounds; Carboxylic Acids; Catalysis; Crystallography, X-Ray; Methane; Molecular Structure; Rhodium; Stereoisomerism; Vinyl Compounds

2014
Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons.
    Journal of the American Chemical Society, 2014, Feb-12, Volume: 136, Issue:6

    Topics: Catalysis; Cyclization; Indoles; Methane; Molecular Structure; Rhodium

2014
Synthesis of proline-based N-heterocyclic carbene ligands.
    Organic letters, 2014, Feb-21, Volume: 16, Issue:4

    Topics: Catalysis; Imidazoles; Ligands; Methane; Molecular Structure; Proline; Rhodium; Stereoisomerism

2014
Preparation of triazoloindoles via tandem copper catalysis and their utility as α-imino rhodium carbene precursors.
    Organic letters, 2014, Feb-21, Volume: 16, Issue:4

    Topics: Catalysis; Copper; Indoles; Methane; Molecular Structure; Rhodium; Stereoisomerism; Sulfones; Triazoles

2014
The divergent synthesis of nitrogen heterocycles by rhodium(II)-catalyzed cycloadditions of 1-sulfonyl 1,2,3-triazoles with 1,3-dienes.
    Angewandte Chemie (International ed. in English), 2014, May-26, Volume: 53, Issue:22

    Topics: Alkadienes; Azepines; Catalysis; Cycloaddition Reaction; Heterocyclic Compounds; Methane; Nitrogen; Rhodium; Triazoles

2014
Intermolecular hydroamination of 1,3-dienes catalyzed by bis(phosphine)carbodicarbene-rhodium complexes.
    Journal of the American Chemical Society, 2014, Apr-30, Volume: 136, Issue:17

    Topics: Allyl Compounds; Amination; Amines; Catalysis; Coordination Complexes; Methane; Models, Molecular; Phosphines; Polyenes; Rhodium

2014
Hydride-rhodium(III)-N-heterocyclic carbene catalysts for vinyl-selective H/D exchange: a structure-activity study.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2014, Jul-01, Volume: 20, Issue:27

    Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Deuterium; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Rhodium; Structure-Activity Relationship; Vinyl Compounds

2014
Highly selective directed arylation reactions via back-to-back dehydrogenative C-H borylation/arylation reactions.
    Chemical communications (Cambridge, England), 2014, Sep-07, Volume: 50, Issue:69

    Topics: Boron Compounds; Catalysis; Crystallography, X-Ray; Dimerization; Heterocyclic Compounds; Hydrocarbons, Aromatic; Methane; Models, Molecular; Rhodium

2014
Highly stereoselective synthesis of cyclopentanes bearing four stereocentres by a rhodium carbene-initiated domino sequence.
    Nature communications, 2014, Aug-01, Volume: 5

    Topics: Alcohols; Catalysis; Cyclopentanes; Diazonium Compounds; Methane; Rhodium; Stereoisomerism; Vinyl Compounds

2014
Divergent outcomes of carbene transfer reactions from dirhodium- and copper-based catalysts separately or in combination.
    Angewandte Chemie (International ed. in English), 2011, Nov-18, Volume: 50, Issue:47

    Topics: Acrolein; Catalysis; Copper; Crystallography, X-Ray; Cycloaddition Reaction; Methane; Molecular Conformation; Rhodium

2011
Rhodium-catalyzed transannulation of N-sulfonyl-1,2,3-triazoles and epoxides: regioselective synthesis of substituted 3,4-dihydro-2H-1,4-oxazines.
    Organic letters, 2014, Sep-05, Volume: 16, Issue:17

    Topics: Catalysis; Combinatorial Chemistry Techniques; Methane; Molecular Structure; Oxazines; Rhodium; Triazoles

2014
Catalytic asymmetric functionalization of aromatic C-H bonds by electrophilic trapping of metal-carbene-induced zwitterionic intermediates.
    Angewandte Chemie (International ed. in English), 2014, Nov-24, Volume: 53, Issue:48

    Topics: Catalysis; Methane; Models, Molecular; Molecular Structure; Rhodium; Stereoisomerism

2014
Direct catalytic addition of alkylnitriles to aldehydes by transition-metal/NHC complexes.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2014, Nov-24, Volume: 20, Issue:48

