carbene has been researched along with methane in 1993 studies
| Studies (carbene) | Trials (carbene) | Recent Studies (post-2010) (carbene) | Studies (methane) | Trials (methane) | Recent Studies (post-2010) (methane) |
|---|---|---|---|---|---|
| 2,067 | 0 | 1,265 | 39,142 | 249 | 26,184 |
| Timeframe | Studies, this research(%) | All Research% |
|---|---|---|
| pre-1990 | 82 (4.11) | 18.7374 |
| 1990's | 33 (1.66) | 18.2507 |
| 2000's | 567 (28.45) | 29.6817 |
| 2010's | 1055 (52.94) | 24.3611 |
| 2020's | 256 (12.84) | 2.80 |
| Authors | Studies |
|---|---|
| Bochkariov, DE; Kogon, AA | 1 |
| Dolder, M; Michel, H; Sigrist, H | 1 |
| McLafferty, FW | 1 |
| Armitage, IM; Brown, MS; Gore, JC | 1 |
| De Matteis, F; King, LJ; Manno, M | 1 |
| Anjaneyulu, PS; Batliwala, HF; Lala, AK; Mogre, RM | 1 |
| Bayley, H; Shih, LB | 1 |
| Eberle, AN | 1 |
| Berkhout, T; Khorana, HG; Radhakrishnan, R; van Deenen, LL; Westerman, J; Wirtz, KW | 1 |
| Curatolo, W; Gupta, CM; Khorana, HG; Radhakrishnan, R | 1 |
| Kushlan, DM; LeMaster, DM | 1 |
| Kushmerick, MJ; Saranathan, M | 1 |
| Hashimoto, M; Hatanaka, Y; Hidari, KI; Kanaoka, Y; Nagai, Y; Sanai, Y; Tezuka, Y | 1 |
| di Domenico, A; Di Marzio, S; Piccardi, A; Testai, E; Vittozzi, L | 1 |
| Hashimoto, M; Hatanka, Y; Kanaoka, Y; Narimatsu, H; Nishihara, S | 1 |
| Cetinkaya, B; Cetinkaya, E; Durmaz, R; Küçükbay, H | 1 |
| Carballeira, NM; González, MV; Pagán, M | 1 |
| Galitz, DS; Peterson, KL; Srivastava, DK | 1 |
| Campbell, N; Cory, DG; Millis, K; Singer, S; Weybright, P | 1 |
| Durette, PL; Grant, SK; Green, BG; Kozarich, JW; Shah, SK; Stiffey-Wilusz, J | 1 |
| Blume, A; Garidel, P | 1 |
| Gousset, H; Liquier, J; Peoch, D; Sanghvi, YS; Taillandier, E | 1 |
| Barry, CE; Mead, D; Schroeder, BG; Yuan, Y; Zhu, Y | 1 |
| Hattori, T; Hirano, K; Kouchi, M; Satouchi, K; Tanaka, T | 1 |
| Bax, A; Delaglio, F; Marquardt, JL; Ottiger, M; Tjandra, N | 1 |
| Carlomagno, T; Griesinger, C; Rexroth, A; Schwalbe, H; Sorensen, OW | 1 |
| Ameri, M; Attwood, D; Booth, C; Collett, JH | 1 |
| de Certaines, JD; Delplanque, B; Leray, G; Leroy, B; Nadal, L; Serrai, H | 1 |
| Jeong, LS; Yoo, SJ | 1 |
| Nagle, JF; Petrache, HI; Tu, K | 1 |
| Babcock, EE; Burns, DK; Dobbins, RL; Garg, A; McGarry, JD; Schick, F; Stein, DT; Szczepaniak, LS | 1 |
| Asakura, T; Ikeo, T; Iwadate, M; Slaninová, J; Ueki, M; Williamson, MP | 1 |
| Sekiguchi, O; Tajima, S; Takahashi, S | 1 |
| Ando, K; Araki, S; Katakai, R; Kato, F; Kawai, M; Kobayashi, K; Oda, Y; Takahashi, Y; Yamada, K; Yamamura, H | 1 |
| Bollen, A; Dekker, HL; Kooter, IM; Moguilevsky, N; Otto, C; van der Veen, LA; Wever, R | 1 |
| Blümich, B; Demco, DE; Schneider, M | 1 |
| Handa, J; Inubushi, T; Matsuda, M; Morikawa, S; Nakasu, S; Shino, A | 1 |
| Doyle, MP | 1 |
| Delcour, AH; Iyer, R; Woster, PM; Wu, Z | 1 |
| Blackledge, M; Douce, R; Gans, P; Guilhaudis, L; Marion, D; Neuburger, M; Simorre, JP | 1 |
| George, C; Marquez, VE; Moon, HR; Shin, KJ | 1 |
| Hashimoto, H; Kajihara, Y; Ogawa, S | 1 |
| Akimoto, T | 1 |
| Chiang, Y; Kresge, AJ; Schepp, NP; Xie, R | 1 |
| Hartwig, JF; Hauck, SI; Lee, S; Stambuli, JP; Stauffer, SR | 1 |
| Antonelli, SM; Holtz, KM; Kantrowitz, ER; Myers, JK; Stec, B; Widlanski, TS | 1 |
| Carlomagno, T; Griesinger, C; Peti, W | 1 |
| Büllesbach, EE; Schwabe, C | 1 |
| Damsté, JS; Geenevasen, JA; Gieskes, WW; Hopmans, EC; Peletier, H; Rijpstra, WI; Schouten, S | 1 |
| Andersson, A; Andrén, PE; Lindblom, G; Orädd, G; Rilfors, L; Strandberg, E | 1 |
| Bartkowska, B; Fürstner, A; Kindler, N; Thiel, OR | 1 |
| Deckers, GH; Kloosterboer, HJ; Schoonen, WG | 1 |
| de Gooijer, ME; de Ries, R; Deckers, G; Hamersma, H; Kloosterboer, HJ; Mathijssen-Mommers, G; Schoonen, WG | 1 |
| Kinoshita, Y; Yamamoto, N; Yamauchi, S | 1 |
| Lamed, R; Olack, G; Patel, D; Richards, FM; Wynn, R | 1 |
| Albaneze-Walker, J; Aldrich, CC; Mammen, J; Merlic, CA; Saghatelian, A | 1 |
| Helquist, P; Ishii, S; Knors, CJ; Mehta, G; Zhao, S | 1 |
| Harvey, RG; Laali, KK; Okazaki, T | 1 |
| Hartel, C; Notz, W; Schmidt, RR; Waldscheck, B | 1 |
| Fujii, Y; Kashihara, M; Teranishi, M | 1 |
| Crum, LA; Kwok, CS; Mourad, PD; Ratner, BD | 1 |
| Maluendes, SA; McLean, AD | 1 |
| Gottlieb, CA; Kovacs, A; Kuiper, TB; Langer, WD; McCarthy, MC; Peng, R; Thaddeus, P; Travers, MJ; Velusamy, T | 1 |
| Isaacs, L; Lagona, J; Witt, D | 1 |
| Chatterjee, AK; Choi, TL; Grubbs, RH; Lee, CW | 1 |
| Blais, JC; Compain, C; Jaouen, G; Salmain, M; Tran-Huy, H | 1 |
| Bégué, JP; Bonnet-Delpon, D; Chorki, F; Crousse, B; Grellepois, F; Ourévitch, M | 1 |
| Schwenter, ME; Vogel, P | 1 |
| Jeong, LS; Kim, HO; Kim, J; Lim, Y; Yoo, SJ | 1 |
| Ren, LM; Zhang, W | 1 |
| Dickerson, RE; Hartley, JA; Kopka, ML; Lown, JW; Mack, D; O'Hare, CC; Sharma, SK; Tandon, M | 1 |
| Baati, R; Barma, DK; Falck, JR; Mioskowski, C; Valleix, A | 1 |
| Feierl, G; Gössnitzer, E; Wagner, U | 1 |
| Crabtree, RH; Eisenstein, O; Sini, G | 1 |
| Connor, EF; Hedrick, JL; Möck, A; Myers, M; Nyce, GW | 1 |
| Fujita, R; Tomisawa, H; Watanabe, N | 1 |
| Beaulieu, C; Halasz, A; Hawari, J; Paquet, L; Spain, J | 1 |
| Bergman, RG; Ellman, JA; Tan, KL | 1 |
| Hundal, LS; Mao, JD; Schmidt-Rohr, K; Thompson, ML | 1 |
| Bunker, PR; Hirano, T; Jensen, P; Kraemer, WP; Odaka, TE | 1 |
| Mascharak, PK; Olmstead, MM; Rowland, JM | 1 |
| Herndon, JW; Zhang, Y | 2 |
| Ghorai, BK; Herndon, JW; Johnson, DL; Menon, S | 1 |
| Layne, J | 1 |
| Dakternieks, D; Gabriele, G; Hadjikakou, S; Jurkschat, K; Mehring, M; Schürmann, M | 1 |
| Chakraborty, A; Chiles, JK; Damkaci, F; Fettinger, JC; Isaacs, L; Lagona, J; Ofori, MA; Witt, D; Wu, A | 1 |
| Komatsu, K; Nemoto, K; Nishiyama, N; Suzuki, K; Yasuda, S | 1 |
| Hillhouse, GL; Mindiola, DJ | 1 |
| Gais, HJ; Raabe, G; Reddy, LR; Woo, CW | 1 |
| Cutarelli, TD; Feldman, KS | 1 |
| Che, CM; Huang, JS; Li, Y; You, XZ; Zhou, ZY | 1 |
| Cutarelli, TD; Di Florio, R; Feldman, KS | 1 |
| Bertolini, TM; Harvey, DF; Nguyen, QH | 1 |
| Choi, BG; Hong, JH; Kim, G; Kook, MC; Kwak, EY; Lee, CK | 1 |
| Dible, BR; Sigman, MS | 2 |
| Fukami, Y; Iami, H; Matsui, H; Mizuno, T; Nishimoto, Y; Ogawa, Y; Okumura, K; Saburi, Y | 1 |
| Gómez-Gallego, M; González, A; Kayali, N; Mancheño, MJ; Martínez-Alvarez, R; Ramírez-López, P; Sierra, MA | 1 |
| Mazzei, M; Melloni, E; Minafra, R; Nieddu, E | 1 |
| Dacres, JE; Freeman, PK | 1 |
| Choi, TL; Day, MW; Ding, S; Grubbs, RH; Morgan, JP; Sanford, MS; Scholl, M; Trnka, TM; Wilhelm, TE | 1 |
| Alonso, J; Barluenga, J; Fañanás, FJ | 2 |
| Ishioka, T; Snyder, RG; Strauss, HL; Yan, W | 1 |
| Hatcher, PG; Kramer, R; Simpson, AJ; Zang, X | 1 |
| Abdulrahman, AM; Al-Mutabagani, LA; Al-Najjar, IM; Al-Refai, JK; Al-Shabanah, LA | 1 |
| Korda, A; Winiarski, J | 1 |
| Endo, T; Kobayashi, J; Toriyabe, Y; Tsuda, M | 1 |
| Anderson, KS; Atreya, CE; Chang, SY; Johnson, EF; Liang, PH; Williamson, J | 1 |
| Chen, B; Cheng, KF; Chiu, P; Ko, RY; Yuen, MS | 1 |
| Brüschweiler, R; Jin, C; Prompers, JJ | 1 |
| Hartwig, JF; Stauffer, SR | 1 |
| Bhushan, B; Halasz, A; Hawari, J; Paquet, L; Spain, JC | 1 |
| Dennis, AL; Miller, MB; Nam, J; Nes, WD; Song, Z; Zhou, W | 1 |
| Goto, M; Kurosaki, H; Mori, H; Sumimoto, M; Tanaka, K | 1 |
| Hemamayi, R; Imanishi, T; Masuda, T; Mayumi, T; Nakagawa, S; Obika, S; Sugimoto, T | 1 |
| Buchwald, SL; Jurkauskas, V; Sadighi, JP | 1 |
| Brada, M; Dzik-Jurasz, AS; Leach, MO; Murphy, PS; Rowland, IJ; Viviers, L | 1 |
| Ayscough, AP; Beckett, RP; Bragg, RA; Clements, JM; Davies, SJ; Doel, S; Grew, C; Launchbury, SB; Perkins, GM; Pratt, LM; Smith, HK; Spavold, ZM; Thomas, SW; Todd, RS; Whittaker, M | 1 |
| Bell, MA; Gilham, PT; Gough, GR | 1 |
| Audic, N; Clavier, H; Guillemin, JC; Mauduit, M | 1 |
| Kumar, MS; Maity, DK; Mohan, H; Naik, GH; Priyadarsini, KI; Satav, JG; Unnikrishnan, MK | 1 |
| Andrus, MB; Jiang, W; Liu, X; Ma, Y; Song, C; Wang, Y; Wu, Q | 1 |
| Diver, ST; Kulkarni, AA | 2 |
| DONE, J; FOWDEN, L | 1 |
| ADACHI, K; MIZUNO, Y; NAKAMURA, K | 1 |
| FOWDEN, L; WEBB, JA | 2 |
| LOVEI, E; MOLNAR, J | 1 |
| MENTZER, C; RATSIMAMANGA, AR | 1 |
| OSTERMAN, FA | 1 |
| BOETTNER, JF; DORMAN, G; FAIRCLOTH, RS; MAAS, PA; MANRY, WE; PATTERSON, RJ; ROGERS, DR | 1 |
| HOEKENGA, MT | 1 |
| SIMON, I | 1 |
| TAUBERGER, G | 1 |
| DULIN, A; MARTIN, JW | 1 |
| ALEXANDER, WM; GARDIER, RW; RICHARDS, AB; WARREN, RJ | 1 |
| PATTERSON, RJ | 1 |
| OYEN, F; ROWE, VK; TORKELSON, TR | 1 |
| BARBIER, M; HUGEL, MF; LEDERER, E | 1 |
| BOERNGEN, S; GEBLER, K; HAUSCHILD, F | 1 |
| BARBIER, M; LEDERER, E; REICHSTEIN, T; SCHINDLER, O | 1 |
| BRUNORI, M; CAPUTO, A; GIULIANO, R | 1 |
| EIDEN, F | 2 |
| SOMA, N; SUNAGAWA, G | 1 |
| SOMA, N | 2 |
| ASSELINEAU, J; TOUBIANA, R | 1 |
| HIGASHINO, T | 1 |
| WIT, JG | 1 |
| BAILEY, E; MURPHY, D; WEST, HF | 1 |
| FUKUMOTO, K; KAMETANI, T | 1 |
| CRESCENZI, E; PALA, G; SEKULES, G | 1 |
| MASTANDREA, R; PONARI, O | 1 |
| ZSOLANI, T | 1 |
| AIMAN, CE; BURGSTAHLER, AW; TROLLOPE, ML | 1 |
| ITO, K; SAITO, M; SEKIYA, M | 1 |
| CALIO, R | 1 |
| HIRAI, K; TAKAMIZAWA, A | 1 |
| MONTEROGARCIA, J | 1 |
| CHEN, YC; HUANG, ML | 1 |
| MONTANINO, G | 1 |
| COPPI, G; MARAZZI-UBERTI, E; MASELLI, A | 1 |
| HARPEL, HS; MANN, DE | 1 |
| NAKAO, H; SUNAGAWA, G | 1 |
| HARKNESS, RA; WINKLER, GK | 1 |
| CHIGNELL, CF; MAY, EL | 1 |
| STERBA, R; STURMA, J | 1 |
| SCHNEKENBURGER, J | 1 |
| KIMURA, M | 2 |
| LLAURADO, JG | 1 |
| Astruc, D; Blais, JC; Daniel, MC; Daro, N; Ruiz, J | 1 |
| Storck, PH; Taber, DF | 1 |
| Li, L; Liu, J; Zhang, H; Zhang, TY; Zhao, Y; Zhou, Y | 1 |
| García, G; García-Granda, S; Mosquera, ME; Patrón, E; Riera, V; Ruiz, J; Van der Maelen, F | 1 |
| Chatterjee, P; Franklin, MR | 1 |
| Acton, DG; Betts, MJ; Dennis, M; Gravestock, MB; Hatter, G; McGregor, A; Swain, ML; Wilson, RG; Woods, L; Wookey, A | 1 |
| Andrus, MB; Cannon, JF; Jiang, W; Ma, Y; Song, C; Wang, X; Xue, G | 1 |
| Boons, GJ; Galan, MC; Glushka, J; Imberty, A; Venot, AP | 1 |
| Bényei, A; Kövér, KE; Somsák, L; Tóth, M | 1 |
| Binoy, J; Hubert Joe, I; Jayakumar, VS; Kartha, VB; Pradeep, B; Sajan, D; Venkata Krishna, K | 1 |
| Balagopal, L; Bindu, S; Mathen, JS; Nair, V; Rajesh, C; Sreekanth, AR; Vinod, AU | 1 |
| Anderson, VE; Ruszczycky, MW | 1 |
| Chaudhuri, A; Singh, RS | 1 |
| Yang, D; Zheng, Y | 1 |
| BENNETT, LL; BRYAN, CE; NEWTON, MA; SIMPSON, L; SKIPPER, HE; WHITE, L | 1 |
| JANKOVIC, BD | 1 |
| FEROLA, R | 1 |
| Caddick, S; Cloke, FG; Davies, BP; de Santana, AP; Hiller, W; Lewis, AK; McCarroll, AJ; Sandham, DA; Titcomb, LR | 1 |
| THORN, MB | 2 |
| Hasegawa, T | 1 |
| Diver, ST; Giessert, AJ | 2 |
| Arai, T; Ikegami, M; Kawai, T | 1 |
| Amador, U; Casarrubios, L; Domínguez, G; Pérez-Castells, J; Rosillo, M | 1 |
| Babu, BR; Sun, BW; Sun, JS; Sørensen, MD; Wengel, J; Zakrzewska, K | 1 |
| Hun Kim, D; Hyun, MH | 1 |
| Alter, GM; Nuss, JE | 1 |
| Baba, M; Gunaga, P; Jeong, LS | 1 |
| Hirai, K; Nakajima, J; Tomioka, H | 1 |
| Fehér, K; Kövér, KE | 1 |
| Botzung-Appert, E; Brasselet, S; Ibanez, A; Le Floc'h, V; Roch, JF; Treussart, F; Zyss, J | 1 |
| Brecker, L; Brinker, UH; Giester, G; Krois, D; Mieusset, JL; Pacar, M | 1 |
| Smith, DM; Woerpel, KA | 1 |
| Hamidov, H; Jeffery, JC; Lynam, JM | 1 |
| Fonseca, MH; List, B | 1 |
| Asao, T; Emura, T; Fukushima, M; Kazuno, H; Suzuki, N; Tada, Y; Wierzba, K; Yamada, Y; Yamashita, J; Yano, S | 1 |
| Asao, T; Emura, T; Fukushima, M; Kazuno, H; Sato, T; Suzuki, N; Tada, Y; Wierzba, K; Yamada, Y; Yamashita, J; Yano, S | 1 |
| Miethchen, R; Reinke, H; Wegert, A | 1 |
| DeLuca, HF; Grzywacz, P; Plum, LA; Prahl, JM; Sicinska, W; Sicinski, RR | 1 |
| Harris, AL; Tao, L | 1 |
| Hochberg, RB; Labaree, DC; Mor, G; Zhang, JX | 1 |
| Brandt, CD; Jung, S; Werner, H; Wolf, J | 1 |
| Deetlefs, M; Esterhuysen, MW; Julius, GR; Meyer, WH; Pohlmann, M; Raubenheimer, HG; Scholz, R | 1 |
| Baker, MV; Barnard, PJ; Berners-Price, SJ; Skelton, BW; White, AH | 1 |
| Faber, K; Fabian, WM; Glueck, SM; Mayer, SF | 1 |
| Cartier, D; Gronemeyer, H; Ivanova, D; Labia, R; Le Guillou, R; Rossin, A; Valla, A | 1 |
| Bennettová, B; Hlavácek, J; Konvalinka, J; Marík, J; Tykva, R | 1 |
| Balensiefer, T; Enders, D | 1 |
| Bax, A; Boisbouvier, J; Bryce, DL; Clore, GM; Miclet, E; Williams, DC | 1 |
| Catalano, VJ; Etogo, AO; Malwitz, MA | 1 |
| Jandera, P; Moravcová, D; Planeta, J; Urban, J | 1 |
| Campbell, JE; Hoveyda, AH; Larsen, AO; Leu, W; Oberhuber, CN | 1 |
| Agrawal, PK | 1 |
| DE VLEESCHHOUWER, GR; VERBEKE, R | 1 |
| CANBACK, T | 3 |
| MAC FARLANE, DW; PELIKAN, EW; SADOVE, MS | 1 |
| Alder, RW; Blake, ME; Chaker, L; Harvey, JN; Paolini, F; Schütz, J | 1 |
| Baker, MV; Barnard, PJ; Berners-Price, SJ; Day, DA | 1 |
| Gräslund, A; Jarvet, J; Kogner, P; Lindskog, M; Spenger, C | 1 |
| Kawamura, K; Matsumoto, K; Suga, S; Suzuki, S; Yoshida, J | 1 |
| Hägele, G; Kolev, TM; Russeva, ED; Stamboliyska, BA; Varbanov, SG | 1 |
| Castro-Rodriguez, I; Hu, X; Meyer, K | 1 |
| Alonso, J; Barluenga, J; Borge, J; Fañanás, FJ; García-Granda, S | 1 |
| Cui, JF; Guo, XM; Luo, XY; Wang, CY; Yao, KD; Yin, YJ | 1 |
| Appell, M; Kennedy, S; Momany, FA; Price, NP; Xu, L | 1 |
| Gridnev, ID; Kathriarachchi, KK; Nakamura, I; Siriwardana, AI; Yamamoto, Y | 1 |
| Gopalsamuthiram, V; Wulff, WD | 1 |
| Gans-Eichler, T; Gudat, D; Nieger, M | 2 |
| Breyfogle, LE; Hillmyer, MA; Jensen, TR; Tolman, WB | 1 |
| Su, MD | 2 |
| Furutani, Y; Harada, H; Kato, S; Mizuno, K; Oue, M; Sawa, M; Tateishi, H; Tsujiuchi, H | 1 |
| Bachert, P; Schmitz, C; Schröder, L | 2 |
| Chamberland, S; Woerpel, KA | 1 |
| Bellemin-Laponnaz, S; César, V; Gade, LH | 1 |
| Cole, PA; Klein, DC; Lebeau, A; Schwarzer, D; Weller, JL; Zheng, W | 1 |
| Shalvoy, R; Van Der Merwe, B; Van Rensburg, AJ; Vermeulen, S; Willford, S | 1 |
| Costello, CE; Cournoyer, JJ; Fallows, E; Ivleva, VB; O'Connor, PB; Pittman, JL; Waskell, L | 1 |
| Edmonds, JS; Morita, M; Nomachi, M | 1 |
| Awenat, KM; Davis, PJ; Ebenezer, W; Moloney, MG | 1 |
| Chase, DB; Pellerin, C; Pelletier, I; Rabolt, JF | 1 |
| Aboul-Enein, HY; Bunaciu, AA; Fleschin, S; Scripcariu, M | 1 |
| Shenoy, SR; Woerpel, KA | 1 |
| Csihony, S; Hedrick, JL; Sentman, AC; Waymouth, RM | 1 |
| Feldman, KS; Iyer, MR | 1 |
| Bax, A; Boisbouvier, J; Miclet, E | 1 |
| Brickey, TW; Craig, NC; Lingenfelter, PT; Osmani, AS; Pearson, A; Rathore, MO | 1 |
| Domek, H; Mieczkowski, J; Pacuszka, T; Panasiewicz, M | 1 |
| Hayashi, T; Kohyama, N; Yamamoto, Y | 1 |
| Campbell, JE; Giudici, RE; Hoveyda, AH; Van Veldhuizen, JJ | 1 |
| Hahn, FE; Langenhahn, V; Le Van, D; Lügger, T; Pape, T | 1 |
| Artaud, C; Elbein, A; Jousheghany, F; Kieber-Emmons, T; Monzavi-Karbassi, B; Whitehead, TL | 1 |
| Green, TK; Kirschner, DL | 1 |
| Moss, RA; Tian, J | 1 |
| Denekamp, C; Sandlers, Y | 1 |
| Kerr, MS; Read de Alaniz, J; Rovis, T | 1 |
| Coulembier, O; Culkin, DA; Dove, AP; Dubois, P; Hedrick, JL; Mespouille, L; Pratt, RC; Sentman, AC; Waymouth, RM | 1 |
| Davies, JR; Kane, PD; Moody, CJ; Slawin, AM | 1 |
| Barluenga, J; Capriati, V; Florio, S; Luisi, R; Perna, FM | 1 |
| Jones, C; Junk, PC; Platts, JA; Rathmann, D; Stasch, A | 1 |
| Bertrand, G; Donnadieu, B; Präsang, C | 1 |
| Bunel, EE; Gandhi, BA; Grady, MJ; Guzei, IA; Scarborough, CC; Stahl, SS | 1 |
| Balamurugan, R; Halcrow, MA; Kilner, CA; Palaniandavar, M; Raja, A; Rajendiran, V; Uma Maheswari, P | 1 |
| Charette, AB; Kendall, C; Legault, CY | 1 |
| Bertrand, G; Canac, Y; Donnadieu, B; Lavallo, V; Präsang, C | 1 |
| Cai, G; Jia, X; Ye, W; Zhai, H; Zhuang, Z | 1 |
| Aguilar, E; Barluenga, J; Fernández-Rodríguez, MA; García-García, P; Merino, I | 2 |
| Kim, M; Lee, D; Miller, RL | 1 |
| Service, RF | 1 |
| Barluenga, J; de Prado, A; Santamaría, J; Tomás, M | 1 |
| Gilbertson, SR; Xu, G | 1 |
| Ochiai, M; Tada, N | 1 |
| Bowen, EG; Wardrop, DJ | 1 |
| Cantat, T; Jaroschik, F; Le Floch, P; Mézailles, N; Nief, F; Ricard, L | 1 |
| Kim, D; Yun, H; Yun, J | 1 |
| Bertrand, G; Canac, Y; DeHope, A; Donnadieu, B; Lavallo, V | 1 |
| Capriati, V; Florio, S; Gasparrini, F; Luisi, R; Perna, FM; Salomone, A | 1 |
| Cai, L; Chen, B; Liang, JL; Taber, DF | 1 |
| Gagneron, J; Gosselin, G; Mathé, C | 1 |
| Darzynkiewicz, E; Guranowski, A; Jemielity, J; Kowalska, J; Pietrowska-Borek, M; Starzynska, E; Stolarski, R | 1 |
| Bojarska, E; Cohen, LS; Darzynkiewicz, E; Davis, RE; Grudzien, E; Jemielity, J; Kalek, M; Rhoads, RE; Stepinski, J; Stolarski, R; Zuberek, J | 1 |
| Esposito, V; Mayol, L; Ohlenschläger, O; Ramachandran, R; Randazzo, A; Virgilio, A | 1 |
| Baddi, L; Lazrek, HB; Ouzebla, D; Redwane, N; Rochdi, A; Sebti, S; Taourirte, M; Vasseur, JJ | 1 |
| Chun, MW; Gunaga, P; Jeong, LS; Kim, HJ; Kim, HO | 1 |
| Nolan, SP; Singh, R | 1 |
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| Häussinger, D; Klehr, J; Prescimone, A; Rumo, C; Stein, A; Tachibana, R; Ward, TR | 1 |
| Liang, F; She, K; Tian, S; Tsui, GC; Wang, H; Wang, Q | 1 |
| Dong, Z; Ma, MY; Xu, J; Yang, Z | 1 |
| Annunziata, A; Cucciolito, ME; Ferraro, G; Imbimbo, P; Merlino, A; Monti, DM; Ruffo, F; Tuzi, A | 1 |
| Lan, J; Li, W; Zhou, P; Zhu, T | 1 |
| Bae, HY; Koo, BJ; Lee, SB; Park, JH | 1 |
| Casini, A; Davies, TE; Dimitratos, N; Fischer, RA; Huang, J; Li, JJ; Morgan, DJ; Thomas, SR; Yang, W | 1 |
| Chiodo, F; Mazzone, G; Richeter, S; Scoditti, S; Sicilia, E | 1 |
| Du, D; Lin, C; Liu, C; Zhang, S | 1 |
| Barrett, C; Ispizua-Rodriguez, X; Koch, CJ; Krishnamurti, V; Surya Prakash, GK; Zhu, Z | 1 |
| Álvarez, E; Calderón-Montaño, JM; Carrasco, CJ; Galindo, A; López-Lázaro, M; Montilla, F | 1 |
| Bora, D; John, SE; Shankaraiah, N | 1 |
| Lee, E; Pietrasiak, E; Song, H | 1 |
| Du, HW; Liu, MS; Shu, W | 1 |
| Barnard, PJ; Hamilton, A; Mather, JC; Soares da Costa, TP; Wyllie, JA | 1 |
| Anderson, EA; Bi, X; Li, L; Li, S; Liu, B; Ning, Y; Sivaguru, P; Zanoni, G; Zhang, X; Zhang, Z | 1 |
| Aquaro, S; Catalano, A; Ceramella, J; Costabile, C; El-Kashef, H; Iacopetta, D; Longo, P; Mariconda, A; Pellegrino, M; Rosano, C; Saturnino, C; Sinicropi, MS; Sirignano, M | 1 |
| Akkawi, NR; Johnson, JD; Teeples, CR; Wilkerson-Hill, SM | 1 |
| Liu, LL; Mei, Y; Zhang, X | 1 |
| Bakker, E; Besnard, C; de Aguirre, A; Di Bari, L; Fabri, B; Guarnieri-Ibáñez, A; Guénée, L; Lacour, J; Moneva Lorente, P; Moreau, D; Nikolova, Y; Pescitelli, G; Poblador-Bahamonde, AI; Soda, Y; Zinna, F | 1 |
| Duan, XY; Li, J; Li, Y; Liu, B; Qi, J; Wu, Y | 1 |
| Christov, CZ; Knorrscheidt, A; Lehnert, N; Palomino, H; Sosa Alfaro, V; Waheed, SO; Weissenborn, M | 1 |
| Eguchi, T; Ehara, M; Endo, M; Kamachi, T; Lei, Z; Nagata, K; Ozawa, T; Pei, XL; Shionoya, M; Shiraogawa, T; Ube, H; Zhao, P | 1 |
| Carter, JH; Das, M; Davies, TE; Ernst, JB; Freakley, SJ; Glorius, F; Hutchings, GJ; Koy, M; Lewis, RJ; Macino, M; Morgan, DJ | 1 |
| Bhaskararao, B; Kee, JM; Kim, DY; Kim, KS; Kozlowski, MC; Rotella, ME | 1 |
| Adams, ER; Glushka, JN; Lahm, ME; Popik, VV; Ren, Z; Robinson, GH; Schaefer, HF; Tran, PM; Wang, Y; Wei, P; Xie, Y | 1 |
| Dickie, DA; Freeman, LA; Gilliard, RJ; Molino, A; Wentz, KE; Wilson, DJD | 1 |
| Bens, T; Bruhn, C; Heinz, M; Holthausen, MC; Leibold, M; Sarkar, B; Siemeling, U; Volk, J | 1 |
| Coulembier, O; Guichard, G; Taton, D; Wirotius, AL; Zaky, MS | 1 |
| Ansari, A; Ansari, M; Kumar, M | 1 |
| Chi, YR; Wei, L; Wu, Y; Yang, X; Zhang, X; Zhou, L | 1 |
| Bonfiglio, A; Dontenwill, M; Fournel, S; Herold-Mende, C; Idbaih, A; Kichler, A; Mathieu, E; Mauro, M; McCartin, C | 1 |
| Chang, MY; Hsueh, NC | 1 |
| Jin, Y; Li, W; Lin, J; Tang, Z; Yang, Y; Yu, X | 1 |
| Ben Ahmed, S; Kotschy, A; Nagy, Z; Paczal, A; Szabo, Z | 1 |
| Barrera, E; Delgado, F; Escalante, CH; Espinoza-Hicks, JC; García-González, AN; Hernández-Benítez, RI; Restrepo-Osorio, RA; Santoyo, BM; Tamariz, J; Yescas-Galicia, D | 1 |
| Caytan, E; Cordier, M; Crassous, J; Del Fré, S; Favereau, L; Gauthier, ES; Kaczmarczyk, D; Srebro-Hooper, M; Vanthuyne, N; Williams, JAG | 1 |
| Bacsa, J; Cao, Y; Dodd, NA; Gray, TG; Sadighi, JP; Towles, EC | 1 |
| Maji, B; Pratap, A; Shukla, PM | 1 |
| Hanif, M; Hartinger, CG; Jamieson, SMF; Leung, E; Riisom, M; Söhnel, T; Tong, KKH | 1 |
| Dong, K; Li, J; Li, RP; Liu, J; Mao, M; Tang, S; Wang, X | 1 |
| Cui, Q; Lai, R | 1 |
| Hu, B; Jiang, P; Jin, Y; Lin, J; Yang, J; Yang, X; Yuan, X | 1 |
| Chi, YR; Liu, Y; Wang, Y; Wu, X | 1 |
| Copéret, C; Gajan, D; Jabbour, R; Kaeffer, N; Lesage, A; Menzildjian, G; Robinson, TC; Rossini, AJ; Venkatesh, A; Völker, LA; Wang, Z | 1 |
| Bauer, F; Fan, R; Fang, W; Kuai, M; Lin, D | 1 |
| Borkar, V; Kanchupalli, V; Kumar, S; Mujahid, M; Nunewar, S | 1 |
| Dong, Z; Jiang, C; Zhao, C | 1 |
| Choi, H; Choi, J; Lee, K | 1 |
| Happy, S; Junaid, M; Yadagiri, D | 1 |
| Annibale, VT; Chitnis, SS; Gates, DP; LaPierre, EA; Manners, I; Oldroyd, NL; Walsgrove, HTG | 1 |
| Anderson, EA; Bi, X; Li, L; Liu, S; Liu, Z; Song, Q; Xiang, M; Yang, Y; Zanoni, G | 1 |
| Arnold, FH; Das, A; Garcia-Borràs, M; Houk, KN; Huang, X; Jimenez-Osés, G; Knight, AM; Schaus, L | 1 |
| Boni, YT; Davies, HML; Vaitla, J | 1 |
| Capaldo, L; de Bruin, B; de Zwart, FJ; Noël, T; Ravelli, D; Vitullo, W; Wan, T | 1 |
| Ji, S; Miao, B; Wang, Z; Xue, M; Zhang, Y | 1 |
| Biju, AT; Sarkar, D; Shee, S | 1 |
| Furuya, T; Harada, S; Ikeda, K; Nemoto, T | 1 |
| Bee, C; Dollinger, G; Hogan, JM; Lee, PS; Morishige, WH; Rajpal, A; Strop, P; Tapia, GC; West, SM; Wong, SC | 1 |
| Du, D; Gao, J; Zhang, S | 1 |
| Arnold, FH; Danelius, E; Gonen, T; Porter, NJ; Unge, J | 1 |
| Fujiwara, T; Hashimoto, K; Inokuma, T; Kuwano, S; Sun, C; Yamada, KI | 1 |
| Parameswaran, P; Parvathy, P | 1 |
| Balskus, EP; Hager, H; Hartwig, JF; Huang, J; Keasling, JD; Ng, TL; Van Cura, D | 1 |
| Ali, S; Chen, ZS; Huang, XY; Ji, K; Li, YZ; Liu, Q; Ma, YT; Yang, F | 1 |
| Arnold, FH; Calvó-Tusell, C; Chen, K; Garcia-Borràs, M; Liu, Z | 1 |
| Choe, S; Choi, H; Kim, J; Ko, YH; Lee, E; Song, H; Yoo, S | 1 |
| Dar, MO; Masoodi, MH; Mir, RH; Mohiuddin, R; Sofi, FA | 1 |
| Chi, YR; Fan, G; Wang, Q; Xu, J; Zheng, P | 1 |
| Deng, L; Loman, T; Palmans, ARA; Sathyan, A | 1 |
| Cheraghi, M; Dusek, M; Eigner, V; Kaboudin, B; Kucerakova, M; Mahdavi, A; Neshat, A; Rezaie, F; Yousefshahi, MR | 1 |
| Burgener, S; Dačević, B; Ward, TR; Zhang, X | 1 |
| Aguilera, MC; Ando, N; Bacik, JP; Fasan, R; Khade, RL; Nam, D; Neidig, ML; Villada, JD; Wei, Y; Zhang, Y | 1 |
129 review(s) available for carbene and methane
| Article | Year |
|---|---|
Enyne metathesis (enyne bond reorganization).
Topics: Alkynes; Amino Acids; Biological Factors; Carbohydrates; Heterocyclic Compounds; Hydrocarbons; Isomerism; Metals; Methane | 2004 |
Combinatorial chemistry and high-throughput screening for the discovery of organocatalysts.
Topics: Catalysis; Chemistry, Organic; Combinatorial Chemistry Techniques; Drug Design; Hydrocarbons; Methane; Models, Chemical; Organometallic Compounds | 2004 |
When and how do diaminocarbenes dimerize?
Topics: Amines; Computer Simulation; Dimerization; Heterocyclic Compounds; Hydrocarbons; Methane; Models, Chemical; Molecular Structure; Organometallic Compounds | 2004 |
Chiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysis.
Topics: Catalysis; Hydrocarbons; Ligands; Methane; Models, Molecular; Molecular Conformation; Organic Chemicals; Organometallic Compounds; Stereoisomerism | 2004 |
Ag(I) N-heterocyclic carbene complexes: synthesis, structure, and application.
Topics: Drug Design; Hydrocarbons; Methane; Molecular Structure; Silver | 2005 |
Chemistry of N-fluoropyridinium salts.
Topics: Fluorine; Hydrocarbons; Methane; Pyridinium Compounds; Salts | 2005 |
Heterocyclic carbenes.
Topics: Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Stereoisomerism | 2006 |
Fischer carbene complexes: beautiful playgrounds to study single electron transfer (SET) reactions.
Topics: Electrons; Hydrocarbons; Metals; Methane; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Stereoisomerism | 2007 |
Recent developments in the metal-catalyzed reactions of metallocarbenoids from propargylic esters.
Topics: Alkynes; Biological Products; Bridged Bicyclo Compounds, Heterocyclic; Catalysis; Cyclization; Cyclopropanes; Esters; Hydrocarbons; Ketones; Methane; Methanol; Models, Chemical; Organometallic Compounds; Propanols; Stereoisomerism; Transition Elements | 2007 |
The chemistry of functionalised N-heterocyclic carbenes.
Topics: Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2007 |
What have we learnt about heavy carbenes through laser flash photolysis studies?
Topics: Computer Simulation; Forecasting; Hydrocarbons; Lasers; Methane; Models, Chemical; Models, Molecular; Photolysis | 2007 |
Intermolecular reactions of electron-rich heterocycles with copper and rhodium carbenoids.
Topics: Copper; Heterocyclic Compounds; Hydrocarbons; Methane; Rhodium | 2007 |
[Development of a new method for consecutive activation of conjugated alkynes based on intramolecular silyl migration].
Topics: Alkynes; Amines; Chemistry, Organic; Chemistry, Pharmaceutical; Humans; Hydrocarbons; Methane; Propionates; Silanes | 2007 |
Synthesis of anti-reverse cap analogs (ARCAs) and their applications in mRNA translation and stability.
Topics: Animals; Cell-Free System; Cells, Cultured; Eukaryotic Initiation Factor-4E; Humans; Magnetic Resonance Spectroscopy; Methane; Models, Biological; Nucleic Acid Conformation; Protein Binding; Protein Biosynthesis; RNA Cap Analogs; RNA Stability; Substrate Specificity; Transcription, Genetic | 2007 |
Advances in the metallotropic [1,3]-shift of alkynyl carbenoids.
Topics: Alkynes; Chromium; Copper; Hydrocarbons; Metals, Heavy; Methane; Molecular Structure; Molybdenum; Organometallic Compounds; Tungsten | 2007 |
Organocatalysis by N-heterocyclic carbenes.
Topics: Aldehydes; Biological Factors; Catalysis; Enzymes; Heterocyclic Compounds; Hydrocarbons; Ketones; Methane; Molecular Structure; Stereoisomerism | 2007 |
Nucleophilic carbenes as organocatalysts.
Topics: Acrolein; Aldehydes; Catalysis; Chemistry, Organic; Hydrocarbons; Imines; Ketones; Ligands; Methane; Models, Molecular; Molecular Conformation; Organic Chemicals; Stereoisomerism | 2007 |
N-heterocyclic carbenes: organocatalysts displaying diverse modes of action.
Topics: Catalysis; Chemistry, Organic; Hydrocarbons; Ligands; Methane; Models, Chemical; Models, Molecular; Molecular Conformation; Organic Chemicals; Organometallic Compounds; Stereoisomerism | 2007 |
[Development of C-C bond formation and asymmetric reactions catalyzed by N-heterocyclic carbenes].
Topics: Acylation; Alcohols; Aldehydes; Carbon; Catalysis; Chemistry, Organic; Heterocyclic Compounds; Methane; Organic Chemistry Phenomena | 2008 |
Development of palladium-carbene catalysts for telomerization and dimerization of 1,3-dienes: from basic research to industrial applications.
Topics: Alkadienes; Catalysis; Chemical Industry; Crystallography, X-Ray; Dimerization; Hydrogenation; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Pilot Projects | 2008 |
N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivity.
Topics: Catalysis; Heterocyclic Compounds; Methane; Organometallic Compounds; Rhodium | 2008 |
Coinage metal catalyzed C-H bond functionalization of hydrocarbons.
Topics: Catalysis; Hydrocarbons; Metals; Methane; Molecular Conformation; Organic Chemicals; Organometallic Compounds; Oxidation-Reduction; Stereoisomerism | 2008 |
Carbene complexes of gold: preparation, medical application and bonding.
Topics: Animals; Catalysis; Gases; Gold; Humans; Methane | 2008 |
Computational and experimental tools in solving some mechanistic problems in the chemistry of Fischer carbene complexes.
Topics: Computer Simulation; Cyclization; Light; Methane; Models, Chemical; Organometallic Compounds; Photochemistry; Temperature | 2008 |
Persistent triplet carbenes.
Topics: Electron Spin Resonance Spectroscopy; Electrons; Methane; Molecular Structure; Solvents; Thermodynamics | 2009 |
The medicinal applications of imidazolium carbene-metal complexes.
Topics: Anti-Bacterial Agents; Antineoplastic Agents; Imidazoles; Metals; Methane; Molecular Conformation | 2009 |
[Exploitation of the chemistry of magnesium carbenoids and their use in organic synthesis].
Topics: Carbon; Chemistry, Organic; Magnesium; Methane; Organic Chemistry Phenomena; Sulfoxides; Temperature | 2009 |
Catalytic carbene insertion into C-H bonds.
Topics: Azo Compounds; Carbon; Catalysis; Copper; Isomerism; Methane; Rhodium | 2010 |
Application of donor/acceptor-carbenoids to the synthesis of natural products.
Topics: Biological Products; Catalysis; Cyclization; Metals; Methane; Organic Chemistry Phenomena | 2009 |
Domino reactions of rhodium(II) carbenoids for alkaloid synthesis.
Topics: Alkaloids; Cyclization; Diazonium Compounds; Methane; Rhodium | 2009 |
Catalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and more.
Topics: Alkenes; Anti-HIV Agents; Biological Products; Catalysis; Coordination Complexes; Metals; Methane; Stereoisomerism | 2010 |
Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.
Topics: Alkenes; Catalysis; Heterocyclic Compounds; Methane; Phosphines; Ruthenium | 2010 |
Ralph F. Hirschmann award address 2009: Merger of organic chemistry with peptide diversity.
Topics: Caspase 8; Methane; Models, Molecular; Molecular Structure; Organic Chemicals; Peptides | 2010 |
Metal-NHC complexes: a survey of anti-cancer properties.
Topics: Animals; Antineoplastic Agents; Apoptosis; Cell Line, Tumor; Cell Proliferation; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Humans; Methane; Organometallic Compounds | 2009 |
Fused polycyclic nucleophilic carbenes - synthesis, structure, and function.
Topics: Methane; Molecular Structure; Polycyclic Compounds; Stereoisomerism | 2009 |
Alkene oligomerisation and polymerisation with metal-NHC based catalysts.
Topics: Alkenes; Catalysis; Heterocyclic Compounds; Lanthanoid Series Elements; Methane; Organometallic Compounds | 2009 |
Phosphine-free chiral metal catalysts for highly effective asymmetric catalytic hydrogenation.
Topics: Catalysis; Coordination Complexes; Heterocyclic Compounds; Hydrogenation; Imines; Ketones; Methane; Phosphines; Quinolines; Stereoisomerism | 2010 |
Beyond catalysis: N-heterocyclic carbene complexes as components for medicinal, luminescent, and functional materials applications.
Topics: Anti-Infective Agents; Antineoplastic Agents; Catalysis; Coordination Complexes; Heterocyclic Compounds; Methane; Organometallic Compounds; Polymers; Ruthenium | 2010 |
Multi-component reactions involving group 6 Fischer carbene complexes: a source of inspiration for future catalytic transformations.
Topics: Alcohols; Alkadienes; Alkynes; Catalysis; Metals; Methane | 2010 |
Stable cyclic carbenes and related species beyond diaminocarbenes.
Topics: Alkadienes; Catalysis; Coordination Complexes; Metals; Methane; Molecular Conformation; Phosphorus; Stereoisomerism | 2010 |
Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.
Topics: Azo Compounds; Biological Products; Carbon; Catalysis; Hydrogen; Methane; Rhodium; Stereoisomerism | 2011 |
Selective functionalisation of saturated C-H bonds with metalloporphyrin catalysts.
Topics: Amination; Carbon; Catalysis; Hydrogen; Hydroxylation; Metalloporphyrins; Methane | 2011 |
Carbene catalysts.
Topics: Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2010 |
Gold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.
Topics: Alkynes; Catalysis; Coordination Complexes; Cyclization; Gold; Methane; Oxidation-Reduction; Oxygen | 2011 |
Advances in metal-carbene complexes as potent anti-cancer agents.
Topics: Antineoplastic Agents; Cell Line; Coordination Complexes; Heterocyclic Compounds; Humans; Metals; Methane; Molecular Structure; Neoplasms | 2012 |
Small organometallic compounds as antibacterial agents.
Topics: Adamantane; Aminobenzoates; Anilides; Anti-Bacterial Agents; Methane; Organometallic Compounds; Penicillins; Quinolones | 2012 |
Progress in palladium-based catalytic systems for the sustainable synthesis of annulated heterocycles: a focus on indole backbones.
Topics: Alkynes; Catalysis; Chemistry Techniques, Synthetic; Indoles; Ligands; Methane; Palladium; Phosphines | 2012 |
Development of efficient catalytic arylation of aldehydes with thioether-imidazolinium carbene ligands.
Topics: Aldehydes; Boron Compounds; Catalysis; Heterocyclic Compounds; Imidazoles; Ligands; Methane; Palladium; Sulfides | 2012 |
NHC-boranes: air- and water-tolerant co-initiators for type II photopolymerizations.
Topics: Acrylates; Air; Boranes; Free Radicals; Heterocyclic Compounds; Methane; Molecular Structure; Photochemical Processes; Polymerization; Water | 2012 |
C-H bond functionalization: emerging synthetic tools for natural products and pharmaceuticals.
Topics: Alkylation; Biological Products; Carbon; Catalysis; Hydrogen; Imines; Metals; Methane; Pharmaceutical Preparations; Stereoisomerism | 2012 |
Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent "gold rush".
Topics: Catalysis; Cycloaddition Reaction; Esters; Methane; Rhodium; Stereoisomerism | 2012 |
A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.
Topics: Aldehydes; Benzoin; Biological Products; Catalysis; Chemistry Techniques, Synthetic; Ketones; Methane; Molecular Structure; Stereoisomerism | 2012 |
Metal N-heterocyclic carbene complexes as potential antitumor metallodrugs.
Topics: Animals; Antineoplastic Agents; Coordination Complexes; Humans; Methane; Models, Molecular; Neoplasms; Transition Elements | 2013 |
Recent developments on domino metathesis reactions in India.
Topics: India; Methane; Molecular Structure; Polycyclic Compounds; Ruthenium | 2012 |
Metal-catalyzed double migratory cascade reactions of propargylic esters and phosphates.
Topics: Alkadienes; Catalysis; Esters; Gold; Halogens; Methane; Phosphates; Platinum | 2013 |
Photoactivatable lipid probes for studying biomembranes by photoaffinity labeling.
Topics: Biotin; Cell Membrane; Fluorescent Dyes; Free Radicals; Imines; Lipids; Membrane Proteins; Methane; Photoaffinity Labels; Sterols | 2013 |
A golden future in medicinal inorganic chemistry: the promise of anticancer gold organometallic compounds.
Topics: Alkynes; Animals; Antineoplastic Agents; Humans; Methane; Neoplasms; Organogold Compounds | 2014 |
Metal-N-heterocyclic carbene complexes as anti-tumor agents.
Topics: Antineoplastic Agents; Auranofin; Cell Line, Tumor; Cisplatin; Coordination Complexes; Copper; Gold; Heterocyclic Compounds; Humans; Methane; Neoplasms; Palladium; Platinum; Silver; Structure-Activity Relationship | 2014 |
Recent advances in cinchona alkaloid catalysis for enantioselective carbon-nitrogen bond formation reactions.
Topics: Aziridines; Azirines; Carbon; Catalysis; Cinchona Alkaloids; Methane; Nitrogen; Stereoisomerism | 2014 |
N-Heterocyclic carbene metal complexes: photoluminescence and applications.
Topics: Catalysis; Coordination Complexes; Luminescence; Methane; Photochemistry | 2014 |
Recent advances in carbon dioxide capture, fixation, and activation by using N-heterocyclic carbenes.
Topics: Carbon Dioxide; Catalysis; Heterocyclic Compounds; Methane; Nitrogen | 2014 |
Benzyl-substituted metallocarbene antibiotics and anticancer drugs.
Topics: Animals; Anti-Bacterial Agents; Antineoplastic Agents; Benzyl Compounds; Cell Line, Tumor; Cell Survival; Copper; Gold; Humans; Imidazoles; Inhibitory Concentration 50; Metals, Heavy; Methane; Microbial Sensitivity Tests; Ruthenium; Silver | 2014 |
Donor-acceptor chemistry in the main group.
Topics: Alkenes; Gallium; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Silicon | 2014 |
Recent developments of metal N-heterocyclic carbenes as anticancer agents.
Topics: Antineoplastic Agents; Cell Proliferation; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Metals; Methane; Molecular Structure; Organometallic Compounds; Structure-Activity Relationship | 2014 |
Recent developments in the Suzuki-Miyaura reaction: 2010-2014.
Topics: Boron Compounds; Catalysis; Heterocyclic Compounds; Hydrocarbons; Iron; Methane; Nickel; Palladium; Water | 2015 |
Recent advances in employing homoenolates generated by N-heterocyclic carbene (NHC) catalysis in carbon-carbon bond-forming reactions.
Topics: Alcohols; Alkenes; Carbon; Chemistry, Organic; Heterocyclic Compounds; Methane; Stereoisomerism | 2015 |
Ir-Catalyzed enantioselective group transfer reactions.
Topics: Catalysis; Cyclopropanes; Imines; Iridium; Methane; Stereoisomerism | 2015 |
N-heterocyclic carbene metal complexes as bio-organometallic antimicrobial and anticancer drugs.
Topics: Animals; Anti-Infective Agents; Antineoplastic Agents; Bacteria; Bacterial Infections; Coordination Complexes; Heterocyclic Compounds; Humans; Metals; Methane; Neoplasms | 2015 |
The nature of chemical innovation: new enzymes by evolution.
Topics: Bacteria; Biocatalysis; Catalysis; Cytochrome P-450 Enzyme System; Directed Molecular Evolution; Enzymes; Evolution, Molecular; Hydrogen Bonding; Imines; Methane; Protein Engineering | 2015 |
NHC Backbone Configuration in Ruthenium-Catalyzed Olefin Metathesis.
Topics: Alkenes; Catalysis; Ligands; Methane; Molecular Structure; Ruthenium | 2016 |
Photo-cross-linked small-molecule affinity matrix as a tool for target identification of bioactive small molecules.
Topics: Biological Products; Methane; Molecular Structure; Proteins; Small Molecule Libraries | 2016 |
Recent Advances in Medicinal Applications of Coinage-Metal (Cu and Ag) N-Heterocyclic Carbene Complexes.
Topics: Chemistry, Pharmaceutical; Coordination Complexes; Copper; Heterocyclic Compounds; Methane; Silver | 2016 |
Non-natural carbenoid and nitrenoid insertion reactions catalyzed by heme proteins.
Topics: Alkenes; Aziridines; Catalysis; Hemeproteins; Imines; Methane | 2016 |
Cooperative Catalysis and Activation with N-Heterocyclic Carbenes.
Topics: Catalysis; Heterocyclic Compounds; Methane; Stereoisomerism | 2016 |
Mechanistic Insights into Gold Organometallic Compounds and their Biomedical Applications.
Topics: Animals; Anti-Bacterial Agents; Antimalarials; Antineoplastic Agents; Coordination Complexes; Gold; Humans; Methane; Mice; Structure-Activity Relationship | 2017 |
Metal Nanoparticles in Ionic Liquids.
Topics: Hydrogen Bonding; Imidazoles; Ionic Liquids; Metal Nanoparticles; Methane; Static Electricity; Viscosity | 2017 |
On the binding modes of metal NHC complexes with DNA secondary structures: implications for therapy and imaging.
Topics: Animals; Antineoplastic Agents; Binding Sites; DNA, Neoplasm; Heterocyclic Compounds; Humans; Metals; Methane; Molecular Imaging; Neoplasms; Nucleic Acid Conformation; Organometallic Compounds | 2017 |
Exploiting and engineering hemoproteins for abiological carbene and nitrene transfer reactions.
Topics: Biocatalysis; Cyclopropanes; Hemeproteins; Imines; Methane; Protein Engineering | 2017 |
Recent Developments in the Medicinal Applications of Silver-NHC Complexes and Imidazolium Salts.
Topics: Anti-Bacterial Agents; Heterocyclic Compounds; Imidazoles; Methane; Salts; Silver | 2017 |
Ligand-Promoted Palladium-Catalyzed Aerobic Oxidation Reactions.
Topics: 2,2'-Dipyridyl; Catalysis; Ligands; Methane; Oxidation-Reduction; Oxygen; Palladium; Pyridines; Quinolines; Safrole | 2018 |
Recent developments in the application of P450 based biocatalysts.
Topics: Bacteria; Biocatalysis; Biological Products; Cytochrome P-450 Enzyme System; Imines; Methane; Plants; Protein Engineering; Substrate Specificity; Yeasts | 2018 |
Recent Advances in the Synthesis of Spiroheterocycles via N-Heterocyclic Carbene Organocatalysis.
Topics: Catalysis; Heterocyclic Compounds; Methane; Spiro Compounds | 2017 |
Anticancer metal-N-heterocyclic carbene complexes of gold, platinum and palladium.
Topics: Animals; Antineoplastic Agents; Disease Models, Animal; Gold; Heterocyclic Compounds; Humans; Ligands; Methane; Molecular Probes; Palladium; Platinum; Sulfhydryl Compounds; Theranostic Nanomedicine | 2018 |
New insights in Au-NHCs complexes as anticancer agents.
Topics: Animals; Antineoplastic Agents; Cell Proliferation; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; Methane; Molecular Structure; Structure-Activity Relationship | 2018 |
Mitochondria-Targeting Anticancer Metal Complexes.
Topics: Antineoplastic Agents; Apoptosis; Coordination Complexes; DNA; Drug Discovery; Humans; Ions; Ligands; Membrane Potential, Mitochondrial; Metals; Methane; Mitochondria; Mitochondrial Proteins; Molecular Structure; Phosphines; Pyridines; Structure-Activity Relationship; Thioredoxin-Disulfide Reductase | 2019 |
Carbene Transfer Reactions Catalysed by Dyes of the Metalloporphyrin Group.
Topics: Metalloporphyrins; Methane | 2018 |
The Experimental Evidence in Support of Glycosylation Mechanisms at the S
Topics: Carbohydrate Conformation; Computer Simulation; Glycosides; Glycosylation; Hydrogen Bonding; Kinetics; Methane; Models, Chemical; Stereoisomerism | 2018 |
Functional Precision Polymers via Stereo- and Regioselective Polymerization Using Group 6 Metal Alkylidene and Group 6 and 8 Metal Alkylidene N-Heterocyclic Carbene Complexes.
Topics: Alkynes; Heterocyclic Compounds; Metals, Heavy; Methane; Molecular Structure; Organometallic Compounds; Polymerization; Polymers; Stereoisomerism | 2019 |
Recent advances in β-lactam synthesis.
Topics: Amides; Anti-Bacterial Agents; beta-Lactams; Catalysis; Chemistry Techniques, Synthetic; Metals; Methane; Oxidation-Reduction; Penicillins | 2018 |
Silver carbene complexes: An emerging class of anticancer agents.
Topics: Animals; Antineoplastic Agents; Coordination Complexes; Humans; Methane; Neoplasms; Silver | 2019 |
Recent advances in gold-NHC complexes with biological properties.
Topics: Antioxidants; Apoptosis; Coordination Complexes; Gold; Gram-Negative Bacteria; Gram-Positive Bacteria; Heterocyclic Compounds; Humans; Methane; Neoplasms | 2019 |
Recent advances in site-selective functionalization of carbohydrates mediated by organocatalysts.
Topics: Carbohydrates; Catalysis; Methane; Molecular Structure; Phosphoric Acids; Stereoisomerism | 2019 |
Adjusting the Structure and Electronic Properties of Carbons for Metal-Free Carbocatalysis of Organic Transformations.
Topics: Acids; Boron; Carbon; Catalysis; Electrochemical Techniques; Electrons; Methane; Models, Molecular; Nanostructures; Nitrogen; Oxidation-Reduction; Sulfur | 2019 |
Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and Their Application to Catalyst-Controlled C-H Functionalization.
Topics: Catalysis; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2019 |
Task-Specific Properties and Prospects of Ionic Liquids in Cross-Coupling Reactions.
Topics: Catalysis; Heterocyclic Compounds; Ionic Liquids; Ligands; Methane; Solvents; Transition Elements | 2019 |
N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis.
Topics: Catalysis; Coordination Complexes; Heterocyclic Compounds; Lewis Acids; Metals; Methane; Stereoisomerism | 2019 |
Organocatalysis Combined with Photocatalysis.
Topics: Aldehydes; Alkenes; Amines; Catalysis; Imines; Light; Methane; Stereoisomerism | 2019 |
Development of New Synthetic Reactions Using Hetero-Heavy Atoms and Their Application to Synthesis of Biofunctional Molecules.
Topics: Animals; Biological Products; Cell Proliferation; Histamine Agonists; Histamine Antagonists; Humans; Metals; Methane; Nitriles; Nucleosides | 2020 |
Recent progress on donor and donor-donor carbenes.
Topics: Azo Compounds; Catalysis; Cyclopropanes; Hydrazones; Metals; Methane; Molecular Structure; Stereoisomerism | 2020 |
N-Heterocyclic Carbene Complexes in C-H Activation Reactions.
Topics: Chemistry Techniques, Synthetic; Heterocyclic Compounds; Imidazoles; Methane; Organometallic Compounds; Oxazoles; Palladium; Thiazoles | 2020 |
C-H Functionalization via Iron-Catalyzed Carbene-Transfer Reactions.
Topics: Biocatalysis; Cyclization; Esters; Hydrogen Bonding; Iron; Methane; Stereoisomerism | 2020 |
Bifunctional N-Heterocyclic Carbenes Derived from l-Pyroglutamic Acid and Their Applications in Enantioselective Organocatalysis.
Topics: Catalysis; Heterocyclic Compounds; Methane; Organic Chemicals; Pyrrolidonecarboxylic Acid; Stereoisomerism | 2020 |
Sulfonate N-Heterocyclic Carbene-Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C-C, C-B, C-H, and C-Si Bonds.
Topics: Alkenes; Allyl Compounds; Boron Compounds; Catalysis; Coordination Complexes; Copper; Heterocyclic Compounds; Imines; Methane; Molecular Structure; Nitriles; Stereoisomerism; Sulfonic Acids | 2020 |
Mononuclear Cu Complexes Based on Nitrogen Heterocyclic Carbene: A Comprehensive Review.
Topics: Coordination Complexes; Copper; Heterocyclic Compounds; Methane; Molecular Structure; Nitrogen | 2020 |
Strain release - an old tool for new transformations.
Topics: Catalysis; Chemistry Techniques, Synthetic; Cycloaddition Reaction; Methane; Organometallic Compounds; Transition Elements | 2020 |
NHC Core Pincer Ligands Exhibiting Two Anionic Coordinating Extremities.
Topics: Anions; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure | 2020 |
Fluorinated-NHC Transition Metal Complexes: Leading Characters as Potential Anticancer Metallodrugs.
Topics: Animals; Antineoplastic Agents; Chemistry, Pharmaceutical; Coordination Complexes; Drug Screening Assays, Antitumor; Fluorine; Halogenation; Heterocyclic Compounds; Humans; Hydrocarbons, Fluorinated; Methane; Molecular Structure; Structure-Activity Relationship; Transition Elements | 2021 |
Calix[3]arene-Analogous Metacyclophanes: Synthesis, Structures and Properties with Infinite Potential.
Topics: Benzene Derivatives; Calixarenes; Chemistry, Organic; Cyclization; Drug Design; Hydrocarbons; Ligands; Metals; Methane; Molecular Conformation; Molecular Structure; Stereoisomerism | 2020 |
Topics: Anti-Infective Agents; Antineoplastic Agents; Bacteria; Coordination Complexes; Fungi; Heterocyclic Compounds; Humans; Metals, Heavy; Methane | 2020 |
Coinage Metal N-Heterocyclic Carbene Complexes: Recent Synthetic Strategies and Medicinal Applications.
Topics: Anti-Infective Agents; Antineoplastic Agents; Cell Survival; Coordination Complexes; Gram-Negative Bacteria; Gram-Positive Bacteria; Heterocyclic Compounds; Humans; Methane; Structure-Activity Relationship | 2021 |
New-to-nature chemistry from old protein machinery: carbene and nitrene transferases.
Topics: Hemeproteins; Imines; Methane; Transferases | 2021 |
Navigating the Unnatural Reaction Space: Directed Evolution of Heme Proteins for Selective Carbene and Nitrene Transfer.
Topics: Cytochrome P-450 Enzyme System; Hemeproteins; Imines; Iron Compounds; Methane; Molecular Structure | 2021 |
Asymmetric organocatalysis: an enabling technology for medicinal chemistry.
Topics: Amines; Antineoplastic Agents; Antiviral Agents; Biological Products; Catalysis; Chemistry, Pharmaceutical; Methane; Organic Chemicals; Phosphoric Acids; Stereoisomerism | 2021 |
Straightforward Construction and Functionalizations of Nitrogen-Containing Heterocycles Through Migratory Insertion of Metal-Carbenes/Nitrenes.
Topics: Catalysis; Imines; Methane; Nitrogen; Transition Elements | 2021 |
Glycosyl Oxocarbenium Ions: Structure, Conformation, Reactivity, and Interactions.
Topics: Glycosylation; Ions; Methane; Models, Molecular; Molecular Conformation | 2021 |
Silver(I)-N-heterocyclic carbene complexes challenge cancer; evaluation of their anticancer properties and in silico studies.
Topics: Heterocyclic Compounds; Methane; Neoplasms; Silver; Structure-Activity Relationship | 2021 |
Ruthenium Complexes Featuring Unsymmetrical N-Heterocyclic Carbene Ligands-Useful Olefin Metathesis Catalysts for Special Tasks.
Topics: Alkenes; Ligands; Methane; Ruthenium | 2021 |
Transition-Metal-Catalyzed C-H Bond Functionalization of Arenes/Heteroarenes via Tandem C-H Activation and Subsequent Carbene Migratory Insertion Strategy.
Topics: Catalysis; Metals; Methane; Transition Elements | 2021 |
Development of Novel Methodology Using Diazo Compounds and Metal Catalysts.
Topics: Azo Compounds; Catalysis; Metals, Heavy; Methane | 2021 |
Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes.
Topics: Catalysis; Methane | 2022 |
Recent advances in transition-metal-catalyzed carbene insertion to C-H bonds.
Topics: Carbon; Catalysis; Methane; Transition Elements | 2022 |
Recent Advances in Catalytic Alkyne Transformation via Copper Carbene Intermediates.
Topics: Alkynes; Catalysis; Copper; Methane | 2022 |
Transition metal-catalysed carbene- and nitrene transfer to carbon monoxide and isocyanides.
Topics: Carbon Monoxide; Cyanides; Imines; Methane; Transition Elements | 2022 |
Exploring Molecular Complexity by N-Heterocyclic Carbene Organocatalysis: New Activation and Reaction Diversity.
Topics: Catalysis; Heterocyclic Compounds; Methane; Stereoisomerism | 2023 |
Iodonium ylides: an emerging and alternative carbene precursor for C-H functionalizations.
Topics: Azo Compounds; Biological Products; Methane; Triazoles | 2022 |
A Review on Generation and Reactivity of the
Topics: Catalysis; Methane | 2022 |
Reactivity of quinone methides with carbenes generated from α-diazocarbonyl compounds and related compounds.
Topics: Catalysis; Indolequinones; Methane | 2022 |
Alkynyl Acylazolium: A Versatile 1,3-Bielectrophilic 3C-Synthon in NHC-Organocatalysis.
Topics: Catalysis; Esters; Methane | 2023 |
Metal complexes of xanthine and its derivatives: Synthesis and biological activity.
Topics: Anti-Bacterial Agents; Coordination Complexes; Heterocyclic Compounds; Methane; Xanthine | 2023 |
1864 other study(ies) available for carbene and methane
| Article | Year |
|---|---|
Application of 3-[3-(3-(trifluoromethyl)diazirin-3-yl)phenyl]-2,3- dihydroxypropionic acid, carbene-generating, cleavable cross-linking reagent for photoaffinity labeling.
Topics: Affinity Labels; Aziridines; Cross-Linking Reagents; Escherichia coli; Hydrocarbons; Methane; Molecular Structure; Ribosomes; RNA, Bacterial; RNA, Ribosomal, 23S; RNA, Transfer, Phe; Succinimides; Ultraviolet Rays | 1992 |
3-(Trifluoromethyl)-3-(m-isothiocyanophenyl)diazirine: synthesis and chemical characterization of a heterobifunctional carbene-generating crosslinking reagent.
Topics: Anion Exchange Protein 1, Erythrocyte; Anions; Azirines; Bacteriorhodopsins; Binding Sites; Biological Transport; Cross-Linking Reagents; Erythrocyte Membrane; Halobacterium; Humans; Hydrocarbons; Isothiocyanates; Membrane Proteins; Methane; Peptide Fragments; Photolysis; Serine Endopeptidases; Thermolysin; Thiocyanates | 1990 |
Studies of unusual simple molecules by neutralization-reionization mass spectrometry.
Topics: Butadienes; Chemical Phenomena; Chemistry; Ethylene Oxide; Free Radicals; Hydrocarbons; Ions; Mass Spectrometry; Methane; Molecular Structure; Thermodynamics | 1990 |
An analysis of magnetic cross-relaxation between water and methylene protons in a model system.
Topics: Animals; Bile; Dogs; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Polyethylene Glycols; Protons; Water | 1989 |
The mechanism of the suicidal, reductive inactivation of microsomal cytochrome P-450 by carbon tetrachloride.
Topics: Animals; Biotransformation; Carbon Monoxide; Carbon Tetrachloride; Cytochrome P-450 Enzyme Inhibitors; Cytochrome P-450 Enzyme System; Enzyme Induction; Heme; Hydrocarbons; Kinetics; Male; Methane; Microsomes, Liver; Oxidation-Reduction; Rats; Rats, Inbred Strains | 1988 |
A new carbene based heterobifunctional reagent. Photochemical crosslinking of aldolase.
Topics: Cross-Linking Reagents; Fructose-Bisphosphate Aldolase; Hydrocarbons; Methane; Photolysis | 1987 |
A carbene-yielding amino acid for incorporation into peptide photoaffinity reagents.
Topics: Affinity Labels; Azirines; Chemical Phenomena; Chemistry; Hydrocarbons; Methane; Peptides; Phenylalanine; Photochemistry; Spectrophotometry, Ultraviolet; Stereoisomerism | 1985 |
Photoaffinity labelling of peptide hormone receptors.
Topics: Affinity Labels; Animals; Azides; Calcium; Cells, Cultured; Free Radicals; Humans; Hydrocarbons; Melanocyte-Stimulating Hormones; Methane; Nitrogen; Photochemistry; Receptors, Cell Surface; Receptors, Pituitary Hormone | 1983 |
Identification of the lipid-binding site of phosphatidylcholine-transfer protein with phosphatidylcholine analogs containing photoactivable carbene precursors.
Topics: Amino Acid Sequence; Androgen-Binding Protein; Animals; Binding Sites; Carrier Proteins; Cattle; Hydrocarbons; Lipid Metabolism; Liver; Methane; Peptide Fragments; Phosphatidylcholines; Phospholipid Transfer Proteins; Photochemistry; Spectrometry, Fluorescence | 1983 |
Photoactivatable carbene-generating phospholipids: physical properties and use in detection of phase separations in lipid mixtures.
Topics: Calorimetry, Differential Scanning; Cross-Linking Reagents; Hydrocarbons; Liposomes; Methane; Oleic Acid; Oleic Acids; Palmitic Acids; Phospholipids; Photochemistry; Temperature | 1981 |
Resolution and sensitivity enhancement of heteronuclear correlation for methylene resonances via 2H enrichment and decoupling.
Topics: Carbon Isotopes; Escherichia coli; Free Radicals; Hydrocarbons; Hydrogen; Magnetic Resonance Spectroscopy; Methane; Protons; Sensitivity and Specificity; Thioredoxins | 1993 |
ANDANTE, a novel frequency-selective adiabatic pulse.
Topics: Algorithms; Fourier Analysis; Hydrocarbons; Image Enhancement; Lactates; Lactic Acid; Lipids; Magnetic Resonance Spectroscopy; Methane; Models, Structural; Signal Processing, Computer-Assisted | 1996 |
Synthesis and characterization of a carbene-generating biotinylated lactosylceramide analog as a novel chromogenic photoprobe for GM3 synthase.
Topics: Animals; Antigens, CD; Biotin; Brain; Carbohydrate Sequence; Cattle; Golgi Apparatus; Hydrocarbons; Lactosylceramides; Liver; Magnetic Resonance Spectroscopy; Methane; Molecular Probes; Molecular Sequence Data; Rats; Sialyltransferases; Spectrometry, Mass, Fast Atom Bombardment | 1996 |
An in vitro investigation of the reductive metabolism of chloroform.
Topics: Animals; Binding Sites; Chloroform; Formaldehyde; Hydrocarbons; Male; Methane; Methylene Chloride; Microsomes, Liver; Oxidation-Reduction; Phospholipids; Rats; Rats, Sprague-Dawley | 1995 |
Synthesis and characterization of a carbene-generating biotinylated N-acetylglucosamine for photoaffinity labeling of beta-(1-->4)-galactosyltransferase.
Topics: Acetylglucosamine; Affinity Labels; Aspartic Acid; Azo Compounds; Biotin; Electrophoresis, Polyacrylamide Gel; Galactosyltransferases; Humans; Hydrocarbons; Kinetics; Luminescent Measurements; Magnetic Resonance Spectroscopy; Mass Spectrometry; Methane; Molecular Structure; Photolysis; Recombinant Proteins; Spectrophotometry | 1996 |
Antimicrobial activity of carbene complexes of rhodium(I) and ruthenium(II).
Topics: Ampicillin; Anti-Bacterial Agents; Benzimidazoles; Enterococcus faecalis; Escherichia coli; Hydrocarbons; Methane; Microbial Sensitivity Tests; Penicillins; Pseudomonas aeruginosa; Rhodium; Ruthenium; Staphylococcus aureus | 1996 |
Neighboring methoxyl participation in the acid catalyzed methoxylation of methylene-interrupted fatty acids.
Topics: Catalysis; Fatty Acids; Gas Chromatography-Mass Spectrometry; Hydrocarbons; Hydrogen-Ion Concentration; Kinetics; Methane | 1997 |
Influence of excision of a methylene group from Glu-376 (Glu376-->Asp mutation) in the medium chain acyl-CoA dehydrogenase-catalyzed reaction.
Topics: Acyl Coenzyme A; Acyl-CoA Dehydrogenase; Acyl-CoA Dehydrogenases; Animals; Aspartic Acid; Catalysis; Enzyme Activation; Glutamic Acid; Humans; Hydrocarbons; Kinetics; Liver; Methane; Models, Molecular; Mutagenesis, Site-Directed; Oxidation-Reduction; Swine | 1998 |
Gradient, high-resolution, magic angle spinning 1H nuclear magnetic resonance spectroscopy of intact cells.
Topics: 3T3 Cells; Adipocytes; Animals; Cell Count; Cell Differentiation; Cell Line; Cell Membrane; Cell Survival; Choline; Coloring Agents; Diffusion; Hydrocarbons; Hydrogen; Inositol; Lipid Metabolism; Lipids; Magnetic Resonance Spectroscopy; Membrane Lipids; Methane; Mice; Phosphatidylcholines; Phospholipids; Phosphorylcholine; Triglycerides; Trypan Blue | 1998 |
Structural requirements for human inducible nitric oxide synthase substrates and substrate analogue inhibitors.
Topics: Arginine; Enzyme Activation; Enzyme Induction; Enzyme Inhibitors; Humans; Hydrocarbons; Lysine; Methane; Nitric Oxide Synthase; Nitric Oxide Synthase Type II; Structure-Activity Relationship; Substrate Specificity | 1998 |
Miscibility of phospholipids with identical headgroups and acyl chain lengths differing by two methylene units: effects of headgroup structure and headgroup charge.
Topics: Calorimetry, Differential Scanning; Computer Simulation; Hydrocarbons; Hydrogen-Ion Concentration; Lipid Bilayers; Methane; Phosphatidic Acids; Thermodynamics | 1998 |
Conformational study of DNA-RNA duplexes containing MMI substituted phosphodiester linkages by FTIR spectroscopy.
Topics: Carbohydrates; DNA; Hydrocarbons; Methane; Nucleic Acid Conformation; Nucleic Acid Heteroduplexes; RNA; Spectroscopy, Fourier Transform Infrared | 1998 |
The biosynthesis of mycolic acids in Mycobacterium tuberculosis. Enzymatic methyl(ene) transfer to acyl carrier protein bound meromycolic acid in vitro.
Topics: Acyl Carrier Protein; Amino Acid Sequence; Base Sequence; Cell-Free System; DNA Primers; Escherichia coli; Hydrocarbons; Methane; Methyltransferases; Molecular Sequence Data; Mycobacterium tuberculosis; Mycolic Acids; Recombinant Proteins | 1998 |
Methylene-interrupted double bond in polyunsaturated fatty acid is an essential structure for metabolism by the fatty acid chain elongation system of rat liver.
Topics: Acetyltransferases; Animals; Arachidonic Acid; Fatty Acid Elongases; Fatty Acids, Unsaturated; gamma-Linolenic Acid; Hydrocarbons; Liver; Male; Methane; Phospholipids; Rats; Rats, Sprague-Dawley; Triglycerides | 1998 |
Measurement of dipolar couplings for methylene and methyl sites in weakly oriented macromolecules and their use in structure determination.
Topics: Humans; Hydrocarbons; Image Processing, Computer-Assisted; Magnetic Resonance Spectroscopy; Methane; Protein Conformation; Ubiquitins | 1998 |
New methylene specific experiments for the measurement of scalar spin-spin coupling constants between protons attached to 13C.
Topics: Carbon Isotopes; Hydrocarbons; Image Processing, Computer-Assisted; Ion Exchange; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Protons | 1998 |
In vitro release of cytarabine from swellable matrices of CnEmCn triblock copolymers.
Topics: Antimetabolites, Antineoplastic; Chemical Phenomena; Chemistry, Pharmaceutical; Chemistry, Physical; Cytarabine; Delayed-Action Preparations; Hydrocarbons; Kinetics; Methane; Pharmaceutic Aids; Polyethylene Glycols | 1998 |
Quantification of plasma lipoprotein fractions by wavelet transform time-domain data processing of the proton nuclear magnetic resonance methylene spectral region.
Topics: Blood Proteins; Cholesterol; Humans; Hydrocarbons; Lipoproteins; Lipoproteins, HDL; Lipoproteins, IDL; Lipoproteins, LDL; Lipoproteins, VLDL; Magnetic Resonance Spectroscopy; Male; Methane | 1998 |
Synthesis and antiviral activity of novel isodideoxy nucleosides with exocyclic methylene.
Topics: Acyclovir; Antiviral Agents; Cell Survival; Cytomegalovirus; Dideoxynucleosides; Drug Design; Ganciclovir; Herpesvirus 1, Human; Herpesvirus 2, Human; HIV-1; Humans; Hydrocarbons; Indicators and Reagents; Methane; Microbial Sensitivity Tests; Structure-Activity Relationship; Xylose; Zidovudine | 1998 |
Analysis of simulated NMR order parameters for lipid bilayer structure determination.
Topics: 1,2-Dipalmitoylphosphatidylcholine; Biophysical Phenomena; Biophysics; Dimyristoylphosphatidylcholine; Hydrocarbons; Lipid Bilayers; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Thermodynamics | 1999 |
Measurement of intracellular triglyceride stores by H spectroscopy: validation in vivo.
Topics: Adipose Tissue; Adolescent; Adult; Animals; Dogs; Female; Humans; Hydrocarbons; Lipodystrophy; Liver; Magnetic Resonance Spectroscopy; Male; Methane; Middle Aged; Muscle, Skeletal; Norepinephrine; Obesity; Rabbits; Triglycerides | 1999 |
Solid phase synthesis and biological activities of [Arg8]-vasopressin methylenedithioether.
Topics: Animals; Arginine Vasopressin; Chromatography, High Pressure Liquid; Dose-Response Relationship, Drug; Female; Hydrocarbons; Magnetic Resonance Spectroscopy; Male; Mass Spectrometry; Methane; Rats; Rats, Wistar; Vasopressins | 1999 |
Elimination of difluorocarbene from the molecular ions of alpha, alpha,alpha-trifluorocresols with a fluorine atom migration in an ion trap mass spectrometer.
Topics: Cresols; Fluorine; Fluorine Compounds; Hydrocarbons; Hydrocarbons, Fluorinated; Mass Spectrometry; Methane | 1999 |
Preparation and properties of novel gramicidin S analogs possessing a tri-, tetra- or pentamethylene bridge between ornithine side chains.
Topics: Anti-Bacterial Agents; Bacillus subtilis; Circular Dichroism; Drug Evaluation, Preclinical; Escherichia coli; Gramicidin; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Microbial Sensitivity Tests; Ornithine; Protein Conformation; Staphylococcus aureus; Structure-Activity Relationship | 1999 |
The sulfonium ion linkage in myeloperoxidase. Direct spectroscopic detection by isotopic labeling and effect of mutation.
Topics: Amino Acid Substitution; Animals; Chlorides; CHO Cells; Cricetinae; Electron Spin Resonance Spectroscopy; Heme; Hydrocarbons; Hydrogen-Ion Concentration; Methane; Models, Chemical; Mutagenesis, Site-Directed; Oxidation-Reduction; Peroxidase; Spectroscopy, Fourier Transform Infrared; Spectrum Analysis, Raman; Sulfonium Compounds; Transfection | 1999 |
1H NMR imaging of residual dipolar couplings in cross-linked elastomers: dipolar-encoded longitudinal magnetization, double-quantum, and triple-quantum filters.
Topics: Algorithms; Butadienes; Elastomers; Electron Spin Resonance Spectroscopy; Hemiterpenes; Humans; Hydrocarbons; Hydrogen; Magnetic Resonance Spectroscopy; Magnetics; Methane; Pentanes; Polymers; Polystyrenes | 1999 |
Noninvasive evaluation of the malignant potential of intracranial meningiomas performed using proton magnetic resonance spectroscopy.
Topics: Adult; Aged; Aged, 80 and over; Antigens, Nuclear; Biomarkers, Tumor; Brain; Cell Division; Cell Transformation, Neoplastic; Choline; Creatine; Diagnosis, Differential; Energy Metabolism; Female; Humans; Hydrocarbons; Ki-67 Antigen; Lactic Acid; Magnetic Resonance Imaging; Magnetic Resonance Spectroscopy; Male; Meningeal Neoplasms; Meninges; Meningioma; Methane; Middle Aged; Necrosis; Neoplasm Recurrence, Local; Nuclear Proteins; Phosphocreatine; Prognosis; Reoperation | 1999 |
Control of enantioselectivity in catalytic metal carbene reactions.
Topics: Catalysis; Chemistry, Organic; Hydrocarbons; Lactams; Lactones; Metals; Methane; Models, Molecular; Molecular Conformation; Stereoisomerism | 1999 |
Molecular basis for the polyamine-ompF porin interactions: inhibitor and mutant studies.
Topics: Amino Acid Substitution; Bacterial Proteins; Binding Sites; Crystallography, X-Ray; Dose-Response Relationship, Drug; Electric Conductivity; Escherichia coli; Hydrocarbons; Kinetics; Liposomes; Methane; Models, Molecular; Molecular Weight; Mutagenesis, Site-Directed; Polyamines; Porins; Protein Binding; Static Electricity; Substrate Specificity | 2000 |
Combined structural and biochemical analysis of the H-T complex in the glycine decarboxylase cycle: evidence for a destabilization mechanism of the H-protein.
Topics: Amino Acid Oxidoreductases; Apoenzymes; Binding Sites; Carrier Proteins; Catalysis; Coenzymes; Computer Simulation; Enzyme Stability; Formaldehyde; Glycine Decarboxylase Complex; Glycine Decarboxylase Complex H-Protein; Glycine Dehydrogenase (Decarboxylating); Hydrocarbons; Kinetics; Methane; Methylamines; Models, Molecular; Nuclear Magnetic Resonance, Biomolecular; Oxidation-Reduction; Pisum sativum; Polyglutamic Acid; Protein Binding; Solutions; Tetrahydrofolates; Thermodynamics; Thioctic Acid | 2000 |
Construction of the bicyclo[3.1.0]hexane template of a conformationally locked carbocyclic adenosine via an olefin keto-carbene cycloaddition.
Topics: Adenosine; Alkenes; Bridged Bicyclo Compounds; Crystallography, X-Ray; Cyclization; Hydrocarbons; Indicators and Reagents; Methane; Molecular Conformation | 2000 |
Galactosyl transfer ability of beta-(1-->4)-galactosyltransferase toward 5a-carba-sugars.
Topics: Animals; Cattle; Galactose; Glucose; Hydrocarbons; Kinetics; Magnetic Resonance Spectroscopy; Methane; N-Acetyllactosamine Synthase; Oxygen; Substrate Specificity | 2000 |
Quantitative analysis of the kinetic constant of the reaction of N,N'-propylenedinicotinamide with the hydroxyl radical using dimethyl sulfoxide and deduction of its structure in chloroform.
Topics: Antioxidants; Chloroform; Dimethyl Sulfoxide; Free Radical Scavengers; Hydrocarbons; Hydroxyl Radical; Kinetics; Methane; Models, Chemical; Models, Molecular; Niacinamide | 2000 |
Generation of the enol of methyl mandelate by flash photolysis of methyl phenyldiazoacetate in aqueous solution and study of rates of ketonization of this enol in that medium.
Topics: Azo Compounds; Buffers; Catalysis; Hydrocarbons; Ketones; Kinetics; Mandelic Acids; Methane; Phenylacetates; Photolysis; Solutions; Water | 2000 |
High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands.
Topics: Alkenes; Amines; Drug Design; Hydrocarbons; Hydrocarbons, Chlorinated; Indicators and Reagents; Kinetics; Ligands; Methane; Models, Molecular; Molecular Structure; Palladium | 2000 |
Alternate modes of binding in two crystal structures of alkaline phosphatase-inhibitor complexes.
Topics: Alkaline Phosphatase; Binding Sites; Carbon; Crystallography, X-Ray; Escherichia coli; Hydrocarbons; Hydrogen Bonding; Kinetics; Methane; Models, Chemical; Models, Molecular; Molecular Sequence Data; Organophosphonates; Phosphonoacetic Acid; Protein Binding; Static Electricity; Sulfhydryl Compounds; Thermodynamics; Zinc | 2000 |
A new method for the simultaneous measurement of magnitude and sign of 1DCH and 1DHH dipolar couplings in methylene groups.
Topics: Carbon Isotopes; Glycine; Hydrocarbons; Methane; Nitrogen Isotopes; Nuclear Magnetic Resonance, Biomolecular; Protein Conformation; Ubiquitins | 2000 |
The relaxin receptor-binding site geometry suggests a novel gripping mode of interaction.
Topics: Amino Acid Sequence; Animals; Arginine; Binding Sites; Brain; Chromatography, High Pressure Liquid; Circular Dichroism; Disulfides; Dose-Response Relationship, Drug; Estrogens; Female; Guanidine; Humans; Hydrocarbons; Isoleucine; Kinetics; Methane; Mice; Models, Molecular; Molecular Sequence Data; Peptides; Phenylalanine; Protein Binding; Pubic Symphysis; Receptors, G-Protein-Coupled; Receptors, Peptide; Sequence Homology, Amino Acid; Thermodynamics; Ultraviolet Rays | 2000 |
Novel polyunsaturated n-alkenes in the marine diatom Rhizosolenia setigera.
Topics: Alkenes; Carbon; Chromatography, Gas; Chromatography, High Pressure Liquid; Diatoms; Gas Chromatography-Mass Spectrometry; Heptanes; Hydrocarbons; Lipids; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Temperature; Time Factors | 2000 |
alpha-methylene ordering of acyl chains differs in glucolipids and phosphatidylglycerol from Acholeplasma laidlawii membranes: (2)H-NMR quadrupole splittings from individual lipids in mixed bilayers.
Topics: Acholeplasma; Deuterium; Glycolipids; Hydrocarbons; Lipid Bilayers; Magnetic Resonance Spectroscopy; Mass Spectrometry; Membrane Lipids; Methane; Molecular Structure; Phosphatidylglycerols; X-Ray Diffraction | 2000 |
What is meant by the term methylene selectivity and how does it influence what I observe in carring out reverse-phase separations?
Topics: Chromatography, Liquid; Hydrocarbons; Methane | 2000 |
Total syntheses of (S)-(-)-zearalenone and lasiodiplodin reveal superior metathesis activity of ruthenium carbene complexes with imidazol-2-ylidene ligands.
Topics: Estrogens, Non-Steroidal; Hydrocarbons; Ligands; Methane; Ruthenium; Zearalenone | 2000 |
Influence of the substitution of 11-methylene, delta(15), and/or 18-methyl groups in norethisterone on receptor binding, transactivation assays and biological activities in animals.
Topics: Animals; Biological Assay; Breast Neoplasms; CHO Cells; Cricetinae; Dose-Response Relationship, Drug; Female; Humans; Hydrocarbons; Injections, Subcutaneous; Ligands; Male; Methane; Methylation; Norethindrone; Orchiectomy; Organ Size; Ovarian Follicle; Ovulation; Progesterone; Prostate; Protein Binding; Rabbits; Rats; Receptors, Androgen; Receptors, Progesterone; Substrate Specificity; Transcriptional Activation; Tumor Cells, Cultured | 2000 |
Contraceptive progestins. Various 11-substituents combined with four 17-substituents: 17alpha-ethynyl, five- and six-membered spiromethylene ethers or six-membered spiromethylene lactones.
Topics: Administration, Oral; Androgens; Animals; Binding Sites; CHO Cells; Cricetinae; Dose-Response Relationship, Drug; Ethers; Female; Humans; Hydrocarbons; Injections, Subcutaneous; Lactones; Methane; Orchiectomy; Ovulation; Progestins; Rabbits; Rats; Rats, Sprague-Dawley; Receptors, Androgen; Receptors, Glucocorticoid; Receptors, Progesterone; Spiro Compounds; Transcriptional Activation; Tumor Cells, Cultured | 2000 |
Improved stereoselective synthesis of optically active methylene lactone, key intermediate for the synthesis of 1,2-oxidized furofuran lignan, by direct alpha-methylenation to butanolide.
Topics: 4-Butyrolactone; Dioxoles; Furans; Hydrocarbons; Lignans; Magnetic Resonance Spectroscopy; Methane; Oxidation-Reduction; Spectrometry, Mass, Electrospray Ionization; Stereoisomerism | 2000 |
Methylene as a possible universal footprinting reagent that will include hydrophobic surface areas: overview and feasibility: properties of diazirine as a precursor.
Topics: Animals; Chickens; Diazomethane; Hydrocarbons; Indicators and Reagents; Methane; Muramidase; Photolysis; Polymers; Protein Conformation; Proteins; Solvents; Spectrometry, Mass, Electrospray Ionization | 2000 |
Total synthesis of the calphostins: application of fischer carbene complexes and thermodynamic control of atropisomers.
Topics: Hydrocarbons; Isomerism; Methane; Molecular Structure; Naphthalenes; Spectrum Analysis; Thermodynamics | 2001 |
Intramolecular C-H insertion reactions of (eta(5)-cyclopentadienyl)dicarbonyliron carbene complexes: scope of the reactions and application to the synthesis of (+/-)-sterpurene and (+/-)-pentalenene.
Topics: Cyclopentanes; Fungi; Hydrocarbons; Iron; Methane; Organometallic Compounds; Sesquiterpenes | 2001 |
First examples of stable arenium ions from large methylene-bridged polycyclic aromatic hydrocarbons (PAHs). Directive effects and charge delocalization mode.
Topics: Hydrocarbons; Magnetic Resonance Spectroscopy; Mass Spectrometry; Methane; Molecular Conformation; Polycyclic Aromatic Hydrocarbons | 2001 |
De novo synthesis of a methylene-bridged Neu5Ac-alpha-(2,3)-gal C-disaccharide.
Topics: Alkenes; Carbohydrate Sequence; Disaccharides; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Molecular Sequence Data | 2001 |
Selective synthesis of 4-methoxyestrogen from 4-hydroxyestrogen.
Topics: Estradiol; Estrogens; Estrogens, Catechol; Hydrocarbons; Methane; Methylation; Temperature | 2001 |
Self-assembled molecular structures as ultrasonically-responsive barrier membranes for pulsatile drug delivery.
Topics: Adipocytes; Animals; Anti-Infective Agents; Cell Line; Ciprofloxacin; Deoxyglucose; Drug Carriers; Drug Delivery Systems; Humans; Hydrocarbons; Hydrogels; Insulin; Methane; Mice; Polymers; Spectroscopy, Fourier Transform Infrared; Time Factors; Ultrasonics | 2001 |
Ab initio predictions on the rotational spectra of carbon-chain carbene molecules.
Topics: Astronomical Phenomena; Astronomy; Carbon; Computer Simulation; Extraterrestrial Environment; Hydrocarbons; Methane; Models, Molecular; Solar System; Spectrum Analysis | 1992 |
First astronomical detection of the cumulene carbon chain molecule H2C6 in TMC-1.
Topics: Astronomy; Carbon; Extraterrestrial Environment; Gases; Hydrocarbons; Methane; Models, Chemical; Spectrum Analysis | 1997 |
Self-association of facially amphiphilic methylene bridged glycoluril dimers.
Topics: Alkynes; Dimerization; Hydrocarbons; Hydrogen Bonding; Imidazoles; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation; Temperature; Thermodynamics | 2001 |
Olefin metathesis involving ruthenium enoic carbene complexes.
Topics: Alkenes; Hydrocarbons; Methane; Organometallic Compounds; Ruthenium | 2001 |
Reaction of hen egg white lysozyme with Fischer-type metallocarbene complexes. Characterization of the conjugates and determination of the metal complex binding sites.
Topics: Animals; Binding Sites; Chickens; Chromatography, High Pressure Liquid; Egg Proteins; Female; Hydrocarbons; Methane; Muramidase; Organometallic Compounds; Peptide Mapping; Protein Binding; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; Trypsin | 2001 |
Fluoro artemisinins: difluoromethylene ketones.
Topics: Animals; Antimalarials; Artemisinins; Drugs, Chinese Herbal; Fluorenes; Hydrocarbons; Ketones; Methane; Plasmodium falciparum; Sesquiterpenes | 2001 |
From 2,2'-methylenedifuran to all stereomeric pentadecane-1,3,5,7,9,11,13,15-octols.
Topics: Alkanes; Furans; Hydrocarbons; Methane; Stereoisomerism | 2001 |
Synthesis of novel (2R,4R)- and (2S,4S)-iso dideoxynucleosides with exocyclic methylene as potential antiviral agents.
Topics: Antiviral Agents; Base Sequence; Cell Line; Dideoxynucleosides; DNA Primers; Hepatitis B virus; Humans; Hydrocarbons; Methane; Spectrum Analysis | 2002 |
Sympathetic cotransmission in rabbit saphenous artery in vitro: effect of electric stimulation and potentiation by alpha,beta-methylene ATP.
Topics: Adenosine Triphosphate; Adrenergic alpha-Antagonists; Adrenergic Fibers; Animals; Arteries; Drug Synergism; Electric Stimulation; Hindlimb; Hydrocarbons; In Vitro Techniques; Male; Methane; Prazosin; Rabbits; Receptors, Purinergic P2; Receptors, Purinergic P2X; Synaptic Transmission; Vasoconstriction | 2001 |
DNA sequence recognition in the minor groove by crosslinked polyamides: The effect of N-terminal head group and linker length on binding affinity and specificity.
Topics: Binding Sites; Cross-Linking Reagents; Deoxyribonuclease I; DNA; DNA-Binding Proteins; Hydrocarbons; Hydrogen Bonding; Kinetics; Methane; Models, Chemical; Models, Statistical; Nucleic Acid Conformation; Nylons; Protein Binding; Repetitive Sequences, Nucleic Acid | 2002 |
Chromium vinylidene carbenoids: stereospecific synthesis of (Z)-2-chloroalk-2-en-1-ols.
Topics: Alcohols; Chromium; Hydrocarbons; Methane; Vinyl Compounds | 2001 |
Synthesis, structure investigations, and antimicrobial activity of selected s-trans-6-aryl-4-isopropyl-2-[2-[(E)-1-phenylalkylidene]-(E)-hydrazino]-1,4-dihydropyrimidine hydrochlorides.
Topics: Anti-Bacterial Agents; Anti-Infective Agents; Antifungal Agents; Candida albicans; Gram-Negative Bacteria; Gram-Positive Bacteria; Guanidines; Hydrocarbons; Methane; Microbial Sensitivity Tests; Pyrimidines | 2002 |
Preferential C-binding versus N-binding in imidazole depends on the metal fragment involved.
Topics: Catalysis; Chemical Phenomena; Chemistry, Physical; Crystallography, X-Ray; Histidine; Hydrocarbons; Imidazoles; Ligands; Metals; Methane; Molecular Structure; Proteins; Stereoisomerism; Thermodynamics | 2002 |
First example of N-heterocyclic carbenes as catalysts for living polymerization: organocatalytic ring-opening polymerization of cyclic esters.
Topics: Caproates; Hydrocarbons; Lactones; Magnetic Resonance Spectroscopy; Methane; Polyesters | 2002 |
Reaction of 1-alkylthioisoquinolinium salts with active methylene compounds.
Topics: Hydrocarbons; Isoquinolines; Methane | 2002 |
Insights into the formation and degradation mechanisms of methylenedinitramine during the incubation of RDX with anaerobic sludge.
Topics: Bacteria, Anaerobic; Biodegradation, Environmental; Hydrocarbons; Hydrolysis; Methane; Phenylenediamines; Rodenticides; Sewage; Triazines | 2002 |
Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole.
Topics: Benzimidazoles; Catalysis; Hydrocarbons; Kinetics; Methane; Thermodynamics | 2002 |
Correlation of poly(methylene)-rich amorphous aliphatic domains in humic substances with sorption of a nonpolar organic contaminant phenanthrene.
Topics: Adsorption; Humic Substances; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Organic Chemicals; Phenanthrenes; Polymers; Water Pollutants, Chemical | 2002 |
The Renner effect in triatomic molecules with application to CH+, MgNC and NH2.
Topics: Algorithms; Chemical Phenomena; Chemistry, Physical; Cyanides; Hydrocarbons; Magnesium; Magnesium Compounds; Methane; Models, Theoretical; Nitrogen; Spectrophotometry, Infrared; Vibration | 2002 |
Unusual reactivity of methylene group adjacent to pyridine-2-carboxamido moiety in iron(III) and cobalt(III) complexes.
Topics: Cobalt; Crystallography, X-Ray; Ferric Compounds; Hydrocarbons; Ligands; Methane; Molecular Conformation; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Pyridines; Spectroscopy, Fourier Transform Infrared; Structure-Activity Relationship | 2002 |
Synthesis of furano[2,3-c]pyran-3-one and thieno[2,3-c]pyran-3-one derivatives through the coupling of 3-alkynyl-2-heteroaromatic carboxaldehydes with Fischer carbene complexes: total synthesis of a Baccharis-derived cadinene derivative.
Topics: Aldehydes; Alkenes; Alkynes; Asteraceae; Biological Factors; Catalysis; Cyclization; Furans; Hydrocarbons; Hydrolysis; Ketones; Kinetics; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Pyrones; Stereoisomerism; Thermodynamics; Thiophenes | 2002 |
Inversion of the direction of stereoinduction in the coupling of chiral gamma,delta-unsaturated Fischer carbene complexes with o-ethynylbenzaldehyde.
Topics: Alkynes; Benzaldehydes; Hydrocarbons; Kinetics; Methane; Models, Molecular; Stereoisomerism; Steroids; Thermodynamics | 2002 |
Characterization and comparison of the chromatographic performance of conventional, polar-embedded, and polar-endcapped reversed-phase liquid chromatography stationary phases.