    Topics: Aldehydes; Coordination Complexes; Heterocyclic Compounds; Imidazoles; Ions; Metals; Methane; Models, Molecular; Molecular Structure; Nitriles; Rhodium; Stereoisomerism; Transition Elements

2014
An ylide transformation of rhodium(I) carbene: enantioselective three-component reaction through trapping of rhodium(I)-associated ammonium ylides by β-nitroacrylates.
    Angewandte Chemie (International ed. in English), 2014, Nov-24, Volume: 53, Issue:48

    Topics: Acrylates; Ammonium Compounds; Catalysis; Methane; Molecular Structure; Rhodium; Stereoisomerism

2014
Intramolecular annulation of aromatic rings with N-sulfonyl 1,2,3-triazoles: divergent synthesis of 3-methylene-2,3-dihydrobenzofurans and 3-methylene-2,3-dihydroindoles.
    Chemical communications (Cambridge, England), 2015, Jan-04, Volume: 51, Issue:1

    Topics: Benzofurans; Catalysis; Coordination Complexes; Cyclization; Indoles; Methane; Rhodium; Triazoles

2015
One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay.
    Organic letters, 2015, Jan-02, Volume: 17, Issue:1

    Topics: Catalysis; Combinatorial Chemistry Techniques; Cyclization; Lewis Acids; Mesylates; Methane; Molecular Structure; Organometallic Compounds; Rhodium; Sulfonamides; Transition Elements; Triazoles

2015
Catalytic hydrodechlorination of benzyl chloride promoted by Rh-N-heterocyclic carbene catalysts.
    ChemSusChem, 2015, Volume: 8, Issue:3

    Topics: Benzyl Compounds; Catalysis; Halogenation; Heterocyclic Compounds; Hydrogen; Methane; Models, Molecular; Molecular Conformation; Rhodium; Silanes

2015
A Rh-catalyzed 1,2-sulfur migration/aza-Diels-Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles.
    Chemical communications (Cambridge, England), 2015, Feb-07, Volume: 51, Issue:11

    Topics: Aza Compounds; Catalysis; Methane; Rhodium; Sulfur; Triazoles

2015
Domino [4 + 1]-annulation of α,β-unsaturated δ-amino esters with Rh(II)-carbenoids – a new approach towards multi-functionalized N-aryl pyrrolidines.
    Organic & biomolecular chemistry, 2015, Mar-07, Volume: 13, Issue:9

    Topics: Amino Acids; Cyclization; Esters; Methane; Molecular Structure; Organometallic Compounds; Pyrrolidines; Rhodium

2015
Rh(II)-catalyzed cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines: switchable reactivity of Rh-azavinylcarbene as [2C]- or aza-[3C]-synthon.
    Chemical communications (Cambridge, England), 2015, Mar-14, Volume: 51, Issue:21

    Topics: Aza Compounds; Azirines; Carbon; Catalysis; Cycloaddition Reaction; Methane; Rhodium; Triazoles

2015
Rhodium(I)-catalyzed asymmetric carbene insertion into B-H bonds: highly enantioselective access to functionalized organoboranes.
    Journal of the American Chemical Society, 2015, Apr-29, Volume: 137, Issue:16

    Topics: Amination; Azo Compounds; Boranes; Catalysis; Crystallography, X-Ray; Ligands; Methane; Models, Molecular; Rhodium; Stereoisomerism

2015
Lipase active site covalent anchoring of Rh(NHC) catalysts: towards chemoselective artificial metalloenzymes.
    Chemical communications (Cambridge, England), 2015, Apr-21, Volume: 51, Issue:31

    Topics: Biomimetic Materials; Catalysis; Catalytic Domain; Fungal Proteins; Heterocyclic Compounds; Lipase; Methane; Organometallic Compounds; Rhodium

2015
An efficient approach to 1,2,3-trisubstituted indole via rhodium catalyzed carbene C(sp(3))-H bond insertion.
    Organic & biomolecular chemistry, 2015, May-07, Volume: 13, Issue:17

    Topics: Catalysis; Indoles; Methane; Molecular Structure; Organometallic Compounds; Rhodium

2015
Stereoselective Synthesis of Highly Substituted Tetrahydrofurans through Diverted Carbene O-H Insertion Reaction.
    Angewandte Chemie (International ed. in English), 2015, Jul-13, Volume: 54, Issue:29