Topics: Chromatography, High Pressure Liquid; Hydrocarbons; Hydrogen Bonding; Hydrogen-Ion Concentration; Methane; Sensitivity and Specificity; Silanes | 2002 |
Solvent-controlled assembling by hydrogen bridges and halogen-halogen interactions of novel organotin oxo clusters.
Topics: Halogens; Hydrocarbons; Hydrogen Bonding; Methane; Molecular Structure; Organotin Compounds; Polymers; Solvents | 2002 |
Methylene-bridged glycoluril dimers: synthetic methods.
Topics: Alkynes; Crystallography, X-Ray; Dimerization; Heterocyclic Compounds, 4 or More Rings; Hydrocarbons; Imidazoles; Methane; Models, Molecular; Molecular Conformation | 2002 |
A 13C NMR study on the adsorption characteristics of HEMA to dentinal collagen.
Topics: Acid Etching, Dental; Adhesiveness; Adsorption; Animals; Carbon; Carbon Isotopes; Cattle; Collagen; Dentin; Dentin-Bonding Agents; Electron Spin Resonance Spectroscopy; Hydrocarbons; Hydrogen Bonding; Hydrogen-Ion Concentration; Hydroxides; Magnetic Resonance Spectroscopy; Methacrylates; Methane | 2002 |
Synthesis, structure, and reactions of a three-coordinate nickel-carbene complex, [1,2-Bis(di-tert-butylphosphino)ethane]Ni=CPh(2).
Topics: Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Nickel; Organometallic Compounds; X-Ray Diffraction | 2002 |
Asymmetric synthesis of anti-homopropargylic alcohols from aldehydes and chiral sulfonimidoyl substituted bis(allyl)titanium complexes through generation and elimination of novel chiral alkylidenecarbene (dimethylamino)sulfoxonium ylides.
Topics: Aldehydes; Alkynes; Dapsone; Hydrocarbons; Methane; Molecular Structure; Organometallic Compounds; Propanols; Stereoisomerism; Sulfones; Titanium | 2002 |
Alkynyliodonium salts in organic synthesis. Application to the total synthesis of the tropoloisoquinoline alkaloid pareitropone.
Topics: Alkaloids; Antineoplastic Agents, Phytogenic; Hydrocarbons; Isoquinolines; Methane; Onium Compounds | 2002 |
Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl)carbenes: isolation, X-ray crystal structures, and carbon atom transfer reactions with hydrocarbons.
Topics: Carbon; Crystallography, X-Ray; Ferric Compounds; Hydrocarbons; Iron; Metalloporphyrins; Methane; Models, Molecular; Molecular Structure; Porphyrins | 2002 |
Total synthesis of the tropoloisoquinoline alkaloid pareitropone via alkynyliodonium salt chemistry and related studies.
Topics: Alkaloids; Antineoplastic Agents, Phytogenic; Combinatorial Chemistry Techniques; Hydrocarbons; Isoquinolines; Methane; Molecular Structure; Onium Compounds | 2002 |
Construction of [4.3.1]propellanes via molybdenum fischer carbene complexes.
Topics: Catalysis; Cyclization; Heterocyclic Compounds, Bridged-Ring; Hydrocarbons; Methane; Molecular Structure; Molybdenum; Polycyclic Aromatic Hydrocarbons; Temperature | 2002 |
Synthesis and antiviral activity of novel exomethylene cyclopropyl pyrimidine nucleosides.
Topics: Antiviral Agents; Heterocyclic Compounds; Hydrocarbons; Methane; Pyrimidine Nucleosides | 2002 |
Unusual reactivity of molecular oxygen with pi-allylnickel(N-heterocyclic carbene) chloride complexes.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Hydrocarbons; Kinetics; Methane; Molecular Structure; Nickel; Organometallic Compounds; Oxygen | 2003 |
Relaxant properties mediated by nitroglycerin in aortic coarctation hypertensive rats.
Topics: Animals; Aorta, Abdominal; Aorta, Thoracic; Aortic Coarctation; Blood Pressure; Charybdotoxin; Disease Models, Animal; Dose-Response Relationship, Drug; Drug Combinations; Heart Rate; Hydrocarbons; Hypertension; Male; Methane; Models, Cardiovascular; Muscle, Smooth, Vascular; Nitroglycerin; Norepinephrine; Rats; Rats, Wistar; Systole; Time Factors; Vasoconstriction; Vasoconstrictor Agents; Vasodilation; Vasodilator Agents | 2002 |
Electrospray mass spectra of group 6 (Fischer) carbenes in the presence of electron-donor compounds.
Topics: Chromium; Electrons; Heterocyclic Compounds; Hydrocarbons; Hydroquinones; Ions; Methane; Nitriles; Spectrometry, Mass, Electrospray Ionization; Tolonium Chloride; Tungsten | 2003 |
Synthesis of 3,3'-(1-piperidino)substituted methylene-bis-isoxazoles preventing stimulus-induced leukocytes activation.
Topics: Humans; Hydrocarbons; Isoxazoles; Leukocytes; Methane; Piperidines | 2003 |
A study into the possible homoaromatic nature of some related carbene and cationic intermediates with the potential for transannular interaction.
Topics: Bridged-Ring Compounds; Chemical Phenomena; Chemistry, Physical; Cyclization; Hydrocarbons; Methane; Models, Chemical; Molecular Conformation; Molecular Structure; Polycyclic Aromatic Hydrocarbons | 2003 |
Synthesis and activity of ruthenium alkylidene complexes coordinated with phosphine and N-heterocyclic carbene ligands.
Topics: Alkenes; Crystallography, X-Ray; Heterocyclic Compounds; Hydrocarbons; Imidazoles; Ligands; Methane; Molecular Structure; Organometallic Compounds; Phosphines; Ruthenium; Triazoles | 2003 |
Solvent-controlled diastereoselective synthesis of cyclopentane derivatives by a [3 + 2] cyclization reaction of alpha,beta-disubstituted (alkenyl)(methoxy)carbene complexes with methyl ketone lithium enolates.
Topics: Aldehydes; Cyclization; Cyclopentanes; Hydrocarbons; Ketones; Lithium; Methane; Organometallic Compounds; Solvents; Stereoisomerism | 2003 |
Normal mode analyses of methyl palmitate all-trans and disordered forms in wagging progressive region.
Topics: Hydrocarbons; Kinetics; Methane; Models, Chemical; Models, Molecular; Palmitates; Protein Conformation; Spectrophotometry, Infrared; Triglycerides | 2003 |
New insights on the structure of algaenan from Botryoccocus braunii race A and its hexane insoluble botryals based on multidimensional NMR spectroscopy and electrospray-mass spectrometry techniques.
Topics: Aldehydes; Biopolymers; Chlorophyta; Hexanes; Hydrocarbons; Methane; Molecular Structure; Molecular Weight; Nuclear Magnetic Resonance, Biomolecular; Solubility; Spectrometry, Mass, Electrospray Ionization | 2003 |
Synthesis, characterization, inequivalency of methylene proton and proton lability in the amino ligand of trans-[dichloro[(N-ferrocenyl methyl)amine](eta2-ethene)platinum] complexes.
Topics: Carbon; Ferrous Compounds; Hydrocarbons; Hydrogen; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Platinum; Protons; Solvents | 2003 |
Synthesis of (3,4) beta-methylenecepham and (3,4) beta-methylene-carbacepham via intramolecular carbene addition to double bond.
Topics: Anti-Bacterial Agents; beta-Lactams; Hydrocarbons; Methane; Molecular Conformation | 2003 |
Application of modified Mosher's method for primary alcohols with a methyl group at C2 position.
Topics: Alcohols; Hydrocarbons; Methane; Phenylacetates | 2003 |
Probing electrostatic channeling in protozoal bifunctional thymidylate synthase-dihydrofolate reductase using site-directed mutagenesis.
Topics: Animals; Binding Sites; Catalysis; Crystallization; Enzyme Stability; Fluorodeoxyuridylate; Folic Acid; Hydrocarbons; Kinetics; Leishmania major; Methane; Models, Molecular; Molecular Structure; Multienzyme Complexes; Mutagenesis, Site-Directed; NADP; Quinazolines; Spectrophotometry; Static Electricity; Structure-Activity Relationship; Substrate Specificity; Tetrahydrofolate Dehydrogenase; Tetrahydrofolates; Thymidylate Synthase | 2003 |
A tandem metal carbene cyclization-cycloaddition approach to the pseudolaric acids.
Topics: Antifungal Agents; Antineoplastic Agents; Catalysis; Combinatorial Chemistry Techniques; Cyclization; Diterpenes; Hydrocarbons; Indicators and Reagents; Methane; Models, Molecular; Stereoisomerism | 2003 |
Cross-correlation suppressed T1 and NOE experiments for protein side-chain 13CH2 groups.
Topics: Amino Acids; Carbon Radioisotopes; Humans; Hydrocarbons; Methane; Nuclear Magnetic Resonance, Biomolecular; Proteins; Ubiquitin | 2003 |
Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study.
Topics: Amines; Dansyl Compounds; Fluorescence Resonance Energy Transfer; Hydrocarbons; Hydrocarbons, Aromatic; Ligands; Methane; Phosphines; Piperazines | 2003 |
Synthesis of pyrroles through coupling of enyne-hydrazones with Fischer carbene complexes.
Topics: Alkynes; Hydrazones; Hydrocarbons; Imines; Methane; Pyrroles; Stereoisomerism | 2003 |
Mechanism of xanthine oxidase catalyzed biotransformation of HMX under anaerobic conditions.
Topics: Azocines; Carbon; Dose-Response Relationship, Drug; Electrons; Formaldehyde; Formates; Heterocyclic Compounds, 1-Ring; Hydrocarbons; Hydrogen-Ion Concentration; Methane; Models, Chemical; NAD; Nitrites; Nitrogen; Nitrous Oxide; Phenylenediamines; Quaternary Ammonium Compounds; Temperature; Time Factors; Xanthine Oxidase | 2003 |
Biosynthesis of phytosterols. Kinetic mechanism for the enzymatic C-methylation of sterols.
Topics: Binding, Competitive; Catalysis; Chromatography, Gel; DNA, Complementary; Dose-Response Relationship, Drug; Electrophoresis, Polyacrylamide Gel; Escherichia coli; Glycine max; Hydrocarbons; Kinetics; Methane; Methylation; Models, Chemical; Phenol; Phytosterols; S-Adenosylmethionine; Substrate Specificity; Time Factors; Triterpenes | 2003 |
Preparation of ternary platinum(II) complexes with N-(omega-phenylalkyl)-1,2-ethanediamine and 2,2'-dipyridine and the effect of the methylene chain length of the N-(omega-phenylalkyl)-1,2-ethanediamine in the complexes on intermolecular interactions with
Topics: 2,2'-Dipyridyl; Arylsulfonates; Ethylenediamines; Hydrocarbons; Ligands; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Organoplatinum Compounds | 2003 |
Inhibition of ICAM-1 gene expression by antisense 2',4'-BNA oligonucleotides.
Topics: Base Sequence; Cells, Cultured; DNA; Gene Expression; Humans; Hydrocarbons; Intercellular Adhesion Molecule-1; Methane; Nucleic Acid Hybridization; Oligonucleotides, Antisense; RNA, Complementary | 2001 |
Conjugate reduction of alpha,beta-unsaturated carbonyl compounds catalyzed by a copper carbene complex.
Topics: Catalysis; Copper; Hydrocarbons; Methane | 2003 |
Could assessment of glioma methylene lipid resonance by in vivo (1)H-MRS be of clinical value?
Topics: Biomarkers, Tumor; Brain Neoplasms; Female; Glioma; Humans; Hydrocarbons; Lipid Metabolism; Magnetic Resonance Spectroscopy; Male; Methane | 2003 |
Structure-activity relationships of the peptide deformylase inhibitor BB-3497: modification of the methylene spacer and the P1' side chain.
Topics: Amidohydrolases; Anti-Bacterial Agents; Enzyme Inhibitors; Hydrocarbons; Hydroxamic Acids; Hydroxylamine; Inhibitory Concentration 50; Metals; Methane; Microbial Sensitivity Tests; Molecular Mimicry; Oligopeptides; Structure-Activity Relationship | 2003 |
The analogue of thymidine triphosphate containing a methylene group in place of the 5' oxygen can serve as a substrate for reverse transcriptase.
Topics: Animals; Beta-Globulins; Hydrocarbons; Methane; Mice; Moloney murine leukemia virus; Oxygen; Rabbits; RNA-Directed DNA Polymerase; Thionucleotides; Thymine Nucleotides | 2003 |
An ionic liquid-supported ruthenium carbene complex: a robust and recyclable catalyst for ring-closing olefin metathesis in ionic liquids.
Topics: Alkenes; Biological Factors; Catalysis; Cyclization; Hydrocarbons; Hydrocarbons, Cyclic; Methane; Organometallic Compounds; Ruthenium | 2003 |
Role of phenolic O-H and methylene hydrogen on the free radical reactions and antioxidant activity of curcumin.
Topics: Animals; Antineoplastic Agents; Antioxidants; Cobalt Radioisotopes; Curcumin; Free Radicals; Gamma Rays; Hydrocarbons; Hydrogen; Hydroxides; Kinetics; Lipid Peroxidation; Male; Methane; Microsomes, Liver; Oxidation-Reduction; Phenols; Rats; Rats, Wistar; Thiobarbituric Acid Reactive Substances | 2003 |
Sonogashira coupling using bulky palladium-phenanthryl imidazolium carbene catalysis.
Topics: Acetylene; Catalysis; Copper; Hydrocarbons; Imidazoles; Ligands; Methane; Molecular Structure; Palladium; Phenanthrenes | 2003 |
Cycloheptadiene ring synthesis by tandem intermolecular enyne metathesis.
Topics: Alkadienes; Alkynes; Catalysis; Cyclization; Cycloheptanes; Cyclopentanes; Hydrocarbons; Methane; Molecular Structure; Ruthenium; Stereoisomerism; Temperature | 2003 |
A third unsaturated amino acid in groundnut plants: evidence for the occurrence of gamma-amino-alpha-methylene-butyric acid.
Topics: Amino Acids; Arachis; Butyrates; Methane; Plants | 1953 |
Benzothiazoles. XII. Studies on reaction between 2-chlorobenzothiazoles and compounds possessing reactive methylene groups.
Topics: Acetoacetates; Benzothiazoles; Malonates; Methane; Thiazoles | 1953 |
gamma-Methylene-alpha-oxoglutaric acid: a constituent of groundnut plants (Arachis hypogaea).
Topics: Arachis; Gamma Rays; Keto Acids; Ketones; Methane; Plants | 1954 |
[Chromoscopic examination of the stomach with 1% methylene blue solution].
Topics: Gastric Juice; Methane; Methylene Blue; Peptic Ulcer | 1954 |
[Phenomenon of antagonism between orotic acid and carboxy-methylene-hydantoin].
Topics: Anticonvulsants; Hydantoins; Imidazoles; Methane; Orotic Acid | 1956 |
Hesperidin-methylene-carboxy-chalcone in chronic kidney diseases.
Topics: Chalcone; Flavones; Hesperidin; Humans; Kidney Diseases; Methane; Renal Insufficiency, Chronic | 1957 |
Hesperidin-methylene-carboxy-chalcone in arthritis, bursitis and myositis.
Topics: Arthritis; Bursitis; Chalcone; Flavones; Hesperidin; Humans; Methane; Myositis | 1957 |
Trial of poly(methylene-4-hydroxy-benzenearsonic acid) in amebiasis.
Topics: Amebiasis; Arsenicals; Dysentery, Amebic; Methane | 1957 |
[A drug with tetanizing effect on frogs; secondary piperidine methylene-disalicylate].
Topics: Animals; Anura; Humans; Methane; Piperidines | 1957 |
[Pharmacology of a new chlorinated insecticidal hydrocarbon: 1,3,4,5,6,7,10,10-octachloro-4,7-methylene-4,7,8,9-tetrahydrophthalan (omtan)].
Topics: Hydrocarbons, Chlorinated; Insecticides; Methane | 1957 |
Mono-derivatives of methylene citric acid.
Topics: Citrates; Citric Acid; Methane | 1958 |
Pharmacology of some mono-derivatives of methylene citric acid.
Topics: Citrates; Citric Acid; Methane | 1958 |
Albedocone in osteoarthritis (hesperidin-methylene-carboxychalcone).
Topics: Flavonoids; Hesperidin; Humans; Methane; Osteoarthritis; Vitamins | 1959 |
The toxicity of bromochloromethane (methylene chlorobromide) as determined on laboratory animals.
Topics: Animals; Animals, Laboratory; Hydrocarbons, Halogenated; Methane | 1960 |
[Isolation of 24-methylene cholesterol from the pollen of different plants].
Topics: Cholesterol; Methane; Plants; Pollen | 1960 |
[Proposals for DAB 7. Part 1. Methylene blue, benzoic acid, sodium benzoate].
Topics: Benzoic Acid; Humans; Methane; Methylene Blue; Sodium Benzoate | 1960 |
Isolation of 24-methylene-cholesterol from honey bees (Apis mellifica L.
Topics: Animals; Bees; Cholesterol; Methane; Sterols | 1959 |
Antitumoral action of new sarcomycin derivatives. I. Importance of ethyl radical and substituted methylene groups.
Topics: Antineoplastic Agents; Methane | 1961 |
[On the condensation of acid amides with active methylene compounds and the preparation of new thiazole derivatives].
Topics: Amides; Hydrocarbons; Methane; Thiazoles | 1962 |
[On the condensation of flavones with reactive methylene compounds].
Topics: Flavones; Methane; Pyrans | 1962 |
[Studies on 7-membered ring compounds. V. The reaction of 2-amino-3-bromotropone with active methylene compounds. (1)].
Topics: Hydrocarbons; Methane; Organic Chemicals | 1962 |
[Studies on seven-membered ring compounds. VI. The reaction of 2-amino-3-bromotropone with active methylene compounds. 2].
Topics: Amines; Hydrocarbons; Methane; Organic Chemicals | 1962 |
[Studies on seven-membered ring compounds. VII. The reaction of 2-amino-3-bromotropone with active methylene compounds. 3].
Topics: Amines; Methane; Organic Chemicals | 1962 |
[Identification of cis-methylene-9,10-hexadecanoic acid as a constituent of certain bacterial lipids].
Topics: Escherichia coli; Fatty Acids; Lipids; Methane; Palmitic Acid; Yersinia pestis | 1962 |
On the reaction of 4-quinazolinecarbonitrile with nucleophilic reagnets. IV. Reaction of 4-quinazolinecarbonitrile with active methylene compounds.
Topics: Cyanides; Heterocyclic Compounds; Methane; Quinolines | 1962 |
Some aspects of the fate of hexachlorophene (2,2' methylene bis (3.4.6. trichlorophenol) in rabbits, rats and dairy cattle.
Topics: Animals; Chlorophenols; Hexachlorophene; Lagomorpha; Methane; Rabbits; Rats | 1962 |
16-METHYLENE-PREDNISOLONE: ADRENAL SUPPRESSION SHOWN BY GAS-CHROMATOGRAPHY.
Topics: Adrenal Insufficiency; Chromatography; Humans; Methane; Methylprednisolone; Prednisolone; Urine | 1963 |
[SYNTHESIS OF PAPAVERINE DERIVATIVES. (12). OXIDATION OF METHYLENE GROUP OF 1-(3,4-DIMETHOXYBENZYL)-6,7-DIMETHOXY-3,4-DIHYDRO(AND 1,2,3,4-TETRAHYDRO)ISOQUINOLINE BY ALUMINA-CHROMATOGRAPHY. (STUDIES ON THE SYNTHESES OF HETEROCYCLIC COMPOUNDS. LXXXVI.)].
Topics: Aluminum Oxide; Chemistry, Pharmaceutical; Chromatography; Isoquinolines; Methane; Oxidation-Reduction; Papaverine; Quinolines; Research | 1963 |
[NEW PHENOLIC ETHERS. I. SYNTHESIS AND PHARMACOLOGY OF ALPHA-GLYCERYL ETHERS OF METHYLENE-BIS-PHENOLS].
Topics: Chemistry, Pharmaceutical; Ethers; Glyceryl Ethers; Methane; Mice; Pharmacology; Pharmacy; Phenols; Research | 1963 |
[ACTION OF ACTH, CORTISONE, PREDNISOLONE AND 16-METHYLENE-PREDNISOLONE ON FIBRINOLYTIC ACTIVITY].
Topics: Adrenal Cortex Hormones; Adrenocorticotropic Hormone; Cortisone; Fibrinolysis; Methane; Pharmacology; Prednisolone; Thrombolytic Therapy | 1963 |
[EXPERIMENTS ON THE DISCOVERY OF NEW FUNGISTATIC AGENTS. VII. THE ANTIMICROBIAL EFFECT OF COMPOUNDS CONTAINING ARYL-AZO-METHYLENE GROUPS].
Topics: Acetates; Acetoacetates; Amides; Anilides; Animals; Anti-Bacterial Agents; Anti-Infective Agents; Antifungal Agents; Antitubercular Agents; Ascaris; Azides; Azo Compounds; Chemical Phenomena; Chemistry; Cyanates; Cyanides; Ketones; Malonates; Methane; Pharmacology; Research; Sulfhydryl Compounds; Thioglycolates; Triazoles; Trichomonas | 1964 |
SYNTHESIS OF 4-METHYLENE-DL-PROLINE: A NATURALLY OCCURRING RACEMIC AMINO-ACID.
Topics: Amino Acids; Malonates; Methane; Proline; Pyrrolidinones; Research; Spectrum Analysis | 1964 |
REACTION OF AMIDE HOMOLOGS. XII. REACTION OF N-ARYLMETHYLENE-1-ACYLAMINO-1-ARYLMETHYLAMINE WITH ACTIVE METHYLENE COMPOUND.
Topics: Alkylation; Amides; Amines; Chemistry, Pharmaceutical; Malonates; Methane; Research | 1964 |
[SERUM LEVELS OF 6-METHYLENE-OXYTETRACYCLINE AFTER REPEATED ORAL ADMINISTRATION].
Topics: Administration, Oral; Biomedical Research; Blood; Capsules; Humans; Methane; Oxytetracycline; Pharmacology | 1964 |
STUDIES ON THE PYRIMIDINE DERIVATIVES. XXXI. REACTIONS OF ETHYL 2-METHOXY-METHYLENE-3-ETHOXYPROPIONATE WITH UREAS.
Topics: Chemistry, Pharmaceutical; Methane; Propionates; Pyrimidines; Research; Urea | 1964 |
[TETRACYCLINE-METHYLENE-LYSINE IN RESPIRATORY TRACT INFECTIONS].
Topics: Anti-Bacterial Agents; Drug Therapy; Humans; Lymecycline; Lysine; Methane; Pharmacology; Respiratory Tract Infections; Tetracycline | 1964 |
[SYNTHESIS OF 16-METHYLENE PREDNISONE ACETATE].
Topics: Acetates; Alkylation; Chemistry, Pharmaceutical; Methane; Methylprednisolone; Prednisone; Research | 1964 |
[FIRST CLINICAL OBSERVATIONS ON THE USE OF A NEW ANTIBIOTIC: 6-METHYLENE-OXYTETRACYCLINE].
Topics: Anti-Bacterial Agents; Biomedical Research; Female; Gynecology; Humans; Methane; Obstetrics; Oxytetracycline; Pharmacology; Pregnancy; Protein Synthesis Inhibitors; Tetracycline | 1964 |
[SALTS OF METHYLENE-BIS-PHENOLIC ACIDS. 3. PHARMACOLOGICAL, BIOLOGICAL AND MICROBIOLOGICAL STUDIES ON NEOMYCIN PAMOATE (DA 1620)].
Topics: Bacteria; Fungi; Hydroxybenzoates; Metabolism; Methane; Neomycin; Pharmacology; Rats; Research; Salts; Toxicology | 1964 |
ANTAGONISM OF DEXTRO-PROPOXYPHENE POISONING IN ALBINO MICE WITH NALORPHINE HC1, LEVALLORPHAN TARTRATE, AND METHYLENE BLU.
Topics: Analgesics; Animals; Antidotes; Dextropropoxyphene; Drug-Related Side Effects and Adverse Reactions; Levallorphan; Methane; Methylene Blue; Mice; Nalorphine; Pharmacology; Poisoning; Quinacrine; Research; Tartrates; Toxicology | 1965 |
STUDIES ON SEVEN-MEMBERED RING COMPOUNDS. 13. REACTION OF 2-BROMO-7-METHOXYTROPONE WITH ACTIVE METHYLENE COMPOUNDS.
Topics: Bromine; Chemical Phenomena; Chemistry; Hydrocarbons; Methane; Research | 1965 |
[EFFECT OF A SYNTHETIC PROGESTERONE DERITICE (1,2-ALPHA METHYLENE-6-CHLORO-DELTA 6-17-ALPHA-HYDROXYPROGESTERONE ACETATE) ALONE AND ASSOCIATED WITH CORTISONE ON THE 17-HYDROZYCORTICOSTEROID EXCRETION IN GUINEA PIG URINE].
Topics: 17-alpha-Hydroxyprogesterone; 17-Hydroxycorticosteroids; Acetates; Animals; Cortisone; Guinea Pigs; Hydroxyprogesterones; Methane; Pharmacology; Progesterone; Research; Urine | 1964 |
STRUCTURES RELATED TO MORPHINE. XXIX. FURTHER EXPERIMENTS ON THE STEREO-CONTROLLED REDUCTION OF 9-METHYLENE-6,7-BENZOMORPHANS.
Topics: Analgesics; Analgesics, Non-Narcotic; Antipyretics; Benzomorphans; Chemistry, Pharmaceutical; Methane; Morphine; Research | 1965 |
[ON THE PERORAL THERAPY OF THE STEIN-LEVENTHAL SYNDROME WITH 16-METHYLENE-6-DEHYDRO-17-ALPHA-ACETOXYPROGESTERON].
Topics: Drug Therapy; Female; Humans; Methane; Polycystic Ovary Syndrome; Progestins; Toxicology | 1964 |
[ON THE PREPARATION OF DELTA-KETOCARBOXYLIC ACIDS. 1. ON ACYL DERIVATIVES OF METHYLENE-ACTIVE DICARBONYL COMPOUNDS].
Topics: Chemical Phenomena; Chemistry; Dicarboxylic Acids; Keto Acids; Methane; Research | 1964 |
Evidence for the occurrence of gamma-methylene-alpha-oxoglutaric acid in groundnut plants (Arachis hypogaea).
Topics: Arachis; Keto Acids; Ketones; Methane; Plants | 1955 |
Reaction between polynitrobenzene and active methylene groups. IV. Reaction between 1-substituted 2,4,6-trinitrobenzene and acetone.
Topics: Acetone; Methane; Nitrobenzenes; Trinitrobenzenes | 1955 |
Reaction between polynitrobenzene and active methylene groups. V. Jaffé and Baljet reactions.
Topics: Acetone; Methane; Picrates | 1955 |
Some biologic actions of 16-methylene derivatives of prednisolone and cortisol in the rat.
Topics: Animals; Biological Products; Hydrocortisone; Inflammation; Methane; Prednisolone; Rats | 1962 |
Synthesis of five generations of redox-stable pentamethylamidoferrocenyl dendrimers and comparison of amidoferrocenyl- and pentamethylamidoferrocenyl dendrimers as electrochemical exoreceptors for the selective recognition of H2PO4-, HSO4-, and adenosine
Topics: Adenosine Triphosphate; Amides; Anions; Cyclopentanes; Electrochemistry; Electrons; Ferrous Compounds; Hydrocarbons; Hydrophobic and Hydrophilic Interactions; Methane; Methylation; Organometallic Compounds; Oxidation-Reduction; Phosphates; Polymers; Sulfates | 2003 |
Synthesis of (-)-tetrodotoxin: preparation of an advanced cyclohexenone intermediate.
Topics: Cyclohexanones; Hydrocarbons; Methane; Ozone; Stereoisomerism; Tetrodotoxin | 2003 |
Imidazolylidene carbene ligated palladium catalysis of the Heck reaction in the presence of air.
Topics: Catalysis; Chemistry, Organic; Hydrocarbons; Imidazoles; Ligands; Methane; Models, Chemical; Palladium; Time Factors | 2003 |
Trapping highly electrophilic metalladiphosphanylcarbenes.
Topics: Cations; Hydrocarbons; Ligands; Metals; Methane; Molecular Conformation; Molecular Structure; Phosphines; Ruthenium; Silver; Stereoisomerism; Thermodynamics | 2003 |
Human cytochrome p450 inhibition and metabolic-intermediate complex formation by goldenseal extract and its methylenedioxyphenyl components.
Topics: Cytochrome P-450 Enzyme Inhibitors; Cytochrome P-450 Enzyme System; Dioxoles; Dose-Response Relationship, Drug; Humans; Hydrastis; Hydrocarbons; Isoenzymes; Methane; Microsomes, Liver; Plant Extracts; Plant Roots | 2003 |
New classes of antibacterial oxazolidinones with C-5, methylene O-linked heterocyclic side chains.
Topics: Animals; Anti-Bacterial Agents; Gram-Positive Bacteria; Heterocyclic Compounds; Hydrocarbons; Methane; Mice; Microbial Sensitivity Tests; Oxazolidinones; Rats; Staphylococcal Infections; Staphylococcus aureus; Structure-Activity Relationship | 2003 |
Borylation of aryldiazonium ions with N-heterocyclic carbene-palladium catalysts formed without added base.
Topics: Boron; Catalysis; Crystallography, X-Ray; Hydrocarbons; Hydrogen-Ion Concentration; Ions; Ligands; Methane; Molecular Conformation; Molecular Structure; Palladium | 2003 |
Chemo-enzymatic synthesis of conformationally constrained oligosaccharides.
Topics: Amides; Amino Sugars; Animals; beta-D-Galactoside alpha 2-6-Sialyltransferase; Carbohydrate Conformation; Carbohydrate Sequence; Fucose; Fucosyltransferases; Guanosine Diphosphate; Hydrocarbons; Liver; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Models, Molecular; Models, Theoretical; Molecular Sequence Data; Oligosaccharides; Protein Conformation; Rats; Sialyltransferases; Trisaccharides | 2003 |
C-glycosylmethylene carbenes: synthesis of anhydro-aldose tosylhydrazones as precursors; generation and a new synthetic route to exo-glycals.
Topics: Carbon; Cyanides; Dioxanes; Glycosides; Hot Temperature; Hydrazines; Hydrocarbons; Hydrogen; Methane; Models, Chemical; Models, Molecular; Nitrogen; Sodium | 2003 |
NIR-FT Raman and infrared spectra and ab initio computations of glycinium oxalate.
Topics: Carbon; Glycine; Hydrocarbons; Hydrogen; Hydrogen Bonding; Methane; Models, Chemical; Oxalates; Spectrophotometry, Infrared; Spectroscopy, Fourier Transform Infrared; Spectrum Analysis, Raman; Thermodynamics | 2004 |
Strategies for heterocyclic construction via novel multicomponent reactions based on isocyanides and nucleophilic carbenes.
Topics: Combinatorial Chemistry Techniques; Cyanides; Cyclization; Heterocyclic Compounds; Hydrocarbons; Methane; Models, Chemical; Molecular Conformation; Molecular Structure; Stereoisomerism | 2003 |
Tartrate dehydrogenase reductive decarboxylation: stereochemical generation of diastereotopically deuterated hydroxymethylenes.
Topics: Alcohol Oxidoreductases; Catalysis; Decarboxylation; Deuterium; Enzyme Activation; Glyceric Acids; Hydrocarbons; Methane; Molecular Conformation; Oxidation-Reduction; Serine; Stereoisomerism; Tartrates | 2004 |
Single additional methylene group in the head-group region imparts high gene transfer efficacy to a transfection-incompetent cationic lipid.
Topics: Animals; beta-Galactosidase; Cations; Cell Line, Tumor; Cell Survival; CHO Cells; Cholesterol; COS Cells; Cricetinae; DNA; Humans; Hydrocarbons; Lipids; Liposomes; Methane; Transfection | 2004 |
Measurement of dipolar cross-correlation in methylene groups in uniformly 13C-, 15N-labeled proteins.
Topics: Carbon Isotopes; Carrier Proteins; Fatty Acid-Binding Proteins; Humans; Hydrocarbons; Lysine; Methane; Nitrogen Isotopes; Nuclear Magnetic Resonance, Biomolecular; Proteins | 2004 |
Carbamates in the chemotherapy of leukemia. VIII. Overall tracer studies on carbonyl-labeled urethan, methylene-labeled urethan, and methylene-labeled ethyl alcohol.
Topics: Carbamates; Esters; Ethanol; Leukemia; Methane; Urethane | 1951 |
The effect of dicoumarol/3,3'-methylen-bis-(4,4'-oxycoumarin)/ on plasma-coagulating action of staphylocoagulase.
Topics: Blood Coagulation; Coagulase; Dicumarol; Methane; Plasma | 1951 |
[Methylene sulfathiazole in the treatment of gastroenteritis of infants].
Topics: Gastroenteritis; Humans; Infant; Infant Nutrition Disorders; Methane; Sulfathiazole; Sulfathiazoles | 1951 |
Studies on high-temperature amination reactions of aromatic chlorides using discrete palladium-N-heterocyclic carbene (NHC) complexes and in situ palladium/imidazolium salt protocols.
Topics: Catalysis; Chemistry, Organic; Chlorides; Hydrocarbons; Imidazoles; Methane; Microwaves; Models, Chemical; Palladium; Salts; Temperature; Time Factors | 2003 |
Studies on the enzymic oxidation of succinic acid containing deuterium in the methylene groups.
Topics: Deuterium; Methane; Oxidation-Reduction; Oxidoreductases; Succinates; Succinic Acid | 1951 |
Structural analysis of biological aliphatic compounds using surface-enhanced Fourier transform Raman spectroscopy.
Topics: Adsorption; Biology; Colloids; Gold; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Mycobacterium kansasii; Mycobacterium tuberculosis; Mycolic Acids; Species Specificity; Spectrometry, Mass, Electrospray Ionization; Spectroscopy, Fourier Transform Infrared; Spectrum Analysis, Raman; Structure-Activity Relationship; Surface Plasmon Resonance; Surface Properties | 2004 |
Exciplex formation between pyrene and guanine in highly polar solvents.
Topics: Acetonitriles; Adenine; Cytosine; Dimethylformamide; Guanine; Hydrocarbons; Methane; Pyrenes; Solvents; Spectrometry, Fluorescence; Thymine; Uracil; Water | 2004 |
Tandem enyne metathesis-Diels-Alder reaction for construction of natural product frameworks.
Topics: Alkadienes; Alkynes; Biological Factors; Catalysis; Hydrocarbons; Indoles; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Ruthenium; Solvents; Vinyl Compounds | 2004 |
Sequence and pH effects of LNA-containing triple helix-forming oligonucleotides: physical chemistry, biochemistry, and modeling studies.
Topics: Base Sequence; Deoxyribonucleases, Type II Site-Specific; DNA; Hot Temperature; Hydrocarbons; Hydrogen-Ion Concentration; Hydrolysis; Methane; Models, Molecular; Nucleic Acid Conformation; Nucleic Acid Heteroduplexes; Oligodeoxyribonucleotides; Purine Nucleotides; Pyrimidine Nucleotides; Restriction Mapping; Spectrophotometry, Ultraviolet; Thermodynamics | 2004 |
Spacer length effect of a chiral stationary phase based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid.
Topics: Alcohols; Amino Acids; Chromatography, High Pressure Liquid; Crown Ethers; Hydrocarbons; Methane; Models, Chemical; Quaternary Ammonium Compounds; Time Factors | 2004 |
Denaturation of replication protein A reveals an alternative conformation with intact domain structure and oligonucleotide binding activity.
Topics: DNA-Binding Proteins; Hydrocarbons; Methane; Oligonucleotides; Peptide Mapping; Protein Binding; Protein Conformation; Protein Denaturation; Protein Folding; Protein Structure, Tertiary; Protein Subunits; Replication Protein A; Spectrum Analysis | 2004 |
Asymmetric synthesis of novel thioiso dideoxynucleosides with exocyclic methylene as potential antiviral agents.
Topics: Antiviral Agents; Catalysis; Cyclization; Dideoxynucleosides; Glycosylation; Hydrocarbons; Methane; Palladium; Purines; Pyrimidines; Solvents; Temperature; Thionucleotides; Xylose | 2004 |
Reaction of tetramethylpiperidine N-oxides with persistent triplet diphenylcarbenes.
Topics: Benzene Derivatives; Cyclic N-Oxides; Diazomethane; Hydrocarbons; Kinetics; Lasers; Methane; Models, Chemical; Molecular Structure; Photolysis; Spectrophotometry, Ultraviolet; Thermodynamics | 2004 |
Measurement of one-bond heteronuclear dipolar coupling contributions for amine and diastereotopic methylene protons.
Topics: Algorithms; Amines; Binding Sites; Glucosamine; Heterocyclic Compounds, 2-Ring; Hydrocarbons; Macromolecular Substances; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation; Protons; Stereoisomerism | 2004 |
In situ diagnostics of the crystalline nature of single organic nanocrystals by nonlinear microscopy.
Topics: Acetonitriles; Benzene Derivatives; Crystallization; Hydrocarbons; Luminescence; Methane; Microscopy; Models, Chemical; Nanotechnology; Semiconductors | 2004 |
Supramolecular recognition and structural elucidation of inclusion complexes of an achiral carbene precursor in beta- and permethylated beta-cyclodextrin.
Topics: beta-Cyclodextrins; Hydrocarbons; Methane; Models, Chemical; Molecular Structure | 2004 |
Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions.
Topics: Acetals; Hydrocarbons; Ions; Methane; Molecular Conformation; Oxidation-Reduction; Stereoisomerism | 2004 |
A nucleic acid base derivative tethered to a ruthenium carbene complex: hydrogen bonded dimers in both the solid state and solution?
Topics: Base Pairing; Dimerization; Hydrocarbons; Hydrogen Bonding; Methane; Models, Molecular; Nucleic Acid Conformation; Nucleic Acids; Ruthenium; Solutions; Uracil | 2004 |
Synthesis and evaluation of 6-methylene-bridged uracil derivatives. Part 1: discovery of novel orally active inhibitors of human thymidine phosphorylase.
Topics: Absorption; Administration, Oral; Animals; Antineoplastic Agents; Enzyme Inhibitors; Female; Humans; Hydrocarbons; Inhibitory Concentration 50; Macaca fascicularis; Male; Methane; Mice; Mice, Nude; Molecular Structure; Stomach Neoplasms; Structure-Activity Relationship; Thymidine Phosphorylase; Uracil; Xenograft Model Antitumor Assays | 2004 |
Synthesis and evaluation of 6-methylene-bridged uracil derivatives. Part 2: optimization of inhibitors of human thymidine phosphorylase and their selectivity with uridine phosphorylase.
Topics: Absorption; Administration, Oral; Animals; Enzyme Inhibitors; Humans; Hydrocarbons; Inhibitory Concentration 50; Methane; Molecular Structure; Rats; Structure-Activity Relationship; Substrate Specificity; Thymidine Phosphorylase; Uracil; Uridine Phosphorylase | 2004 |
Synthesis of 2,3- or 1,2-unsaturated derivatives of 2-deoxy-2-trifluoromethylhexopyranoses.
Topics: Carbohydrate Conformation; Carbohydrates; Chromatography; Chromatography, Thin Layer; Cyanides; Deoxy Sugars; Fluorenes; Glycosides; Hydrocarbons; Hydrogen; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Models, Molecular; Pyrans; X-Rays | 2004 |
Ring synthesis by stereoselective, methylene-free enyne cross metathesis.
Topics: Alkadienes; Alkylation; Alkynes; Catalysis; Cyclization; Cyclohexanes; Cyclohexenes; Cyclooctanes; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Stereoisomerism | 2004 |
2-Methylene analogs of 1alpha-hydroxy-19-norvitamin D3: synthesis, biological activities and docking to the ligand binding domain of the rat vitamin D receptor.
Topics: Animals; Binding Sites; Calcitriol; Female; HL-60 Cells; Humans; Hydrocarbons; Ligands; Methane; Mice; Models, Molecular; Rats; Receptors, Calcitriol | 2004 |
Biochemical requirements for inhibition of Connexin26-containing channels by natural and synthetic taurine analogs.
Topics: Amines; Animals; Binding Sites; Binding, Competitive; Biological Transport; Cattle; Chromatography, Gel; Connexin 26; Connexins; Cytoplasm; Dimerization; Dose-Response Relationship, Drug; Gap Junction beta-1 Protein; Hydrocarbons; Hydrogen-Ion Concentration; Ligands; Liposomes; Methane; Mice; Models, Chemical; Phosphatidylserines; Protein Isoforms; Protein Structure, Tertiary; Protons; Rats; Stereoisomerism; Substrate Specificity; Sulfonic Acids; Sulfur; Taurine | 2004 |
Estrogen to antiestrogen with a single methylene group resulting in an unusual steroidal selective estrogen receptor modulator.
Topics: Animals; Body Weight; Bone and Bones; Cell Line, Tumor; Cholesterol; Dose-Response Relationship, Drug; Estradiol; Estrogen Antagonists; Estrogen Receptor alpha; Estrogen Receptor beta; Estrogens; Female; Humans; Hydrocarbons; Methane; Organ Size; Rats; Rats, Sprague-Dawley; Receptors, Estrogen; Selective Estrogen Receptor Modulators; Transfection; Uterus | 2004 |
Vinyl and carbene ruthenium(II) complexes from hydridoruthenium(II) precursors.
Topics: Crystallography, X-Ray; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Ruthenium; Vinyl Compounds | 2004 |
Preparation and characterisation of palladium, platinum and manganese di(organo)carbene complexes from quinolinone and quinolinium precursors.
Topics: Crystallography, X-Ray; Hydrocarbons; Manganese; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Platinum; Quinolones | 2004 |
Dinuclear gold(I) complexes of bridging bidentate carbene ligands: synthesis, structure and spectroscopic characterisation.
Topics: Antineoplastic Agents; Bridged-Ring Compounds; Crystallography, X-Ray; Gold; Hydrocarbons; Ligands; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation; Molecular Structure; Temperature | 2004 |
Biocatalytic asymmetric rearrangement of a methylene-interrupted bis-epoxide: simultaneous control of four asymmetric centers through a biomimetic reaction cascade.
Topics: Actinomycetales; Biomimetics; Catalysis; Cyclization; Epoxide Hydrolases; Epoxy Compounds; Hydrocarbons; Hydrolysis; Methane; Molecular Structure; Stereoisomerism | 2004 |
Structure-activity relationships of methylene or terminal side chain modified retinoids on the differentiation and cell death signaling in NB4 promyelocytic leukemia cells.
Topics: Cell Death; Cell Differentiation; Cell Line, Tumor; Humans; Hydrocarbons; Leukemia, Promyelocytic, Acute; Methane; Retinoids; Structure-Activity Relationship | 2004 |
Synthesis and application of methyleneoxy pseudodipeptide building blocks in biologically active peptides.
Topics: Acetaldehyde; Acetates; Amino Acids; Animals; Carbon; Dipeptides; Diptera; Female; HIV Protease; HIV Protease Inhibitors; Hydrocarbons; Magnetic Resonance Spectroscopy; Male; Methane; Models, Chemical; Nitrogen; Oocytes; Protein Structure, Tertiary; Stereoisomerism | 2004 |
Nucleophilic carbenes in asymmetric organocatalysis.
Topics: Acylation; Biomimetics; Catalysis; Hydrocarbons; Methane; Thiamine; Transketolase | 2004 |
Relaxation-optimized NMR spectroscopy of methylene groups in proteins and nucleic acids.
Topics: DNA; Hydrocarbons; Methane; Models, Molecular; Nuclear Magnetic Resonance, Biomolecular; Nucleic Acid Conformation; Proteins | 2004 |
Pyridine substituted N-heterocyclic carbene ligands as supports for Au(I)-Ag(I) interactions: formation of a chiral coordination polymer.
Topics: Crystallography, X-Ray; Gold; Heterocyclic Compounds; Hydrocarbons; Ligands; Magnetic Resonance Spectroscopy; Metals, Heavy; Methane; Models, Chemical; Molecular Conformation; Organometallic Compounds; Polymers; Pyridines; Silver | 2004 |
Comparison of monolithic silica and polymethacrylate capillary columns for LC.
Topics: 1-Propanol; Butylene Glycols; Calibration; Chromatography, High Pressure Liquid; Chromatography, Liquid; Electrophoresis, Capillary; Hydrocarbons; Kinetics; Methane; Naphthalenes; Polymethacrylic Acids; Silicon Dioxide; Sulfonic Acids; Time Factors; Water | 2004 |
Bidentate NHC-based chiral ligands for efficient Cu-catalyzed enantioselective allylic alkylations: structure and activity of an air-stable chiral Cu complex.
Topics: Alkylation; Allyl Compounds; Catalysis; Copper; Heterocyclic Compounds, 1-Ring; Hydrocarbons; Ligands; Methane; Organometallic Compounds; Ruthenium; Stereoisomerism | 2004 |
Dependence of 1H NMR chemical shifts of geminal protons of glycosyloxy methylene (H2-26) on the orientation of the 27-methyl group of furostane-type steroidal saponins.
Topics: Hydrocarbons; Hydrogen; Methane; Molecular Structure; Nuclear Magnetic Resonance, Biomolecular; Protons; Saponins; Steroids; Tribulus | 2004 |
On the pharmacology of iodomethylate of dimethylamino-1-methylene-dioxy-2,3-propane (2249 F, dilvasene).
Topics: Methane; Propane; Quaternary Ammonium Compounds | 1950 |
Investigations on the Raymond reaction; studies on the reaction between aromatic nitro compounds and active methylene groups. Part I.
Topics: Glucosides; Methane; Nitro Compounds; Pharmacies; Pharmacy | 1950 |
Investigations on the Raymond reaction; studies on the reaction between aromatic nitro compounds and active methylene groups (concl.).
Topics: Glucosides; Humans; Methane; Nitro Compounds; Pharmacies; Pharmacy | 1950 |
Prolonged postanesthetic depression and apnea attributed to deca-methylene-bis (trimethylammonium bromide).
Topics: Anesthesia; Anesthesiology; Apnea; Bromides; Curare; Depression; Depressive Disorder; Methane | 1950 |
Mitochondrial permeability transition induced by dinuclear gold(I)-carbene complexes: potential new antimitochondrial antitumour agents.
Topics: Animals; Antineoplastic Agents; Biological Transport; Cyclosporine; Gold Compounds; Hydrocarbons; Ion Channels; Methane; Mitochondria, Liver; Mitochondrial Membrane Transport Proteins; Mitochondrial Permeability Transition Pore; Mitochondrial Swelling; Molecular Structure; Permeability; Rats | 2004 |
Predicting resistance or response to chemotherapy by proton magnetic resonance spectroscopy in neuroblastoma.
Topics: Animals; Antineoplastic Agents; Camptothecin; Cell Line, Tumor; Choline; Cisplatin; Drug Resistance, Neoplasm; Etoposide; Hydrocarbons; Irinotecan; Magnetic Resonance Spectroscopy; Matched-Pair Analysis; Methane; Neuroblastoma; Predictive Value of Tests; Protons; Rats; Rats, Nude; Reproducibility of Results; Transplantation, Heterologous | 2004 |
Generation of alkoxycarbenium ion pools from thioacetals and applications to glycosylation chemistry.
Topics: Acetals; Glycosylation; Hydrocarbons; Methane | 2004 |
Experimental and computational studies of the structure and vibrational spectra of aminomethyl-dimethyl-phosphine oxide and its 15N labeled isomer.
Topics: Amines; Computers; Hydrocarbons; Isomerism; Methane; Molecular Conformation; Nitrogen Isotopes; Oxides; Phosphines; Spectrophotometry, Infrared; Static Electricity; Vibration | 2004 |
Dioxygen activation by a low-valent cobalt complex employing a flexible tripodal N-heterocyclic carbene ligand.
Topics: Cobalt; Heterocyclic Compounds; Hydrocarbons; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Organometallic Compounds; Oxygen; Phosphines; Spectrophotometry, Infrared; Spectrophotometry, Ultraviolet | 2004 |
Diastereoselective synthesis of cycloheptadienol derivatives by a formal [5+2] carbocyclization reaction of alpha,beta,gamma,delta-diunsaturated (methoxy)carbene complexes with methyl ketone lithium enolates.
Topics: Crystallography, X-Ray; Cyclization; Cycloheptanes; Hydrocarbons; Ketones; Lithium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2004 |
A study on biomineralization behavior of N-methylene phosphochitosan scaffolds.
Topics: Apatites; Biocompatible Materials; Biotechnology; Calcium Chloride; Calcium Phosphates; Chitosan; Hydrocarbons; Methane; Microscopy, Electron, Scanning; Models, Chemical; Phosphorylation; Polymers; Spectroscopy, Fourier Transform Infrared; Temperature; Time Factors; X-Ray Diffraction | 2004 |
Conformational analysis of chirally deuterated tunicamycin as an active site probe of UDP-N-acetylhexosamine:polyprenol-P N-acetylhexosamine-1-P translocases.
Topics: Binding Sites; Carbohydrate Conformation; Cations, Divalent; Deuterium Exchange Measurement; Disaccharides; Galactosamine; Glycosides; Hydrocarbons; Isomerism; Magnesium; Methane; Molecular Probes; N-Acetylhexosaminyltransferases; Nuclear Magnetic Resonance, Biomolecular; Protein Binding; Protein Conformation; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; Streptomyces; Substrate Specificity; Tunicamycin; Uracil | 2004 |
Synthesis of pyridinylpyrrole derivatives via the palladium-catalyzed reaction of acetylpyridines with methyleneaziridines.
Topics: Aziridines; Catalysis; Hydrocarbons; Methane; Palladium; Pyridines; Pyrroles | 2004 |
A new convergent strategy for the synthesis of calixarenes via a triple annulation of Fischer carbene complexes.
Topics: Alkynes; Benzene Derivatives; Calixarenes; Cyclization; Hydrocarbons; Methane | 2004 |
Synthesis and unprecedented oxidation of a cationic Sb-analogue of an Arduengo's carbene.
Topics: Antimony; Cations; Crystallography, X-Ray; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Oxidation-Reduction | 2004 |
Stereoelective polymerization of D,L-lactide using N-heterocyclic carbene based compounds.
Topics: Crystallography, X-Ray; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Polyesters; Stereoisomerism; Zinc | 2004 |
Theoretical study on the reactivities of stannylene and plumbylene and the origin of their activation barriers.
Topics: Computer Simulation; Free Radicals; Germanium; Hydrocarbons; Lead; Methane; Models, Chemical; Organometallic Compounds; Organotin Compounds; Silanes; Thermodynamics | 2004 |
Tryptamine-based human beta3-adrenergic receptor agonists. Part 2: SAR of the methylene derivatives.
Topics: Adrenergic beta-3 Receptor Agonists; Adrenergic beta-Agonists; Animals; CHO Cells; Cloning, Molecular; Cricetinae; Cyclic AMP; Drug Evaluation, Preclinical; Humans; Hydrocarbons; Methane; Molecular Conformation; Structure-Activity Relationship; Sulfonamides; Tryptamines | 2004 |
Phase modulation in dipolar-coupled A2 spin systems: effect of maximum state mixing in 1H NMR in vivo.
Topics: Creatine; Humans; Hydrocarbons; Hydrogen Bonding; Leg; Magnetic Resonance Spectroscopy; Male; Methane; Muscle, Skeletal | 2004 |
Molecular dynamics and information on possible sites of interaction of intramyocellular metabolites in vivo from resolved dipolar couplings in localized 1H NMR spectra.
Topics: Adult; Carnosine; Creatine; Humans; Hydrocarbons; Hydrogen Bonding; Least-Squares Analysis; Leg; Magnetic Resonance Spectroscopy; Male; Methane; Muscle, Skeletal; Protein Conformation; Protons; Signal Processing, Computer-Assisted; Taurine | 2004 |
Using nucleophilic substitution reactions to understand how a remote alkyl or alkoxy substituent influences the conformation of eight-membered ring oxocarbenium ions.
Topics: Acetates; Alkylation; Cyclization; Hydrocarbons; Ions; Methane; Models, Chemical; Oxocins; Stereoisomerism | 2004 |
Cellular stability of serotonin N-acetyltransferase conferred by phosphonodifluoromethylene alanine (Pfa) substitution for Ser-205.
Topics: 14-3-3 Proteins; Alanine; Amino Acids; Animals; Arylalkylamine N-Acetyltransferase; CHO Cells; Cloning, Molecular; Cricetinae; DNA, Complementary; Electrophoresis, Polyacrylamide Gel; Hydrocarbons; Immunohistochemistry; Kinetics; Mass Spectrometry; Melatonin; Methane; Models, Biological; Models, Chemical; Organophosphonates; Peptides; Phosphorylation; Protein Binding; Protein Processing, Post-Translational; Protein Structure, Tertiary; Proteins; Serine; Sheep | 2005 |
The application of polymethylene waxes as conditioning agent in hair relaxers.
Topics: Emulsions; Hair; Hair Preparations; Humans; Hydrocarbons; Methane; Microscopy, Electron, Scanning; Particle Size; Polymers; Viscosity | 2004 |
Cross enyne metathesis of para-substituted styrenes: a kinetic study of enyne metathesis.
Topics: Alkynes; Catalysis; Hydrocarbons; Kinetics; Methane; Molecular Structure; Ruthenium; Styrenes | 2005 |
Deamidation: Differentiation of aspartyl from isoaspartyl products in peptides by electron capture dissociation.
Topics: Aspartic Acid; Biochemistry; Carbon; Fourier Analysis; Hydrocarbons; Ions; Isoaspartic Acid; Mass Spectrometry; Methane; Microscopy, Electron; Models, Chemical; Peptides; Protein Folding; Protein Isoforms; Protein Processing, Post-Translational; Proteins; Software | 2005 |
Deuterium exchange in arsenobetaine and dimethylarsinoylacetic acid.
Topics: Acetates; Animals; Arsenicals; Buffers; Deuterium; Hydrocarbons; Hydrogen-Ion Concentration; Kinetics; Magnetic Resonance Spectroscopy; Marine Biology; Methane; Models, Chemical; Protons | 2005 |
A chemical method for the convenient surface functionalisation of polymers.
Topics: Chemistry Techniques, Analytical; Hydrocarbons; Methane; Molecular Structure; Polymers; Surface Properties | 2005 |
New developments in planar array infrared spectroscopy.
Topics: Algorithms; Equipment Design; Equipment Failure Analysis; Hydrocarbons; Image Enhancement; Methane; Online Systems; Polystyrenes; Refractometry; Reproducibility of Results; Sensitivity and Specificity; Spectrophotometry, Infrared; Transducers | 2005 |
Synthesis and analytical characteristics of new progesterone skeleton haptens.
Topics: Animals; Antibody Specificity; Bromus; Cattle; Chromatography, Thin Layer; Haptens; Hydrocarbons; Immune Sera; Immunoassay; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Progesterone; Serum Albumin, Bovine; Sulfhydryl Compounds | 2005 |
Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions.
Topics: Acetals; Catalysis; Cyclization; Hydrocarbons; Indicators and Reagents; Ions; Methane; Models, Chemical; Molecular Structure; Oxidation-Reduction | 2005 |
Silver(I)-carbene complexes/ionic liquids: novel N-heterocyclic carbene delivery agents for organocatalytic transformations.
Topics: Catalysis; Cyclization; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Organometallic Compounds; Silver; Temperature | 2005 |
Allenyl azide cycloaddition chemistry. synthesis of pyrrolidine-containing bicycles and tricycles via the possible intermediacy of azatrimethylenemethane species.
Topics: Alkadienes; Aza Compounds; Azides; Bridged Bicyclo Compounds; Cyclization; Hydrocarbons; Methane; Polycyclic Compounds; Pyrrolidines | 2005 |
Measurement of eight scalar and dipolar couplings for methine-methylene pairs in proteins and nucleic acids.
Topics: Anisotropy; Bacterial Proteins; Base Sequence; Carbon Isotopes; Escherichia coli; Hydrocarbons; Methane; Nitrogen Isotopes; Nuclear Magnetic Resonance, Biomolecular; Nucleic Acid Conformation; Nucleic Acids; Protein Conformation; Protein Structure, Secondary; Protein Structure, Tertiary; Proteins; RNA, Bacterial; RNA, Ribosomal, 23S | 2005 |
Vibrational spectroscopy of 3,4-difluorocyclobutenes: cis-d0, trans-d0 and trans-d4 species.
Topics: Cyclobutanes; Fluorocarbons; Gases; Hydrocarbons; Hydrocarbons, Fluorinated; Hydrogen Bonding; Methane; Models, Molecular; Spectrophotometry; Spectrophotometry, Infrared; Spectrum Analysis, Raman; Temperature | 2005 |
HPLC-based procedure for the preparation of carbene-generating photoreactive GM3 and GM1 ganglioside derivatives radioiodinated to high specific radioactivity with chloramine T as an oxidant.
Topics: Animals; Chloramines; Chromatography, High Pressure Liquid; Diazomethane; Dogs; Fatty Acids; Fatty Alcohols; G(M1) Ganglioside; G(M3) Ganglioside; Hydrocarbons; Iodine Radioisotopes; Isotope Labeling; Methane; Oxidants; Photochemistry; Tosyl Compounds; Trialkyltin Compounds | 2005 |
Synthesis of a methylene analog of 5-amino-1-beta-D-ribofuranosylimidazole-4-carboxamide monophosphate (ZMP).
Topics: Aminoimidazole Carboxamide; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Ribonucleotides | 2005 |
A readily available chiral Ag-based N-heterocyclic carbene complex for use in efficient and highly enantioselective Ru-catalyzed olefin metathesis and Cu-catalyzed allylic alkylation reactions.
Topics: Alkenes; Alkylation; Allyl Compounds; Catalysis; Copper; Crystallography, X-Ray; Heterocyclic Compounds; Hydrocarbons; Imidazolines; Methane; Organometallic Compounds; Ruthenium; Silver; Stereoisomerism | 2005 |
Template synthesis of a coordinated tetracarbene ligand with crown ether topology.
Topics: Crown Ethers; Crystallography, X-Ray; Hydrocarbons; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism; Transition Elements | 2005 |
1H-NMR metabolic markers of malignancy correlate with spontaneous metastases in a murine mammary tumor model.
Topics: Animals; Antigens, Neoplasm; Biomarkers; Biomarkers, Tumor; Cell Adhesion; Cell Proliferation; Cell Separation; Flow Cytometry; Glycolysis; Humans; Hydrocarbons; Magnetic Resonance Spectroscopy; Mammary Neoplasms, Animal; Methane; Mice; Mice, Inbred BALB C; Neoplasm Metastasis; Oligosaccharides; Phenotype; Phosphorylcholine; Prognosis; Sialyl Lewis X Antigen; Time Factors | 2005 |
Diastereoselective synthesis of five- and seven-membered rings by [2+2+1], [3+2], [3+2+2], and [4+3] carbocyclization reactions of beta-substituted (alkenyl)(methoxy)carbene complexes with methyl ketone lithium enolates.
Topics: Cyclization; Hydrocarbons; Ketones; Lithium; Magnetic Resonance Spectroscopy; Mass Spectrometry; Methane; Stereoisomerism | 2005 |
Nonaqueous synthesis of a selectively modified, highly anionic sulfopropyl ether derivative of cyclomaltoheptaose (beta-cyclodextrin) in the presence of 18-crown-6.
Topics: Anions; beta-Cyclodextrins; Carbohydrate Conformation; Carbon; Deuterium Oxide; Electrophoresis, Capillary; Hydrocarbons; Hydrogen; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Naphthalenes; Potassium; Thiophenes; Ultraviolet Rays | 2005 |
Concurrent cyclopropanation by carbenes and carbanions.
Topics: Alkenes; Anions; Carbon; Cyclization; Cyclopropanes; Halogens; Hydrocarbons; Methane; Molecular Structure | 2005 |
Formation and stability of oxocarbenium ions from glycosides.
Topics: Glycosides; Glycosylation; Hydrocarbons; Ions; Methane; Molecular Structure | 2005 |
An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes.
Topics: Catalysis; Heterocyclic Compounds; Hydrocarbons; Methane; Models, Chemical; Salts; Stereoisomerism; Triazoles | 2005 |
Latent, thermally activated organic catalysts for the on-demand living polymerization of lactide.
Topics: Catalysis; Ethanol; Hydrocarbons; Kinetics; Lactic Acid; Ligands; Methane; Molecular Structure; Molecular Weight; Temperature; Time Factors; Triazoles | 2005 |
Control of competing N-H insertion and Wolff rearrangement in dirhodium(II)-catalyzed reactions of 3-indolyl diazoketoesters. synthesis of a potential precursor to the marine 5-(3-indolyl)oxazole martefragin A.
Topics: Alkaloids; Amides; Amines; Azo Compounds; Catalysis; Cations, Divalent; Esters; Hydrocarbons; Indoles; Methane; Models, Chemical; Oxazoles; Rhodium; Stereoisomerism | 2005 |
Asymmetric synthesis of cyclopropanes from lithiated aryloxiranes and alpha,beta-unsaturated Fischer carbene complexes.
Topics: Carboxylic Acids; Cyclopropanes; Ethylene Oxide; Hydrocarbons; Hydrocarbons, Cyclic; Lithium; Methane; Molecular Structure; Stereoisomerism | 2005 |
Synthesis, characterisation and theoretical studies of amidinato-indium(I) and thallium(I) complexes: isomers of neutral group 13 metal(I) carbene analogues.
Topics: Amidines; Hydrocarbons; Hydrogen Bonding; Indium; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Sensitivity and Specificity; Stereoisomerism; Thallium | 2005 |
Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties.
Topics: Amidines; Boron Compounds; Crystallography, X-Ray; Heterocyclic Compounds; Hydrocarbons; Methane | 2005 |
PdII complexes possessing a seven-membered N-heterocyclic carbene ligand.
Topics: Heterocyclic Compounds; Hydrocarbons; Ligands; Macromolecular Substances; Methane; Molecular Structure; Nitrogen; Organometallic Compounds; Palladium | 2005 |
Copper(II) complexes of tridentate pyridylmethylethylenediamines: role of ligand steric hindrance on DNA binding and cleavage.
Topics: Animals; Cattle; Copper; Crystallography, X-Ray; Diamines; DNA; Electrochemistry; Ethylenes; Hydrocarbons; Ligands; Methane; Molecular Structure; Nucleic Acid Denaturation; Plasmids; Pyridines; Spectrum Analysis; Temperature; Viscosity | 2005 |
Structure and reactivity of a new anionic N-heterocyclic carbene silver(I) complex.
Topics: Anions; Heterocyclic Compounds; Hydrocarbons; Imines; Methane; Models, Molecular; Molecular Structure; Silver Compounds; Temperature | 2005 |
Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference.
Topics: Amines; Catalysis; Crystallography, X-Ray; Electrons; Hydrocarbons; Hydrocarbons, Cyclic; Metals; Methane; Models, Molecular; Molecular Structure | 2005 |
One-step assembly of functionalized gamma-butyrolactones from benzoins or benzaldehydes via an N-heterocyclic carbene-mediated tandem reaction.
Topics: 4-Butyrolactone; Benzaldehydes; Benzoin; Catalysis; Hydrocarbons; Methane; Molecular Structure | 2005 |
Lithium benzocyclobuteneoxide as a precursor of a vinylogous enolate: solvent-controlled synthesis of highly functionalized seven-membered benzocarbocycles.
Topics: Cyclobutanes; Hydrocarbons; Methane; Organometallic Compounds; Solvents | 2005 |
Cross and ring-closing metathesis of 1,3-diynes: metallotropic [1,3]-shift of ruthenium carbenes.
Topics: Alkynes; Hydrocarbons; Methane; Molecular Structure; Organometallic Compounds; Ruthenium | 2005 |
American Chemical Society meeting. Safer alternative could replace widespread contaminant.
Topics: Animals; Caprylates; Carcinogens; Fluorocarbons; Humans; Hydrocarbons; Hydrocarbons, Fluorinated; Methane; Polymers; Solvents; Textiles | 2005 |
Uncatalyzed Mukaiyama-Michael reaction: rapid access to simple and complex enantiopure gamma-butenolides.
Topics: 4-Butyrolactone; Hydrocarbons; Methane; Molecular Structure; Stereoisomerism | 2005 |
Development of building blocks for the synthesis of N-heterocyclic carbene ligands.
Topics: Amino Acids; Catalysis; Heterocyclic Compounds; Hydrocarbons; Ligands; Methane; Molecular Structure; Palladium | 2005 |
Domino Michael addition-carbene rearrangement-cyclization reaction of 1-alkynyl(aryl)-lambda3-bromanes with 2-mercapto-1,3-benzazoles.
Topics: Alkylation; Benzene; Benzothiazoles; Bromine Compounds; Cyclization; Fluorenes; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Sulfhydryl Compounds | 2005 |
A formal synthesis of (+)-lactacystin.
Topics: Acetylcysteine; Alkylation; Hydrocarbons; Methane; Molecular Structure; Pyrroles | 2005 |
New mono- and bis-carbene samarium complexes: synthesis, X-ray crystal structures and reactivity.
Topics: Crystallography, X-Ray; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Samarium; Stereoisomerism | 2005 |
A new alternative to Stryker's reagent in hydrosilylation: synthesis, structure, and reactivity of a well-defined carbene-copper(II) acetate complex.
Topics: Crystallography, X-Ray; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Silanes; Stereoisomerism | 2005 |
A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes.
Topics: Hydrocarbons; Hydrocarbons, Cyclic; Ligands; Methane; Molecular Structure; Organometallic Compounds; Palladium; Rhodium; Transition Elements | 2005 |
An efficient route to tetrahydronaphthols via addition of ortho-lithiated stilbene oxides to alpha,beta-unsaturated fischer carbene Complexes.
Topics: Cyclization; Hydrocarbons; Lithium; Macromolecular Substances; Methane; Molecular Structure; Naphthols; Stereoisomerism; Stilbenes | 2005 |
A model study toward the total synthesis of N-deacetyllappaconitine.
Topics: Aconitine; Alkylation; Cyclization; Cyclohexanes; Cyclohexenes; Hydrocarbons; Methane; Models, Chemical; Molecular Structure | 2005 |
Synthesis and study of conformationally restricted 3'-deoxy-3',4'-exo-methylene nucleoside analogues.
Topics: Anti-HIV Agents; Antiviral Agents; Hepatitis B; Hepatitis B virus; HIV; HIV Infections; Hydrocarbons; In Vitro Techniques; Methane; Models, Chemical; Nucleic Acid Conformation; Nucleosides; RNA Viruses; Virus Replication | 2005 |
Synthesis and enzymatic characterization of methylene analogs of adenosine 5'-tetraphosphate (P4A).
Topics: Adenine Nucleotides; Chromatography, High Pressure Liquid; Chromatography, Thin Layer; Diphosphonates; Escherichia coli; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Phosphates; RNA Caps; Saccharomyces cerevisiae | 2005 |
Synthesis and biochemical properties of novel mRNA 5' cap analogs resistant to enzymatic hydrolysis.
Topics: Animals; Dose-Response Relationship, Drug; Eukaryotic Initiation Factor-4E; Humans; Hydrocarbons; Hydrolysis; Kinetics; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Nematoda; Organophosphonates; Oxygen; Protein Binding; Protein Biosynthesis; Rabbits; RNA Cap Analogs; RNA, Messenger; Spectrometry, Mass, Electrospray Ionization | 2005 |
Structural studies on LNA quadruplexes.
Topics: Circular Dichroism; DNA; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Molecular Biology; Nucleic Acid Conformation; Nucleic Acid Denaturation; Nucleic Acid Heteroduplexes; Organophosphorus Compounds; RNA; Temperature; Thrombin | 2005 |
Natural phosphate doped with KI in HMDS: a mild and efficient reagent for alkylation and glycosylation of nucleobases.
Topics: Alkylation; Catalysis; Chromatography; Glycosides; Glycosylation; Hydrocarbons; Indicators and Reagents; Methane; Models, Chemical; Molecular Biology; Nucleosides; Phosphates; Potassium Iodide | 2005 |
Stereoselective synthesis of novel thioiso dideoxy nucleosides with exocyclic methylene as potential antiviral agents.
Topics: Antiviral Agents; Chemistry, Pharmaceutical; Drug Design; Hydrocarbons; Methane; Models, Chemical; Nucleosides; Stereoisomerism; Temperature; Xylose | 2005 |
Synthesis of phosphorus esters by transesterification mediated by N-heterocyclic carbenes (NHCs).
Topics: Catalysis; Esterification; Esters; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Phosphorus | 2005 |
Different behavior of nitrenes and carbenes on photolysis and thermolysis: formation of azirine, ylidic cumulene, and cyclic ketenimine and the rearrangement of 6-phenanthridylcarbene to 9-phenanthrylnitrene.
Topics: Azirines; Electron Spin Resonance Spectroscopy; Ethylenes; Hot Temperature; Hydrocarbons; Imines; Ketones; Methane; Models, Molecular; Phenanthridines; Photolysis; Spectrophotometry; Thermodynamics | 2005 |
Synthesis and antiviral evaluation of novel exomethylene acyclic nucleosides and phosphonic acid nucleosides.
Topics: Antiviral Agents; Cell Line; Cell Survival; Cytomegalovirus; Humans; Methane; Molecular Structure; Nucleosides; Organophosphonates; Structure-Activity Relationship | 2005 |
Synthesis of donor-acceptor alkynylcyclopropanes by diastereoselective cyclopropanation of electron-deficient alkenes with alkoxyalkynyl Fischer carbene complexes.
Topics: Alkenes; Alkynes; Cyclization; Cyclopropanes; Electrons; Hydrocarbons; Methane; Microwaves; Models, Molecular; Molecular Structure; Stereoisomerism | 2005 |
Iron in the service of chromium: the ortho-benzannulation of trans,trans-dienyl Fischer carbene complexes.
Topics: Chromium; Hydrocarbons; Iron; Methane; Molecular Structure | 2005 |
Rhodium N-heterocyclic carbene-catalyzed [4 + 2] and [5 + 2] cycloaddition reactions.
Topics: Catalysis; Cyclization; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Rhodium | 2006 |
Asymmetric intramolecular crossed-benzoin reactions by N-heterocyclic carbene catalysis.
Topics: Benzoin; Catalysis; Cyclization; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Stereoisomerism | 2006 |
Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes.
Topics: Amines; Crystallography, X-Ray; Hydrocarbons; Methane; Molecular Structure; Organoplatinum Compounds; Phosphines | 2006 |
N-heterocyclic carbene catalyzed reaction of enals and 1,2-dicarbonyl compounds: stereoselective synthesis of spiro gamma-butyrolactones.
Topics: 4-Butyrolactone; Aldehydes; Catalysis; Hydrocarbons; Isatin; Methane; Molecular Structure; Spiro Compounds; Stereoisomerism | 2006 |
Unsymmetrically N,N'-substituted saturated carbenes: synthesis, reactivity and preparation of a rhodium(I) carbene complex.
Topics: Amines; Dimerization; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Models, Molecular; Rhodium; Sulfur; X-Ray Diffraction | 2006 |
Activation of TMSCN by N-heterocyclic carbenes for facile cyanosilylation of carbonyl compounds.
Topics: Acetophenones; Benzaldehydes; Catalysis; Cyanides; Cyclization; Hydrocarbons; Methane; Molecular Structure; Nitriles; Trimethylsilyl Compounds | 2006 |
Umpolung of Michael acceptors catalyzed by N-heterocyclic carbenes.
Topics: Alkenes; Alkylation; Catalysis; Cyclization; Heterocyclic Compounds; Hydrocarbons; Hydrocarbons, Cyclic; Methane | 2006 |
Electronic spectroscopy of the A1A'' <-- X1A' system of CDF.
Topics: Deuterium; Fluorides; Hydrocarbons; Hydrogen; Methane; Models, Chemical; Quantum Theory; Rotation; Spectrometry, Fluorescence; Vibration | 2006 |
Cyano-phosphorylation of aldehydes catalyzed by a nucleophilic N-heterocyclic carbene.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Hydrocarbons; Imidazoles; Indicators and Reagents; Magnetic Resonance Spectroscopy; Methane; Phosphorylation; Spectrophotometry, Infrared | 2006 |
Photochemical fishing approaches for identifying target proteins and elucidating the structure of a ligand-binding region using carbene-generating photoreactive probes.
Topics: Azides; Biotinylation; Carbohydrates; DNA; Hydrocarbons; Ligands; Light; Methane; Microscopy, Fluorescence; Models, Biological; Models, Chemical; Peptides; Photoaffinity Labels; Photochemistry; Proteins; RNA, Transfer | 2006 |
Reaction of dimethoxycarbene-DMAD zwitterion with 1,2-diones and anhydrides: a novel synthesis of highly substituted dihydrofurans and spirodihydrofurans.
Topics: Alkynes; Anhydrides; Furans; Hydrocarbons; Ketones; Methane; Molecular Structure; Spiro Compounds; Stereoisomerism | 2006 |
Hydrolysis of Fischer carbene complexes. Steric effects of the pi-donor group.
Topics: Hydrocarbons; Hydrogen-Ion Concentration; Hydrolysis; Methane; Molecular Structure | 2006 |
Synthesis and application of chiral N-heterocyclic carbene-oxazoline ligands: iridium-catalyzed enantioselective hydrogenation.
Topics: Catalysis; Combinatorial Chemistry Techniques; Crystallography, X-Ray; Hydrocarbons; Hydrogenation; Imidazoles; Iridium; Ligands; Magnetic Resonance Spectroscopy; Methane; Organometallic Compounds; Oxazoles; Stereoisomerism | 2006 |
The influence of N-substitution on the reductive elimination behaviour of hydrocarbyl-palladium-carbene complexes--a DFT study.
Topics: Hydrocarbons; Imidazoles; Ligands; Methane; Models, Chemical; Models, Molecular; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Palladium; Quantum Theory | 2006 |
Stereospecific synthesis of a carbene-generating angiotensin II analogue for comparative photoaffinity labeling: improved incorporation and absence of methionine selectivity.
Topics: Angiotensin II; Animals; Chlorocebus aethiops; COS Cells; Diazomethane; Humans; Hydrocarbons; Iodine Radioisotopes; Isotope Labeling; Methane; Methionine; Models, Molecular; Mutation; Phenylalanine; Photoaffinity Labels; Radioligand Assay; Receptor, Angiotensin, Type 2; Stereoisomerism; Structure-Activity Relationship | 2006 |
Unexpected ring-opening reactions of aziridines with aldehydes catalyzed by nucleophilic carbenes under aerobic conditions.
Topics: Aldehydes; Aziridines; Catalysis; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Oxidation-Reduction | 2006 |
Exploring protein interfaces with a general photochemical reagent.
Topics: Amino Acid Sequence; Animals; Antibodies, Monoclonal; Diazomethane; Immunoglobulin G; Methane; Models, Molecular; Molecular Probes; Molecular Sequence Data; Muramidase; Peptide Mapping; Peptides; Photoaffinity Labels; Protein Conformation; Protein Folding; Protein Structure, Tertiary; Proteins | 2006 |
CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.
Topics: Amines; Carbon Monoxide; Ethylenes; Hydrocarbons; Hydrocarbons, Cyclic; Ketones; Methane; Models, Molecular; Spectrum Analysis; Thermodynamics | 2006 |
Use of an electron-reservoir complex together with air to generate N-heterocyclic carbenes.
Topics: Electrons; Heterocyclic Compounds; Hydrocarbons; Methane; Oxidation-Reduction | 2006 |
Development of isomerization and cycloisomerization with use of a ruthenium hydride with N-heterocyclic carbene and its application to the synthesis of heterocycles.
Topics: Heterocyclic Compounds; Hydrocarbons; Isomerism; Methane; Molecular Structure; Organometallic Compounds; Ruthenium | 2006 |
Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes.
Topics: Catalysis; Diazonium Compounds; Gold; Heterocyclic Compounds; Hydrocarbons; Methane; Models, Chemical; Molecular Structure | 2006 |
Unprecedented reactivity pattern of chromium fischer carbene complexes. Direct application to one-pot synthesis of 4-aryl-3,4-dihydrocoumarins on a multigram scale.
Topics: Chromium; Coumarins; Hydrocarbons; Methane; Molecular Structure; Organometallic Compounds | 2006 |
New entry into beta-lactams via reaction of dimethoxycarbene with isocyanates.
Topics: beta-Lactams; Hydrocarbons; Isocyanates; Methane; Molecular Structure | 2006 |
Time-resolved kinetic studies on quenching of HCF(A1A'') by alkane and alcohol molecules.
Topics: Alcohols; Alkanes; Free Radicals; Gases; Hydrocarbons; Hydrocarbons, Halogenated; Kinetics; Lasers; Light; Methane; Photolysis; Temperature; Time Factors; Ultraviolet Rays | 2005 |
The cycloadditions of various substituted carbenes, silylenes, and germylenes onto the diamond (100) surface: a theoretical exploration.
Topics: Cyclization; Diamond; Germanium; Hydrocarbons; Methane; Models, Chemical; Silicon Compounds; Surface Properties | 2006 |
Modeling the competitive dissociation of protonated 2,3-butanedione. The enthalpy of formation of methylhydroxycarbene.
Topics: Diacetyl; Hydrocarbons; Methane; Models, Chemical; Molecular Structure; Protons; Thermodynamics | 2005 |
Lithium carbenoids-ultra-reactive yet selective reagents for methylenation and halomethylenation of sulfones.
Topics: Alkenes; Hydrocarbons; Hydrocarbons, Halogenated; Lithium; Methane; Methylation; Models, Molecular; Molecular Conformation; Stereoisomerism; Sulfones; Vinyl Compounds | 2006 |
1,2-migration in rhodium(II) carbene transfer reaction: remarkable steric effect on migratory aptitude.
Topics: Azo Compounds; Catalysis; Chromatography, Thin Layer; Electronics; Hydrocarbons; Methane; Models, Molecular; Rhodium | 2006 |
Emission spectroscopic investigation of triplet diarylcarbene generated in molecular sieve VPI-5.
Topics: Adsorption; Electron Spin Resonance Spectroscopy; Hydrocarbons; Methane; Models, Molecular; Molecular Conformation; Spectrophotometry | 2005 |
Preparation of a copper ion complex of sterically congested diphenyldiazomethanes having a pyridine ligand and characterization of their photoproducts.
Topics: Copper; Diazomethane; Hydrocarbons; Ligands; Methane; Photolysis; Pyridines | 2005 |
Ortho-para spin isomers of the protons in the methylene group--possible implications for protein structure.
Topics: Amino Acids; Isomerism; Methane; Models, Chemical; Proteins; Protons; Structure-Activity Relationship | 2006 |
N-heterocyclic carbene catalyzed C--C bond cleavage in redox esterifications of chiral formylcyclopropanes.
Topics: Catalysis; Chromatography, High Pressure Liquid; Cyclopropanes; Esterification; Formates; Heterocyclic Compounds; Hydrocarbons; Methane; Oxidation-Reduction | 2006 |
In situ generation of gold nanoparticles on a protein surface: Fischer carbene complex as reducing agent.
Topics: Chlorides; Ethylene Glycols; Gold; Gold Compounds; Hydrocarbons; Methane; Molecular Structure; Nanoparticles; Organometallic Compounds; Oxidation-Reduction; Particle Size; Reducing Agents; Serum Albumin, Bovine; Surface Properties; Tungsten | 2006 |
Efficient N-heterocyclic carbene-catalyzed O- to C-acyl transfer.
Topics: Amino Acids; Aza Compounds; Carbonates; Catalysis; Hydrocarbons; Lactones; Methane; Molecular Structure; Stereoisomerism | 2006 |
Luminescence studies of the intracellular distribution of a dinuclear gold(I) N-heterocyclic carbene complex.
Topics: Animals; Cells, Cultured; Crystallization; Gold Compounds; Heterocyclic Compounds; Hydrocarbons; Luminescence; Methane; Mice; Models, Chemical | 2006 |
Gold(I)-catalyzed intermolecular cyclopropanation of enynes with alkenes: trapping of two different gold carbenes.
Topics: Alkenes; Alkynes; Catalysis; Cyclization; Cyclopropanes; Gold; Hydrocarbons; Methane; Stereoisomerism | 2006 |
Total synthesis of antofine using the net [5+5]-cycloaddition of gamma,delta-unsaturated carbene complexes and 2-alkynylphenyl ketones as a key step.
Topics: Hydrocarbons; Indoles; Ketones; Methane; Molecular Structure; Phenanthrolines | 2006 |
Chromene chromium carbene complexes in the syntheses of naphthopyran and naphthopyrandione units present in photochromic materials and biologically active natural products.
Topics: Benzopyrans; Biological Products; Chromium; Hydrocarbons; Methane; Pyrans | 2006 |
Diastereoselective multicomponent cyclizations of Fischer carbene complexes, lithium enolates, and allylmagnesium bromide leading to highly substituted five- and six-membered carbocycles.
Topics: Alcohols; Allyl Compounds; Bromides; Cyclization; Cyclohexanes; Cyclopentanes; Hydrocarbons; Lithium; Magnesium; Methane; Organometallic Compounds; Stereoisomerism | 2006 |
Complexes of an anionic gallium(I) N-heterocyclic carbene analogue with group 14 element(II) fragments: synthetic, structural and theoretical studies.
Topics: Anions; Crystallography, X-Ray; Gallium; Heterocyclic Compounds; Hydrocarbons; Metals, Heavy; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds | 2006 |
Gold(I) and silver(I) mixed-metal trinuclear complexes: dimeric products from the reaction of gold(I) carbeniates or benzylimidazolates with silver(I) 3,5-diphenylpyrazolate.
Topics: Crystallography, X-Ray; Dimerization; Gold; Gold Compounds; Hydrocarbons; Imidazoles; Methane; Models, Molecular; Molecular Structure; Pyrazoles; Silver; Silver Compounds | 2006 |
Steric effects in the aerobic oxidation of pi-allylnickel(II) complexes with N-heterocyclic carbenes.
Topics: Allyl Compounds; Heterocyclic Compounds; Hydrocarbons; Magnetic Resonance Spectroscopy; Mass Spectrometry; Methane; Models, Molecular; Molecular Conformation; Nickel; Organometallic Compounds; Oxidation-Reduction; Spectroscopy, Fourier Transform Infrared | 2006 |
Stereoselective polymerization of rac- and meso-lactide catalyzed by sterically encumbered N-heterocyclic carbenes.
Topics: Catalysis; Hydrocarbons; Magnetic Resonance Spectroscopy; Methane; Polyesters; Stereoisomerism | 2006 |
Enyne metathesis-oxidation sequence for the synthesis of 2-phosphono pyrroles: proof of the "yne-then-ene" pathway.
Topics: Amines; Catalysis; Hydrocarbons; Methane; Molecular Structure; Oxidation-Reduction; Phosphorus; Pyrroles; Spectrum Analysis | 2007 |
Racemization in Prins cyclization reactions.
Topics: Acetates; Cyclization; Diphosphonates; Hydrocarbons; Hydrogen Peroxide; Isotope Labeling; Magnetic Resonance Spectroscopy; Mesylates; Methane; Models, Chemical; Optical Rotation; Pyrans; Solvents; Stereoisomerism; Temperature; Thermodynamics | 2006 |
Alkene cyclopropanation catalyzed by Halterman iron porphyrin: participation of organic bases as axial ligands.
Topics: Alkenes; Catalysis; Cyclopropanes; Diazonium Compounds; Hydrocarbons; Imidazoles; Iron; Kinetics; Ligands; Metalloporphyrins; Methane; Molecular Structure; Pyridines; Ruthenium Compounds; Stereoisomerism | 2006 |
Function of an N-heterocyclic carbene ligand based on concept of chiral mimetic.
Topics: Heterocyclic Compounds; Hydrocarbons; Ligands; Methane; Molecular Conformation; Molecular Mimicry; Stereoisomerism | 2006 |
Spin-spin contributions to the zero-field splitting tensor in organic triplets, carbenes and biradicals-a density functional and ab initio study.
Topics: Algorithms; Chlorophyll; Chlorophyll A; Electron Spin Resonance Spectroscopy; Free Radicals; Hydrocarbons; Methane; Molecular Structure; Oxygen; Quantum Theory | 2006 |
Epimerization reaction of a substituted vinylcyclopropane catalyzed by ruthenium carbenes: mechanistic analysis.
Topics: Catalysis; Cyclopropanes; Hydrocarbons; Methane; Models, Chemical; Molecular Conformation; Ruthenium; Stereoisomerism; Vinyl Compounds | 2006 |
Hydroaminomethylation with novel rhodium-carbene complexes: an efficient catalytic approach to pharmaceuticals.
Topics: Alkenes; Amines; Catalysis; Hydrocarbons; Imidazoles; Ligands; Methane; Methylation; Models, Chemical; Molecular Structure; Organometallic Compounds; Pharmaceutical Preparations; Piperidines; Propane; Rhodium; Styrenes | 2007 |
Removing the sting from the tail: reversible protonation of scorpionate ligands in cobalt(II) tris(carbene)borate complexes.
Topics: Boronic Acids; Chemistry, Inorganic; Cobalt; Crystallography, X-Ray; Hydrocarbons; Ligands; Magnetic Resonance Spectroscopy; Methane; Methylation; Molecular Structure; Protons | 2006 |
Chiral N-heterocyclic carbene catalyzed, enantioselective oxodiene Diels-Alder reactions with low catalyst loadings.
Topics: Aldehydes; Alkenes; Catalysis; Heterocyclic Compounds; Hydrocarbons; Ketones; Lactones; Methane; Stereoisomerism | 2006 |
Spectroscopic identification of carbenium and ammonium isomers of protonated aniline (AnH+): IR spectra of weakly bound AnH+ -Ln clusters (L = Ar, N2).
Topics: Aniline Compounds; Argon; Hydrocarbons; Isomerism; Ligands; Methane; Nitrogen; Protons; Quaternary Ammonium Compounds; Spectrometry, Mass, Electrospray Ionization; Spectrophotometry, Infrared | 2006 |
Lewis base activation of grignard reagents with N-heterocyclic carbenes. Cu-free catalytic enantioselective additions to gamma-chloro-alpha,beta-unsaturated esters.
Topics: Allyl Compounds; Catalysis; Copper; Esters; Heterocyclic Compounds; Hydrocarbons; Hydrocarbons, Chlorinated; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Stereoisomerism | 2006 |
Density functional theory studies on the mechanism of the reduction of CO2 to CO catalyzed by copper(I) boryl complexes.
Topics: Boron; Carbon Dioxide; Carbon Monoxide; Catalysis; Copper; Heterocyclic Compounds; Hydrocarbons; Hydrogen Bonding; Ligands; Methane; Molecular Structure; Organometallic Compounds; Oxidation-Reduction | 2006 |
A three-component tandem reductive aldol reaction catalyzed by N-heterocyclic carbene-copper complexes.
Topics: Catalysis; Copper; Heterocyclic Compounds; Hydrocarbons; Methane; Models, Molecular; Oxidation-Reduction | 2006 |
Quinone-annulated N-heterocyclic carbene-transition-metal complexes: observation of pi-backbonding using FT-IR spectroscopy and cyclic voltammetry.
Topics: Electrochemistry; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Organometallic Compounds; Quinones; Sensitivity and Specificity; Spectroscopy, Fourier Transform Infrared; Stereoisomerism; Transition Elements | 2006 |
All-carbon quaternary stereogenic centers by enantioselective cu-catalyzed conjugate additions promoted by a chiral N-heterocyclic carbene.
Topics: Carbon; Catalysis; Copper; Crystallography, X-Ray; Hydrocarbons; Methane; Organometallic Compounds; Stereoisomerism | 2007 |
Tandem oxidation of allylic and benzylic alcohols to esters catalyzed by N-heterocyclic carbenes.
Topics: Allyl Compounds; Benzyl Alcohols; Catalysis; Esters; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2007 |
Theoretical study on the mechanism of the [2+1] thermal cycloaddition between alkenes and stable singlet (phosphino)(silyl)carbenes.
Topics: Alkenes; Computer Simulation; Cyclization; Cyclopropanes; Hydrocarbons; Methane; Models, Chemical; Molecular Structure; Organosilicon Compounds; Stereoisomerism; Thermodynamics | 2007 |
Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation).
Topics: Electrons; Hydrocarbons; Methane; Molecular Structure; Organometallic Compounds; Palladium | 2007 |
Structural and theoretical investigation of 2-iminoimidazolines--carbene analogues of iminophosphoranes.
Topics: Catalysis; Crystallography, X-Ray; Ethylenes; Guanidine; Hydrocarbons; Hydrogen Bonding; Imidazolines; Imines; Ligands; Methane; Methanol; Models, Chemical; Nitrogen; Organometallic Compounds; Oxygen; Phosphoranes; Silicon; Sulfur; Titanium; Trimethylsilyl Compounds | 2007 |
Rigid dipeptide mimics: synthesis of enantiopure C6-functionalized pyrrolizidinone amino acids.
Topics: Alkylation; Amino Acids; Carbon; Carboxylic Acids; Catalysis; Crystallography, X-Ray; Dimethyl Sulfoxide; Diminazene; Dipeptides; Hydrocarbons; Hydrogen; Hydrogen Bonding; Methane; Models, Chemical; Molecular Mimicry; Molecular Structure; Pyrroles; Pyrrolidinones; Stereoisomerism; Temperature | 2007 |
N-heterocyclic carbene-catalyzed Mukaiyama aldol reactions.
Topics: Acetophenones; Aldehydes; Catalysis; Ethers; Hydrocarbons; Methane; Models, Chemical; Stereoisomerism; Temperature; Trimethylsilyl Compounds | 2007 |
Carbene stabilization by aryl substituents. Is bigger better?
Topics: Hydrocarbons; Methane; Molecular Structure | 2007 |
Zwitterionic polymerization of lactide to cyclic poly(lactide) by using N-heterocyclic carbene organocatalysts.
Topics: Cyclization; Heterocyclic Compounds; Hydrocarbons; Lactic Acid; Methane; Models, Chemical; Organometallic Compounds; Polyesters; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization | 2007 |
Stabilization of unsymmetrically annelated imidazol-2-ylidenes with respect to their higher group 14 homologues by n-/pi-HOMO inversion.
Topics: Electrons; Hydrocarbons; Imidazoles; Methane; Molecular Structure; Silanes; Spectrum Analysis | 2007 |
Enantioselective, cyclopentene-forming annulations via NHC-catalyzed benzoin-oxy-cope reactions.
Topics: Benzoin; Catalysis; Cyclopentanes; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Oxygen; Stereoisomerism | 2007 |
Total synthesis of (+/-) -phenserine via [4+1] cyclization of a bis(alkylthio)carbene and an indole isocyanate.
Topics: Cyclization; Hydrocarbons; Indoles; Isocyanates; Methane; Molecular Structure; Physostigmine; Sulfides | 2007 |
CuCl-induced formation and migration of isoindazolyl carbenoids.
Topics: Azo Compounds; Computers; Copper; Cyclization; Cyclopropanes; Diynes; Hydrocarbons; Indazoles; Isomerism; Methane; Models, Molecular; Molecular Structure | 2007 |
Weak distance dependence of through-bond interactions in tetrahydro-4H-thiopyran-4-ylidene end-capped oligo(cyclohexylidenes); a computational survey.
Topics: Computer Simulation; Energy Transfer; Hydrocarbons; Methane; Models, Chemical; Models, Molecular; Molecular Conformation; Pyrazoles | 2007 |
A highly enantioselective intramolecular Michael reaction catalyzed by N-heterocyclic carbenes.
Topics: Acetylation; Amides; Catalysis; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Stereoisomerism | 2007 |
Carbene-pyridine chelating 2Fe2S hydrogenase model complexes as highly active catalysts for the electrochemical reduction of protons from weak acid (HOAc).
Topics: Acetic Acid; Biomimetics; Catalysis; Electrochemistry; Hydrocarbons; Hydrogenase; Imidazolidines; Iron Chelating Agents; Iron-Sulfur Proteins; Methane; Models, Molecular; Organometallic Compounds; Oxidation-Reduction; Protons; Pyridines | 2007 |
Synthesis of stable isothiazole carbenes.
Topics: Crystallography, X-Ray; Dimerization; Hydrocarbons; Imidazoles; Methane; Models, Molecular; Molecular Structure; Protons; Thermodynamics; Thiazoles | 2007 |
Fischer carbene catalysis of alkynol cycloisomerization: application to the synthesis of the altromycin B disaccharide.
Topics: Alcohols; Alkynes; Aminoglycosides; Catalysis; Cyclization; Disaccharides; Hydrocarbons; Isomerism; Methane; Molecular Structure; Photochemistry | 2007 |
The total synthesis of siphonazole, a structurally unusual bis-oxazole natural product.
Topics: Biological Products; Hydrocarbons; Methane; Oxazoles; Rhodium | 2007 |
Mechanism of rhodium-catalyzed carbene formation from diazo compounds.
Topics: Azo Compounds; Catalysis; Hydrocarbons; Methane; Molecular Structure; Rhodium | 2007 |
Chiral N-heterocyclic carbenes in natural product synthesis: application of Ru-catalyzed asymmetric ring-opening/cross-metathesis and Cu-catalyzed allylic alkylation to total synthesis of baconipyrone C.
Topics: Alkylation; Catalysis; Copper; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Pyrones; Ruthenium; Stereoisomerism | 2007 |
Cyclodimerization of alkynes with phosphine-free ruthenium carbene complexes: carbene consumption by a shunted alkyne oligomerization.
Topics: Alkynes; Cyclization; Dimerization; Hydrocarbons; Methane; Phosphines; Polymers; Ruthenium Compounds | 2007 |
New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines.
Topics: Hydrocarbons; Methane; Phosphines; Phosphorus | 2006 |
Photo-cross-linked small-molecule microarrays as chemical genomic tools for dissecting protein-ligand interactions.
Topics: Binding, Competitive; Cross-Linking Reagents; Genomics; Glass; Hydrocarbons; Ligands; Methane; Photoaffinity Labels; Photochemistry; Protein Array Analysis; Proteins; Radioligand Assay; Structure-Activity Relationship; Surface Properties; Ultraviolet Rays | 2006 |
Stable P-heterocyclic carbenes: scope and limitations.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Phosphines | 2007 |
A mixed-valent, Fe(II)Fe(I), diiron complex reproduces the unique rotated state of the [FeFe]hydrogenase active site.
Topics: Binding Sites; Biomimetic Materials; Electron Spin Resonance Spectroscopy; Ferrous Compounds; Hydrocarbons; Hydrogenase; Imidazoles; Iron-Sulfur Proteins; Methane; Models, Molecular; Oxidation-Reduction; Protein Conformation; Spectrophotometry, Infrared | 2007 |
On the mechanism and stereochemistry of chiral lithium-carbenoid-promoted cyclopropanation reactions.
Topics: Cyclopropanes; Hydrocarbons; Lithium; Methane; Molecular Conformation; Thermodynamics | 2007 |
Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Hydrocarbons; Ligands; Methane; Models, Molecular; Molecular Structure; Nitrogen; Porphyrins | 2007 |
Small-molecule N-heterocyclic-carbene-containing olefin-metathesis catalysts for use in water.
Topics: Alkenes; Catalysis; Cyclization; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Water | 2007 |
Concurrent cyclopropanation by carbenes and carbanions? A density functional theory study on the reaction pathways.
Topics: Cyclopropanes; Halogens; Hydrocarbons; Methane; Models, Molecular; Molecular Conformation | 2007 |
Coordination features of bis(N-heterocyclic carbenes) and bis(oxazolines) with 1,3-alkylidene-2,4,6-trimethylbenzene spacers. Synthesis of the ligands and silver and palladium complexes.
Topics: Alkenes; Benzene Derivatives; Heterocyclic Compounds; Hydrocarbons; Isomerism; Ligands; Methane; Organometallic Compounds; Oxazoles; Palladium; Silver | 2007 |
Tuning the reactivity of dirhodium(II) complexes with axial N-heterocyclic carbene ligands: the arylation of aldehydes.
Topics: Aldehydes; Heterocyclic Compounds; Hydrocarbons; Ligands; Methane; Models, Molecular; Molecular Structure; Rhodium | 2007 |
Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes.
Topics: Alkenes; Catalysis; Hydrocarbons; Methane; Organometallic Compounds; Ruthenium; Stereoisomerism | 2007 |
(N-heterocyclic carbene)gold(I)-catalyzed cycloisomerization of cyclohexadienyl alkynes to Tetracyclo[3.3.0.0(2,8).0(4,6)]octanes.
Topics: Alkynes; Catalysis; Crystallography, X-Ray; Cyclization; Cyclohexenes; Gold; Hydrocarbons; Methane; Octanes; Stereoisomerism | 2007 |
New N-heterocyclic carbene ligand and its application in asymmetric nickel-catalyzed aldehyde/alkyne reductive couplings.
Topics: Aldehydes; Alkynes; Catalysis; Hydrocarbons; Ligands; Macrocyclic Compounds; Methane; Molecular Structure; Nickel; Oxidation-Reduction; Stereoisomerism | 2007 |
Synthesis of alkyl-substituted six-membered lactones through ring-closing metathesis of homoallyl acrylates. An easy route to pyran-2-ones, constituents of tobacco flavor.
Topics: Carbon; Catalysis; Chemistry, Organic; Hydrocarbons; Lactones; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Nicotiana; Pyrans; Ruthenium | 2007 |
A singlet aryl-CF3 carbene: 2-benzothienyl(trifluoromethyl)carbene and interconversion with a strained cyclic allene.
Topics: Affinity Labels; Alkadienes; Diazomethane; Hydrocarbons; Hydrocarbons, Fluorinated; Methane; Molecular Structure; Spectrophotometry, Infrared; Spectrophotometry, Ultraviolet | 2007 |
Non-metathesis reactions of ruthenium carbene catalysts and their application to the synthesis of nitrogen-containing heterocycles.
Topics: Alkenes; Catalysis; Cyclization; Cyclopropanes; Free Radicals; Heterocyclic Compounds; Hydrocarbons; Hydrogenation; Indoles; Isomerism; Methane; Molecular Structure; Nitrogen; Ruthenium Compounds; Silanes | 2007 |
Synthesis of N-heterocyclic carbene palladium(II) bis-phosphine complexes and their decomposition in the presence of aryl halides.