    Topics: Catalysis; Copper; Furans; Methane; Rhodium; Stereoisomerism

2015
Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes.
    Journal of the American Chemical Society, 2015, Jul-29, Volume: 137, Issue:29

    Topics: Catalysis; Hydrogenation; Ketones; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Phenols; Rhodium; Stereoisomerism

2015
Rh(II)-Catalyzed Reactions of Diazoesters with Organozinc Reagents.
    Organic letters, 2015, Aug-21, Volume: 17, Issue:16

    Topics: Azo Compounds; Catalysis; Hydrazones; Indicators and Reagents; Ketones; Methane; Molecular Structure; Organometallic Compounds; Rhodium; Zinc

2015
Catalytic Asymmetric Four-Component Reaction for the Rapid Construction of 3,3-Disubstituted 3-Indol-3'-yloxindoles.
    Organic letters, 2015, Sep-04, Volume: 17, Issue:17

    Topics: Catalysis; Glyoxylates; Indoles; Methane; Models, Molecular; Molecular Structure; Phosphoric Acids; Rhodium; Stereoisomerism

2015
Rh-Catalyzed Reactions of 3-Diazoindolin-2-imines: Synthesis of Pyridoindoles and Tetrahydrofuropyrroloindoles.
    Organic letters, 2015, Sep-18, Volume: 17, Issue:18

    Topics: Catalysis; Furans; Heterocyclic Compounds, 4 or More Rings; Imines; Indoles; Methane; Molecular Structure; Rhodium

2015
Total Synthesis of the Posttranslationally Modified Polyazole Peptide Antibiotic Plantazolicin A.
    Angewandte Chemie (International ed. in English), 2015, Dec-07, Volume: 54, Issue:50

    Topics: Anti-Bacterial Agents; Azoles; Catalysis; Dose-Response Relationship, Drug; Methane; Methicillin-Resistant Staphylococcus aureus; Microbial Sensitivity Tests; Molecular Structure; Oligopeptides; Polymers; Rhodium; Structure-Activity Relationship

2015
Divergent Reactivity of Rhodium(I) Carbenes Derived from Indole Annulations.
    Angewandte Chemie (International ed. in English), 2015, Oct-26, Volume: 54, Issue:44

    Topics: Indoles; Methane; Molecular Structure; Organometallic Compounds; Rhodium

2015
Pyridazine N-Oxides as Precursors of Metallocarbenes: Rhodium-Catalyzed Transannulation with Pyrroles.
    Organic letters, 2015, Dec-04, Volume: 17, Issue:23

    Topics: Antineoplastic Agents; Catalysis; Cyclic N-Oxides; Indoles; Methane; Molecular Structure; Nitrogen; Pyridazines; Pyrroles; Rhodium

2015
Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration.
    Accounts of chemical research, 2016, Jan-19, Volume: 49, Issue:1

    Topics: Alkenes; Catalysis; Cyclization; Diazonium Compounds; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism

2016
Moving from Classical Ru-NHC to Neutral or Charged Rh-NHC Based Catalysts in Olefin Metathesis.
    Molecules (Basel, Switzerland), 2016, Jan-30, Volume: 21, Issue:2

    Topics: Alkenes; Catalysis; Heterocyclic Compounds; Methane; Molecular Conformation; Organometallic Compounds; Rhodium; Ruthenium

2016
A multi-target caffeine derived rhodium(i) N-heterocyclic carbene complex: evaluation of the mechanism of action.
    Dalton transactions (Cambridge, England : 2003), 2016, Aug-16, Volume: 45, Issue:33

    Topics: Animals; Apoptosis; Bacteria; Caffeine; Cell Cycle; Cell Line, Tumor; Cell Survival; Chick Embryo; Chorioallantoic Membrane; Coordination Complexes; DNA Damage; Humans; Membrane Potential, Mitochondrial; Methane; Reactive Oxygen Species; Rhodium; Wound Healing

2016
Hydrogen Production and Storage on a Formic Acid/Bicarbonate Platform using Water-Soluble N-Heterocyclic Carbene Complexes of Late Transition Metals.
    ChemSusChem, 2016, Oct-06, Volume: 9, Issue:19

    Topics: Bicarbonates; Catalysis; Formates; Heterocyclic Compounds; Hot Temperature; Hydrogen; Indium; Kinetics; Methane; Rhodium; Solubility; Water

2016
Catalytic activation of carbon-carbon bonds in cyclopentanones.
    Nature, 2016, 11-24, Volume: 539, Issue:7630

    Topics: Biological Products; Carbon; Catalysis; Chemistry Techniques, Synthetic; Cyclohexanones; Cyclopentanes; Hydrogen Bonding; Methane; Molecular Structure; Pyridines; Quantum Theory; Rhodium; Terpenes; Tetralones

2016
Metal NHC Complexes with Naphthalimide Ligands as DNA-Interacting Antiproliferative Agents.
    ChemMedChem, 2017, 02-03, Volume: 12, Issue:3

    Topics: Apoptosis; Cell Proliferation; Circular Dichroism; Coordination Complexes; Crystallography, X-Ray; Cymenes; DNA; Drug Stability; HT29 Cells; Humans; Intercalating Agents; Ligands; MCF-7 Cells; Methane; Molecular Conformation; Monoterpenes; Naphthalimides; Rhodium; Ruthenium; Spectrophotometry, Ultraviolet

2017
Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds.
    Nature, 2017, 11-30, Volume: 551, Issue:7682

    Topics: Biological Products; Carbon; Catalysis; Cytochrome P-450 Enzyme System; Hydrogen; Hydrogen Bonding; Methane; Models, Molecular; Molecular Structure; Rhodium; Steroids; Vitamin E

2017
Harnessing the β-Silicon Effect for Regioselective and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization by Donor/Acceptor Carbenes Derived from 1-Sulfonyl-1,2,3-triazoles.
    Organic letters, 2018, 04-20, Volume: 20, Issue:8

    Topics: Catalysis; Methane; Molecular Structure; Rhodium; Silicon; Stereoisomerism; Triazoles

2018
Polycyclic Indoline-Benzodiazepines through Electrophilic Additions of α-Imino Carbenes to Tröger Bases.
    Angewandte Chemie (International ed. in English), 2018, 06-11, Volume: 57, Issue:24

    Topics: Benzodiazepines; Catalysis; Imines; Indoles; Methane; Models, Molecular; Polycyclic Compounds; Rhodium; Stereoisomerism; Triazoles

2018
Enantioselective Synthesis of Indolines, Benzodihydrothiophenes, and Indanes by C-H Insertion of Donor/Donor Carbenes.
    Angewandte Chemie (International ed. in English), 2018, 11-12, Volume: 57, Issue:46

    Topics: Catalysis; Indans; Indoles; Methane; Oxidation-Reduction; Rhodium; Stereoisomerism; Thiophenes

2018
Urea Insertion Reaction of Rhodium-Carbenoid.
    Chemical & pharmaceutical bulletin, 2018, Volume: 66, Issue:11

    Topics: Catalysis; Methane; Molecular Structure; Rhodium; Urea

2018
Functionalization of GlucoPyranosides at position 5 by 1,5 C-H insertion of Rh(II)-Carbenes: Dramatic influence of the anomeric configuration.
    Carbohydrate research, 2019, Dec-01, Volume: 486

    Topics: Catalysis; Electron Transport; Glycosides; Methane; Rhodium; Stereoisomerism

2019
A Combined Spectroscopic and Protein Crystallography Study Reveals Protein Interactions of Rh
    Inorganic chemistry, 2020, Dec-07, Volume: 59, Issue:23

    Topics: Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Muramidase; Rhodium

2020
Programmable site-selective labeling of oligonucleotides based on carbene catalysis.
    Nature communications, 2021, 03-16, Volume: 12, Issue:1

    Topics: Base Sequence; Carbon-13 Magnetic Resonance Spectroscopy; Catalysis; Cross-Linking Reagents; DNA; DNA-Directed RNA Polymerases; Methane; Oligonucleotides; Promoter Regions, Genetic; Proton Magnetic Resonance Spectroscopy; Rhodium; Staining and Labeling; Substrate Specificity; Viral Proteins

2021
α-Amino-iso-Butyric Acid Foldamers Terminated with Rhodium(I) N-Heterocyclic Carbene Catalysts.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2022, Feb-16, Volume: 28, Issue:9

    Topics: Butyric Acid; Catalysis; Heterocyclic Compounds; Iridium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism

2022
Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions.
    Journal of the American Chemical Society, 2022, 02-02, Volume: 144, Issue:4