Topics: Hydrocarbons; Hydrocarbons, Halogenated; Methane; Molecular Conformation; Molecular Structure; Organometallic Compounds; Palladium; Phosphines | 2007 |
The first N-heterocyclic carbene-based nickel catalyst for C-S coupling.
Topics: Carbon; Catalysis; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Nickel; Nitrogen; Sulfur; Transition Elements | 2007 |
Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes.
Topics: Alkadienes; Catalysis; Cross-Linking Reagents; Gold; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Vinyl Compounds | 2007 |
Up to seven-component adducts by unprecedented multiple alkyne and carbonyl insertions in the metal-carbon bond of chromium alkoxy alkynyl carbene complexes.
Topics: Alkynes; Carbon; Chromium; Crystallography, X-Ray; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds | 2007 |
Asymmetric total synthesis of (-)-indicol by a carbene cyclization-cycloaddition cascade strategy.
Topics: Azo Compounds; Catalysis; Cyclization; Diterpenes; Hydrocarbons; Ketones; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Ruthenium; Stereoisomerism | 2007 |
Deactivation of ruthenium olefin metathesis catalysts through intramolecular carbene-arene bond formation.
Topics: Alkenes; Benzene Derivatives; Catalysis; Crystallography, X-Ray; Cyclization; Hydrocarbons; Ligands; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Organometallic Compounds; Ruthenium; Sensitivity and Specificity; Stereoisomerism | 2007 |
Diastereoselective synthesis of three-, five-, six-, and seven-membered rings from Fischer carbene complexes and 4-unsubstituted 1-amino-1,3-dienes.
Topics: Alkenes; Amination; Benzaldehydes; Cyclization; Hydrocarbons; Methane; Molecular Structure; Stereoisomerism | 2008 |
Rapid synthesis of medium-ring fused polycarbocyclic systems by rearrangement of carbenoid-derived oxonium ylides.
Topics: Biological Products; Hydrocarbons; Macrocyclic Compounds; Methane; Molecular Structure; Oxygen; Time Factors | 2007 |
Nucleophilic carbene and HOAt relay catalysis in an amide bond coupling: an orthogonal peptide bond forming reaction.
Topics: Amides; Aza Compounds; Catalysis; Hydrocarbons; Methane; Molecular Structure; Peptides; Stereoisomerism; Triazoles | 2007 |
Total synthesis of (+/-)-phomactin B2 via an intramolecular cyclohexadienone annulation of a chromium carbene complex.
Topics: Chromium; Cyclization; Cyclohexanes; Cyclohexenes; Epoxy Compounds; Heterocyclic Compounds, 3-Ring; Hydrocarbons; Methane; Molecular Conformation; Organometallic Compounds; Stereoisomerism | 2007 |
N-heterocyclic carbene-catalyzed redox amidations of alpha-functionalized aldehydes with amines.
Topics: Aldehydes; Amides; Amines; Catalysis; Hydrocarbons; Methane; Molecular Structure; Oxidation-Reduction; Triazoles | 2007 |
A general and regioselective synthesis of cyclopentenone derivatives through nickel(0)-mediated [3 + 2] cyclization of alkenyl Fischer carbene complexes and internal alkynes.
Topics: Alkenes; Alkynes; Boron; Catalysis; Cyclization; Cyclopentanes; Hydrocarbons; Methane; Models, Chemical; Nickel; Palladium; Stereoisomerism | 2007 |
Anticancer and antimicrobial metallopharmaceutical agents based on palladium, gold, and silver N-heterocyclic carbene complexes.
Topics: Anti-Infective Agents; Antineoplastic Agents; Bacillus subtilis; Cell Line, Tumor; Cell Proliferation; Cisplatin; Gold; Heterocyclic Compounds; Humans; Hydrocarbons; Methane; Microbial Viability; Molecular Structure; Silver; Tumor Suppressor Protein p53 | 2007 |
Electronic stabilization of ground state triplet carbenes.
Topics: Computer Simulation; Electrons; Hydrocarbons; Methane; Models, Chemical; Molecular Structure; Quantum Theory | 2007 |
Assessing native and non-native conformational states of a protein by methylene carbene labeling: the case of Bacillus licheniformis beta-lactamase.
Topics: Bacillus; beta-Lactamases; Computer Simulation; Methane; Protein Conformation; Protein Folding; Spectrometry, Fluorescence | 2007 |
An electronic rationale for observed initiation rates in ruthenium-mediated olefin metathesis: charge donation in phosphine and N-heterocyclic carbene ligands.
Topics: Alkenes; Electrons; Heterocyclic Compounds; Hydrocarbons; Kinetics; Ligands; Methane; Phosphines; Ruthenium | 2007 |
Carbocyclization reaction of omega-iodo- and 1,omega-diiodo-1-alkynes without the loss of iodine atoms through a carbenoid-chain process.
Topics: Alkynes; Cyclization; Hydrocarbons; Iodine; Methane; Molecular Structure; Stereoisomerism | 2008 |
Concise assembly of highly substituted furan-fused 1,4-thiazepines and their Diels-Alder reactions with benzynes.
Topics: Alkynes; Benzene Derivatives; Ethylenes; Hydrocarbons; Ketones; Methane; Molecular Structure; Stereoisomerism; Thiazepines | 2008 |
Tris(2,4,6-trimethoxyphenyl)methyl carbenium ion for charge derivatization of amines and amino acids.
Topics: Amines; Amino Acids; Electrochemistry; Ions; Methane; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; Static Electricity | 2008 |
Enantioselective, NHC-catalyzed bicyclo-beta-lactam formation via direct annulations of enals and unsaturated N-sulfonyl ketimines.
Topics: Amino Acids, Sulfur; beta-Lactams; Bridged Bicyclo Compounds; Catalysis; Hydrocarbons; Methane; Stereoisomerism | 2008 |
Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene.
Topics: Alkenes; Amination; Aziridines; Catalysis; Heterocyclic Compounds; Hydrocarbons; Ketones; Methane; Molecular Structure; Palladium; Stereoisomerism | 2008 |
The in vitro incorporation of the methylene carbon atom of glycine bone marrow fats.
Topics: Bone Marrow; Carbon; Carbon Isotopes; Glycine; In Vitro Techniques; Methane | 1949 |
Oxidation of a methylene group with hypochlorite.
Topics: Hypochlorous Acid; Methane; Oxidation-Reduction | 1948 |
The distribution in rat tissues of the methylene carbonatom of glycine labeled with C14.
Topics: Animals; Fabaceae; Glycine; Methane; Rats | 1949 |
Studies on the reaction between aromatic nitro compounds and active methylene groups.
Topics: Humans; Hydrocarbons; Methane; Nitro Compounds | 1949 |
N-heterocyclic carbene ligands in copper-catalyzed addition of diethylzinc to N-sulfonylimines.
Topics: Catalysis; Copper; Heterocyclic Compounds; Hydrocarbons; Imidazoles; Imines; Ligands; Methane; Molecular Structure; Organometallic Compounds; Sulfones | 2008 |
Increased efficiency in cross-metathesis reactions of sterically hindered olefins.
Topics: Alkenes; Catalysis; Heterocyclic Compounds; Hydrocarbons; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Ruthenium | 2008 |
Reactive intermediates from DMDO oxidation of ynamides. Trapping of a de novo chiral push-pull carbene via cyclopropanation.
Topics: Cyclopropanes; Epoxy Compounds; Hydrocarbons; Methane; Molecular Structure; Oxazoles; Oxidation-Reduction | 2008 |
The catalytic dehydrogenation of ammonia-borane involving an unexpected hydrogen transfer to ligated carbene and subsequent carbon-hydrogen activation.
Topics: Ammonia; Boranes; Catalysis; Computer Simulation; Hydrocarbons; Hydrogen; Hydrogenation; Ligands; Methane; Models, Chemical; Nickel; Organometallic Compounds; Quantum Theory | 2008 |
Thermal and catalytic transylidations between halonium ylides and synthesis and reaction of stable aliphatic chloronium ylides.
Topics: Alkenes; Catalysis; Cyclooctanes; Cyclopropanes; Halogens; Hot Temperature; Hydrocarbons; Hydrocarbons, Halogenated; Methane; Rhodium | 2008 |
Synthesis and activity of ruthenium olefin metathesis catalysts coordinated with thiazol-2-ylidene ligands.
Topics: Alkenes; Catalysis; Crystallography, X-Ray; Cyclization; Hydrocarbons; Ligands; Methane; Molecular Structure; Organometallic Compounds; Ruthenium; Thiazoles | 2008 |
Pd-catalyzed aryl amination mediated by well defined, N-heterocyclic carbene (NHC)-Pd precatalysts, PEPPSI.
Topics: Amination; Catalysis; Heterocyclic Compounds; Hydrocarbons; Ligands; Methane; Palladium; Phosphines; Temperature | 2008 |
Studies on the effect of the substitution of deuterium in the methylene groups of succinic acid on the action of succinic dehydrogenase.
Topics: Deuterium; Electron Transport Complex II; Enzymes; Methane; Succinate Dehydrogenase; Succinic Acid | 1949 |
Highly diastereo- and enantioselective additions of homoenolates to nitrones catalyzed by N-heterocyclic carbenes.
Topics: Aldehydes; Catalysis; Esters; Heterocyclic Compounds; Hydrocarbons; Methane; Molecular Structure; Nitrogen Oxides; Stereoisomerism | 2008 |
N-heterocyclic carbene-catalyzed silyl enol ether formation.
Topics: Catalysis; Combinatorial Chemistry Techniques; Ethers; Hydrocarbons; Ketones; Methane; Molecular Structure; Organosilicon Compounds | 2008 |
Ruthenium carbene complexes bearing an anionic carboxylate chelated to a hemilabile ligand.
Topics: Anions; Carboxylic Acids; Catalysis; Crystallography, X-Ray; Cyclization; Esters; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Ruthenium; Time Factors | 2008 |
Molecular structure and vibrational assignment of melaminium phthalate by density functional theory (DFT) and ab initio Hartree-Fock (HF) calculations.
Topics: Carbon; Data Interpretation, Statistical; Hydrogen Bonding; Methane; Models, Chemical; Models, Statistical; Molecular Conformation; Molecular Structure; Phthalic Acids; Reproducibility of Results; Spectrophotometry; Spectrophotometry, Infrared; Triazines; X-Rays | 2008 |
Mild synthesis of organophosphorus compounds: reaction of phosphorus-containing carbenoids with organoboranes.
Topics: Boranes; Esters; Hydrocarbons; Methane; Molecular Structure; Organophosphorus Compounds; Phosphorus | 2008 |
Diastereoselective cyclopropanation of ketone enols with Fischer carbene complexes.
Topics: Cyclization; Cyclopropanes; Hydrocarbons; Ketones; Lithium; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2008 |
Direct amination of homoenolates catalyzed by N-heterocyclic carbenes.
Topics: Amination; Catalysis; Heterocyclic Compounds; Hydrocarbons; Ketones; Methane; Molecular Structure; Stereoisomerism | 2008 |
Synthesis, stability, and antimicrobial studies of electronically tuned silver acetate N-heterocyclic carbenes.
Topics: Acetates; Anti-Bacterial Agents; Burkholderia; Crystallography, X-Ray; Dose-Response Relationship, Drug; Electrons; Escherichia coli; Heterocyclic Compounds; Methane; Methylation; Microbial Sensitivity Tests; Models, Molecular; Molecular Structure; Organometallic Compounds; Pseudomonas aeruginosa; Silver Compounds; Structure-Activity Relationship; Water | 2008 |
N-heterocyclic carbene-catalyzed nucleophilic aroylation of fluorobenzenes.
Topics: Benzaldehydes; Benzophenones; Catalysis; Fluorobenzenes; Heterocyclic Compounds; Hydrocarbons; Methane | 2008 |
Methylene-bridged bis(benzimidazolium) salt as a highly efficient catalyst for the benzoin reaction in aqueous media.
Topics: Benzaldehydes; Benzimidazoles; Benzoin; Catalysis; Hydrocarbons; Methane; Molecular Structure; Salts; Stereoisomerism; Water | 2008 |
Highly active iridium(I) complexes for catalytic hydrogen isotope exchange.
Topics: Catalysis; Deuterium; Heterocyclic Compounds; Hydrocarbons; Hydrogen; Iridium; Isotope Labeling; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Phosphines | 2008 |
Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes.
Topics: Aldehydes; Alkenes; Benzaldehydes; Catalysis; Hydrocarbons; Methane; Models, Molecular; Stereoisomerism; Triazoles | 2008 |
Correlation between thermal and mass spectral techniques for the characterization of allenylidene and carbene complexes.
Topics: Alkenes; Carbon; Carbon Monoxide; Differential Thermal Analysis; Gases; Hot Temperature; Kinetics; Ligands; Mass Spectrometry; Methane; Models, Chemical; Nitrogen; Solvents; Temperature; Thermodynamics; Thermogravimetry | 2008 |
Calix[4]arene derivatives monosubstituted at all four methylene bridges.
Topics: Alcohols; Calixarenes; Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure; Phenols; Propanols; Stereoisomerism; Trifluoroethanol | 2008 |
N-heterocyclic carbene complexes of Rh: reaction with dioxygen without oxidation.
Topics: Heterocyclic Compounds; Methane; Models, Chemical; Models, Molecular; Molecular Structure; Organometallic Compounds; Oxygen; Rhodium; Spectrometry, X-Ray Emission | 2008 |
Formation of monometallic single-molecule magnets with an Stotal value of 3/2 in diluted frozen solution.
Topics: Anisotropy; Cobalt; Crystallography, X-Ray; Freezing; Hydrocarbons; Magnetics; Methane; Models, Molecular; Molecular Conformation; Molecular Structure; Organometallic Compounds; Photochemistry; Pyridines; Spin Labels; Temperature | 2008 |
Aziridination of aliphatic alkenes catalyzed by N-heterocyclic carbene copper complexes.
Topics: Alkenes; Aziridines; Catalysis; Copper; Methane; Molecular Structure | 2008 |
Synthesis of naphthalenes through three-component coupling of alkynes, Fischer carbene complexes, and benzaldehyde hydrazones via isoindole intermediates.
Topics: Alkynes; Benzaldehydes; Hydrazones; Isoindoles; Methane; Naphthalenes | 2008 |
Thermal C2-C6 cyclization of enyne-carbodiimides: experimental evidence contradicts a diradical and suggests a carbene intermediate.
Topics: Alkadienes; Amination; Carbodiimides; Carbon; Crystallography, X-Ray; Cyclization; Free Radicals; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Temperature | 2008 |
Palladium-catalyzed carbene insertion and trapping with carbon nucleophiles.
Topics: Carbon; Catalysis; Diazomethane; Hydrocarbons, Halogenated; Methane; Molecular Structure; Palladium; Silanes; Stereoisomerism; Trimethylsilyl Compounds; Vinyl Compounds | 2008 |
Room-temperature Kumada cross-coupling of unactivated aryl chlorides catalyzed by N-heterocylic carbene-based nickel(II) complexes.
Topics: Catalysis; Hydrocarbons, Aromatic; Hydrocarbons, Chlorinated; Ligands; Methane; Molecular Structure; Nickel; Organometallic Compounds; Pyridines; Stereoisomerism; Temperature | 2008 |
Molecular electrostatic potentials of divalent carbon(0) compounds.
Topics: Boranes; Carbon; Ligands; Methane; Models, Chemical; Protons; Static Electricity | 2008 |
N-heterocyclic carbene (NHC)-catalyzed direct amidation of aldehydes with nitroso compounds.
Topics: Acrolein; Aldehydes; Aziridines; Catalysis; Combinatorial Chemistry Techniques; Hydroxamic Acids; Methane; Molecular Structure; Nitroso Compounds | 2008 |
Organoiron compounds derived from the indium 'carbene analogues', [In(N(Ar)C(Me))2CH] (Ar = dipp = 2,6-iPr2C6H3; = Mes = 2,4,6-Me3C6H2).
Topics: Crystallography, X-Ray; Ferric Compounds; Indium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Stereoisomerism | 2008 |
Gas-phase carbene radical anions: new mechanistic insights.
Topics: Anions; Gases; Hydrocarbons, Chlorinated; Kinetics; Methane; Thermodynamics | 2008 |
Olefin metathesis catalyst: stabilization effect of backbone substitutions of N-heterocyclic carbene.
Topics: Alkenes; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Ruthenium | 2008 |
Synthesis of hyperbranched poly(aryl amine)s via a carbene insertion approach.
Topics: Amines; Chromatography, Gel; Fluorine; Magnetic Resonance Spectroscopy; Methane; Polymers; Solvents; Spectrophotometry, Infrared; Spectrophotometry, Ultraviolet | 2008 |
Highly convenient amine-free sonogashira coupling in air in a polar mixed aqueous medium by trans- and cis-[(NHC)2PdX2] (X=Cl, Br) complexes of N/O-functionalized N-heterocyclic carbenes.
Topics: Heterocyclic Compounds; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Spectrometry, Mass, Electrospray Ionization; Spectrophotometry, Infrared; Water | 2008 |
Intermolecular hydroamination of allenes with N-unsubstituted carbamates catalyzed by a gold(I) N-heterocyclic carbene complex.
Topics: Alkadienes; Benzoates; Carbamates; Catalysis; Combinatorial Chemistry Techniques; Methane; Molecular Structure; Organogold Compounds; Stereoisomerism | 2008 |
C-H carbene insertion of alpha-diazo acetamides by photolysis in non-conventional media.
Topics: Carbon; Diazonium Compounds; Hydrogen; Methane; Molecular Structure; Photolysis; Solvents | 2008 |
Total synthesis of (-)-dactylolide and formal synthesis of (-)-zampanolide via target oriented beta-C-glycoside formation.
Topics: Alkenes; Bridged Bicyclo Compounds, Heterocyclic; Cell Line, Tumor; Cell Survival; Cross-Linking Reagents; Glycosides; Humans; Lactones; Macrolides; Methane; Molecular Structure; Oxidation-Reduction; Palladium | 2008 |
Rh-N-heterocyclic carbene (NHC) complex-catalyzed addition of phenylboronic acid to N-sulfonyl and N-phosphinoyl aldimines.
Topics: Boronic Acids; Catalysis; Heterocyclic Compounds; Imines; Methane | 2008 |
Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation levels (n = 4, 8).
Topics: Biomimetic Materials; Ferrous Compounds; Iron-Sulfur Proteins; Methane; Models, Molecular; Nitrogenase; Oxidation-Reduction; Solutions; Spectroscopy, Mossbauer; X-Ray Diffraction | 2008 |
Series of mixed valent Fe(II)Fe(I) complexes that model the Hox state of [FeFe]hydrogenase: redox properties, density-functional theory investigation, and reactivities with extrinsic CO.
Topics: Binding Sites; Carbon Monoxide; Electrochemistry; Electrons; Hydrogenase; Iron; Iron-Sulfur Proteins; Ligands; Methane; Organometallic Compounds; Oxidation-Reduction; Quantum Theory; Spectroscopy, Fourier Transform Infrared | 2008 |
Metal carbene dimerization: versatile approach to polyalkynylethenes.
Topics: Dimerization; Ethylenes; Metals; Methane | 2008 |
A new type of self-supported, polymeric Ru-carbene complex for homogeneous catalysis and heterogeneous recovery: synthesis and catalytic activities for ring-closing metathesis.
Topics: Catalysis; Cyclization; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Organometallic Compounds; Polymers; Ruthenium | 2008 |
Ruthenium-based olefin metathesis catalysts coordinated with unsymmetrical N-heterocyclic carbene ligands: synthesis, structure, and catalytic activity.
Topics: Alkenes; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Kinetics; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Ruthenium; Stereoisomerism; Time Factors | 2008 |
End capping ring-opening olefin metathesis polymerization polymers with vinyl lactones.
Topics: Alkenes; Dioxoles; Lactones; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Organometallic Compounds; Polymers; Reference Standards; Ruthenium; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; Stereoisomerism; Time Factors | 2008 |
A non-cross-linked soluble polystyrene-supported ruthenium catalyst for carbenoid transfer reactions.
Topics: Alkenes; Catalysis; Cross-Linking Reagents; Cyclopropanes; Metal Nanoparticles; Methane; Microscopy, Electron, Transmission; Molecular Structure; Polystyrenes; Ruthenium; Solubility; Spectrum Analysis | 2008 |
Ultrafast UV-vis and IR studies of p-biphenylyl acetyl and carbomethoxy carbenes.
Topics: Diazonium Compounds; Ketones; Methane; Models, Chemical; Molecular Structure; Phenylacetates; Spectrophotometry, Infrared; Spectrophotometry, Ultraviolet; Time Factors | 2008 |
Chiral NHC-catalyzed oxodiene Diels-Alder reactions with alpha-chloroaldehyde bisulfite salts.
Topics: Aldehydes; Cyclization; Heterocyclic Compounds; Hydrocarbons, Chlorinated; Lactones; Methane; Stereoisomerism; Sulfites | 2008 |
C-H insertion processes on stabilized indolyl and ortho-aminophenyl Fischer carbene complexes: synthesis of azepino[3,2,1-hi] indole, benzazepine and indole derivatives.
Topics: Alkynes; Azepines; Benzazepines; Indoles; Methane; Molecular Structure; Stereoisomerism | 2008 |
Palladium-catalyzed 1,2-addition of potassium aryl- and alkenyltrifluoroborates to aldehydes using thioether-imidazolinium carbene ligands.
Topics: Aldehydes; Alkenes; Borates; Catalysis; Hydrocarbons, Cyclic; Hydrocarbons, Fluorinated; Imidazolines; Ligands; Methane; Models, Chemical; Palladium; Potassium; Solutions; Sulfides; Water | 2008 |
Pd-catalyzed efficient one-pot sequential cross-coupling reactions of aryl dihalides.
Topics: Benzene Derivatives; Catalysis; Hydrocarbons, Halogenated; Ligands; Methane; Palladium | 2008 |
Chiral N-heterocyclic carbene-catalyzed formal [4+2] cycloaddition of ketenes with enones: highly enantioselective synthesis of trans- and cis-delta-lactones.
Topics: Cyclization; Ethylenes; Heterocyclic Compounds; Ketones; Lactones; Magnetic Resonance Spectroscopy; Methane; Spectrometry, Mass, Electrospray Ionization; Stereoisomerism | 2008 |
Tamed tigers: stabilization of reactive carbenes.
Topics: Crystallography, X-Ray; Hydroxylation; Metals; Methane; Molecular Structure; Oxygen | 2008 |
A highly active water-soluble cross-coupling catalyst based on dendritic polyglycerol N-heterocyclic carbene palladium complexes.
Topics: Catalysis; Dendrimers; Glycerol; Ligands; Methane; Palladium; Polymers; Solubility; Water | 2008 |
Practical Heck-Mizoroki coupling protocol for challenging substrates mediated by an N-heterocyclic carbene-ligated palladacycle.
Topics: Catalysis; Heterocyclic Compounds; Methane; Organometallic Compounds; Palladium | 2008 |
Intramolecular Huisgen-type cyclization of platinum-bound pyrylium ions with alkenes and subsequent insertion into a benzylic C-H bond.
Topics: Alkenes; Benzene; Carbon; Catalysis; Crystallography, X-Ray; Cyclization; Hydrogen; Ions; Methane; Models, Molecular; Molecular Structure; Platinum Compounds | 2008 |
Evaluation of incremental correlation energies for open-shell systems: application to the intermediates of the 4-exo cyclization, arduengo carbenes and an anionic water cluster.
Topics: Anions; Carboxylic Acids; Computer Simulation; Cyclization; Electrons; Methane; Models, Chemical; Quantum Theory; Water | 2008 |
Substituent effects on singlet-triplet gaps and mechanisms of 1,2-rearrangements of 1,3-oxazol-2-ylidenes to 1,3-oxazoles.
Topics: Computer Simulation; Electrons; Methane; Models, Chemical; Molecular Structure; Oxazoles; Stereoisomerism; Vibration | 2008 |
Mitochondria-targeted chemotherapeutics: the rational design of gold(I) N-heterocyclic carbene complexes that are selectively toxic to cancer cells and target protein selenols in preference to thiols.
Topics: Antineoplastic Agents; Apoptosis; Breast Neoplasms; Cell Line, Tumor; Cysteine; Drug Design; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; Methane; Mitochondria; Mitochondrial Proteins; Organometallic Compounds; Selenocysteine; Thioredoxin-Disulfide Reductase | 2008 |
An unprecedented, figure-of-eight, dinuclear iridium(I) dicarbene and new iridium(III) 'pincer' complexes.
Topics: Cations; Heterocyclic Compounds; Imidazoles; Iridium; Ligands; Methane; Molecular Structure; Organometallic Compounds | 2008 |
Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis.
Topics: Amides; Catalysis; Heterocyclic Compounds; Indoles; Ligands; Methane; Models, Chemical; Oxindoles; Palladium; Stereoisomerism | 2008 |
N-heterocyclic carbene-catalyzed oxidation of unactivated aldehydes to esters.
Topics: Alcohols; Aldehydes; Catalysis; Esters; Methane; Oxidation-Reduction | 2008 |
Does Gd@C82 have an anomalous endohedral structure? Synthesis and single crystal X-ray structure of the carbene adduct.
Topics: Adamantane; Crystallography, X-Ray; Fullerenes; Gadolinium; Methane; Molecular Structure; Organometallic Compounds | 2008 |
Lessons from nature: biomimetic organocatalytic carbon-carbon bond formations.
Topics: Amino Acids; Biomimetics; Carbohydrates; Carbon; Catalysis; Chemistry, Organic; Dihydroxyacetone; Methane; Models, Molecular; Organic Chemicals; Phosphoenolpyruvate; Stereoisomerism; Sugar Acids; Transketolase | 2008 |
Mechanism of hydrolysis of dicholine esters with long polymethylene chain by human butyrylcholinesterase.
Topics: Amino Acid Motifs; Butyrylcholinesterase; Carbon; Catalytic Domain; Choline; Esters; Humans; Hydrolysis; Kinetics; Mass Spectrometry; Methane; Models, Biological; Models, Molecular; Pipecolic Acids; Protein Binding; Serine | 2008 |
A second generation formal synthesis of (-)-cephalotaxine.
Topics: Diazomethane; Harringtonines; Homoharringtonine; Methane; Proline; Stereoisomerism; Tin Compounds; Trimethylsilyl Compounds | 2008 |
Chemistry. Bringing stability to highly reduced iron-sulfur clusters.
Topics: Aniline Compounds; Cysteine; Dimerization; Electrons; Ferrous Compounds; Imidazoles; Iron-Sulfur Proteins; Ligands; Methane; Models, Molecular; Molecular Mimicry; Oxidation-Reduction; Oxidoreductases; Spectroscopy, Mossbauer; Sulfur; X-Ray Diffraction | 2008 |
Formal cycloaddition of disubstituted ketenes with 2-oxoaldehydes catalyzed by chiral N-heterocyclic carbenes.
Topics: Aldehydes; Catalysis; Ethylenes; Ketones; Methane; Stereoisomerism | 2008 |
Copper-catalyzed highly enantioselective carbenoid insertion into Si-H bonds.
Topics: Catalysis; Copper; Hydrogen; Methane; Silanes; Silicon; Stereoisomerism | 2008 |
A [(NHC)CuCl] complex as a latent Click catalyst.
Topics: Acetylene; Azides; Catalysis; Copper; Crystallography, X-Ray; Cyclization; Heterocyclic Compounds; Imidazolidines; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism; Triazoles | 2008 |
Pressure jump relaxation investigations of lipid membranes using FTIR spectroscopy.
Topics: Energy Transfer; Kinetics; Methane; Molecular Conformation; Phase Transition; Phospholipids; Pressure; Spectroscopy, Fourier Transform Infrared; Thermodynamics; Vibration; Water | 2009 |
Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates.
Topics: Alkadienes; Amides; Catalysis; Malonates; Methane; Molecular Structure; Phenylalanine; Stereoisomerism; Sulfonylurea Compounds | 2008 |
Reduction of pyrrolyl- and indolylamides with BH3 x THF: cyclodeoxygenation versus deoxygenation.
Topics: Amides; Boranes; Cyclization; Indoles; Kinetics; Methane; Phenols; Pyrroles | 2008 |
Efficient Negishi coupling reactions of aryl chlorides catalyzed by binuclear and mononuclear nickel-N-heterocyclic carbene complexes.
Topics: Catalysis; Cross-Linking Reagents; Heterocyclic Compounds; Hydrocarbons, Chlorinated; Methane; Nickel | 2008 |
Pyrido[1,2-a][1,2,4]triazol-3-ylidenes as a new family of stable annulated N-heterocyclic carbenes: synthesis, reactivity, and their application in coordination chemistry and organocatalysis.
Topics: Catalysis; Heterocyclic Compounds; Methane; Triazoles | 2008 |
Biomimetic carbene-catalyzed oxidations of aldehydes using TEMPO.
Topics: Aldehydes; Biomimetics; Catalysis; Cyclic N-Oxides; Esters; Heterocyclic Compounds; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2008 |
Steric effect of methylene groups.
Topics: Humans; Methane | 1948 |
Reactions of alpha-cyanoprene (1-cyanobuta-1 : 3-diene); Addition of reactive methylene compounds.
Topics: Methane; Polyenes | 1948 |
Cinchoninaldehyde and reactive methylene compounds.
Topics: Methane | 1948 |
An improved method for the synthesis of zirconium (CCC-N-heterocyclic carbene) pincer complexes and applications in hydroamination.
Topics: Amination; Amines; Heterocyclic Compounds; Methane; Organometallic Compounds; Zirconium | 2008 |
Carbene-stabilized diphosphorus.
Topics: Imidazoles; Imidazolidines; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Phosphorus | 2008 |
Chiral palladium(II) complexes possessing a tridentate N-heterocyclic carbene amidate alkoxide ligand: access to oxygen-bridging dimer structures.
Topics: Boronic Acids; Catalysis; Dimerization; Heterocyclic Compounds; Ligands; Methane; Organometallic Compounds; Oxygen; Palladium; Stereoisomerism | 2008 |
Nucleophilic carbene catalyzed synthesis of 1,2 amino alcohols via azidation of epoxy aldehydes.
Topics: Aldehydes; Amino Alcohols; Azides; Catalysis; Hydroxylation; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation; Oxazoles; Stereoisomerism | 2008 |
Trifluoromethyldiazirine: an effective photo-induced cross-linking probe for exploring amyloid formation.
Topics: Amino Acid Sequence; Amyloid; Amyloid beta-Peptides; Azirines; Cross-Linking Reagents; Methane; Peptides; Phenylalanine; Protein Structure, Tertiary; Spectrometry, Mass, Electrospray Ionization; Ultraviolet Rays | 2008 |
Toxicity of copper(I)-NHC complexes against human tumor cells: induction of cell cycle arrest, apoptosis, and DNA cleavage.
Topics: Apoptosis; Cell Cycle; Cell Line, Tumor; Copper; DNA Cleavage; Heterocyclic Compounds; Humans; Ligands; Methane; Organometallic Compounds | 2009 |
A new bio-active surface for protein immobilisation via copper-free 'click' between azido SAM and alkynyl Fischer carbene complex.
Topics: Animals; Azides; Cattle; Dansyl Compounds; Immobilized Proteins; Methane; Serum Albumin, Bovine; Silicates; Spectrometry, Fluorescence | 2008 |
[4+2] cycloaddition of ketenes with N-benzoyldiazenes catalyzed by N-heterocyclic carbenes.
Topics: Aza Compounds; Benzene; Catalysis; Cyclization; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Stereoisomerism | 2009 |
NHC-catalyzed reactions of aryloxyacetaldehydes: a domino elimination/conjugate addition/acylation process for the synthesis of substituted coumarins.
Topics: Acetaldehyde; Catalysis; Coumarins; Cyclization; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2009 |
Cyclic ketimines as superior electrophiles for NHC-catalyzed homoenolate additions with broad scope and low catalyst loadings.
Topics: Acrolein; Catalysis; Chemistry, Organic; Cyclization; Imidazoles; Imines; Ketones; Lactams; Methane; Models, Chemical; Molecular Structure; Stereoisomerism | 2008 |
Mechanism of the [(NHC)Au(I)]-catalyzed rearrangement of allylic acetates. A DFT study.
Topics: Acetates; Allyl Compounds; Catalysis; Computer Simulation; Gold; Heterocyclic Compounds; Methane; Models, Chemical; Molecular Structure; Organogold Compounds | 2009 |
Addition of N-heterocyclic carbenes to imines: phenoxide assisted deprotonation of an imidazolium moiety and generation of breslow intermediates derived from imines.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Imines; Methane; Models, Molecular; Molecular Structure; Oxides; Protons; Stereoisomerism | 2009 |
Efficient and selective telomerization of 1,3-butadiene with diols catalyzed by palladium-carbene complexes.
Topics: Butadienes; Catalysis; Ethers; Glycols; Methane; Organometallic Compounds; Palladium; Polymers; Substrate Specificity | 2009 |
Efficient and divergent synthesis of cyclophosphamide analogues from 2-arylamino-3-acetyl-5,6-dihydro-4H-pyrans.
Topics: Acetylation; Amines; Cyclophosphamide; Hydrogen; Methane; Models, Molecular; Molecular Structure; Pyrans | 2008 |
Asymmetric esterification of ketenes catalyzed by an N-heterocyclic carbene.
Topics: Catalysis; Esterification; Ketones; Methane; Molecular Structure; Stereoisomerism | 2009 |
From solvolysis to self-assembly.
Topics: Alkynes; Chemistry, Organic; History, 20th Century; History, 21st Century; Iodine; Macromolecular Substances; Methane; United States; Vinyl Compounds | 2009 |
Photochromic diarylethene-containing ionic liquids and N-heterocyclic carbenes.
Topics: Ethylenes; Heterocyclic Compounds; Ionic Liquids; Methane; Models, Molecular; Molecular Structure; Photochemistry; Spectrophotometry | 2009 |
Conformations of N-heterocyclic carbene ligands in ruthenium complexes relevant to olefin metathesis.
Topics: Benzylidene Compounds; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Conformation; Quantum Theory; Ruthenium; X-Ray Diffraction | 2009 |
Synthesis, characterization and catalytic activity of saturated and unsaturated N-heterocyclic carbene iridium(i) complexes.
Topics: Aniline Compounds; Benzyl Alcohol; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Iridium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2009 |
N-heterocyclic carbene-induced zwitterionic ring-opening polymerization of ethylene oxide and direct synthesis of alpha,omega-difunctionalized poly(ethylene oxide)s and poly(ethylene oxide)-b-poly(epsilon-caprolactone) block copolymers.
Topics: Ethylene Oxide; Imidazoles; Lactones; Methane; Molecular Structure; Polyethylene Glycols | 2009 |
Novel (+)N(<--L)2 species with two lone pairs on nitrogen: systems isoelectronic to carbodicarbenes.
Topics: Methane; Nitrogen; Static Electricity; Thermodynamics | 2009 |
Synthesis and reactions of mono- and dinuclear Ni(I) thiolate complexes.
Topics: Amides; Cyclic N-Oxides; Electrochemistry; Electron Spin Resonance Spectroscopy; Heterocyclic Compounds; Methane; Nickel; Organometallic Compounds; Sulfhydryl Compounds | 2009 |
Efficient boron-copper additions to aryl-substituted alkenes promoted by NHC-based catalysts. enantioselective Cu-catalyzed hydroboration reactions.
Topics: Alkenes; Boron; Boronic Acids; Catalysis; Copper; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2009 |
Photochemical generation, intramolecular reactions, and spectroscopic detection of oxonium ylide and carbene intermediates in a crystalline ortho-(1,3-dioxolan-2-yl)-diaryldiazomethane.
Topics: Azo Compounds; Crystallography, X-Ray; Dioxolanes; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Photochemistry; Spectrophotometry, Ultraviolet; Spectroscopy, Fourier Transform Infrared; Stereoisomerism; Time Factors; Ultraviolet Rays | 2009 |
Efficient three-component Strecker reaction of aldehydes/ketones via NHC-amidate palladium(II) complex catalysis.
Topics: Aldehydes; Amides; Catalysis; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Palladium | 2009 |
Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2009 |
Complexes of four-membered group 13 metal(I) N-heterocyclic carbene analogues with platinum(II) fragments.
Topics: Crystallography, X-Ray; Gallium; Heterocyclic Compounds; Indium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Platinum | 2009 |
Unusual mechanistic course of some NHC-mediated transesterifications.
Topics: Catalysis; Crystallography, X-Ray; Esterification; Ethanol; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation; Molecular Structure; Vinyl Compounds | 2009 |
Alpha-zirconium phosphonates: versatile supports for N-heterocyclic carbenes.
Topics: Catalysis; Heterocyclic Compounds; Methane; Organometallic Compounds; Organophosphonates; Zirconium | 2009 |
Mössbauer, electron paramagnetic resonance, and theoretical studies of a carbene-based all-ferrous Fe4S4 cluster: electronic origin and structural identification of the unique spectroscopic site.
Topics: Azotobacter vinelandii; Electron Spin Resonance Spectroscopy; Iron-Sulfur Proteins; Methane; Models, Chemical; Models, Molecular; Nitrogenase | 2009 |
Synthesis of fluoroalkene dipeptide isosteres by an intramolecular redox reaction utilizing N-heteorocyclic carbenes (NHCs).
Topics: Alkenes; Biomimetics; Dipeptides; Heterocyclic Compounds; Methane; Oxidation-Reduction; Silanes | 2009 |
Conversion of carbon dioxide into methanol with silanes over N-heterocyclic carbene catalysts.
Topics: Carbon Dioxide; Catalysis; Magnetic Resonance Spectroscopy; Methane; Methanol; Silanes | 2009 |
Effects of NHC-backbone substitution on efficiency in ruthenium-based olefin metathesis.
Topics: Alkenes; Catalysis; Ligands; Malonates; Methane; Ruthenium | 2009 |
Calcium carbene complexes with boranophosphorano side-arms: CaC[P(Ph)(2)BH(3)](2).
Topics: Boranes; Calcium; Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure | 2009 |
Chemoselective tryptophan labeling with rhodium carbenoids at mild pH.
Topics: Hydrogen-Ion Concentration; Methane; Models, Molecular; Organometallic Compounds; Rhodium; Solutions; Solvents; Tryptophan; Water | 2009 |
Methyleneimidazoline complexes of iridium, rhodium, and palladium from selective C(sp3)-H bond activation.
Topics: Crystallography, X-Ray; Imidazoles; Iridium; Methane; Molecular Conformation; Molecular Structure; Organometallic Compounds; Palladium; Rhodium; Thermodynamics | 2009 |
The antimicrobial efficacy of sustained release silver-carbene complex-loaded L-tyrosine polyphosphate nanoparticles: characterization, in vitro and in vivo studies.
Topics: Administration, Inhalation; Animals; Anti-Infective Agents; Biocompatible Materials; Cystic Fibrosis; Drug Resistance, Multiple, Bacterial; Humans; Male; Materials Testing; Methane; Mice; Mice, Inbred C57BL; Microbial Sensitivity Tests; Molecular Structure; Nanoparticles; Nebulizers and Vaporizers; Organophosphates; Particle Size; Polymers; Pseudomonas aeruginosa; Respiratory Tract Infections; Silver | 2009 |
N-heterocyclic carbene-functionalized ruthenium phosphinidenes: what a difference a twist makes.
Topics: Catalysis; Heterocyclic Compounds; Methane; Molecular Conformation; Phosphines; Ruthenium | 2009 |
N-heterocycle carbene (NHC)-ligated cyclopalladated N,N-dimethylbenzylamine: a highly active, practical and versatile catalyst for the Heck-Mizoroki reaction.
Topics: Acrylates; Benzylamines; Bromides; Catalysis; Cinnamates; Esters; Imidazoles; Kinetics; Methane; Palladium; Pharmaceutical Preparations; Phosphines; Stereoisomerism; Structure-Activity Relationship | 2009 |
Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls.
Topics: Allyl Compounds; Boron; Chemical Phenomena; Ketones; Methane | 2009 |
N-heterocyclic carbene gold(I) catalyzed transformation of N-tethered 1,5-bisallenes to 6,7-dimethylene-3-azabicyclo[3.1.1]heptanes.
Topics: Alkadienes; Azabicyclo Compounds; Catalysis; Cyclization; Gold; Isomerism; Methane | 2009 |
Monodentate non-C(2)-symmetric chiral N-heterocyclic carbene complexes for enantioselective synthesis. Cu-catalyzed conjugate additions of aryl- and alkenylsilylfluorides to cyclic enones.
Topics: Alkenes; Catalysis; Copper; Cycloparaffins; Cyclopentanes; Fluorides; Heterocyclic Compounds, 1-Ring; Ketones; Methane; Organometallic Compounds; Stereoisomerism | 2009 |
In vitro and murine efficacy and toxicity studies of nebulized SCC1, a methylated caffeine-silver(I) complex, for treatment of pulmonary infections.
Topics: Animals; Anti-Bacterial Agents; Caffeine; Cell Line; Disease Models, Animal; Male; Methane; Methylation; Mice; Mice, Inbred C57BL; Pseudomonas aeruginosa; Pseudomonas Infections; Respiratory Tract Infections; Silver Compounds | 2009 |
Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives.
Topics: Aldehydes; Alkynes; Amines; Catalysis; Cyclohexenes; Gold; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Organometallic Compounds; Quinolines | 2009 |
Stereoelectronic effect for the selectivity in C-H insertion of alkylidene carbenes and its application to the synthesis of platensimycin.
Topics: Adamantane; Alkenes; Aminobenzoates; Anilides; Ethers; Ketones; Methane; Stereoisomerism | 2009 |
N-heterocyclic carbene-catalyzed domino ring-opening/redox amidation/cyclization reactions of formylcyclopropane 1,1-diesters: direct construction of a 6-5-6 tricyclic hydropyrido[1,2-a]indole skeleton.
Topics: Amides; Catalysis; Cyclization; Cyclopropanes; Heterocyclic Compounds, 3-Ring; Indoles; Methane; Oxidation-Reduction | 2009 |
The synthesis of polyoxygenated, enantiomerically pure cyclopentane derivatives on route to neplanocin A stereoisomers via alkylidenecarbene species prepared from sugar templates.
Topics: Adenosine; Carbohydrates; Cyclopentanes; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Conformation; Oxygen; Quantum Theory; Stereoisomerism | 2009 |
Alpha'-hydroxyenones as mechanistic probes and scope-expanding surrogates for alpha,beta-unsaturated aldehydes in N-heterocyclic carbene-catalyzed reactions.
Topics: Alcohols; Aldehydes; Alkenes; Catalysis; Cyclopentanes; Ketones; Lactams; Methane | 2009 |
Cumulated advantages of enzymatic and carbene chemistry for the non-organometallic synthesis of (co)polyesters.
Topics: Biocatalysis; Enzymes; Fungal Proteins; Lipase; Magnetic Resonance Spectroscopy; Methane; Organometallic Compounds; Polyesters | 2009 |
Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes.
Topics: Isomerism; Magnetic Resonance Spectroscopy; Manganese; Metals; Methane; Organogold Compounds; Oxazoles; Thiazoles | 2009 |
Overexpression of a FAD3 desaturase increases synthesis of a polymethylene-interrupted dienoic fatty acid in seeds of Arabidopsis thaliana L.
Topics: Arabidopsis; Arabidopsis Proteins; Fatty Acid Desaturases; Fatty Acids, Unsaturated; Gene Expression Regulation, Enzymologic; Gene Expression Regulation, Plant; Linoleic Acids; Lipid Metabolism; Methane; Plants, Genetically Modified; Seeds; Transfection; Up-Regulation | 2009 |
QTAIM analysis of ligand properties and mechanisms of tuning of 6-membered ring N-heterocyclic carbenes in transition metal complexes through ring-substituent variation.
Topics: Heterocyclic Compounds; Ligands; Methane; Organometallic Compounds; Quantum Theory; Transition Elements | 2009 |
Excited-state lifetime of propadienylidene, l-C3H2.
Topics: Hot Temperature; Methane; Photochemistry; Polyenes; Propane | 2009 |
The photoionisation of two phenylcarbenes and their diazirine precursors investigated using synchrotron radiation.
Topics: Chlorine; Diazomethane; Fluorine; Hot Temperature; Methane; Molecular Structure; Phenols; Photochemistry; Radiation; Spectrometry, Mass, Electrospray Ionization; Synchrotrons | 2009 |
A facile route to C2-substituted imidazolium ionic liquids.
Topics: Alkylation; Heterocyclic Compounds; Imidazolines; Ionic Liquids; Magnetic Resonance Spectroscopy; Methane; Molecular Structure | 2009 |
Carbon...carbon weak interactions.
Topics: Acetylene; Carbon; Carbon Compounds, Inorganic; Carbon Dioxide; Carbon Monoxide; Cyanates; Electrons; Ethylenes; Methane; Models, Molecular; Molecular Conformation; Nitriles; Quantum Theory; Sulfides | 2009 |
Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes.
Topics: Alcohols; Amides; Catalysis; Cycloparaffins; Methane; Models, Molecular; Molecular Conformation; Molybdenum; Organometallic Compounds; Polymers; Pyrroles; Ruthenium; Solvents; Stereoisomerism; Substrate Specificity | 2009 |
High-accuracy extrapolated ab initio thermochemistry of the propargyl radical and the singlet C(3)H(2) carbenes.
Topics: Computer Simulation; Free Radicals; Methane; Models, Chemical; Quantum Theory; Thermodynamics | 2009 |
The rhodium carbene route to oxazoles: a remarkable catalyst effect.
Topics: Amides; Catalysis; Crystallography, X-Ray; Esters; Methane; Oxazoles; Rhodium | 2009 |
Highly stereoselective synthesis of (Z,E)-1-halo-1,3-dienol esters via rearrangement of Fischer chromium chloro-carbenes using microwave irradiation.
Topics: Chlorides; Chromium Compounds; Esters; Methane; Microwaves; Molecular Structure; Stereoisomerism | 2009 |
Iridium-catalyzed X-H insertions of sulfoxonium ylides.
Topics: Catalysis; Combinatorial Chemistry Techniques; Esters; Iridium; Ketones; Lactams; Methane; Molecular Structure; Sulfoxides | 2009 |
On the dichotomic reactivity of lithiated styrene oxide: a computational and multinuclear magnetic resonance investigation.
Topics: Epoxy Compounds; Lithium; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Stereoisomerism | 2009 |
One-pot synthesis of unsymmetrical N-heterocyclic carbene ligands from N-(2-iodoethyl)arylamine salts.
Topics: Amines; Combinatorial Chemistry Techniques; Hydrocarbons, Iodinated; Imidazoles; Ligands; Methane; Molecular Structure; Salts | 2009 |
Stereogenic-at-metal Zn- and Al-based N-heterocyclic carbene (NHC) complexes as bifunctional catalysts in Cu-free enantioselective allylic alkylations.
Topics: Alkylation; Allyl Compounds; Aluminum; Catalysis; Methane; Models, Molecular; Stereoisomerism; Zinc | 2009 |
The [3 + 2] cycloaddition reaction of thiazole carbene-derived C-C-Se 1,3-dipoles: a concise and highly efficient strategy for the construction of multifunctional dihydroselenophenes and selenopheno[2,3-b]pyrazines.
Topics: Alkenes; Alkynes; Catalysis; Cyclization; Methane; Pyrazines; Thiazoles | 2009 |
Carbenes introduction.
Topics: Chemistry, Organic; Methane; Oxidation-Reduction | 2009 |
Impact of solvent polarity on N-heterocyclic carbene-catalyzed beta-protonations of homoenolate equivalents.
Topics: Catalysis; Combinatorial Chemistry Techniques; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Conformation; Molecular Structure; Oxidation-Reduction; Solvents | 2009 |
Palladium(II) carboxylates and palladium(I) carbonyl carboxylate complexes as catalysts for olefin cyclopropanation with ethyl diazoacetate.
Topics: Alkenes; Catalysis; Diazonium Compounds; Methane; Palladium; Styrene | 2009 |
Enantioselective synthesis of beta-trifluoromethyl-beta-lactones via NHC-catalyzed ketene-ketone cycloaddition reactions.
Topics: Catalysis; Cyclization; Ethylenes; Ketone Bodies; Ketones; Lactones; Methane; Molecular Structure; Stereoisomerism | 2009 |
Silylene-mediated ring contraction of homoallylic ethers to form allylic silanes.
Topics: Allyl Compounds; Catalysis; Cyclohexane Monoterpenes; Cyclopentanes; Ethers; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Silanes; Silicon; Terpenes | 2009 |
Chemodivergent metathesis of dienynes catalyzed by ruthenium-indenylidene complexes: an experimental and computational study.
Topics: Alkenes; Alkynes; Catalysis; Ligands; Methane; Molecular Structure; Organometallic Compounds; Ruthenium | 2009 |
A concise route to pyridines from hydrazides by metal carbene N-H insertion, 1,2,4-triazine formation, and Diels-Alder reaction.
Topics: Catalysis; Cyclization; Hydrazines; Methane; Molecular Structure; Pyridines; Triazines | 2009 |
Enantioselective synthesis of aza-beta-lactams via NHC-catalyzed [2 + 2] cycloaddition of ketenes with diazenedicarboxylates.
Topics: beta-Lactams; Catalysis; Cyclization; Dicarboxylic Acids; Ethylenes; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Stereoisomerism | 2009 |
Phosphine- and carbene-ligated silver acetate: easily-accessed synthons for reactions with silylated nucleophiles.
Topics: Hydrogen Peroxide; Methane; Microbial Sensitivity Tests; Models, Molecular; Oxygen; Phosphines; Silver; Silver Compounds | 2009 |
Asymmetric synthesis of functionalized cyclopentanones via a multicatalytic secondary amine/N-heterocyclic carbene catalyzed cascade sequence.
Topics: Amines; Catalysis; Cyclopentanes; Methane; Stereoisomerism | 2009 |
One-pot synthesis and immobilisation of sulfonate-tethered N-heterocyclic carbene complexes on polycationic dendrimers.
Topics: Dendrimers; Heterocyclic Compounds; Methane; Molecular Structure; Polyamines; Polyelectrolytes; Sulfones; Transition Elements | 2009 |
Tin analogues of "Arduengo carbenes": synthesis of 1,3,2lambda2-diazastannoles and transfer of Sn atoms between a 1,3,2lambda2-diazastannole and a diazadiene.
Topics: Aza Compounds; Crystallography, X-Ray; Methane; Molecular Conformation; Thermodynamics; Tin | 2002 |
An efficient nucleophilic carbene catalyst for the asymmetric benzoin condensation.
Topics: Benzoin; Catalysis; Chemistry, Organic; Electrons; Fatty Alcohols; Methane; Models, Chemical; Salts; Stereoisomerism; Thiamine | 2002 |
Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO(2)Et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reactions.
Topics: Crystallography, X-Ray; Methane; Molecular Conformation; Molecular Structure; Porphyrins; Ruthenium; Stereoisomerism | 2009 |
Oxidative carboxylation of arylaldehydes with water by a sulfoxylalkyl-substituted N-heterocyclic carbene catalyst.
Topics: Aldehydes; Carboxylic Acids; Catalysis; Imidazoles; Methane; Oxidation-Reduction; Water | 2009 |
Separation, recovery and reuse of N-heterocyclic carbene catalysts in transesterification reactions.
Topics: Catalysis; Esterification; Methane; Molecular Structure | 2009 |
Supramolecular NHC ligands: on the influence of Zn(II)-templates on the activity of Rh(I)(cod) complexes in 'carbene polymerization'.
Topics: Catalysis; Cations, Divalent; Heterocyclic Compounds; Ligands; Methane; Models, Chemical; Molecular Weight; Organometallic Compounds; Polymers; Rhodium; Zinc | 2009 |
Efficient chiral N-heterocyclic carbene/copper(I)-catalyzed asymmetric allylic arylation with aryl Grignard reagents.
Topics: Alkenes; Catalysis; Copper; Heterocyclic Compounds; Methane; Molecular Structure | 2009 |
A tetranuclear molecular rectangle from four gold(I) atoms linked by dicarbene and diphosphine ligands.
Topics: Gold; Ligands; Magnetic Resonance Spectroscopy; Methane; Organometallic Compounds; Phosphines | 2009 |
Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii).
Topics: Heterocyclic Compounds; Isomerism; Methane; Organic Chemistry Phenomena; Platinum | 2009 |
Chemistry. Carbenes in action.
Topics: Catalysis; Chemical Phenomena; Crystallization; Heterocyclic Compounds; Iron; Ligands; Methane; Molecular Structure; Organometallic Compounds; Temperature | 2009 |
Carbenes as catalysts for transformations of organometallic iron complexes.
Topics: Catalysis; Chemical Phenomena; Crystallization; Crystallography, X-Ray; Ferrous Compounds; Heterocyclic Compounds; Iron; Ligands; Methane; Models, Chemical; Molecular Structure; Organometallic Compounds; Temperature | 2009 |
Synthesis of novel synthetic intermediates from the reaction of benzimidazole and triazole carbenes with ketenimines and their application in the construction of spiro-pyrroles.
Topics: Benzimidazoles; Cyclization; Imines; Methane; Molecular Structure; Pyrroles; Spiro Compounds; Stereoisomerism; Triazoles | 2009 |
Carbene reactivity of 4-diazo-4H-imidazoles toward nucleophiles and aromatic compounds.
Topics: Alcohols; Amines; Antineoplastic Agents; Azo Compounds; Cyclization; Fluorocarbons; Hydrocarbons, Aromatic; Hydrogen; Imidazoles; Methane; Nitrogen; Oxygen; Photochemistry; Pyridines; Solvents; Temperature | 2009 |
N-Heterocyclic carbene-catalyzed monoacylation of 1,4-naphthoquinones with aldehydes.
Topics: Acylation; Aldehydes; Catalysis; Heterocyclic Compounds; Hydroquinones; Methane; Molecular Structure; Naphthoquinones | 2009 |
Intramolecular alkynylcyclopropanation of olefins catalyzed by Bi(OTf)3: stereoselective synthesis of 1-alkynyl-3-azabicyclo[3.1.0]hexanes.
Topics: Alkenes; Bismuth; Bridged Bicyclo Compounds, Heterocyclic; Catalysis; Crystallography, X-Ray; Cyclopropanes; Hexanes; Methane; Molecular Conformation; Stereoisomerism; Sulfhydryl Compounds | 2009 |
Cyclic poly(alpha-peptoid)s and their block copolymers from N-heterocyclic carbene-mediated ring-opening polymerizations of N-substituted N-carboxylanhydrides.
Topics: Cyclization; Heterocyclic Compounds; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Peptides; Peptoids; Polyanhydrides; Spectrometry, Mass, Electrospray Ionization; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization | 2009 |
Ab initio study of lithium-bonded complexes with carbene as an electron donor.
Topics: Chemical Phenomena; Electrons; Hydrogen Bonding; Lithium; Lithium Compounds; Methane; Models, Chemical; Molecular Structure; Organometallic Compounds; Quantum Theory; Spectrophotometry, Infrared; Static Electricity | 2009 |
Rhodium carbene routes to oxazoles and thiazoles. Catalyst effects in the synthesis of oxazole and thiazole carboxylates, phosphonates, and sulfones.
Topics: Carboxylic Acids; Catalysis; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Organophosphonates; Oxazoles; Rhodium; Stereoisomerism; Structure-Activity Relationship; Sulfones; Thiazoles | 2010 |
Allylcopper intermediates with N-heterocyclic carbene ligands: synthesis, structure, and catalysis.
Topics: Aldehydes; Catalysis; Copper; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds | 2010 |
N-heterocyclic carbene-catalyzed enantioselective Mannich reactions with alpha-aryloxyacetaldehydes.
Topics: Acetaldehyde; Amines; Catalysis; Esters; Heterocyclic Compounds; Mannich Bases; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2009 |
Rh(II)-catalyzed reaction of alpha-diazocarbonyl compounds bearing beta-trichloroacetylamino substituent: C-H insertion versus 1,2-H shift.
Topics: Amino Acids; Azo Compounds; Catalysis; Crystallography, X-Ray; Methane; Molecular Conformation; Rhodium | 2010 |
Palladium complexes of abnormal N-heterocyclic carbenes as precatalysts for the much preferred Cu-free and amine-free Sonogashira coupling in air in a mixed-aqueous medium.
Topics: Air; Amines; Catalysis; Copper; Crystallography, X-Ray; Methane; Molecular Conformation; Palladium; Thermodynamics; Water | 2009 |
A new approach to switching of enantioselectivity in NHC-Cu-catalyzed conjugate addition of alkylzincs to cyclic enones.
Topics: Alkynes; Catalysis; Copper; Cyclohexanones; Heterocyclic Compounds; Mesylates; Methane; Molecular Structure; Stereoisomerism; Zinc | 2009 |
Shell crosslinked nanoparticles carrying silver antimicrobials as therapeutics.
Topics: Anti-Infective Agents; Cross-Linking Reagents; Escherichia coli; Heterocyclic Compounds; Methane; Microbial Sensitivity Tests; Nanoparticles; Pseudomonas aeruginosa; Silver | 2010 |
Rhodium-mediated activation of an alkane-type C-H bond.
Topics: Alkanes; Carbon; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Rhodium | 2010 |
N-Heterocyclic carbene-catalyzed intramolecular aldehyde-nitrile cross coupling: an easy access to 3- aminochromones.
Topics: Aldehydes; Catalysis; Chromones; Heterocyclic Compounds; Methane; Molecular Structure; Nitriles | 2010 |
Cleavable linker for photo-cross-linked small-molecule affinity matrix.
Topics: Binding Sites; Blotting, Western; Chromatography, Liquid; Cross-Linking Reagents; Disulfides; Enzymes, Immobilized; Ligands; Mass Spectrometry; Methane; Microspheres; Organophosphorus Compounds; Photoaffinity Labels; Photochemistry; Protein Binding; Protein Phosphatase 2; Sepharose | 2010 |
Anion-exchange-triggered 1,3-shift of an NH proton to iridium in protic n-heterocyclic carbenes: hydrogen-bonding and ion-pairing effects.
Topics: Anions; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogen Bonding; Iridium; Methane; Molecular Conformation; Protons; Thermodynamics; Water | 2010 |
Unexpected CO2 splitting reactions to form CO with N-heterocyclic carbenes as organocatalysts and aromatic aldehydes as oxygen acceptors.
Topics: Aldehydes; Carbon Dioxide; Carbon Monoxide; Carboxylic Acids; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Oxygen | 2010 |
Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes.
Topics: Alkynes; Amines; Catalysis; Crystallography, X-Ray; Gold; Methane; Molecular Conformation; Quaternary Ammonium Compounds | 2010 |
Perceptible influence of Pd and Pt heterocyclic carbene-pyridyl complexes in catalytic diboration of cyclic alkenes.
Topics: Borates; Catalysis; Cycloparaffins; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Palladium; Platinum; Pyridines | 2010 |
Sequential five-component construction of the cyclopenta[e][1,3]oxazine skeleton using stable 2-azetine derivatives.
Topics: Azetines; Crystallography, X-Ray; Cyclization; Methane; Molecular Conformation; Oxazines; Stereoisomerism | 2010 |
IPr* an easily accessible highly hindered N-heterocyclic carbene.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Methane; Molecular Conformation; Rhodium; Silver | 2010 |
2-Pyridylnitrene and 3-pyridazylcarbene and their relationship via ring-expansion, ring-opening, ring-contraction, and fragmentation.
Topics: Cyclization; Imines; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Nitriles; Photolysis; Pyridazines; Spiro Compounds | 2010 |
Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes.
Topics: Methane; Molecular Structure; Rhodium; Stereoisomerism; Triazoles | 2010 |
Nucleophilic heterocyclic carbene as a novel catalyst for cyclopropanation of cyano acrylates.
Topics: Acetophenones; Acrylates; Catalysis; Cyclization; Diazonium Compounds; Kinetics; Methane; Models, Chemical; Stereoisomerism; Temperature | 2010 |
Enantioselective conjugate silyl additions to cyclic and acyclic unsaturated carbonyls catalyzed by Cu complexes of chiral N-heterocyclic carbenes.
Topics: Catalysis; Copper; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Organometallic Compounds; Silanes; Stereoisomerism | 2010 |
N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids.
Topics: Carboxylic Acids; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2010 |
A bonding model for gold(I) carbene complexes.
Topics: Cyclopropanes; Gold; Ligands; Methane; Molecular Structure; Organogold Compounds | 2009 |
Swift and efficient synthesis of 4-phenylquinazolines: involvement of N-heterocyclic carbene in the key cyclization step.
Topics: Cyclization; Guanidine; Heterocyclic Compounds; Methane; Molecular Structure; Quinazolines | 2010 |
Rational exploration of N-heterocyclic carbene (NHC) palladacycle diversity: a highly active and versatile precatalyst for Suzuki-Miyaura coupling reactions of deactivated aryl and alkyl substrates.
Topics: Catalysis; Cross-Linking Reagents; Crystallography, X-Ray; Dimerization; Heterocyclic Compounds; Imidazoles; Methane; Models, Molecular; Palladium | 2010 |
A comparison between nickel and palladium precatalysts of 1,2,4-triazole based N-heterocyclic carbenes in hydroamination of activated olefins.
Topics: Alkenes; Amination; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogenation; Methane; Models, Molecular; Molecular Structure; Nickel; Palladium; Triazoles | 2010 |
Biomedical properties of a series of ruthenium-N-heterocyclic carbene complexes based on oxidant activity in vitro and assessment in vivo of biosafety in zebrafish embryos.
Topics: Animals; Heart; Heterocyclic Compounds; Larva; Methane; Molecular Structure; Oxidants; Ruthenium Compounds; Structure-Activity Relationship; Zebrafish | 2010 |
Orthogonal synthesis of densely functionalized pyrroles and thiophenes from the reactions of imidazo[1,5-a]pyridine carbene-derived zwitterions with electron-deficient alkynes.
Topics: Alkynes; Cyclization; Electrons; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Pyridines; Pyrroles; Stereoisomerism; Thiophenes | 2010 |
Total synthesis of kendomycin featuring intramolecular Dötz benzannulation.
Topics: Chromium; Methane; Rifabutin; Spectrophotometry, Ultraviolet | 2010 |
Functionalized 4-aminoquinolines by rearrangement of pyrazole N-heterocyclic carbenes.
Topics: Aminoquinolines; Antimalarials; Catalysis; Coordination Complexes; Heterocyclic Compounds; Methane; Pyrazoles | 2010 |
About the so-called 1,3-dioxymethylene-cyclopentanone- (2).
Topics: Cyclopentanes; Methane | 1947 |
Methylene and para-phenylene analogs of plasmocid.
Topics: Aminoquinolines; Malaria; Methane | 1946 |
Palladium-catalyzed heck coupling reaction of aryl bromides in aqueous media using tetrahydropyrimidinium salts as carbene ligands.
Topics: Bromides; Catalysis; Chemistry, Organic; Ligands; Methane; Palladium; Pyrimidines; Salts; Styrene; Water | 2010 |
Cooperative N-heterocyclic carbene/Lewis acid catalysis for highly stereoselective annulation reactions with homoenolates.
Topics: Acrolein; Catalysis; Chalcone; Cyclopentanes; Methane; Models, Chemical; Stereoisomerism | 2010 |
A DFT study of the possible role of vinylidene and carbene intermediates in the mechanism of the enzyme acetylene hydratase.
Topics: Ethylenes; Hydro-Lyases; Methane; Thermodynamics | 2010 |
Synthesis of 2-acylfurans from 3-(1-alkynyl)-2-alken-1-ones via the oxidation of gold-carbene intermediates by H2O2.
Topics: Alkenes; Catalysis; Cyclization; Furans; Gold; Hydrogen Peroxide; Methane; Oxidation-Reduction | 2010 |
Design, synthesis, and diversification of 5,5-dimethyl cyclohexen-1,4-dione library.
Topics: Cyclohexanones; Cyclohexenes; Drug Design; Esterification; Hydrocarbons, Iodinated; Methane; Quinones; Small Molecule Libraries | 2010 |
Vinylogous aldol products from chiral crotylsilanes obtained by enantioselective Rh(II) and Cu(I) carbenoid Si-H insertion.
Topics: Aldehydes; Copper; Hydrogen; Methane; Rhenium; Silanes; Silicones; Stereoisomerism | 2010 |
A general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes.
Topics: Aldehydes; Alkynes; Catalysis; Ligands; Methane; Nickel; Oxidation-Reduction; Stereoisomerism; Substrate Specificity | 2010 |
2H-Azirines from a concerted addition of alkylcarbenes to nitrile groups.
Topics: Alkenes; Azirines; Crystallography, X-Ray; Fumarates; Methane; Models, Molecular; Molecular Conformation; Photolysis; Stereoisomerism | 2010 |
Cyclometalated gold(III) complexes with N-heterocyclic carbene ligands as topoisomerase I poisons.
Topics: Animals; Antineoplastic Agents; Carcinoma, Hepatocellular; Computer Simulation; Coordination Complexes; DNA Topoisomerases, Type I; Gold; Hep G2 Cells; Heterocyclic Compounds; Humans; Ligands; Liver Neoplasms; Methane; Mice; Mice, Nude; Topoisomerase I Inhibitors | 2010 |
Conical intersections in triplet excited states of methylene from the anti-Hermitian contracted Schrödinger equation.
Topics: Algorithms; Methane; Quantum Theory | 2010 |
Gold(I) complexes of N-heterocyclic carbene ligands containing benzimidazole: synthesis and antimicrobial activity.
Topics: Anti-Bacterial Agents; Antifungal Agents; Benzimidazoles; Candida albicans; Candida tropicalis; Enterococcus faecalis; Escherichia coli; Gold; Ligands; Magnetic Resonance Spectroscopy; Methane; Pseudomonas aeruginosa; Spectrophotometry, Infrared; Staphylococcus aureus | 2010 |
Synthesis and antimicrobial activity of novel Ag-N-hetero-cyclic carbene complexes.
Topics: Anti-Bacterial Agents; Antifungal Agents; Candida albicans; Candida tropicalis; Enterococcus faecalis; Escherichia coli; Heterocyclic Compounds; Imidazolidines; Magnetic Resonance Spectroscopy; Methane; Nitrogen; Pseudomonas aeruginosa; Silver; Staphylococcus aureus | 2010 |
Highly convenient regioselective intermolecular hydroamination of alkynes yielding ketimines catalyzed by gold(I) complexes of 1,2,4-triazole based N-heterocyclic carbenes.
Topics: Alkynes; Amination; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Imines; Methane; Models, Molecular; Molecular Structure; Nitriles; Organogold Compounds; Stereoisomerism; Triazoles | 2010 |
Nickel-catalyzed hydroheteroarylation of vinylarenes.
Topics: Catalysis; Heterocyclic Compounds; Methane; Nickel; Styrene; Vinyl Compounds | 2010 |
Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene.
Topics: Heterocyclic Compounds; Imidazoles; Methane | 2010 |
Heterotopic silver-NHC complexes: from coordination polymers to supramolecular assemblies.
Topics: Coordination Complexes; Methane; Molecular Conformation; Polymers; Silver; Zinc | 2010 |
NHC catalyzed transformation of aromatic aldehydes to acids by carbon dioxide: an unexpected reaction.
Topics: Aldehydes; Carbon Dioxide; Carboxylic Acids; Catalysis; Methane; Molecular Structure | 2010 |
Synthesis and structure of a bis-N-heterocyclic carbene complex of uranium tetrachloride exhibiting short ClC(carbene) contacts.
Topics: Chlorides; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Uranium | 2009 |
Direct observation of a carbonylation reaction relevant to CO/alkene copolymerization in a methylpalladium carbonyl complex containing a bis(N-heterocyclic carbene) ligand.
Topics: Alkenes; Carbon Monoxide; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium | 2009 |
Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Iridium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds | 2009 |
[Ru(NHC)(xantphos)(CO)H(2)] complexes: intramolecular C-H activation and applications in C-C bond formation.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Ruthenium; Stereoisomerism; Xanthenes | 2009 |
N-donor functionalized N-heterocyclic carbene nickel(II) complexes in the Kumada coupling.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Nickel; Organometallic Compounds; Stereoisomerism | 2009 |
AgOC(CF(3))(3): an alternative and efficient reagent for preparing transition metal-NHC-carbene complexes.
Topics: Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism; Transition Elements | 2009 |
Easy preparation of Cp*-functionalized N-heterocyclic carbenes and their coordination to rhodium and iridium.
Topics: Crystallography, X-Ray; Cyclopentanes; Heterocyclic Compounds; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2009 |
Synthesis and characterization of IPr(Me)-containing silver(I), gold(I) and gold(III) complexes.
Topics: Crystallography, X-Ray; Gold; Heterocyclic Compounds; Imidazoles; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Silver; Stereoisomerism | 2009 |
Synthesis and structure of early transition metal NHC complexes.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Transition Elements | 2009 |
Sulfonate- or carboxylate-functionalized N-heterocyclic bis-carbene ligands and related water soluble silver complexes.
Topics: Carboxylic Acids; Heterocyclic Compounds; Ligands; Methane; Molecular Structure; Organometallic Compounds; Silver; Solubility; Stereoisomerism; Sulfonic Acids; Water | 2009 |
Coordination chemistry and catalytic activity of N-heterocyclic carbene iridium(I) complexes.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Iridium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2009 |
NHC-manganese(i) complexes as carbene transfer agents.
Topics: Crystallography, X-Ray; Gold; Heterocyclic Compounds; Ligands; Manganese; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Silver; Stereoisomerism | 2009 |
Cobalt(iii) complexes bearing bidentate, tridentate, and tetradentate N-heterocyclic carbenes: synthesis, X-ray structures and catalytic activities.
Topics: Cobalt; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2009 |
N-heterocyclic carbenes bearing two, one and no nitrogen atoms at the ylidene carbon: insight from theoretical calculations.
Topics: Carbon; Computer Simulation; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Nitrogen; Organometallic Compounds; Rhodium; Thermodynamics | 2009 |
Pyrazolyl-N-heterocyclic carbene complexes of rhodium as hydrogenation catalysts: The influence of ligand steric bulk on catalyst activity.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogenation; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Pyrazolones; Rhodium; Stereoisomerism | 2009 |
Synthesis of tetra- and pentacoordinate palladium complexes of functionalized N-heterocyclic carbenes and a comparative study of their catalytic activities.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Stereoisomerism | 2009 |
N-heterocyclic carbenes of iridium(I): ligand effects on the catalytic activity in transfer hydrogenation.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogenation; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2009 |
Synthesis, structural characterisation and anti-proliferative activity of NHC gold amino acid and peptide conjugates.
Topics: Amino Acids; Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Crystallography, X-Ray; Dipeptides; Drug Screening Assays, Antitumor; Gold; HeLa Cells; Heterocyclic Compounds; Humans; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Stereoisomerism; Structure-Activity Relationship | 2009 |
Facile C-S, S-H, and S-S bond cleavage using a nickel(0) NHC complex.
Topics: Carbon; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogen; Ligands; Methane; Models, Molecular; Molecular Structure; Nickel; Organometallic Compounds; Stereoisomerism; Sulfhydryl Compounds; Sulfur | 2009 |
Synthesis and characterization of Pd(II)-methyl complexes with N-heterocyclic carbene-amine ligands.
Topics: Amines; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Silver; Stereoisomerism | 2009 |
Synthesis, characterization and catalytic activity of novel N-heterocyclic carbene-palladium complexes.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Stereoisomerism | 2009 |
Synthetic and structural studies on amine coordination to Pd-N-heterocyclic carbene complexes.
Topics: Amines; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Stereoisomerism | 2009 |
Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2009 |
Liquid crystals of gold(I) N-heterocyclic carbene complexes.
Topics: Crystallography, X-Ray; Gold; Heterocyclic Compounds; Imidazoles; Liquid Crystals; Metal Nanoparticles; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Particle Size; Stereoisomerism | 2009 |
Synthesis, structures and catalytic activities of ruthenium(ii) carbonyl chloride complexes containing pyridine-functionalised N-heterocyclic carbenes.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Pyridines; Ruthenium; Stereoisomerism | 2009 |
Synthesis of rhodium(I) and iridium(I) complexes of chiral N-heterocyclic carbenes and their application to asymmetric transfer hydrogenation.
Topics: Amines; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogenation; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2009 |
Controlling the coordination modes of a new and highly flexible ligand bearing two N-heterocyclic carbene moieties at a bipyridine backbone.
Topics: 2,2'-Dipyridyl; Copper; Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Silver; Stereoisomerism | 2009 |
Main-chain organometallic polymers comprising redox-active iron(II) centers connected by ditopic N-heterocyclic carbenes.
Topics: Crystallography, X-Ray; Ferrous Compounds; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Oxidation-Reduction; Polymers; Stereoisomerism | 2009 |
Reactions of 'pincer' pyridine dicarbene complexes of Fe(0) with silanes.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Hydrogenation; Iron; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Pyridines; Silanes; Stereoisomerism | 2009 |
Atropochiral (C,C)-chelating NHC-ylide ligands: synthesis and resolution of palladium(II) complexes thereof.
Topics: Chelating Agents; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Stereoisomerism | 2009 |
Reactions of indenyl-functionalized imidazolium salts and N-heterocyclic carbenes with Ru(3)(CO)(12).
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Indenes; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Ruthenium Compounds; Salts; Stereoisomerism | 2009 |
Magnesium and zinc complexes of functionalised, saturated N-heterocyclic carbene ligands: carbene lability and functionalisation, and lactide polymerisation catalysis.
Topics: Catalysis; Crystallography, X-Ray; Dioxanes; Heterocyclic Compounds; Ligands; Magnesium; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Stereoisomerism; Zinc | 2009 |
One-step formation of cyclometallated Au(III) N,S-heterocyclic carbene: crystallographic analysis.
Topics: Crystallography, X-Ray; Gold; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Stereoisomerism | 2009 |
1,1'-Bis(N-benzimidazolylidene)ferrocene: synthesis and study of a novel ditopic ligand and its transition metal complexes.
Topics: Benzimidazoles; Crystallography, X-Ray; Ferrous Compounds; Heterocyclic Compounds; Iridium; Ligands; Metallocenes; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Stereoisomerism | 2009 |
Carbene-anchored/pendent-imidazolium species as precursors to di-N-heterocyclic carbene-bridged mixed-metal complexes.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Iridium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Rhodium; Stereoisomerism | 2009 |
Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Phosphines; Salts; Silver; Stereoisomerism | 2009 |
Palladium complexes of o-xylyl-linked alkoxybenzimidazolin-2-ylidenes: interesting structural conformations and application as pre-catalysts.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Imidazolines; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Stereoisomerism | 2009 |
A theobromine derived silver N-heterocyclic carbene: synthesis, characterization, and antimicrobial efficacy studies on cystic fibrosis relevant pathogens.
Topics: Animals; Anti-Bacterial Agents; Crystallography, X-Ray; Cystic Fibrosis; Disease Models, Animal; Dose-Response Relationship, Drug; Female; Heterocyclic Compounds; Methane; Mice; Mice, Inbred C57BL; Microbial Sensitivity Tests; Models, Molecular; Molecular Structure; Organometallic Compounds; Pseudomonas aeruginosa; Silver; Stereoisomerism; Theobromine | 2009 |
Trapping a difluorocarbene-platinum fragment by base coordination.
Topics: Fluorine Compounds; Hydrolysis; Methane; Models, Molecular; Molecular Structure; Platinum Compounds | 2010 |
Ruthenium-catalyzed synthesis of functional conjugated dienes via addition of two carbene units to alkynes.
Topics: Alkadienes; Alkynes; Catalysis; Methane; Ruthenium Compounds; Silicon Compounds | 2010 |
Catalytic enantioselective total syntheses of bakkenolides I, J, and S: application of a carbene-catalyzed desymmetrization.
Topics: Biological Products; Catalysis; Methane; Molecular Structure; Sesquiterpenes; Stereoisomerism | 2010 |
NHC-iron-catalyzed aerobic oxidative aromatic esterification of aldehydes using boronic acids.
Topics: Aldehydes; Amides; Benzoates; Boronic Acids; Catalysis; Esterification; Ferrous Compounds; Methane; Molecular Structure; Oxidation-Reduction | 2010 |
Fascinating frontiers of N/O-functionalized N-heterocyclic carbene chemistry: from chemical catalysis to biomedical applications.
Topics: Alkenes; Alkynes; Anti-Infective Agents; Antineoplastic Agents; Catalysis; Coordination Complexes; Heterocyclic Compounds; Methane; Nitrogen; Oxygen; Polyesters; Transition Elements | 2010 |
Orientation and stereodynamic paths of planar monodentate ligands in square planar nickel N2S complexes.
Topics: Computer Simulation; Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Ligands; Methane; Models, Molecular; Molecular Structure; Nickel; Organometallic Compounds; Pyridines; Stereoisomerism; Sulfhydryl Compounds; Thermodynamics | 2010 |
Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs).
Topics: Crystallization; Ions; Isomerism; Methane; Models, Molecular; Molecular Structure; Triazoles | 2010 |
Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical.
Topics: Boranes; Free Radicals; Heterocyclic Compounds; Hydrogen; Kinetics; Methane; Molecular Structure; Stereoisomerism | 2010 |
Radical deoxygenation of xanthates and related functional groups with new minimalist N-heterocyclic carbene boranes.
Topics: Boranes; Free Radicals; Heterocyclic Compounds; Methane; Molecular Structure; Molecular Weight; Oxygen; Stereoisomerism; Thiones | 2010 |
An enantioselective Claisen rearrangement catalyzed by N-heterocyclic carbenes.
Topics: Azoles; Catalysis; Methane; Nitrogen; Stereoisomerism; Substrate Specificity | 2010 |
From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature.
Topics: Crystallography, X-Ray; Methane; Molecular Conformation; Oxygen; Silanes; Silicon; Temperature; Urea | 2010 |
Effect of the nature of the substituent in N-alkylimidazole ligands on the outcome of deprotonation: ring opening versus the formation of N-heterocyclic carbene complexes.
Topics: Alkenes; Amines; Crystallography, X-Ray; Imidazoles; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhenium | 2010 |
Synthesis, structure, and reactivity of a stabilized phosphiranylium salt.
Topics: Cations; Mesylates; Methane; Models, Molecular; Molecular Structure; Phosphorus Compounds; Salts | 2010 |
Synthesis and catalytic activity of gold chiral nitrogen acyclic carbenes and gold hydrogen bonded heterocyclic carbenes in cyclopropanation of vinyl arenes and in intramolecular hydroalkoxylation of allenes.
Topics: Alkadienes; Catalysis; Crystallography, X-Ray; Cyclopropanes; Gold; Heterocyclic Compounds; Hydrogen Bonding; Methane; Models, Molecular; Molecular Structure; Nitrogen; Organogold Compounds; Stereoisomerism | 2010 |
Stereoselective synthesis of tertiary ethers through geometric control of highly substituted oxocarbenium ions.
Topics: Alkynes; Ethers; Ions; Methane; Models, Chemical; Oxidation-Reduction; Stereoisomerism | 2010 |
A DFT study of addition reaction between fragment ion (CH₂) units and fullerene (C₆₀) molecule.
Topics: Electrons; Fullerenes; Ions; Methane; Models, Chemical; Models, Molecular; Models, Theoretical; Quantum Theory; Thermodynamics | 2011 |
Synthesis of cyclic imides from simple diols.
Topics: Amines; Catalysis; Cyclization; Imides; Methane; Phthalimides; Piperidones; Ruthenium; Succinimides | 2010 |
Enantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters.
Topics: Boron Compounds; Catalysis; Copper; Esters; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Stereoisomerism; Sulfhydryl Compounds | 2010 |
Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions.
Topics: Boronic Acids; Catalysis; Copper; Heterocyclic Compounds; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2010 |
A carbene-carbene complex equilibrium.
Topics: Computer Simulation; Diazomethane; Methane; Thermodynamics | 2010 |
'Carbene radicals' in Co(II)(por)-catalyzed olefin cyclopropanation.
Topics: Alkenes; Catalysis; Cobalt; Computer Simulation; Cyclopropanes; Free Radicals; Methane; Molecular Structure; Organometallic Compounds; Porphyrins; Stereoisomerism; Thermodynamics | 2010 |
N-heterocyclic carbene catalysed asymmetric cross-benzoin reactions of heteroaromatic aldehydes with trifluoromethyl ketones.
Topics: Aldehydes; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Ketones; Methane; Models, Molecular; Molecular Structure; Stereoisomerism | 2010 |
Silver triflate and N-heterocyclic carbene co-catalyzed reaction of N'-(2-alkynylbenzylidene)hydrazide, methanol with alpha,beta-unsaturated aldehyde.
Topics: Aldehydes; Azides; Catalysis; Heterocyclic Compounds; Isoquinolines; Mesylates; Methane; Methanol; Molecular Structure; Stereoisomerism | 2010 |
Gold-catalyzed annulation/fragmentation: formation of free gold carbenes by retro-cyclopropanation.
Topics: Benzene Derivatives; Catalysis; Crystallography, X-Ray; Cyclization; Cyclopropanes; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Stereoisomerism | 2010 |
Quantitative catalyst-substrate association relationships between metathesis molybdenum or ruthenium carbene complexes and their substrates.
Topics: Alkadienes; Alkenes; Alkynes; Catalysis; Methane; Molecular Structure; Molybdenum; Organometallic Compounds; Ruthenium; Stereoisomerism | 2010 |
Cellular uptake, cytotoxicity, and innate immune response of silica-titania hollow nanoparticles based on size and surface functionality.
Topics: Adenosine Triphosphate; Amines; Animals; Apoptosis; Biological Transport; Carboxylic Acids; Cell Line, Tumor; Cell Survival; Humans; Immunity, Innate; Macrophages; Methane; Mice; Nanocapsules; Nanotechnology; Necrosis; Oxidative Stress; Particle Size; Reactive Oxygen Species; Silicon Dioxide; Surface Properties; Titanium | 2010 |
Mechanism of the aminolysis of Fischer alkoxy and thiocarbene complexes: a DFT study.
Topics: Amines; Chromium; Computer Simulation; Methane; Molecular Structure; Organometallic Compounds; Quantum Theory; Stereoisomerism; Sulfhydryl Compounds | 2010 |
The catalytic role of N-heterocyclic carbene in a metal-free conversion of carbon dioxide into methanol: a computational mechanism study.
Topics: Carbon Dioxide; Catalysis; Heterocyclic Compounds; Methane; Methanol; Molecular Dynamics Simulation; Molecular Structure | 2010 |
Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates.
Topics: Boronic Acids; Catalysis; Copper; Crystallography, X-Ray; Indoles; Isatin; Ligands; Methane; Molecular Conformation; Oxindoles; Stereoisomerism | 2010 |
Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents.
Topics: Copper; Gold; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Palladium; Stereoisomerism | 2010 |
Gold(I) "click" 1,2,3-triazolylidenes: synthesis, self-assembly and catalysis.
Topics: Catalysis; Click Chemistry; Crystallography, X-Ray; Gold; Ligands; Methane; Models, Molecular; Molecular Structure; Organogold Compounds | 2011 |
α-Aroyloxyaldehydes: scope and limitations as alternatives to α-haloaldehydes for NHC-catalysed redox transformations.
Topics: Aldehydes; Catalysis; Cyclization; Esters; Heterocyclic Compounds; Methane; Molecular Structure; Oxidation-Reduction | 2011 |
Organic-inorganic hybrid silica material derived from a monosilylated Grubbs-Hoveyda ruthenium carbene as a recyclable metathesis catalyst.
Topics: Catalysis; Cyclization; Magnetic Resonance Spectroscopy; Methane; Microwaves; Models, Chemical; Nitrogen; Organic Chemicals; Porosity; Ruthenium; Silicon Dioxide; Temperature | 2010 |
Diazirine-modified gold nanoparticle: template for efficient photoinduced interfacial carbene insertion reactions.
Topics: Alkenes; Diazomethane; Gold; Ligands; Magnetic Resonance Spectroscopy; Metal Nanoparticles; Methane; Photolysis | 2010 |
N-heterocyclic carbene-catalyzed conjugate additions of alcohols.
Topics: Alcohols; Catalysis; Heterocyclic Compounds; Methane | 2010 |
Dialkynyl carbene derivatives: generation and characterization of triplet tert-butylpentadiynylidene (t-Bu-C≡C-C̈-C≡C-H) and dimethylpentadiynylidene (Me-C≡C-C̈-C≡C-Me).
Topics: Alkynes; Computer Simulation; Methane; Molecular Structure; Stereoisomerism | 2010 |
Synthesis of simple diynals, diynones, their hydrazones, and diazo compounds: precursors to a family of dialkynyl carbenes (R(1)-C≡C-C-C≡C-R(2)).
Topics: Alcohols; Alkynes; Azo Compounds; Hydrazones; Ketones; Methane; Molecular Structure; Stereoisomerism | 2010 |
Cross-coupling in a flow microreactor: space integration of lithiation and Murahashi coupling.
Topics: Bromides; Catalysis; Equipment Design; Ligands; Lithium; Methane; Microchemistry; Palladium | 2010 |
Enantioselective formal [2+2] cycloaddition of ketenes with nitroso compounds catalyzed by N-heterocyclic carbenes.
Topics: Catalysis; Cyclization; Ketones; Methane; Nitroso Compounds; Stereoisomerism | 2010 |
High-efficiency blue and white organic light-emitting devices incorporating a blue iridium carbene complex.
Topics: Iridium; Light; Luminescent Agents; Methane; Optics and Photonics | 2010 |
Catalysts by the meter: rapid screening approach of N-heterocyclic carbene ligand based catalysts.
Topics: Catalysis; Chromatography; Heterocyclic Compounds; High-Throughput Screening Assays; Ligands; Methane; Molecular Structure; Silicon Dioxide | 2011 |
Site-specific introduction of gold-carbenoids by intermolecular oxidation of ynamides or ynol ethers.
Topics: Amides; Catalysis; Esters; Ethers; Gold; Imides; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2011 |
Multicomponent reaction of imidazo[1,5-a]pyridine carbenes with aldehydes and dimethyl acetylenedicarboxylate or allenoates: a straightforward approach to fully substituted furans.
Topics: Aldehydes; Alkynes; Furans; Methane; Molecular Structure; Naphthalenes; Pyridines; Stereoisomerism | 2010 |
Isoquinoline-based chiral monodentate N-heterocyclic carbenes.
Topics: Amides; Catalysis; Heterocyclic Compounds; Isoquinolines; Ligands; Methane; Models, Molecular; Molecular Structure; Stereoisomerism | 2010 |
Preparation of NHC borane complexes by Lewis base exchange with amine- and phosphine-boranes.
Topics: Amines; Boranes; Heterocyclic Compounds; Methane; Molecular Structure; Phosphines; Stereoisomerism | 2010 |
Asymmetric nanocatalysis: N-heterocyclic carbenes as chiral modifiers of Fe3O4/Pd nanoparticles.
Topics: Catalysis; Ferrosoferric Oxide; Heterocyclic Compounds; Metal Nanoparticles; Methane; Microscopy, Electron, Scanning; Microscopy, Electron, Transmission; Molecular Structure; Palladium; Spectrophotometry, Atomic; Surface Properties | 2010 |
Total synthesis of (+)-demethoxycardinalin 3.
Topics: Benzoquinones; Methane; Molecular Conformation; Stereoisomerism | 2010 |
Photolysis of 4-chlororesorcinol in water: competitive formation of a singlet ketene and a triplet carbene.
Topics: Binding, Competitive; Cyclohexenes; Electrons; Ethylenes; Ketones; Methane; Photolysis; Resorcinols; Spectrum Analysis; Water | 2010 |
Efficient catalytic, oxidative lactonization for the synthesis of benzodioxepinones using thiazolium-derived carbene catalysts.
Topics: Azo Compounds; Benzoxepins; Catalysis; Lactones; Methane; Molecular Structure; Oxidation-Reduction; Sulfhydryl Compounds | 2010 |
The total synthesis of (-)-7-deoxyloganin via N-heterocyclic carbene catalyzed rearrangement of α,β-unsaturated enol esters.
Topics: Catalysis; Esters; Heterocyclic Compounds; Iridoids; Methane; Molecular Structure; Stereoisomerism | 2010 |
Proton affinities of phosphines versus N-heterocyclic carbenes.
Topics: Dimerization; Heterocyclic Compounds; Methane; Molecular Structure; Phosphines; Protons | 2010 |
Hydride ion-carrier ability in Rh(I) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand.
Topics: Crystallography, X-Ray; Electrochemistry; Heterocyclic Compounds; Hydrogen; Ions; Ligands; Methane; Niacinamide; Organometallic Compounds; Rhodium; Spectrometry, Mass, Electrospray Ionization; Spectrophotometry, Ultraviolet | 2010 |
Iridium metal complexes containing N-heterocyclic carbene ligands for blue-light-emitting electrochemical cells.
Topics: Crystallography, X-Ray; Electrochemistry; Heterocyclic Compounds; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Quantum Theory | 2010 |
Direct functionalization of indoles: copper-catalyzed malonyl carbenoid insertions.
Topics: Catalysis; Copper; Indoles; Methane; Molecular Structure | 2010 |
Synthesis of a room-temperature-stable dimeric copper(I) hydride.
Topics: Copper; Dimerization; Methane; Models, Molecular; Temperature | 2011 |
N-heterocyclic carbene-catalyzed tandem aza-benzoin/Michael reactions: on site reversal of the reactivity of N-Boc imines.
Topics: Aza Compounds; Benzoin; Binding Sites; Catalysis; Cyclization; Heterocyclic Compounds; Imines; Indenes; Methane; Molecular Structure; Pyrrolidinones; Stereoisomerism | 2011 |
Rh(II) carbene-promoted activation of the anomeric C-H bond of carbohydrates: a stereospecific entry toward α- and β-ketopyranosides.
Topics: Carbohydrate Sequence; Carbohydrates; Ketones; Methane; Molecular Sequence Data; Pyrans; Rhodium; Stereoisomerism | 2010 |
Highly chemoselective direct crossed aliphatic-aromatic acyloin condensations with triazolium-derived carbene catalysts.
Topics: Aldehydes; Catalysis; Fatty Alcohols; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Stereoisomerism; Triazoles | 2011 |
Functional activity in humans of dimethylamino-1-methyl-dioxy-2-3-propane iodomethylate (2249); active vasodilator by mouth.
Topics: Humans; Methane; Vasomotor System | 1946 |
Periodate oxidation of certain active methylene groups.
Topics: Methane; Oxidation-Reduction; Periodic Acid | 1946 |
The 3,5-benzylidene and 3,5-methylene acetals of gluco-gulo-hepitol.
Topics: Acetals; Animals; Arabinose; Methane; Mustelidae | 1946 |
Steric effect of methylene groups.
Topics: Methane | 1946 |
alpha-Methylene butyrolactone from Erythronium americanum.
Topics: Humans; Lactones; Methane | 1946 |
[Chlorethylidene methylene narcosis].
Topics: Anesthesia; Anesthesiology; Humans; Methane; Stupor | 1945 |
The protein-formaldehyde reaction; the question of methylene bridges and the unreactivity of benzoyl-d (-)-alanine toward formaldehyde.
Topics: Alanine; Formaldehyde; Humans; Methane; Proteins | 1946 |
Therapeutic activities of dimethylamino-I-methylene-dioxy-2-3-propane iodomethylate (2249 F), an active vasodilator by the oral route.
Topics: Humans; Methane; Vasomotor System | 1946 |
Direct and efficient N-heterocyclic carbene-catalyzed hydroxymethylation of aldehydes.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Ketones; Methane; Methylation; Molecular Structure; Stereoisomerism | 2011 |
Copper- and copper-N-heterocyclic carbene-catalyzed C-H activating carboxylation of terminal alkynes with CO2 at ambient conditions.
Topics: Alkynes; Carbon Dioxide; Catalysis; Chemical Engineering; Copper; Methane; Molecular Structure; Propionates | 2010 |
Di- and trisubstituted γ-lactams via Rh(II)-carbenoid reaction of N-Cα-branched, N-bis(trimethylsilyl)methyl α-diazoamides. Synthesis of (±)-α-allokainic acid.
Topics: Amides; Azo Compounds; Kainic Acid; Lactams; Methane; Molecular Structure; Rhodium; Trimethylsilyl Compounds | 2010 |
Novel platinum-N-heterocyclic carbene complex is more cardiotoxic than cis-platin in rats.
Topics: Animals; Antineoplastic Agents; Cisplatin; Heart; Heterocyclic Compounds; Injections, Intraperitoneal; Male; Methane; Myocardium; Organoplatinum Compounds; Oxidative Stress; Rats; Rats, Sprague-Dawley | 2011 |
NHC-catalyzed intramolecular redox amidation for the synthesis of functionalized lactams.
Topics: Amination; Catalysis; Heterocyclic Compounds; Hydrogen; Lactams; Methane; Molecular Structure; Oxidation-Reduction | 2010 |
Insights into the carbene-initiated aggregation of [Fe(cot)(2)].
Topics: Catalysis; Cyclooctanes; Iron; Ligands; Magnetic Resonance Spectroscopy; Methane; Organometallic Compounds | 2011 |
The non-metathetic role of Grubbs' carbene complexes: from hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction.
Topics: Alkenes; Catalysis; Hydrogen; Methane; Microwaves; Molecular Conformation; Molecular Structure | 2011 |
Novel benzyl-substituted N-heterocyclic carbene-silver acetate complexes: synthesis, cytotoxicity and antibacterial studies.
Topics: Acetates; Anti-Bacterial Agents; Benzyl Compounds; Cell Line, Tumor; Cell Survival; Escherichia coli; Heterocyclic Compounds; Humans; Imidazoles; Methane; Microbial Sensitivity Tests; Silver Compounds; Staphylococcus aureus; X-Ray Diffraction | 2011 |
Telomestatin: formal total synthesis and cation-mediated interaction of its seco-derivatives with G-quadruplexes.
Topics: Base Sequence; Biophysical Phenomena; Cations, Monovalent; G-Quadruplexes; Humans; Ligands; Methane; Models, Molecular; Oxazoles; Rhodium | 2011 |
Enantioselective [4+2] cycloaddition of ketenes and 1-azadienes catalyzed by N-heterocyclic carbenes.
Topics: Aza Compounds; Catalysis; Crystallography, X-Ray; Cyclization; Ethylenes; Heterocyclic Compounds; Ketones; Methane; Molecular Conformation; Stereoisomerism | 2011 |
Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones.
Topics: Alkenes; Aluminum; Catalysis; Copper; Halogens; Ketones; Metals; Methane; Organometallic Compounds; Silicon; Stereoisomerism; Substrate Specificity | 2011 |
Heterobimetallic complexes containing an N-heterocyclic carbene based multidentate ligand and catalyzed tandem click/Sonogashira reactions.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism; Transition Elements | 2011 |
Pd(II) immobilized on mesoporous silica by N-heterocyclic carbene ionic liquids and catalysis for hydrogenation.
Topics: Catalysis; Hydrogenation; Ionic Liquids; Methane; Microscopy, Electron, Transmission; Palladium; Photoelectron Spectroscopy; Porosity; Silicon Dioxide; Spectroscopy, Fourier Transform Infrared; X-Ray Diffraction | 2011 |
Indenyl-functionalised triethylborane adduct of N-heterocyclic carbene: stepwise coordination of indenyl and NHC ligands toward molybdenum fragment.
Topics: Boranes; Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Indenes; Ligands; Methane; Models, Molecular; Molecular Structure; Molybdenum; Organometallic Compounds; Stereoisomerism | 2011 |
Facile synthesis of metal N-heterocyclic carbene complexes.
Topics: Electrochemistry; Heterocyclic Compounds; Imidazoles; Methane; Organometallic Compounds | 2011 |
The effect of sulfoxides on the stereoselective construction of tetrahydrofurans: total synthesis of (+)-goniothalesdiol.
Topics: Biological Products; Cyclization; Furans; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation; Molecular Structure; Stereoisomerism; Sulfoxides | 2011 |
Total syntheses of the histone deacetylase inhibitors largazole and 2-epi-largazole: application of N-heterocyclic carbene mediated acylations in complex molecule synthesis.
Topics: Acylation; Biological Products; Cell Line, Tumor; Cell Survival; Depsipeptides; Drug Screening Assays, Antitumor; Enzyme Inhibitors; Heterocyclic Compounds; Histone Deacetylase Inhibitors; Humans; Male; Methane; Stereoisomerism; Structure-Activity Relationship; Thiazoles | 2011 |
Synthesis of 2-keto-imidazoles utilizing N-arylamino-substituted N-heterocyclic carbenes.
Topics: Heterocyclic Compounds; Imidazoles; Methane; Molecular Structure; Stereoisomerism | 2011 |
(N-heterocyclic carbene)-Pd-catalyzed anaerobic oxidation of secondary alcohols and domino oxidation-arylation reactions.
Topics: Alcohols; Catalysis; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Palladium; Stereoisomerism | 2011 |
Late-stage diversification of chiral N-heterocyclic-carbene precatalysts for enantioselective homoenolate additions.
Topics: Catalysis; Heterocyclic Compounds; Methane; Stereoisomerism; Triazoles | 2011 |
Gold(III) N-heterocyclic carbene complexes mediated synthesis of β-enaminones from 1,3-dicarbonyl compounds and aliphatic amines.
Topics: Amines; Gold; Heterocyclic Compounds; Ketones; Methane | 2011 |
Well-defined N-heterocyclic carbene silver halides of 1-cyclohexyl-3-arylmethylimidazolylidenes: synthesis, structure and catalysis in A3-reaction of aldehydes, amines and alkynes.
Topics: Acetylene; Aldehydes; Alkynes; Amines; Bromides; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogen Bonding; Ligands; Methane; Molecular Structure; Piperidines; Silver Compounds; Stereoisomerism; Structure-Activity Relationship; X-Ray Diffraction | 2011 |
Chiral N-heterocyclic carbene-copper(I)-catalyzed asymmetric allylic arylation of aliphatic allylic bromides: steric and electronic effects on γ-selectivity.