    Topics: Carbon; Catalysis; Coordination Complexes; Hydrogen; Kinetics; Methane; Rhodium; Stereoisomerism; Thermodynamics

2022
Efficient Nicotinamide Adenine Dinucleotide Regeneration with a Rhodium-Carbene Catalyst and Isolation of a Hydride Intermediate.
    Inorganic chemistry, 2022, Apr-18, Volume: 61, Issue:15

    Topics: Methane; NAD; Oxidation-Reduction; Regeneration; Rhodium

2022
Synthesis of α-Amino Cyclobutanones via Formal 1,3-Hydroxy Migration Triggered by Formation of α-Imino Rhodium Carbene.
    Organic letters, 2022, 04-22, Volume: 24, Issue:15

    Topics: Catalysis; Methane; Rhodium

2022
Bis[cyclic (alkyl)(amino)carbene] isomers: Stable
    Chemical communications (Cambridge, England), 2022, Jun-01, Volume: 58, Issue:45

    Topics: Alkenes; Ligands; Methane; Rhodium

2022
Rhodium(I) Carbene-Promoted Enantioselective C-H Functionalization of Simple Unprotected Indoles, Pyrroles and Heteroanalogues: New Mechanistic Insights.
    Angewandte Chemie (International ed. in English), 2022, 08-22, Volume: 61, Issue:34

    Topics: Catalysis; Indoles; Methane; Pyrroles; Rhodium; Stereoisomerism

2022
Catalytic (3 + 2) umpolung annulations of α-thioacyl carbenes with aryl isothiocyanates.
    Chemical communications (Cambridge, England), 2022, Jul-14, Volume: 58, Issue:57

    Topics: Catalysis; Imines; Isothiocyanates; Methane; Rhodium

2022
Chemo- and Regioselective Multiple C(sp
    Angewandte Chemie (International ed. in English), 2022, 10-10, Volume: 61, Issue:41

    Topics: Malonates; Methane; Molecular Structure; Rhodium

2022
Chiral Bismuth-Rhodium Paddlewheel Complexes Empowered by London Dispersion: The C-H Functionalization Nexus.
    Angewandte Chemie (International ed. in English), 2022, 11-07, Volume: 61, Issue:45

    Topics: Bismuth; Catalysis; London; Rhodium; Stereoisomerism

2022
Asymmetric Cyclopropanation with 4-Aryloxy-1-sulfonyl-1,2,3-triazoles: Expanding the Range of Rhodium-Stabilized Donor/Acceptor Carbenes to Systems with an Oxygen Donor Group.
    The Journal of organic chemistry, 2022, 11-04, Volume: 87, Issue:21

    Topics: Catalysis; Molecular Structure; Oxygen; Rhodium; Stereoisomerism; Triazoles

2022
Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins.
    Chemical communications (Cambridge, England), 2022, Nov-29, Volume: 58, Issue:95

    Topics: Electronics; Heterocyclic Compounds; Porphyrins; Rhodium

2022
Catalyst Controlled Site- and Stereoselective Rhodium(II) Carbene C(sp
    Organic letters, 2023, 01-13, Volume: 25, Issue:1

    Topics: Catalysis; Methane; Rhodium; Stereoisomerism

2023
Theoretical Investigation of Chemoselectivity between C-H Insertion and Amide Insertion in Intramolecular Rhodium-Carbene Reactions.
    Chemical & pharmaceutical bulletin, 2023, Volume: 71, Issue:2

    Topics: Catalysis; Methane; Nitrogen; Rhodium

2023
    Organic letters, 2023, Jun-09, Volume: 25, Issue:22

    Topics: Catalysis; Molecular Structure; Phthalimides; Rhodium; Stereoisomerism

2023
Modulating Escape Channels of Cycloheptatrienyl Rhodium Carbenes To Form Semibullvalene.
    The Journal of organic chemistry, 2023, Jul-07, Volume: 88, Issue:13

    Topics: Azo Compounds; Carbon; Catalysis; Rhodium

2023
Amphiphilic polymeric nanoparticles enable homogenous rhodium-catalysed NH insertion reactions in living cells.
    Nanoscale, 2023, Aug-03, Volume: 15, Issue:30

    Topics: Catalysis; HeLa Cells; Humans; Methane; Nanoparticles; Rhodium

2023