Topics: Catalysis; Copper; Electrons; Heterocyclic Compounds; Hydrocarbons, Brominated; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2011 |
Investigation of a series of silver-N-heterocyclic carbenes as antibacterial agents: activity, synergistic effects, and cytotoxicity.
Topics: Anti-Bacterial Agents; Heterocyclic Compounds; Ligands; Methane; Molecular Structure; Silver Compounds | 2011 |
NHC-catalyzed/titanium(IV)-mediated highly diastereo- and enantioselective dimerization of enals.
Topics: Aldehydes; Alkenes; Catalysis; Cyclopentanes; Dimerization; Lewis Acids; Methane; Molecular Structure; Stereoisomerism; Titanium | 2011 |
Theoretical investigation of carbon-sulfur triple bonds.
Topics: Carbon; Methane; Models, Chemical; Molecular Conformation; Sulfur; Thermodynamics | 2011 |
Magnetic behaviors of heterospin chains consisting of cobalt(II) complexes and dipyridylcarbenes.
Topics: 2,2'-Dipyridyl; Cobalt; Crystallography, X-Ray; Magnetics; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2011 |
Highly enantioselective synthesis of α-amino acid derivatives by an NHC-catalyzed intermolecular Stetter reaction.
Topics: Amino Acids; Catalysis; Heterocyclic Compounds; Methane; Stereoisomerism | 2011 |
Stereoconvergent synthesis of chiral allylboronates from an E/Z mixture of allylic aryl ethers using a 6-NHC-Cu(I) catalyst.
Topics: Allyl Compounds; Boronic Acids; Catalysis; Copper; Ethers; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2011 |
Pd-NHC catalyzed conjugate addition versus the Mizoroki-Heck reaction.
Topics: Butanones; Catalysis; Heterocyclic Compounds; Methane; Organometallic Compounds; Palladium; Styrene | 2011 |
Theoretical investigations on the mechanism of benzoin condensation catalyzed by pyrido[1,2-a]-2-ethyl[1,2,4]triazol-3-ylidene.
Topics: Benzaldehydes; Benzoin; Catalysis; Furans; Hydrogen; Methane; Models, Chemical; Molecular Structure; Protons; Pyridines; Quantum Theory; tert-Butyl Alcohol; Triazoles | 2011 |
α,β-Unsaturated acyl azoliums from N-heterocyclic carbene catalyzed reactions: observation and mechanistic investigation.
Topics: Acylation; Azo Compounds; Catalysis; Cyclization; Heterocyclic Compounds; Kinetics; Magnetic Resonance Spectroscopy; Methane; Oxidation-Reduction | 2011 |
Lewis acid activated synthesis of highly substituted cyclopentanes by the N-heterocyclic carbene catalyzed addition of homoenolate equivalents to unsaturated ketoesters.
Topics: Catalysis; Cyclopentanes; Esters; Heterocyclic Compounds; Lewis Acids; Methane; Stereoisomerism; Titanium | 2011 |
Addition of N-heterocyclic carbenes to a ruthenium(VI) nitrido polyoxometalate: a new route to cyclic guanidines.
Topics: Guanidines; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Ruthenium; Silver; Tungsten | 2011 |
Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts.
Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Metals; Methane; Molecular Conformation | 2011 |
Synthesis and catalytic activity of histidine-based NHC ruthenium complexes.
Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Histidine; Hydrogenation; Methane; Molecular Conformation; Ruthenium | 2011 |
Total synthesis and absolute stereochemistry of seragakinone A.
Topics: Anti-Bacterial Agents; Benzoin; Biological Products; Cyclization; Heterocyclic Compounds, 4 or More Rings; Methane; Stereoisomerism | 2011 |
A unique three-dimensional coordination cluster based on a silver carbene complex.
Topics: Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure; Nickel; Organometallic Compounds; Silver Nitrate; Stereoisomerism | 2011 |
Homogeneous catalysis: Catalysts feel the force.
Topics: Catalysis; Coordination Complexes; Mechanical Phenomena; Metals; Methane; Polymers; Sonication | 2009 |
Activating catalysts with mechanical force.
Topics: Alkenes; Catalysis; Coordination Complexes; Ligands; Mechanical Phenomena; Metals; Methane; Polymers; Ruthenium; Silver | 2009 |
Coordination chemistry at carbon.
Topics: Carbon; Electrons; Ligands; Methane; Molecular Structure; Nitriles; Organic Chemicals; Oxidation-Reduction; Oxygen; Phosphoranes | 2009 |
Gold catalysis: Carbene or cation?
Topics: Catalysis; Cations; Gold; Methane; Molecular Structure | 2009 |
Facile oxygenation reactions of ruthenium acetylide complex containing substituted olefinic group.
Topics: Alkenes; Alkynes; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Oxygen; Propanols; Ruthenium | 2011 |
Synthesis and characterization of metallodendritic palladium-biscarbene complexes derived from 1,1'-methylenebis(1,2,4-triazole).
Topics: Catalysis; Dendrimers; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Palladium; Triazoles | 2011 |
Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.
Topics: Alkynes; Aluminum; Catalysis; Copper; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2011 |
Catalytic hydrodefluorination of pentafluorobenzene by [Ru(NHC)(PPh3)2(CO)H2]: a nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity.
Topics: Catalysis; Coordination Complexes; Fluorine; Ligands; Methane; Quantum Theory; Ruthenium; Stereoisomerism | 2011 |
N-Heterocyclic carbene-catalyzed (4+2) cycloaddition/decarboxylation of silyl dienol ethers with α,β-unsaturated acid fluorides.
Topics: Acids; Catalysis; Cyclization; Cyclohexenes; Decarboxylation; Ethers; Heterocyclic Compounds; Hydrocarbons, Fluorinated; Methane; Molecular Structure; Stereoisomerism | 2011 |
Propargyl alcohols as β-oxocarbenoid precursors for the ruthenium-catalyzed cyclopropanation of unactivated olefins by redox isomerization.
Topics: Alkenes; Alkynes; Catalysis; Cyclization; Methane; Molecular Structure; Oxidation-Reduction; Propanols; Ruthenium; Stereoisomerism | 2011 |
A Fischer carbene within an Arduengo carbene.
Topics: Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2011 |
N-heterocyclic carbene catalyzed aroylation of 3,5-dichloro-2(1H)-pyrazinones.
Topics: Aldehydes; Biological Products; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Pyrazines; Stereoisomerism | 2011 |
N-heterocyclic carbene Pt(II) complexes from caffeine: synthesis, structures and photoluminescent properties.
Topics: Caffeine; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Molecular Conformation; Platinum; Quantum Theory; Spectrophotometry, Ultraviolet | 2011 |
N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts.
Topics: Acrolein; Boronic Acids; Catalysis; Heterocyclic Compounds; Imidazoles; Methane; Molecular Structure; Particle Size; Porosity; Stereoisomerism; Surface Properties | 2011 |
Rapidly photoactivatable ATP probes for specific labeling of tropomyosin within the actomyosin protein complex.
Topics: Actomyosin; Adenosine Triphosphate; Affinity Labels; Binding Sites; Biotinylation; Chromatography, Affinity; Computer Simulation; Diazomethane; Methane; Photochemical Processes; Tropomyosin | 2011 |
NHC/iron cooperative catalysis: aerobic oxidative esterification of aldehydes with phenols.
Topics: Aldehydes; Catalysis; Esterification; Heterocyclic Compounds; Iron; Methane; Molecular Structure; Oxidation-Reduction; Phenols | 2011 |
Mass spectrometry of laser-initiated carbene reactions for protein topographic analysis.
Topics: Amino Acids; Calmodulin; Diazomethane; Lasers; Mass Spectrometry; Methane; Muscle, Skeletal; Myoglobin; Myosin-Light-Chain Kinase; Photolysis | 2011 |
The determination of oxidative damage in heart tissue of rats caused by ruthenium(II) and gold(I) N-heterocyclic carbene complexes.
Topics: Analysis of Variance; Animals; Catalase; Coordination Complexes; Glutathione; Gold; Heart; Heterocyclic Compounds; Male; Malondialdehyde; Methane; Myocardium; Oxidative Stress; Rats; Rats, Sprague-Dawley; Ruthenium; Superoxide Dismutase | 2011 |
The mechanism of H2 activation by (amino)carbenes.
Topics: Hydrogen; Methane; Quantum Theory | 2011 |
Ligand-controlled highly regioselective and asymmetric hydrogenation of quinoxalines catalyzed by ruthenium N-heterocyclic carbene complexes.
Topics: Catalysis; Coordination Complexes; Heterocyclic Compounds; Hydrogenation; Ligands; Methane; Quinoxalines; Ruthenium; Solvents; Stereoisomerism | 2011 |
N-Heterocyclic carbene-mediated oxidative esterification of aldehydes: ester formation and mechanistic studies.
Topics: Aldehydes; Benzoates; Catalysis; Cinnamates; Esterification; Esters; Heterocyclic Compounds; Methane; Nitrogen; Oxidation-Reduction | 2011 |
Experimental and computational exploration of indolizinyl carbene generation. A route to biindolizines.
Topics: Cyclization; Cyclopropanes; Indolizines; Methane; Models, Molecular; Molecular Conformation; Pyridines; Quantum Theory; Temperature | 2011 |
O-Glycosidation reactions promoted by in situ generated silver N-heterocyclic carbenes in ionic liquids.
Topics: Galactosides; Glycosides; Imidazoles; Ionic Liquids; Methane; Nitrophenols; Nuclear Magnetic Resonance, Biomolecular; Silver | 2011 |
Xanthone natural products via N-heterocyclic carbene catalysis: total synthesis of atroviridin.
Topics: Benzoquinones; Biological Products; Catalysis; Heterocyclic Compounds; Methane; Xanthones | 2011 |
A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene.
Topics: Coordination Complexes; Crystallography, X-Ray; Cyclization; Heterocyclic Compounds; Ligands; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation; Sulfhydryl Compounds; Toluene; Transition Elements | 2011 |
Density functional theory study of an all ferrous 4Fe-4S cluster.
Topics: Electron Spin Resonance Spectroscopy; Iron; Iron-Sulfur Proteins; Magnetics; Methane; Models, Molecular; Nitrogenase; Quantum Theory; Spectroscopy, Mossbauer; Spin Trapping; Sulfur; Thermodynamics | 2011 |
Carbene-mediated transformations of 1-(benzylideneamino)benzimidazoles.
Topics: Benzimidazoles; Catalysis; Methane; Models, Molecular; Molecular Conformation | 2011 |
Carbene-functionalized single-walled carbon nanotubes and their electrical properties.
Topics: Methane; Nanotechnology; Nanotubes, Carbon; Semiconductors; Transistors, Electronic | 2011 |
On the role of CO2 in NHC-catalyzed oxidation of aldehydes.
Topics: Aldehydes; Carbon Dioxide; Catalysis; Methane; Molecular Structure; Oxidation-Reduction | 2011 |
Exploiting the facile release of trifluoroacetate for the α-methylenation of the sterically hindered carbonyl groups on (+)-sclareolide and (-)-eburnamonine.
Topics: Cell Line, Tumor; Diterpenes; Humans; Inhibitory Concentration 50; Ketones; Methane; Trifluoroacetic Acid; Vinca Alkaloids | 2011 |
Direct functionalisation of group 10 N-heterocyclic carbene complexes for diversity enhancement.
Topics: Alkynes; Azides; Catalysis; Coordination Complexes; Heterocyclic Compounds; Methane; Palladium; Platinum | 2011 |
Organic base effects in NHC promoted O- to C-carboxyl transfer; chemoselectivity profiles, mechanistic studies and domino catalysis.
Topics: Carbonates; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2011 |
Insight into the role of the counteranion of an imidazolium salt in organocatalysis: a combined experimental and computational study.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Methane; Models, Molecular; Molecular Structure; Salts | 2011 |
Ligand steric contours to understand the effects of N-heterocyclic carbene ligands on the reversal of regioselectivity in Ni-catalyzed reductive couplings of alkynes and aldehydes.
Topics: Aldehydes; Alkynes; Catalysis; Heterocyclic Compounds; Ligands; Methane; Nickel; Oxidation-Reduction; Silanes | 2011 |
Highly selective ruthenium metathesis catalysts for ethenolysis.
Topics: Alkenes; Catalysis; Crystallography, X-Ray; Methane; Molecular Structure; Oleic Acids; Ruthenium | 2011 |
Selective, nickel-catalyzed hydrogenolysis of aryl ethers.
Topics: Alcohols; Biomass; Carbon; Catalysis; Chemical Phenomena; Ethers; Hydrocarbons, Aromatic; Hydrogen; Hydrogenation; Ligands; Lignin; Methane; Nickel; Oxygen; Phenyl Ethers; Temperature | 2011 |
N-Heterocyclic carbenes and charge separation in heterometallic s-block silylamides.
Topics: Amides; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Metals, Alkali; Metals, Alkaline Earth; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds | 2011 |
Photochemistry of group 6 Fischer carbene complexes: beyond the photocarbonylation reaction.
Topics: Chromium; Coordination Complexes; Ethylenes; Imines; Ketones; Lactams; Methane; Photochemical Processes | 2011 |
Copper-catalyzed 1,4-addition of organoboronates to alkylidene cyanoacetates: mechanistic insight and application to asymmetric catalysis.
Topics: Acetates; Boronic Acids; Catalysis; Copper; Cyclization; Heterocyclic Compounds; Methane | 2011 |
Cytotoxicity of gold(I) N-heterocyclic carbene complexes assessed by using human tumor cell lines.
Topics: Cell Line, Tumor; Gold; Humans; Methane; Molecular Structure; Organogold Compounds | 2011 |
Synthesis of benzocycloheptanones through coupling of δ,ε-unsaturated chromium carbene complexes and 2-alkynylbenzoyl derivatives.
Topics: Alkynes; Benzene Derivatives; Chromium; Cyclization; Cycloheptanes; Methane; Molecular Structure; Naphthalenes | 2011 |
Nickel N-heterocyclic carbene-pyridine complexes that exhibit selectivity for electrocatalytic reduction of carbon dioxide over water.
Topics: Carbon Dioxide; Carbon Monoxide; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Molecular Conformation; Nickel; Oxidation-Reduction; Pyridines; Water | 2011 |
Gold(I)-catalyzed formation of benzo[b]furans from 3-silyloxy-1,5-enynes.
Topics: Alkynes; Benzofurans; Catalysis; Crystallography, X-Ray; Cyclization; Gold; Methane; Molecular Conformation; Silanes | 2011 |
Sequential transformations to access polycyclic chemotypes: asymmetric crotylation and metal carbenoid reactions.
Topics: Bridged Bicyclo Compounds; Catalysis; Cyclization; Metals; Methane; Stereoisomerism | 2011 |
Chelated ruthenium catalysts for Z-selective olefin metathesis.
Topics: Alkenes; Catalysis; Chelating Agents; Crystallography, X-Ray; Methane; Molecular Structure; Ruthenium | 2011 |
Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis.
Topics: Alkenes; Catalysis; Methane; Molecular Structure; Organometallic Compounds; Protons; Ruthenium | 2011 |
Engineering bioactive surfaces with Fischer carbene complex: protein A on self-assembled monolayer for antibody sensing.
Topics: Animals; Click Chemistry; Glass; Gold; Hydrogen-Ion Concentration; Immunoglobulin G; Membranes, Artificial; Methane; Molecular Structure; Organometallic Compounds; Particle Size; Rabbits; Staphylococcal Protein A; Staphylococcus aureus; Stereoisomerism; Surface Properties; Tungsten | 2011 |
Dynamic behaviour attributed to chiral carbohydrate substituents of N-heterocyclic carbene ligands in square planar nickel complexes.
Topics: Carbohydrates; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Molecular Conformation; Nickel; Stereoisomerism; Temperature | 2011 |
Proton-induced dynamic equilibrium between cyclometalated ruthenium rNHC (remote N-heterocyclic carbene) tautomers with an NAD+/NADH function.
Topics: Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; NAD; Organometallic Compounds; Oxidation-Reduction; Protons; Ruthenium; Stereoisomerism | 2011 |
Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.
Topics: Alkanes; Carbon; Catalysis; Methane; Rhodium; Stereoisomerism; Sulfonamides; Triazoles | 2011 |
Mechanistic insights on N-heterocyclic carbene-catalyzed annulations: the role of base-assisted proton transfers.
Topics: Catalysis; Cyclization; Cyclopentanes; Heterocyclic Compounds; Methane; Molecular Conformation; Protons; Quantum Theory; Stereoisomerism | 2011 |
Remarkable metal-complexed phosphorus analogues of the cyclopropenylcarbene-cyclobutadiene rearrangement.
Topics: Butadienes; Coordination Complexes; Cyclobutanes; Cyclopropanes; Methane; Organic Chemistry Phenomena; Phosphines; Phosphorus | 2011 |
Covalent immobilization of active lysozyme on Si/glass surface using alkoxy Fischer carbene complex on SAM.
Topics: Alkenes; Enzymes, Immobilized; Glass; Membranes, Artificial; Methane; Molecular Structure; Muramidase; Organosilicon Compounds; Serum Albumin, Bovine; Surface Properties | 2011 |
Highly regioselective [3 + 2] annulation of azomethine imines with 1-alkynyl Fischer carbene complexes to functionalized N,N-bicyclic pyrazolidin-3-ones.
Topics: Alkynes; Azo Compounds; Bridged Bicyclo Compounds, Heterocyclic; Cyclization; Imines; Methane; Models, Molecular; Molecular Structure; Oxidation-Reduction; Pyrazoles; Stereoisomerism; Thiosemicarbazones | 2011 |
Covalent diamond-gold nanojewel hybrids via photochemically generated carbenes.
Topics: Crystallization; Diamond; Gold; Methane; Nanocomposites; Nanoparticles; Photochemical Processes | 2011 |
A platinum Chugaev carbene complex as a potent anticancer agent.
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Survival; Crystallography, X-Ray; DNA, Superhelical; Humans; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Neoplasms; Organoplatinum Compounds; Stereoisomerism; Sulfhydryl Compounds | 2011 |
Oxidative esterification, thioesterification, and amidation of aldehydes by a two-component organocatalyst system using a chiral N-heterocyclic carbene and redox-active riboflavin.
Topics: Aldehydes; Amides; Catalysis; Esterification; Methane; Oxidation-Reduction; Riboflavin; Sulfhydryl Compounds | 2011 |
Carbon-silicon and carbon-carbon bond formation by elimination reactions at metal N-heterocyclic carbene complexes.
Topics: Carbon; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Scandium; Silicon; Stereoisomerism; Yttrium | 2011 |
A novel water-soluble NHC-Pd polymer: an efficient and recyclable catalyst for the Suzuki coupling of aryl chlorides in water at room temperature.
Topics: Catalysis; Chlorides; Heterocyclic Compounds; Hydrocarbons, Aromatic; Methane; Palladium; Polyethylene Glycols; Polymers; Water | 2011 |
Preparation and characterization of amino-linked heterocyclic carbene palladium, gold, and silver complexes and their use as anticancer agents that act by triggering apoptotic cell death.
Topics: Antineoplastic Agents; Apoptosis; bcl-2 Homologous Antagonist-Killer Protein; Cell Line, Tumor; Coordination Complexes; Cyclin A; Cyclin B; Cyclin-Dependent Kinase 2; Drug Screening Assays, Antitumor; Gold; Humans; Imidazoles; Methane; Palladium; S Phase; Silver; Structure-Activity Relationship; Tumor Suppressor Protein p53 | 2011 |
Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives.
Topics: Alkenes; Catalysis; Catechols; Heterocyclic Compounds; Methane; Nitro Compounds; Oxidation-Reduction | 2011 |
Ab initio study of the decomposition of 2,5-dimethylfuran.
Topics: Furans; Humans; Hydroxyl Radical; Kinetics; Methane; Molecular Structure; Thermodynamics | 2011 |
Nitrenium ions as ligands for transition metals.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Ions; Ligands; Methane; Models, Molecular; Molecular Structure; Nitrogen; Organometallic Compounds; Transition Elements | 2011 |
Organocatalytic hydroacylation of unactivated alkenes.
Topics: Acylation; Aldehydes; Alkenes; Catalysis; Heterocyclic Compounds; Methane | 2011 |
Ruthenium-catalysed synthesis of fluorinated bicyclic amino esters through tandem carbene addition/cyclopropanation of enynes.
Topics: Alkynes; Amines; Bridged Bicyclo Compounds; Catalysis; Chemistry, Pharmaceutical; Cyclization; Drug Discovery; Esters; Fluorine; Halogenation; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Organometallic Compounds; Peptidomimetics; Proline; Ruthenium; Stereoisomerism | 2011 |
Umpolung reactivity of indole through gold catalysis.
Topics: Alkynes; Catalysis; Gold; Imines; Indoles; Methane; Stereoisomerism | 2011 |
Trapping the parent inorganic ethylenes H2SiGeH2 and H2SiSnH2 in the form of stable adducts at ambient temperature.
Topics: Coordination Complexes; Crystallography, X-Ray; Ethylenes; Germanium; Methane; Molecular Conformation; Silicon; Temperature | 2011 |
N-heterocyclic carbene stabilized dichlorosilylene transition-metal complexes of V(I), Co(I), and Fe(0).
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Silicon Compounds; Stereoisomerism; Transition Elements | 2011 |
N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams.
Topics: Catalysis; Imines; Lactams; Methane; Stereoisomerism | 2011 |
Chiral (acyclic diaminocarbene)gold(I)-catalyzed dynamic kinetic asymmetric transformation of propargyl esters.
Topics: Alkynes; Catalysis; Esters; Gold; Methane; Stereoisomerism | 2011 |
Enantioselective Diels-Alder reactions of enals and alkylidene diketones catalyzed by N-heterocyclic carbenes.
Topics: Aldehydes; Catalysis; Cyclization; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Stereoisomerism | 2011 |
Experimental charge density analysis of a gallium(I) N-heterocyclic carbene analogue.
Topics: Gallium; Heterocyclic Compounds; Methane; Models, Molecular; Organometallic Compounds; Quantum Theory | 2011 |
N-heterocyclic carbene ligands as mimics of imidazoles/histidine for the stabilization of di- and trinitrosyl iron complexes.
Topics: Crystallography, X-Ray; Ferric Compounds; Heterocyclic Compounds; Histidine; Imidazoles; Ligands; Methane; Models, Molecular; Molecular Conformation; Nitric Oxide; Stereoisomerism | 2011 |
Design and synthesis of C2-symmetric N-heterocyclic carbene precursors and metal carbenoids.
Topics: Drug Design; Heterocyclic Compounds; Metals; Methane | 2011 |
Reaction of β-lactam carbenes with 2-pyridyl isonitriles: a one-pot synthesis of 2-carbonyl-3-(pyridylamino)imidazo[1,2-a]pyridines useful as fluorescent probes for mercury ion.
Topics: beta-Lactams; Fluorescent Dyes; Mercury; Methane; Nitriles; Pyridines | 2011 |
Pentafluorophenylhalocarbenes.
Topics: Alkenes; Azirines; Cyclopropanes; Methane; Molecular Structure; Stereoisomerism | 2011 |
N-heterocyclic carbene-catalyzed aza-Michael addition.
Topics: Amines; Catalysis; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Stereoisomerism | 2011 |
Probing intermetallic coupling in dinuclear N-heterocyclic carbene ruthenium(II) complexes.
Topics: Crystallography, X-Ray; Electrochemistry; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Ruthenium; Stereoisomerism | 2011 |
Reactivity of N-(1,2,4-triazolyl)-substituted 1,2,3-triazoles.
Topics: Methane; Molecular Structure; Rhodium; Stereoisomerism; Triazoles | 2011 |
Organocatalytic iminium ion/carbene reaction cascade for the formation of optically active 2,4-disubstituted cyclopentenones.
Topics: Catalysis; Cyclopentanes; Imines; Ions; Methane; Molecular Structure; Stereoisomerism | 2011 |
Variable coordination of amine functionalised N-heterocyclic carbene ligands to Ru, Rh and Ir: C-H and N-H activation and catalytic transfer hydrogenation.
Topics: Amides; Amines; Catalysis; Chelating Agents; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogenation; Iridium; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhenium; Ruthenium; Stereoisomerism | 2011 |
Highly stereoselective synthesis of 1,2,3-trisubstituted indanes via oxidative N-heterocyclic carbene-catalyzed cascades.
Topics: Catalysis; Heterocyclic Compounds; Indans; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2011 |
Evaluation of reproductive toxicity in male rats treated with novel synthesized ruthenium(II) and gold(I)-NHC complexes.
Topics: Animals; Antineoplastic Agents; Coordination Complexes; Heterocyclic Compounds; Male; Methane; Organ Size; Organogold Compounds; Rats; Rats, Sprague-Dawley; Reproduction; Ruthenium; Spermatozoa; Testosterone | 2012 |
Synthesis of substituted [3]dendralenes and their unique cycloaddition reactions.
Topics: Aldehydes; Alkenes; Cyclization; Cyclohexenes; Dimerization; Methane; Molecular Conformation; Stereoisomerism | 2011 |
Characteristics and nature of the intermolecular interactions in boron-bonded complexes with carbene as electron donor: an ab initio, SAPT and QTAIM study.
Topics: Boron; Boron Compounds; Electrons; Hydrogen Bonding; Kinetics; Methane; Models, Chemical; Quantum Theory; Static Electricity; Thermodynamics | 2012 |
Formal Diels-Alder reactions of chalcones and formylcyclopropanes catalyzed by chiral N-heterocyclic carbenes.
Topics: Catalysis; Chalcones; Cyclohexanes; Cyclopropanes; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2011 |
Calix[4]arenes with one and two N-linked imidazolium units as precursors of N-heterocyclic carbene complexes. Coordination chemistry and use in Suzuki-Miyaura cross-coupling.
Topics: Calixarenes; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Methane; Models, Molecular; Molecular Conformation; Palladium; Phenols; Stereoisomerism | 2011 |
Syntheses, crystal structures, reactivity, and photochemistry of gold(III) bromides bearing N-heterocyclic carbenes.
Topics: Bromides; Coordination Complexes; Crystallography, X-Ray; Gold; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Photochemistry; Stereoisomerism | 2011 |
Enantioselective synthesis of dihydropyridinones via NHC-catalyzed aza-Claisen reaction.
Topics: Aza Compounds; Catalysis; Heterocyclic Compounds; Hydrogenation; Methane; Molecular Structure; Pyridones; Stereoisomerism | 2011 |
N-Heterocyclic carbene catalysis: enantioselective formal [2+2] cycloaddition of ketenes and N-sulfinylanilines.
Topics: Aniline Compounds; Catalysis; Cyclization; Ethylenes; Heterocyclic Compounds; Ketones; Methane; Oxides; Stereoisomerism; Sulfur | 2011 |
Probing the origin of degenerate metathesis selectivity via characterization and dynamics of ruthenacyclobutanes containing variable NHCs.
Topics: Butanes; Catalysis; Heterocyclic Compounds; Methane; Ruthenium | 2011 |
Efficient synthesis of benzofuranones: N-heterocyclic carbene (NHC)/base-catalyzed hydroacylation-Stetter-rearrangement cascade.
Topics: Alkynes; Benzofurans; Catalysis; Methane; Molecular Structure | 2011 |
Force field parametrization and molecular dynamics simulation of flexible POSS-linked (NHC; phosphine) Ru catalytic complexes.
Topics: Catalysis; Heterocyclic Compounds; Methane; Molecular Conformation; Molecular Dynamics Simulation; Organometallic Compounds; Organosilicon Compounds; Phosphines; Ruthenium | 2011 |
Phenanthrene-fused azo-ene-ynes: synthesis of dibenzo[f,h]cinnoline and dibenzo[e,g]isoindazole derivatives.
Topics: Azo Compounds; Benzene; Chemistry, Organic; Cyclization; Dimerization; Heterocyclic Compounds, 2-Ring; Indazoles; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Phenanthrenes; Thermodynamics | 2011 |
The molecular mechanism of enzymatic glycosyl transfer with retention of configuration: evidence for a short-lived oxocarbenium-like species.
Topics: Enzymes; Glucosyltransferases; Glycosyltransferases; Ions; Methane; Molecular Dynamics Simulation; Quantum Theory | 2011 |
Wide-range color tuning of iridium biscarbene complexes from blue to red by different N⁁N ligands: an alternative route for adjusting the emission colors.
Topics: Color; Coordination Complexes; Electrochemical Techniques; Iridium; Ligands; Methane; Quantum Theory; Spectrometry, Fluorescence | 2011 |
The doping effect of fluorinated aromatic solvents on the rate of ruthenium-catalysed olefin metathesis.
Topics: Alkenes; Catalysis; Hydrocarbons, Fluorinated; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Ruthenium | 2011 |
Dynamics of carbene cycloadditions.
Topics: Cyclization; Methane; Quantum Theory | 2011 |
Introduction of abnormal N-heterocyclic carbene as an efficient organocatalyst: ring opening polymerization of cyclic esters.
Topics: Caproates; Catalysis; Dioxanes; Esters; Heterocyclic Compounds; Hydrogen Bonding; Lactones; Methane; Polymerization | 2011 |
Preparation of photo-cross-linked small molecule affinity matrices for affinity selection of protein targets for biologically active small molecules.
Topics: Chromatography, Affinity; Cross-Linking Reagents; Cyclosporine; Mass Spectrometry; Methane; Microspheres; Photochemical Processes; Proteins; Sepharose; Small Molecule Libraries | 2012 |
In vitro antimicrobial studies of silver carbene complexes: activity of free and nanoparticle carbene formulations against clinical isolates of pathogenic bacteria.
Topics: Anti-Infective Agents; Bacteria; Bacterial Infections; Fungi; Humans; Methane; Microbial Sensitivity Tests; Microbial Viability; Mycoses; Nanoparticles; Silver | 2012 |
Nanoparticle encapsulated silver carbene complexes and their antimicrobial and anticancer properties: a perspective.
Topics: Animals; Anti-Bacterial Agents; Antineoplastic Agents; Cell Line, Tumor; Drug Carriers; Heterocyclic Compounds; Humans; Methane; Microbial Sensitivity Tests; Models, Molecular; Molecular Structure; Nanoparticles; Organometallic Compounds; Silver | 2012 |
Asymmetric N-H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids.
Topics: Amines; Amino Acids; Catalysis; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Phosphoric Acids; Rhodium; Spiro Compounds; Stereoisomerism | 2011 |
Room-temperature synthesis of tetra-ortho-substituted biaryls by NHC-catalyzed Suzuki-Miyaura couplings.
Topics: Catalysis; Combinatorial Chemistry Techniques; Cross-Linking Reagents; Heterocyclic Compounds; Methane; Molecular Structure; Naphthalenes; Palladium; Stereoisomerism; Temperature | 2011 |
Enantioselective Stetter reactions of enals and modified chalcones catalyzed by N-heterocyclic carbenes.
Topics: Anions; Catalysis; Chalcones; Methane; Stereoisomerism; Triazoles | 2011 |
Probing protein surface with a solvent mimetic carbene coupled to detection by mass spectrometry.
Topics: Amino Acid Sequence; Animals; Cattle; Chromatography, Reverse-Phase; Diazomethane; Humans; Methane; Molecular Sequence Data; Peptide Fragments; Peptide Mapping; Photolysis; Protein Folding; Proteins; Spectrometry, Mass, Electrospray Ionization; Tandem Mass Spectrometry | 2012 |
Synthesis and biological studies of silver N-heterocyclic carbene complexes derived from 4,5-diarylimidazole.
Topics: Anti-Bacterial Agents; Antineoplastic Agents; Bacteria; Bacterial Infections; Breast Neoplasms; Cell Line, Tumor; Colonic Neoplasms; Coordination Complexes; Crystallography, X-Ray; Female; Heterocyclic Compounds; HT29 Cells; Humans; Imidazoles; Methane; Models, Molecular; Silver | 2011 |
Concise formal synthesis of (-)-7-deoxyloganin via N-heterocyclic carbene catalysed rearrangement of α,β-unsaturated enol esters.
Topics: Catalysis; Esters; Glycosylation; Iridoids; Isomerism; Methane; Molecular Structure; Oxidation-Reduction | 2011 |
NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines.
Topics: Catalysis; Imines; Iron; Methane; Organometallic Compounds; Silanes | 2012 |
The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates.
Topics: Catalysis; Electrons; Hydrogen; Imines; Methane; Models, Theoretical; Molecular Structure; Rhodium | 2012 |
Transient innermolecular carbene-hemicarcerand complex of fluorophenylcarbene.
Topics: Bridged-Ring Compounds; Methane; Molecular Conformation | 2011 |
Skeletal isomerization of butene in ferrierite: assessing the energetic and structural differences between carbenium and alkoxide based pathways.
Topics: Alkenes; Methane; Models, Molecular; Molecular Structure; Oxides; Quantum Theory; Stereoisomerism; Thermodynamics; Zeolites | 2011 |
Designing N-heterocyclic carbenes: simultaneous enhancement of reactivity and enantioselectivity in the asymmetric hydroacylation of cyclopropenes.
Topics: Acylation; Crystallography, X-Ray; Cyclopropanes; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Stereoisomerism | 2011 |
Chemoselective conversion of α-unbranched aldehydes to amides, esters, and carboxylic acids by NHC-catalysis.
Topics: Aldehydes; Amides; Carboxylic Acids; Catalysis; Esters; Methane; Substrate Specificity | 2012 |
Application of a C2-symmetric copper carbenoid in the enantioselective hydrosilylation of dialkyl and aryl-alkyl ketones.
Topics: Catalysis; Copper; Ketones; Methane; Organosilicon Compounds; Stereoisomerism | 2011 |
Catalytic kinetic resolution of cyclic secondary amines.
Topics: Amines; Catalysis; Cyclization; Hydroxamic Acids; Kinetics; Methane; Stereoisomerism | 2011 |
Synthesis of endohedral metallofullerene glycoconjugates by carbene addition.
Topics: Diazomethane; Fullerenes; Glycoconjugates; Methane; Models, Molecular; Molecular Structure; Nuclear Magnetic Resonance, Biomolecular; Organometallic Compounds; Stereoisomerism | 2011 |
Regio- and stereoselective synthesis of cyclopentenones: intermolecular pseudo-Pauson-Khand cyclization.
Topics: Alkenes; Alkynes; Chromium; Cyclization; Cyclopentanes; Methane; Stereoisomerism; Tungsten | 2012 |
Tailored ruthenium-N-heterocyclic carbene hybrid catalytic materials for the hydrogenation of carbon dioxide in the presence of amine.
Topics: Carbon Dioxide; Catalysis; Heterocyclic Compounds; Hydrogenation; Magnetic Resonance Spectroscopy; Methane; Recycling; Ruthenium; Silicon Dioxide | 2011 |
Gold(I)-NHC complexes of antitumoral diarylimidazoles: structures, cellular uptake routes and anticancer activities.
Topics: Antineoplastic Agents; Cation Transport Proteins; Cell Line, Tumor; Cell Survival; Cells, Cultured; Copper Transport Proteins; Crystallography, X-Ray; Fibroblasts; Gold; Heterocyclic Compounds; HL-60 Cells; HT29 Cells; Humans; Imidazoles; Metallochaperones; Methane; Models, Molecular; Molecular Chaperones; Molecular Structure; Neoplasms; Organic Cation Transport Proteins; Organometallic Compounds; Tubulin | 2012 |
Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C-C forming reactions involving Ni-alkyl-β-silanes.
Topics: Heterocyclic Compounds; Methane; Molecular Structure; Nickel; Organometallic Compounds; Silanes; Stereoisomerism | 2012 |
The design and synthesis of novel IBiox N-heterocyclic carbene ligands derived from substituted amino-indanols.
Topics: Chemistry Techniques, Synthetic; Drug Design; Heterocyclic Compounds; Indans; Ligands; Methane; Oxazoles | 2012 |
Gold-catalyzed formal [3 + 3] and [4 + 2] cycloaddition reactions of nitrosobenzenes with alkenylgold carbenoids.
Topics: Catalysis; Cyclization; Gold; Methane; Nitroso Compounds; Stereoisomerism | 2011 |
β-Hairpin stabilization through an interstrand triazole bridge.
Topics: Chemistry, Pharmaceutical; Magnetic Resonance Spectroscopy; Methane; Peptides; Peptidomimetics; Protein Folding; Protein Structure, Secondary; Proteins; Triazoles | 2012 |
Stable N-heterocyclic carbene (NHC)-palladium(0) complexes as active catalysts for olefin cyclopropanation reactions with ethyl diazoacetate.
Topics: Catalysis; Crystallography, X-Ray; Diazonium Compounds; Heterocyclic Compounds; Ligands; Methane; Molecular Structure; Organometallic Compounds; Palladium; Stereoisomerism | 2011 |
The first facile stereoselectivity switch in the polymerization of rac-lactide--from heteroselective to isoselective dialkylgallium alkoxides with the help of N-heterocyclic carbenes.
Topics: Alcohols; Dioxanes; Gallium; Heterocyclic Compounds; Methane; Nitrogen; Polymerization; Stereoisomerism; Substrate Specificity | 2012 |
Theoretical investigations of the reactivities of four-membered N-heterocyclic carbene analogues of the group 13 elements.
Topics: Heterocyclic Compounds; Metals, Heavy; Methane; Molecular Structure; Organometallic Compounds; Quantum Theory; Stereoisomerism | 2012 |
Synthesis and characterization of cyclic and linear helical poly(alpha-peptoids)s by N-heterocyclic carbene-mediated ring-opening polymerizations of N-substituted N-carboxyanhydrides.
Topics: Anhydrides; Circular Dichroism; Cyclization; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Peptoids | 2011 |
N-Heterocyclic carbene catalyzed C-glycosylation: a concise approach from Stetter reaction.
Topics: Acylation; Catalysis; Disaccharides; Glycosylation; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure | 2012 |
Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.
Topics: Alkadienes; Allyl Compounds; Carbon; Catalysis; Copper; Methane; Stereoisomerism | 2012 |
Complexes of Ge(IV)- and Sn(IV)-fluorides with cyclic and acyclic carbenes: bis(dialkylamino)-difluoromethylenes as carbene sources.
Topics: Chemical Phenomena; Crystallography, X-Ray; Fluorides; Germanium; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Organometallic Compounds; Tin Compounds; X-Ray Diffraction | 2012 |
NHC-catalyzed thioesterification of aldehydes by external redox activation.
Topics: Aldehydes; Catalysis; Esterification; Methane; Oxidants; Oxidation-Reduction; Phenazines | 2012 |
Studies of the H-D exchange mechanism of malonganenone B.
Topics: Deuterium; Diterpenes; Hydrogen; Imidazoles; Kinetics; Methane; Molecular Structure | 2012 |
N-heterocyclic carbene-mediated hydroacylation-Sonogashira/Heck/Suzuki coupling in a single pot: a new cascade reaction.
Topics: Acylation; Heterocyclic Compounds; Methane; Molecular Structure | 2012 |
Rapid access to chroman-3-ones through gold-catalyzed oxidation of propargyl aryl ethers.
Topics: Alkynes; Catalysis; Chromans; Ethers; Gold; Methane; Oxidation-Reduction | 2012 |
A robust zirconium N-heterocyclic carbene complex for the living and highly stereoselective ring-opening polymerization of rac-lactide.
Topics: Coordination Complexes; Dioxanes; Methane; Models, Molecular; Polymerization; Stereoisomerism; Zirconium | 2012 |
N-heterocyclic carbene catalyzed reactions of α-bromo-α,β-unsaturated aldehydes/α,β-dibromoaldehydes with 1,3-dinucleophilic reagents.
Topics: Aldehydes; Catalysis; Esters; Hydrocarbons, Brominated; Indicators and Reagents; Ketones; Methane; Molecular Structure; Stereoisomerism | 2012 |
Highly enantioselective cyclizations of conjugated trienes with low catalyst loadings: a robust chiral N-heterocyclic carbene enabled by acetic acid cocatalyst.
Topics: Acetic Acid; Catalysis; Cyclization; Heterocyclic Compounds; Kinetics; Methane; Molecular Structure; Stereoisomerism | 2012 |
Conjugate-addition organopolymerization: rapid production of acrylic bioplastics by N-heterocyclic carbenes.
Topics: Crystallography, X-Ray; Cyclization; Methane; Molecular Structure; Polymers; Polymethyl Methacrylate; Time Factors | 2012 |
Cyclopropylmethyl palladium species from carbene migratory insertion: new routes to 1,3-butadienes.
Topics: Butadienes; Catalysis; Cyclopropanes; Iodobenzenes; Methane; Methylation; Molecular Structure; Palladium | 2012 |
Zwitterionic dithiocarboxylates derived from N-heterocyclic carbenes: coordination to gold surfaces.
Topics: Carboxylic Acids; Crystallography, X-Ray; Gold; Heterocyclic Compounds; Ligands; Methane; Optical Phenomena; Oxidation-Reduction; Surface Properties | 2012 |
Cross-coupling of non-activated chloroalkanes with aryl Grignard reagents in the presence of iron/N-heterocyclic carbene catalysts.
Topics: Alkanes; Catalysis; Heterocyclic Compounds; Iron; Methane; Molecular Structure; Stereoisomerism | 2012 |
Understanding the mechanism of the intramolecular stetter reaction. A DFT study.
Topics: Catalysis; Heterocyclic Compounds; Methane; Models, Molecular | 2012 |
Ruthenium NHC catalyzed highly asymmetric hydrogenation of benzofurans.
Topics: Benzofurans; Catalysis; Heterocyclic Compounds; Hydrogenation; Methane; Molecular Structure; Organometallic Compounds; Ruthenium | 2012 |
Enhanced cytotoxicity of silver complexes bearing bidentate N-heterocyclic carbene ligands.
Topics: Antineoplastic Agents; Cell Line, Tumor; Heterocyclic Compounds; Humans; Ligands; Methane; Organometallic Compounds; Silver | 2012 |
N-heterocyclic carbene-catalyzed internal redox reaction of alkynals: an efficient synthesis of allenoates.
Topics: Alkadienes; Alkynes; Catalysis; Combinatorial Chemistry Techniques; Methane; Molecular Structure; Oxidation-Reduction | 2012 |
N-Heterocyclic carbene-catalyzed three-component domino reaction of alkynyl aldehydes with oxindoles.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Hydrogenation; Indoles; Methane; Molecular Structure; Oxindoles; Spiro Compounds; Stereoisomerism | 2012 |
Dehydrative fragmentation of 5-hydroxyalkyl-1H-tetrazoles: a mild route to alkylidenecarbenes.
Topics: Combinatorial Chemistry Techniques; Methane; Molecular Structure; Stilbenes; Tetrazoles | 2012 |
Anticancer activity of silver-N-heterocyclic carbene complexes: caspase-independent induction of apoptosis via mitochondrial apoptosis-inducing factor (AIF).
Topics: Apoptosis; Apoptosis Inducing Factor; Caspases; Cell Cycle; Cell Line, Tumor; Cell Proliferation; Coordination Complexes; Drug Resistance, Neoplasm; Flow Cytometry; Heterocyclic Compounds; Humans; Inhibitory Concentration 50; Methane; Models, Biological; Molecular Structure; Silver | 2012 |
Synthesis, characterization, and antimicrobial activity of silver carbene complexes derived from 4,5,6,7-tetrachlorobenzimidazole against antibiotic resistant bacteria.
Topics: Anti-Bacterial Agents; Bacteria; Benzimidazoles; Chemistry Techniques, Synthetic; Drug Resistance, Bacterial; Methane; Microbial Sensitivity Tests; Organometallic Compounds; Silver | 2012 |
Competitive [2,3]- and [1,2]-oxonium ylide rearrangements. Concerted or stepwise?
Topics: Acetoacetates; Catalysis; Crystallography, X-Ray; Methane; Molecular Conformation; Molecular Structure; Onium Compounds; Rhodium; Stereoisomerism | 2012 |
Could diastereoselectivity in the presence of O-2 chiral nonparticipating groups be an indicator of glycopyranosyl oxacarbenium ions in glycosylation reactions?
Topics: Glycosides; Glycosylation; Indicators and Reagents; Ions; Methane; Models, Molecular; Stereoisomerism | 2012 |
Introducing axial chirality into mesoionic 4,4'-bis(1,2,3-triazole) dicarbenes.
Topics: Chromatography, High Pressure Liquid; Crystallography, X-Ray; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Triazoles | 2012 |
Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents.
Topics: Aldehydes; Alkenes; Crystallography, X-Ray; Cyclization; Cyclopropanes; Epoxy Compounds; Ketones; Methane; Molecular Conformation; Stereoisomerism | 2012 |
Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(III) complex of a D4-symmetric Halterman porphyrin ligand.
Topics: Carbon; Catalysis; Hydrogen; Iridium; Ligands; Metalloporphyrins; Methane; Silicon; Stereoisomerism; Substrate Specificity | 2012 |
Isolable analogues of the Breslow intermediate derived from chiral triazolylidene carbenes.
Topics: Anions; Catalysis; Chemistry; Crystallization; Crystallography, X-Ray; Ions; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Molecular Structure; Nitrogen; Probability; Stereoisomerism; Temperature; Thiamine; Triazoles | 2012 |
Chromatographic examination of the chemical composition and sequence distribution of copolymers from ethyl and benzyl diazoacetate.
Topics: Chromatography, Gel; Diazonium Compounds; Gas Chromatography-Mass Spectrometry; Methane; Molecular Weight; Polymers | 2012 |
Photochemistry of furyl- and thienyldiazomethanes: spectroscopic characterization of triplet 3-thienylcarbene.
Topics: Carbon; Computer Simulation; Diazomethane; Electrochemistry; Electron Spin Resonance Spectroscopy; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Models, Molecular; Molecular Conformation; Photochemistry; Software; Spectrophotometry | 2012 |
High-resolution mapping of carbene-based protein footprints.
Topics: Amino Acid Sequence; Chromatography, High Pressure Liquid; Methane; Peptides; Photolysis; Protein Footprinting; Static Electricity; Tandem Mass Spectrometry | 2012 |
Enantioselective activation of stable carboxylate esters as enolate equivalents via N-heterocyclic carbene catalysts.
Topics: Carboxylic Acids; Catalysis; Esters; Heterocyclic Compounds; Imines; Methane; Molecular Structure; Stereoisomerism | 2012 |
An N-heterocyclic carbene/Lewis acid strategy for the stereoselective synthesis of spirooxindole lactones.
Topics: Catalysis; Indoles; Lactones; Lewis Acids; Methane; Molecular Structure; Spiro Compounds; Stereoisomerism | 2012 |
Enantioselective cyclopropanation of enals by oxidative N-heterocyclic carbene catalysis.
Topics: Aldehydes; Catalysis; Cyclopropanes; Methane; Oxidation-Reduction; Stereoisomerism; Sulfur | 2012 |
Alkylation of pyridone derivatives by nickel/Lewis acid catalysis.
Topics: Alkenes; Alkylation; Catalysis; Lewis Acids; Methane; Nickel; Pyridones | 2012 |
Access to spirocyclic oxindoles via N-heterocyclic carbene-catalyzed reactions of enals and oxindole-derived α,β-unsaturated imines.
Topics: Aldehydes; beta-Lactams; Catalysis; Imines; Indoles; Methane; Molecular Structure; Oxindoles; Spiro Compounds; Stereoisomerism | 2012 |
Selective olefination of carbonyl compounds via metal-catalyzed carbene transfer from diazo reagents.
Topics: Aldehydes; Alkenes; Azo Compounds; Ketones; Metals; Methane; Molecular Structure; Stereoisomerism | 2012 |
Gold-catalyzed carbene transfer to alkynes: access to 2,4-disubstituted furans.
Topics: Alkynes; Catalysis; Cyclization; Furans; Gold; Methane; Sulfur | 2012 |
Highly selective intramolecular carbene insertion into primary C-H bond of α-diazoacetamides mediated by a (p-cymene)ruthenium(II) carboxylate complex.
Topics: Acetamides; Azo Compounds; Carboxylic Acids; Coordination Complexes; Cymenes; Methane; Models, Molecular; Monoterpenes; Ruthenium | 2012 |
Rhodium(II)-catalyzed cyclization of bis(N-tosylhydrazone)s: an efficient approach towards polycyclic aromatic compounds.
Topics: Azo Compounds; Catalysis; Cyclization; Hydrazones; Methane; Polycyclic Compounds; Rhodium | 2012 |
Ligand-controlled regioselectivity in the hydrothiolation of alkynes by rhodium N-heterocyclic carbene catalysts.
Topics: Alkynes; Catalysis; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Rhodium; Stereoisomerism; Substrate Specificity; Sulfhydryl Compounds; Sulfides | 2012 |
Highly regio- and stereoselective dirhodium vinylcarbene induced nitrone cycloaddition with subsequent cascade carbenoid aromatic cycloaddition/N-O cleavage and rearrangement.
Topics: Methane; Nitrogen; Nitrogen Oxides; Oxygen; Rhodium; Stereoisomerism; Vinyl Compounds | 2012 |
N-Heterocyclic carbene catalyzed oxidative macrolactonization: total synthesis of (+)-dactylolide.
Topics: Alkylation; Bridged Bicyclo Compounds, Heterocyclic; Catalysis; Heterocyclic Compounds; Lactones; Methane; Oxidation-Reduction; Stereoisomerism | 2012 |
Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis.
Topics: Acylation; Amines; Catalysis; Heterocyclic Compounds; Methane; Oxidation-Reduction; Photochemical Processes | 2012 |
Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes.
Topics: Aldehydes; Amides; Boron; Catalysis; Copper; Esters; Heterocyclic Compounds; Ketones; Methane; Stereoisomerism; Substrate Specificity | 2012 |
New catalysts for the transition-metal-catalyzed synthesis of aziridines.
Topics: Azides; Aziridines; Catalysis; Methane; Stereoisomerism; Transition Elements | 2012 |
A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity.
Topics: Amines; Crystallography, X-Ray; Cyclization; Electrochemistry; Heterocyclic Compounds; Methane; Molecular Structure | 2012 |
Rhodium(II)- and copper(II)-catalyzed reactions of enol diazoacetates with nitrones: metal carbene versus Lewis acid directed pathways.
Topics: Acetates; Catalysis; Copper; Lewis Acids; Methane; Nitrogen Oxides; Rhodium; Stereoisomerism | 2012 |
Enol acetal synthesis through carbenoid C-H insertion into tetrahydrofuran catalyzed by CpRu complexes.
Topics: Acetals; Azo Compounds; Carbon; Catalysis; Coordination Complexes; Furans; Hydrogen; Methane; Ruthenium | 2012 |
N-Heterocyclic carbene-mediated zwitterionic polymerization of N-substituted N-carboxyanhydrides toward poly(α-peptoid)s: kinetic, mechanism, and architectural control.
Topics: Anhydrides; Heterocyclic Compounds; Kinetics; Methane; Molecular Structure; Peptoids; Polymerization | 2012 |
Oxidative γ-addition of enals to trifluoromethyl ketones: enantioselectivity control via Lewis acid/N-heterocyclic carbene cooperative catalysis.
Topics: Alkenes; Catalysis; Heterocyclic Compounds; Ketones; Lewis Acids; Methane; Oxidation-Reduction; Stereoisomerism; Substrate Specificity | 2012 |
Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton.
Topics: Androgens; Androstadienes; Catalysis; Hydrogen; Methane; Oxygen; Rhodium; Silver | 2012 |
N-heterocyclic carbene (NHC)-catalyzed highly diastereo- and enantioselective oxo-Diels-Alder reactions for synthesis of fused pyrano[2,3-b]indoles.
Topics: Aldehydes; Catalysis; Cyclization; Heterocyclic Compounds, 3-Ring; Indoles; Methane; Molecular Structure; Pyrones; Stereoisomerism | 2012 |
Mesoionic oxides: facile access from triazolium salts or triazolylidene copper precursors, and catalytic relevance.
Topics: Catalysis; Cesium; Copper; Methane; Oxides; Salts; Triazoles | 2012 |
Carbenic vs. ionic mechanistic pathway in reaction of cyclohexanone with bromoform.
Topics: Cyclohexanones; Ions; Ketones; Methane; Models, Molecular; Molecular Conformation; Oxygen; Solvents; Thermodynamics; Trihalomethanes | 2012 |
An N-heterocyclic carbene containing a bithiophene backbone: synthesis and coordination chemistry.
Topics: Coordination Complexes; Heterocyclic Compounds; Methane; Molecular Structure; Thiophenes | 2012 |
Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration.
Topics: Azo Compounds; Catalysis; Computer Simulation; Cyclopropanes; Hydrogen; Methane; Molecular Conformation; Rhodium; Stereoisomerism | 2012 |
Pyrazine functionalized Ag(I) and Au(I)-NHC complexes are potential antibacterial agents.
Topics: Anti-Bacterial Agents; Binding Sites; Biofilms; Coordination Complexes; Gold; Gram-Negative Bacteria; Gram-Positive Bacteria; Heterocyclic Compounds; Methane; Microbial Sensitivity Tests; Molecular Docking Simulation; Peptidoglycan; Pyrazines; Silver | 2012 |
Catalytic oxidation/C-H functionalization of N-arylpropiolamides by means of gold carbenoids: concise route to 3-acyloxindoles.
Topics: Amides; Catalysis; Gold; Indoles; Methane; Molecular Structure; Oxidation-Reduction | 2012 |
NHC-catalyzed C-O or C-N bond formation: efficient approaches to α,β-unsaturated esters and amides.
Topics: Amides; Carbon; Catalysis; Esters; Heterocyclic Compounds; Methane; Nitrogen; Oxidation-Reduction; Oxygen; Stereoisomerism | 2012 |
Catalytic dynamic kinetic resolutions with N-heterocyclic carbenes: asymmetric synthesis of highly substituted β-lactones.
Topics: Aldehydes; Catalysis; Cyclopentanes; Heterocyclic Compounds; Kinetics; Lactones; Methane; Stereoisomerism | 2012 |
Borenium ion catalyzed hydroboration of alkenes with N-heterocyclic carbene-boranes.
Topics: Alkenes; Boranes; Boron; Catalysis; Ions; Methane | 2012 |
Stereospecific synthesis and catalytic activity of L-histidylidene metal complexes.
Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Histidine; Iridium; Ligands; Methane; Molecular Conformation; Phosphines; Rhodium; Stereoisomerism; Temperature | 2012 |
N-heterocyclic carbene boranes as electron-donating and electron-accepting components of π-conjugated systems.
Topics: Boranes; Electrochemistry; Electrons; Heterocyclic Compounds; Methane; Molecular Structure; Quantum Theory | 2012 |
On the organocatalytic activity of N-heterocyclic carbenes: role of sulfur in thiamine.
Topics: Aldehydes; Benzoin; Catalysis; Heterocyclic Compounds; Imidazoles; Methane; Molecular Structure; Quantum Theory; Sulfur; Thiamine; Thiazoles; Triazoles | 2012 |
Theoretical study on the mechanism of Ag-catalyzed synthesis of 3-alkylideneoxindoles from N-aryl-α-diazoamides: a Lewis acid or Ag-carbene pathway?
Topics: Amides; Azo Compounds; Catalysis; Cyclization; Indoles; Lewis Acids; Methane; Models, Molecular; Nitrogen; Oxindoles; Quantum Theory; Silver | 2012 |
Lewis base mediated dismutation of trichlorosilane.
Topics: Crystallography, X-Ray; Lewis Bases; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Silanes | 2012 |
N-heterocyclic carbene-catalyzed homoenolate additions with N-aryl ketimines as electrophiles: efficient synthesis of spirocyclic γ-lactam oxindoles.
Topics: Catalysis; Heterocyclic Compounds; Imines; Indoles; Lactams; Methane; Molecular Structure; Nitriles; Oxindoles; Spiro Compounds; Stereoisomerism | 2012 |
Nanofiber composites containing N-heterocyclic carbene complexes with antimicrobial activity.
Topics: Anti-Bacterial Agents; Bacteria; Electrochemical Techniques; Fungi; Gold Compounds; Methane; Microbial Sensitivity Tests; Nanocomposites; Nanofibers; Nanotechnology; Particle Size | 2012 |
Catalytic generation of zinc carbenes from alkynes: zinc-catalyzed cyclopropanation and Si-H bond insertion reactions.
Topics: Alkynes; Catalysis; Cyclopropanes; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Silicon; Stereoisomerism; Zinc | 2012 |
Oxyanion steering and CH-π interactions as key elements in an N-heterocyclic carbene-catalyzed [4 + 2] cycloaddition.
Topics: Anions; Catalysis; Cyclization; Heterocyclic Compounds; Lactones; Methane; Models, Molecular; Oxygen; Stereoisomerism | 2012 |
Regioselective and stepwise [8 + 2] cycloaddition reaction between alkynyl-Fischer carbene complexes and tropothione.
Topics: Alkynes; Cyclization; Methane; Molecular Structure; Stereoisomerism; Thiones; Thiophenes | 2012 |
N-heterocyclic carbene-palladium(II)-1-methylimidazole complex-catalyzed Suzuki-Miyaura coupling of aryl sulfonates with arylboronic acids.
Topics: Arylsulfonates; Biphenyl Compounds; Boronic Acids; Catalysis; Heterocyclic Compounds; Imidazoles; Methane; Molecular Structure; Organometallic Compounds; Palladium | 2012 |
Bis(tridentate) ruthenium-terpyridine complexes featuring microsecond excited-state lifetimes.
Topics: Coordination Complexes; Ligands; Methane; Pyridines; Ruthenium | 2012 |
An acyclic imino-substituted silylene: synthesis, isolation, and its facile conversion into a zwitterionic silaimine.
Topics: Crystallography, X-Ray; Imino Acids; Methane; Models, Molecular; Molecular Structure; Nitrogen; Silicon | 2012 |
Comparative study of C^N and N^C type cyclometalated ruthenium complexes with a NAD+/NADH function.
Topics: Crystallography, X-Ray; Electrochemical Techniques; Ethylamines; Kinetics; Ligands; Light; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; NAD; Organometallic Compounds; Photochemical Processes; Protons; Ruthenium; Stereoisomerism; Thermodynamics | 2012 |
Photoinduced carbene generation from diazirine modified task specific phosphonium salts to prepare robust hydrophobic coatings.
Topics: Diazomethane; Hydrophobic and Hydrophilic Interactions; Methane; Organophosphorus Compounds; Photochemical Processes | 2012 |
Photogeneration of benzhydryl cations by near-UV laser flash photolysis of pyridinium salts.
Topics: Cations; Methane; Molecular Structure; Photochemical Processes; Photolysis; Pyridinium Compounds; Salts; Spectrophotometry, Ultraviolet; Ultraviolet Rays | 2012 |
Cross-coupling of diarylborinic acids and anhydrides with arylhalides catalyzed by a phosphite/N-heterocyclic carbene co-supported palladium catalyst system.
Topics: Anhydrides; Biphenyl Compounds; Borinic Acids; Catalysis; Heterocyclic Compounds; Hydrocarbons, Halogenated; Methane; Molecular Structure; Organometallic Compounds; Palladium; Phosphites | 2012 |
Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate.
Topics: Alkynes; Azides; Catalysis; Copper; Cycloaddition Reaction; Cyclopropanes; Methane; Silver; Triazoles | 2013 |
Silica gel promotes reductions of aldehydes and ketones by N-heterocyclic carbene boranes.
Topics: Alcohols; Aldehydes; Boranes; Catalysis; Ketones; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Oxidation-Reduction; Silica Gel | 2012 |
Magnetic properties of 1 : 4 complexes of CoCl2 and pyridines carrying carbenes (S(0) = 4/2, 6/2, and 8/2) in diluted frozen solution; influence of carbene multiplicity on heterospin single-molecule magnets.
Topics: Cobalt; Coordination Complexes; Freezing; Magnetics; Methane; Photolysis; Pyridines; Solutions; Temperature | 2012 |
Sulfur containing platinum(II) complexes with N-heterocyclic carbene ligands obtained by reactions of a hydrosulfido complex.
Topics: Coordination Complexes; Electrochemistry; Heterocyclic Compounds; Hydrogen Sulfide; Ligands; Methane; Oxidation-Reduction; Platinum; Sulfur | 2012 |
Arylation of rhodium(II) azavinyl carbenes with boronic acids.
Topics: Amines; Aza Compounds; Boronic Acids; Catalysis; Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2012 |
Synthesis of bicyclic imidazoles via [2 + 3] cycloaddition between nitriles and regioselectively generated α-imino gold carbene intermediates.
Topics: Alkynes; Catalysis; Cyclization; Cycloaddition Reaction; Gold Compounds; Heterocyclic Compounds, 2-Ring; Imidazoles; Methane; Molecular Structure; Nitriles; Stereoisomerism | 2012 |
Synthesis of 5'-methylene-phosphonate furanonucleoside prodrugs: application to D-2'-deoxy-2'-α-fluoro-2'-β-C-methyl nucleosides.
Topics: Amides; Antiviral Agents; Hepacivirus; Methane; Molecular Structure; Nucleosides; Phosphoric Acids; Prodrugs | 2012 |
Synthesis of tetrahydropyridazines by a metal-carbene-directed enantioselective vinylogous N-H insertion/Lewis acid-catalyzed diastereoselective Mannich addition.
Topics: Catalysis; Cycloaddition Reaction; Lewis Acids; Methane; Pyridazines; Rhodium; Stereoisomerism | 2012 |
One-pot gold-catalyzed synthesis of azepino[1,2-a]indoles.
Topics: Azepines; Catalysis; Indoles; Methane; Organogold Compounds | 2012 |
Synthesis and biological activity of ester- and amide-functionalized imidazolium salts and related water-soluble coinage metal N-heterocyclic carbene complexes.
Topics: Amides; Antineoplastic Agents; Cell Death; Cell Line, Tumor; Cell Proliferation; Crystallography, X-Ray; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Esters; HEK293 Cells; Heterocyclic Compounds; Humans; Imidazoles; Magnetic Resonance Spectroscopy; MCF-7 Cells; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Salts; Solubility; Structure-Activity Relationship; Water | 2012 |
Synthesis of furan-3-carboxylic and 4-methylene-4,5-dihydrofuran-3-carboxylic esters by direct palladium iodide catalyzed oxidative carbonylation of 3-yne-1,2-diol derivatives.
Topics: Alkynes; Carboxylic Acids; Catalysis; Esters; Furans; Iodides; Methane; Molecular Structure; Oxidation-Reduction; Palladium | 2012 |
Enantioselective synthesis of β,γ-unsaturated α-fluoroesters catalyzed by N-heterocyclic carbenes.
Topics: Catalysis; Esters; Fluorine; Heterocyclic Compounds; Methane; Stereoisomerism | 2012 |
N-Heterocyclic carbene-catalyzed annulation of α-cyano-1,4-diketones with ynals.
Topics: Alkynes; Catalysis; Ketones; Methane; Molecular Structure; Nitriles; Stereoisomerism | 2012 |
Structures and reactivities of O-methylated Breslow intermediates.
Topics: Benzoin; Crystallography, X-Ray; Heterocyclic Compounds; Kinetics; Methane; Methylation; Molecular Conformation; Structure-Activity Relationship | 2012 |
Efficient generation of pyridines by ruthenium carbene mediated [2 + 2 + 2] cyclotrimerization.
Topics: Catalysis; Cyclization; Methane; Molecular Structure; Pyridines; Ruthenium Compounds | 2012 |
Rollover cyclometalation pathway in rhodium catalysis: dramatic NHC effects in the C-H bond functionalization.
Topics: 2,2'-Dipyridyl; Catalysis; Cyclization; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Quantum Theory; Quinolines; Rhodium; Stereoisomerism | 2012 |
N-heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed amination between aryl chlorides and amides.
Topics: Amides; Amination; Aniline Compounds; Catalysis; Heterocyclic Compounds; Hydrocarbons, Chlorinated; Imidazoles; Methane; Molecular Structure; Organometallic Compounds; Palladium | 2012 |
Highly enantioselective [4 + 2] cyclization of chloroaldehydes and 1-azadienes catalyzed by N-heterocyclic carbenes.
Topics: Aldehydes; Aza Compounds; Cyclization; Hydrogenation; Methane; Molecular Structure; Pyridones; Stereoisomerism | 2012 |
Aerosolized antimicrobial agents based on degradable dextran nanoparticles loaded with silver carbene complexes.
Topics: Administration, Inhalation; Anti-Infective Agents; Dextrans; Drug Carriers; Methane; Microbial Sensitivity Tests; Microscopy, Electron, Scanning; Microscopy, Electron, Transmission; Nanoparticles; Particle Size; Pharmaceutical Preparations; Pseudomonas aeruginosa; Silver; Solubility; Staphylococcus aureus | 2012 |
A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of an NHC-Rh hydrosilylation catalyst.
Topics: Catalysis; Chelating Agents; Heterocyclic Compounds; Histidine; Methane; Molecular Structure; Rhodium; Silanes | 2012 |
Tempering the reactivities of postulated α-oxo gold carbenes using bidentate ligands: implication of tricoordinated gold intermediates and the development of an expedient bimolecular assembly of 2,4-disubstituted oxazoles.
Topics: Catalysis; Gold; Ligands; Methane; Models, Molecular; Molecular Structure; Oxazoles | 2012 |
Carbenoid-mediated N-O bond insertion and its application in the synthesis of pyridines.
Topics: Coordination Complexes; Ethers; Methane; Nitrogen; Oximes; Oxygen; Pyridines; Rhodium | 2012 |
Highly enantioselective addition of enals to isatin-derived ketimines catalyzed by N-heterocyclic carbenes: synthesis of spirocyclic γ-lactams.
Topics: Aldehydes; Catalysis; Imines; Indoles; Isatin; Lactams; Methane; Molecular Structure; Nitriles; Oxindoles; Spiro Compounds; Stereoisomerism | 2012 |
Umpolung by N-heterocyclic carbenes: generation and reactivity of the elusive 2,2-diamino enols (Breslow intermediates).
Topics: Azoles; Benzoin; Crystallography, X-Ray; Diamines; Magnetic Resonance Imaging; Methane; Stereoisomerism | 2012 |
Synthesis of bridged polycyclic ring systems via carbene cascades terminating in C-H bond insertion.
Topics: Alkynes; Esters; Ketones; Methane; Molecular Structure; Polycyclic Compounds | 2012 |
Suzuki-Miyaura reactions catalyzed by C₂-symmetric Pd-multi-dentate N-heterocyclic carbene complexes.
Topics: Catalysis; Heterocyclic Compounds; Methane; Palladium | 2012 |
N-heterocyclic carbene catalyzed synthesis of oxime esters.
Topics: Aldehydes; Catalysis; Esters; Heterocyclic Compounds; Methane; Molecular Structure; Oximes | 2013 |
N-heterocyclic carbene-catalyzed [4 + 2] cycloaddition of ketenes and 3-aroylcoumarins: highly enantioselective synthesis of dihydrocoumarin-fused dihydropyranones.
Topics: Catalysis; Coumarins; Crystallography, X-Ray; Cyclization; Ethylenes; Heterocyclic Compounds; Ketones; Methane; Models, Molecular; Molecular Structure; Pyrones; Stereoisomerism | 2013 |
N-heterocyclic-carbene-catalyzed asymmetric oxidative hetero-Diels-Alder reactions with simple aliphatic aldehydes.
Topics: Aldehydes; Catalysis; Coordination Complexes; Heterocyclic Compounds; Imines; Lactams; Lactones; Methane; Stereoisomerism | 2012 |
Hydrogen shuttling: synthesis and reactivity of a 14-electron iridium complex featuring a bis(alkyl) tethered N-heterocyclic carbene ligand.
Topics: Electrons; Heterocyclic Compounds; Hydrogen; Iridium; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds | 2012 |
Bromide ion binding by a dinuclear gold(I) N-heterocyclic carbene complex: a spectrofluorescence and X-ray absorption spectroscopic study.
Topics: Bromides; Coordination Complexes; Gold; Ions; Methane; X-Ray Absorption Spectroscopy | 2013 |
Synthesis, characterization, and electrochemical properties of diiron propaneditellurolate (PDTe) complexes as active site models of [FeFe]-hydrogenases.
Topics: Catalysis; Catalytic Domain; Coordination Complexes; Crystallography, X-Ray; Electrochemical Techniques; Hydrogen; Hydrogenase; Iron; Iron Compounds; Iron-Sulfur Proteins; Methane; Molecular Conformation; Phosphines; Tellurium | 2013 |
Evaluation of arene ruthenium(II) N-heterocyclic carbene complexes as organometallics interacting with thiol and selenol containing biomolecules.
Topics: Animals; Cathepsin B; Cell Proliferation; Coordination Complexes; DNA; Embryo, Nonmammalian; Glutathione Reductase; HT29 Cells; Humans; MCF-7 Cells; Methane; Ruthenium; Selenium Compounds; Sulfhydryl Compounds; Thioredoxin-Disulfide Reductase; Trypsin; Zebrafish | 2013 |
Expanding the scope of donor/acceptor carbenes to N-phthalimido donor groups: diastereoselective synthesis of 1-cyclopropane α-amino acids.
Topics: Alkenes; Amino Acids; Catalysis; Cyclopropanes; Methane; Phthalimides; Stereoisomerism; Triazoles | 2012 |
Ring expansion and rearrangements of rhodium(II) azavinyl carbenes.
Topics: Alkenes; Catalysis; Click Chemistry; Heterocyclic Compounds; Methane; Rhodium; Stereoisomerism; Triazoles | 2012 |
Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes.
Topics: Catalysis; Cyclization; Gold; Methane; Stereoisomerism | 2013 |
Biosynthetically directed ²H labelling for stereospecific resonance assignments of glycine methylene groups.
Topics: Deuterium; Glycine; Isotope Labeling; Methane; Nuclear Magnetic Resonance, Biomolecular | 2013 |
A tetracarbene-oxoiron(IV) complex.
Topics: Coordination Complexes; Crystallography, X-Ray; Iron; Methane; Molecular Conformation; Organometallic Compounds; Spectroscopy, Mossbauer | 2013 |
A concise assembly of electron-deficient 2,4-dienes and 2,4-dienals: regio- and stereoselective exo-Diels-Alder and redox reactions through sequential amine and carbene catalysis.
Topics: Amines; Catalysis; Cycloaddition Reaction; Electrons; Methane; Oxidation-Reduction; Stereoisomerism | 2013 |
[bmim][Br] as a solvent and activator for the Ga-mediated Barbier allylation: direct formation of an N-heterocyclic carbene from Ga metal.
Topics: Catalysis; Gallium; Heterocyclic Compounds; Imidazoles; Methane; Solvents | 2012 |
Impact of diradical character on two-photon absorption: bis(acridine) dimers synthesized from an allenic precursor.
Topics: Acridines; Dimerization; Methane; Models, Molecular; Molecular Structure; Photons; Quantum Theory | 2013 |
N-Heterocyclic carbene metal complexes in medicinal chemistry.
Topics: Animals; Anti-Bacterial Agents; Antineoplastic Agents; Chemistry, Pharmaceutical; Coordination Complexes; Embryo, Nonmammalian; Gram-Negative Bacteria; Gram-Positive Bacteria; Heterocyclic Compounds; Methane; Mice; Mice, Nude; Microbial Sensitivity Tests; Platinum; Rats; Silver; Transition Elements; Transplantation, Heterologous; Zebrafish | 2013 |
N-Heterocyclic-carbene-catalyzed reaction of α-bromo-α,β-unsaturated aldehyde or α,β-dibromoaldehyde with isatins: an efficient synthesis of spirocyclic oxindole-dihydropyranones.
Topics: Aldehydes; Catalysis; Chemistry Techniques, Synthetic; Halogenation; Indoles; Isatin; Methane; Oxindoles; Spiro Compounds | 2013 |
N-heterocyclic carbene-catalyzed Ireland-Coates Claisen rearrangement: synthesis of functionalized β-lactones.
Topics: Catalysis; Heterocyclic Compounds; Lactones; Methane; Molecular Structure; Stereoisomerism | 2013 |
Monomeric bis(anilido)iron(II) Complexes with N-heterocyclic carbene ligation: synthesis, characterization, and redox reactivity toward aryl halides.
Topics: Anilides; Ferrous Compounds; Heterocyclic Compounds; Hydrocarbons, Halogenated; Ligands; Methane; Models, Molecular; Molecular Structure; Oxidation-Reduction | 2013 |
Direct α-functionalization of simple aldehydes via oxidative N-heterocyclic carbene catalysis.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Oxidation-Reduction | 2013 |
Metal center dependent coordination modes of a tricarbene ligand.
Topics: Coordination Complexes; Crystallography, X-Ray; Ligands; Methane; Models, Molecular; Molecular Structure; Palladium | 2013 |
Olefin cyclopropanation via carbene transfer catalyzed by engineered cytochrome P450 enzymes.
Topics: Alkenes; Bacillus megaterium; Catalysis; Cyclopropanes; Cytochrome P-450 Enzyme System; Methane; Models, Chemical; Protein Engineering; Stereoisomerism | 2013 |
Low-spin hexacoordinate Mn(III): synthesis and spectroscopic investigation of homoleptic tris(pyrazolyl)borate and tris(carbene)borate complexes.
Topics: Borates; Coordination Complexes; Crystallography, X-Ray; Manganese; Methane; Models, Molecular; Pyrazoles; Quantum Theory | 2013 |
Mechanism and origins of ligand-controlled selectivities in [Ni(NHC)]-catalyzed intramolecular (5 + 2) cycloadditions and homo-ene reactions: a theoretical study.
Topics: Alkynes; Catalysis; Cyclization; Cyclopropanes; Ethers; Heterocyclic Compounds; Ligands; Methane; Molecular Structure; Nickel; Organometallic Compounds; Quantum Theory | 2013 |
Conversion of a singlet silylene to a stable biradical.
Topics: Carbon; Crystallography, X-Ray; Free Radicals; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Quantum Theory; Silicon Compounds; Thermodynamics | 2013 |
Synthesis, structures, and antimalarial activities of some silver(I), gold(I) and gold(III) complexes involving N-heterocyclic carbene ligands.
Topics: Antimalarials; Candida; Crystallography, X-Ray; Dose-Response Relationship, Drug; Gold; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Parasitic Sensitivity Tests; Plasmodium falciparum; Silver; Structure-Activity Relationship | 2013 |
Kinetic resolution of tertiary alcohols: highly enantioselective access to 3-hydroxy-3-substituted oxindoles.
Topics: Alcohols; Catalysis; Esterification; Heterocyclic Compounds; Indoles; Kinetics; Methane; Oxindoles; Stereoisomerism | 2013 |
Versatile reactivity of rhodium-iminocarbenes derived from N-sulfonyl triazoles.
Topics: Alcohols; Catalysis; Click Chemistry; Methane; Rhodium; Triazoles | 2013 |
Synthesis of difluoromethyl ethers with difluoromethyltriflate.
Topics: Boronic Acids; Ethers; Fluorine; Methane; Oxidation-Reduction; Phenols | 2013 |
A simple metal-promoted three-step access to n/5/m angular carbocyclic systems.
Topics: Alkynes; Catalysis; Chromium; Cyclization; Gold; Malonates; Methane; Molecular Structure; Polycyclic Compounds; Stereoisomerism; Tin | 2013 |
Highly selective catalyst-dependent competitive 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates.
Topics: Azo Compounds; Catalysis; Cyclization; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Siloxanes | 2013 |
Chemistry. Re-engineering nature's catalysts.
Topics: Alkenes; Cyclopropanes; Cytochrome P-450 Enzyme System; Methane | 2013 |
Isolable, copper(I) dicarbonyl complexes supported by N-heterocyclic carbenes.
Topics: Copper; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds | 2013 |
The regio- and stereospecific intermolecular dehydrative alkoxylation of allylic alcohols catalyzed by a gold(I) N-heterocyclic carbene complex.
Topics: Allyl Compounds; Catalysis; Ethers; Gold; Methane; Molecular Structure; Propanols; Stereoisomerism | 2013 |
Heterocoupling of 2-naphthols enabled by a copper-N-heterocyclic carbene complex.
Topics: 2-Naphthylamine; Catalysis; Copper; Heterocyclic Compounds; Methane; Molecular Structure; Naphthols; Organometallic Compounds; Oxidation-Reduction | 2013 |
A different route to functional polyolefins: olefin-carbene copolymerisation.
Topics: Alkenes; Catalysis; Methane; Molecular Structure; Organometallic Compounds; Polymerization; Rhodium | 2013 |
31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the π-accepting properties of carbenes.
Topics: Heterocyclic Compounds; Magnetic Resonance Spectroscopy; Methane; Phosphines; Phosphorus | 2013 |
Gold(III) complexes containing N-heterocyclic carbene ligands: thiol "switch-on" fluorescent probes and anti-cancer agents.
Topics: Animals; Antineoplastic Agents; Fluorescent Dyes; Gold; HeLa Cells; Heterocyclic Compounds; Humans; Inhibitory Concentration 50; Ligands; Magnetic Resonance Spectroscopy; Methane; Mice; Organometallic Compounds; Tumor Burden | 2013 |
N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed Suzuki-Miyaura coupling of benzylic chlorides with arylboronic acids or potassium phenyltrifluoroborate in neat water.
Topics: Benzyl Compounds; Borates; Boronic Acids; Catalysis; Heterocyclic Compounds; Imidazoles; Methane; Molecular Structure; Organometallic Compounds; Palladium; Water | 2013 |
Continuous synthesis and use of N-heterocyclic carbene copper(I) complexes from insoluble Cu2O.
Topics: Catalysis; Chemistry, Organic; Copper; Crystallography, X-Ray; Imidazoles; Methane; Models, Molecular; Molecular Structure; Stereoisomerism | 2013 |
Copper-catalyzed C-O bond formation: an efficient one-pot highly regioselective synthesis of furans from (2-furyl)carbene complexes.
Topics: Alkynes; Catalysis; Copper; Cyclization; Furans; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2013 |
Phosphacycles as building blocks for main group cages.
Topics: Arsenic; Crystallography, X-Ray; Cycloaddition Reaction; Heterocyclic Compounds; Methane; Molecular Conformation; Phosphorus | 2013 |
Carbene-mediated functionalization of the anomeric C-H bond of carbohydrates: scope and limitations.
Topics: Carbohydrates; Chemistry, Organic; Disaccharides; Glycosides; Glycosylation; Hydrogen Bonding; Methane; Molecular Conformation; Rhodium | 2013 |
A new access to 4 H-quinolizines from 2-vinylpyridine and alkynes promoted by rhodium-N-heterocyclic-carbene catalysts.
Topics: Alkynes; Catalysis; Coordination Complexes; Methane; Pyridines; Quinolizines; Rhodium; Stereoisomerism | 2013 |
Synthesis and structure of carbene-stabilized N-centered cations [L2N]+, [L2NR]2+, [LNR3]2+ , and [L3N]3+.
Topics: Amines; Cations; Methane; Models, Molecular; Molecular Structure; Nitrogen | 2013 |
Peptide-tethered monodentate and chelating histidylidene metal complexes: synthesis and application in catalytic hydrosilylation.
Topics: Amino Acid Sequence; Catalysis; Chelating Agents; Coordination Complexes; Heterocyclic Compounds; Histidine; Iridium; Methane; Oligopeptides; Rhodium; Silicon | 2013 |
Organocatalytic C-H bond arylation of aldehydes to bis-heteroaryl ketones.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Onium Compounds; Salts | 2013 |
Insights into the strength and nature of carbene···halogen bond interactions: a theoretical perspective.
Topics: Computer Simulation; Halogens; Methane; Models, Chemical; Molecular Structure; Static Electricity; Thermodynamics | 2013 |
NHC-Cu-catalyzed protoboration of monosubstituted allenes. Ligand-controlled site selectivity, application to synthesis and mechanism.
Topics: Alkadienes; Catalysis; Copper; Heterocyclic Compounds; Ligands; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism | 2013 |
Improving carbene-copper-catalyzed asymmetric synthesis of α-aminoboronic esters using benzimidazole-based precursors.
Topics: Benzimidazoles; Boronic Acids; Catalysis; Copper; Esters; Heterocyclic Compounds; Methane; Molecular Structure | 2013 |
Assembly of spirooxindole derivatives containing four consecutive stereocenters by using cascade reactions catalyzed by an N-heterocyclic carbene.
Topics: Biological Products; Catalysis; Combinatorial Chemistry Techniques; Indoles; Methane; Molecular Structure; Oxindoles; Spiro Compounds; Stereoisomerism | 2013 |
Transannulation of 1-sulfonyl-1,2,3-triazoles with heterocumulenes.
Topics: Catalysis; Imidazoles; Isocyanates; Isothiocyanates; Methane; Polyenes; Rhodium; Sulfinic Acids; Thiazoles; Triazoles | 2013 |
Bicyclic pyrazolidinone derivatives from diastereoselective catalytic [3 + 3]-cycloaddition reactions of enoldiazoacetates with azomethine imines.
Topics: Azo Compounds; Bridged Bicyclo Compounds, Heterocyclic; Catalysis; Cyclization; Cycloaddition Reaction; Imines; Methane; Molecular Structure; Pyrazoles; Rhodium; Stereoisomerism; Thiosemicarbazones | 2013 |
Rhodium-catalyzed conversion of furans to highly functionalized pyrroles.
Topics: Catalysis; Furans; Imines; Methane; Pyrroles; Rhodium | 2013 |
Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene-carbene adducts.
Topics: Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Organophosphorus Compounds; Phosphines | 2013 |
Luminescent biscarbene iridium(III) complexes as living cell imaging reagents.
Topics: Cell Line, Tumor; Cell Survival; Contrast Media; Coordination Complexes; HeLa Cells; Heterocyclic Compounds; Humans; Iridium; Methane; Microscopy, Fluorescence; Temperature | 2013 |
Luminescent organoplatinum(II) complexes containing bis(N-heterocyclic carbene) ligands selectively target the endoplasmic reticulum and induce potent photo-toxicity.
Topics: Apoptosis; Cell Line, Tumor; Cell Survival; Coordination Complexes; Cytotoxins; Endoplasmic Reticulum; Endoplasmic Reticulum Stress; Humans; Ligands; Light; Luminescence; Methane; Organoplatinum Compounds | 2013 |
N-heterocyclic carbene catalyzed addition of aldehydes to diazo compounds: stereoselective synthesis of N-acylhydrazones.
Topics: Aldehydes; Azo Compounds; Catalysis; Hydrazones; Methane; Molecular Structure; Stereoisomerism | 2013 |
Easy access to silicon(0) and silicon(II) compounds.
Topics: Crystallography, X-Ray; Electrochemical Techniques; Halogenation; Methane; Models, Molecular; Silicon; Silicon Compounds; Spectrophotometry, Ultraviolet | 2013 |
Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine.
Topics: Alkynes; Amination; Catalysis; Crystallography, X-Ray; Gold; Heterocyclic Compounds; Hydrazines; Ligands; Methane; Models, Molecular; Molecular Structure; Organogold Compounds | 2013 |
Exploring nitrogen ligand diversity in trans-N-heterocyclic carbene-amine platinum complexes: synthesis, characterization, and application to fluorescence.
Topics: Amines; Coordination Complexes; Fluorescent Dyes; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Nitrogen; Platinum; Structure-Activity Relationship | 2013 |
Carbene generation by cytochromes and electronic structure of heme-iron-porphyrin-carbene complex: a quantum chemical study.
Topics: Cytochrome P-450 Enzyme System; Electrons; Heme; Hydroxylation; Methane; Models, Molecular; Porphyrins; Quantum Theory; Thermodynamics; Water | 2013 |
Isolation of a neutral P8 cluster by [2+2] cycloaddition of a diphosphene facilitated by carbene activation of white phosphorus.
Topics: Cyclization; Methane; Models, Molecular; Molecular Structure; Phosphines; Phosphorus | 2013 |
Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters.
Topics: Methane; Models, Molecular; Molecular Structure; Organophosphorus Compounds; Phosphorus | 2013 |
NHC-mediated enantioselective formal [4 + 2] cycloadditions of alkylarylketenes and β,γ-unsaturated α-ketocarboxylic esters and amides.
Topics: Amides; Carboxylic Acids; Crystallography, X-Ray; Cyclization; Esters; Ethylenes; Heterocyclic Compounds; Ketones; Methane; Models, Molecular; Molecular Structure; Stereoisomerism | 2013 |
Enzyme promiscuity: using a P450 enzyme as a carbene transfer catalyst.
Topics: Biocatalysis; Cycloparaffins; Cytochrome P-450 Enzyme System; Methane; Molecular Structure; Organometallic Compounds | 2013 |
An efficient approach to the securinega alkaloids empowered by cooperative N-heterocyclic carbene/Lewis acid catalysis.
Topics: Alkaloids; Catalysis; Euphorbiaceae; Heterocyclic Compounds; Lewis Acids; Methane; Molecular Structure | 2013 |
Pericyclic rearrangements of N-heterocyclic carbenes of indazole to substituted 9-aminoacridines.
Topics: Aminacrine; Cyclization; Indazoles; Methane; Molecular Structure; Palladium | 2013 |
Phosphorus(V) complexes with acyclic monoaminocarbene ligands via oxidative addition.
Topics: Amines; Crystallography, X-Ray; Fluorides; Ligands; Methane; Models, Molecular; Molecular Structure; Oxidation-Reduction; Phosphorus | 2013 |
Synthesis and structure of a carbene-stabilized boraallene coordinated to rhodium.
Topics: Alkadienes; Boron Compounds; Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Quantum Theory; Rhodium | 2013 |
Optimizing P,N-bidentate ligands for oxidative gold catalysis: efficient intermolecular trapping of α-oxo gold carbenes by carboxylic acids.
Topics: Carboxylic Acids; Catalysis; Gold; Ligands; Methane; Nitrogen; Oxidation-Reduction; Phosphorus; X-Ray Diffraction | 2013 |
Ruthenium catalysts for hydrogenation of aromatic and aliphatic esters: make use of bidentate carbene ligands.
Topics: Carboxylic Acids; Catalysis; Esters; Hydrogenation; Ligands; Methane; Ruthenium | 2013 |
Sterically tuned Ag(I)- and Pd(II)-N-heterocyclic carbene complexes of imidazol-2-ylidenes: synthesis, crystal structures, and in vitro antibacterial and anticancer studies.
Topics: Anti-Bacterial Agents; Antineoplastic Agents; Cell Survival; Escherichia coli; HCT116 Cells; Humans; Imidazoles; Methane; Molecular Structure; Staphylococcus aureus | 2013 |
Fluorescent silver(I) and gold(I)-N-heterocyclic carbene complexes with cytotoxic properties: mechanistic insights.
Topics: Animals; Cell Line, Tumor; Cell Survival; Cytosol; Dimerization; Drug Screening Assays, Antitumor; Glutathione Reductase; Gold; Humans; Liver; Methane; Microscopy, Fluorescence; Mitochondria; Neoplasms; Oxidation-Reduction; Peroxiredoxin III; Rats; Reactive Oxygen Species; Silver; Thioredoxin-Disulfide Reductase | 2013 |
Functionalized N-heterocyclic carbene nonspectator ligands upon internal alkyne activation reactions.
Topics: Alkynes; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Ruthenium | 2013 |
Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC).
Topics: Carbon Monoxide; Crystallography, X-Ray; Disulfides; Heterocyclic Compounds; Iron; Kinetics; Methane; Models, Molecular; Molecular Conformation; Nitrogen Oxides; Oxidation-Reduction; Quantum Theory; Sulfhydryl Compounds; Thermodynamics | 2013 |
Oligonorbornenes with hammock-like crown ether pendants as artificial transmembrane ion channel.
Topics: Catalysis; Crown Ethers; Ion Channels; Liposomes; Methane; Phosphatidylcholines | 2013 |
Straightforward synthesis of [Au(NHC)X] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes.
Topics: Bromides; Chlorides; Gold; Heterocyclic Compounds; Iodine; Methane; Molecular Structure; Organogold Compounds | 2013 |
A comparative study on dinuclear and multinuclear Ni(II), Pd(II), and Pt(II) complexes of a thiolato-functionalized, benzannulated N-heterocyclic carbene ligand.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Nickel; Organometallic Compounds; Palladium; Platinum; Sulfhydryl Compounds | 2013 |
Substituent effects on the electrochemical, spectroscopic, and structural properties of Fischer mono- and biscarbene complexes of chromium(0).
Topics: Chromium; Electrochemical Techniques; Methane; Molecular Structure; Organometallic Compounds; Quantum Theory | 2013 |
Simple and efficient synthesis of [MCI(NHC)] (M = Au, Ag) complexes.
Topics: Gold; Heterocyclic Compounds, 1-Ring; Imidazoles; Methane; Silver | 2013 |
Catalytic activation of carbohydrates as formaldehyde equivalents for Stetter reaction with enones.
Topics: Carbohydrates; Catalysis; Formaldehyde; Heterocyclic Compounds; Ketones; Methane; Molecular Structure | 2013 |
N-heterocyclic carbenes--catalysts for the preparation of polyhedral silsesquioxanes.
Topics: Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Organosilicon Compounds | 2013 |
Metathesis reactions of a manganese borylene complex with polar heteroatom-carbon double bonds: a pathway to previously inaccessible carbene complexes.
Topics: Boron Compounds; Carbon; Coordination Complexes; Crystallography, X-Ray; Cyclization; Imides; Ketones; Methane; Models, Molecular; Molecular Conformation; Organophosphorus Compounds; Sulfides | 2013 |
Ruthenium(II)/N-heterocyclic carbene catalyzed [3+2] carbocyclization with aromatic N-H ketimines and internal alkynes.
Topics: Alkynes; Amines; Carbon; Catalysis; Hydrogen; Hydrogen Bonding; Imines; Ligands; Metals; Methane; Nitriles; Nitrogen; Protons; Ruthenium; Temperature | 2013 |
Generation of rhodium(I) carbenes from ynamides and their reactions with alkynes and alkenes.
Topics: Alkenes; Alkynes; Amides; Methane; Molecular Structure; Organometallic Compounds; Rhodium | 2013 |
Amine-N-heterocyclic carbene cascade catalysis for the asymmetric synthesis of fused indane derivatives with multiple chiral centres.
Topics: Amines; Benzoin; Catalysis; Cycloaddition Reaction; Indans; Methane; Stereoisomerism | 2013 |
Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams.
Topics: Alkenes; Catalysis; Heterocyclic Compounds; Lactams; Methane; Molecular Structure; Nitro Compounds; Stereoisomerism | 2013 |
Ether-imidazolium carbenes for Suzuki-Miyaura cross-coupling of heteroaryl chlorides with aryl/heteroarylboron reagents.
Topics: Boron Compounds; Boronic Acids; Catalysis; Ethers; Hydrocarbons, Chlorinated; Imidazoles; Indicators and Reagents; Ligands; Methane; Molecular Structure | 2013 |
Mechanistic and preparative studies of radical chain homolytic substitution reactions of N-heterocyclic carbene boranes and disulfides.
Topics: Boranes; Disulfides; Free Radicals; Heterocyclic Compounds; Methane; Molecular Structure | 2013 |
Dispersion forces and counterintuitive steric effects in main group molecules: heavier group 14 (Si-Pb) dichalcogenolate carbene analogues with sub-90° interligand bond angles.
Topics: Chalcogens; Methane; Molecular Structure; Organometallic Compounds; Quantum Theory | 2013 |
[3,3]-Sigmatropic rearrangement versus carbene formation in gold-catalyzed transformations of alkynyl aryl sulfoxides: mechanistic studies and expanded reaction scope.
Topics: Catalysis; Cyclization; Gold; Methane; Molecular Structure; Quantum Theory; Sulfhydryl Compounds; Sulfoxides | 2013 |
Postsynthetic modification of dicarbene-derived metallacycles via photochemical [2 + 2] cycloaddition.
Topics: Cyclization; Gold; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Photochemical Processes; Silver | 2013 |
Room temperature and solvent-free iridium-catalyzed selective alkylation of anilines with alcohols.
Topics: Alcohols; Alkylation; Amines; Catalysis; Iridium; Methane; Phosphines; Rhodium; Temperature | 2013 |
NHC-capped cyclodextrins (ICyDs): insulated metal complexes, commutable multicoordination sphere, and cavity-dependent catalysis.
Topics: Catalysis; Coordination Complexes; Copper; Cyclodextrins; Ethers, Cyclic; Gold Compounds; Heterocyclic Compounds; Methane; Resorcinols; Stereoisomerism | 2013 |
Observation of a stable carbene at the active site of a thiamin enzyme.
Topics: Biocatalysis; Catalytic Domain; Methane; Models, Molecular; Molecular Structure; Pyruvate Oxidase; Thiamine | 2013 |
Stereoselective synthesis of a promising flower-inducing KODA analog, (9R,12S,13R,15Z)-9-hydroxy-12,13-methylene-10-oxooctadec-15-enoic acid.
Topics: Chromatography, High Pressure Liquid; Fatty Acids, Unsaturated; Flowers; Linoleic Acid; Methane; Stereoisomerism | 2013 |
NHC-mediated cross-coupling of sugar-derived cyclic nitrones with enals: general and efficient synthesis of polyhydroxylated pyrrolizidines and indolizidines.
Topics: Carbohydrates; Catalysis; Chemistry Techniques, Synthetic; Enzyme Inhibitors; Glycoside Hydrolases; Heterocyclic Compounds; Indolizidines; Ketones; Methane; Nitrogen Oxides; Pyrrolizidine Alkaloids | 2013 |
Adducts of nitrous oxide and N-heterocyclic carbenes: syntheses, structures, and reactivity.
Topics: Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Nitrous Oxide; Water | 2013 |
NHC-catalysed aerobic aldehyde-esterifications with alcohols: no additives or cocatalysts required.
Topics: Alcohols; Aldehydes; Catalysis; Esterification; Methane; Oxidation-Reduction; Oxygen | 2013 |
Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion.
Topics: Anions; Borohydrides; Crystallography, X-Ray; Gold; Methane; Molecular Conformation; Protons | 2013 |
Direct β-activation of saturated aldehydes to formal Michael acceptors through oxidative NHC catalysis.
Topics: Aldehydes; Catalysis; Esters; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism; Triazoles | 2013 |
Aerobic oxidation of NHC-catalysed aldehyde esterifications with alcohols: benzoin, not the Breslow intermediate, undergoes oxidation.
Topics: Aldehydes; Benzoin; Catalysis; Esterification; Methane; Oxidation-Reduction | 2013 |
Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enones.
Topics: Aluminum; Carbon; Catalysis; Copper; Heterocyclic Compounds; Methane; Organometallic Compounds; Stereoisomerism | 2013 |
A serine-substituted P450 catalyzes highly efficient carbene transfer to olefins in vivo.
Topics: Alkenes; Biocatalysis; Cytochrome P-450 Enzyme System; Escherichia coli; Methane; Mutation; Serine | 2013 |
Protein engineering: Chemistry gets the assist.
Topics: Alkenes; Cytochrome P-450 Enzyme System; Methane; Serine | 2013 |
N-heterocyclic carbene catalyzed [4+3] annulation of enals and o-quinone methides: highly enantioselective synthesis of benzo-ε-lactones.
Topics: Aldehydes; Benzoquinones; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Indolequinones; Lactones; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Stereoisomerism | 2013 |
Cobalt-catalyzed C-H bond functionalizations with aryl and alkyl chlorides.
Topics: Alkylation; Carbon; Catalysis; Chlorides; Cobalt; Heterocyclic Compounds; Hydrogen; Indoles; Methane | 2013 |
Highly Z-selective and enantioselective ring-opening/cross-metathesis catalyzed by a resolved stereogenic-at-Ru complex.
Topics: Catalysis; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Ruthenium; Stereoisomerism | 2013 |
A dual Lewis base activation strategy for enantioselective carbene-catalyzed annulations.
Topics: Aldehydes; Benzene Derivatives; Catalysis; Indolequinones; Lewis Bases; Methane | 2013 |
Direct synthesis of cis-dihalido-bis(NHC) complex of nickel(II) and catalytic application in olefin addition polymerization: effect of halogen co-ligands and density functional theory study.
Topics: Alkenes; Catalysis; Crystallography, X-Ray; Halogens; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Nickel; Organometallic Compounds; Polymerization; Quantum Theory | 2013 |
NHC organocatalytic formal LUMO activation of α,β-unsaturated esters for reaction with enamides.
Topics: Amides; Catalysis; Esters; Heterocyclic Compounds; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Oxidation-Reduction; Quantum Theory; Stereoisomerism | 2013 |
Cu-catalyzed formal methylative and hydrogenative carboxylation of alkynes with carbon dioxide: efficient synthesis of α,β-unsaturated carboxylic acids.
Topics: Alkynes; Carbon Dioxide; Carboxylic Acids; Catalysis; Coordination Complexes; Copper; Heterocyclic Compounds; Hydrogenation; Methane; Methylation; Nickel; Scandium; Stereoisomerism; Zirconium | 2013 |
Ruthenium carbenes supported on mesoporous silicas as highly active and selective hybrid catalysts for olefin metathesis reactions under continuous flow.
Topics: Alkenes; Catalysis; Methane; Ruthenium | 2013 |
Convenient syntheses of cyanuric chloride-derived NHC ligands, their Ag(I) and Au(I) complexes and antimicrobial activity.
Topics: Anti-Infective Agents; Bacteria; Candida albicans; Coordination Complexes; Gold; Heterocyclic Compounds; Imidazoles; Ligands; Methane; Silver; Triazines | 2013 |
Cationic gold(I) heteroleptic complexes bearing a pyrazole-derived N-heterocyclic carbene: syntheses, characterizations, and cytotoxic activities.
Topics: Benzimidazoles; Cell Line, Tumor; Cell Survival; Coordination Complexes; Gold; Heterocyclic Compounds; Humans; Ligands; Methane; Molecular Conformation; Pyrazoles | 2013 |
Cobalt-catalyzed intramolecular olefin hydroarylation leading to dihydropyrroloindoles and tetrahydropyridoindoles.
Topics: Catalysis; Cobalt; Cyclization; Cycloparaffins; Heterocyclic Compounds; Indoles; Methane; Molecular Structure; Pyrroles | 2013 |
Ligand effects of NHC-iridium catalysts for signal amplification by reversible exchange (SABRE).
Topics: Catalysis; Coordination Complexes; Hydrogen; Iridium; Ligands; Methane; Pyridines | 2013 |
Enhanced rate and selectivity by carboxylate salt as a basic cocatalyst in chiral N-heterocyclic carbene-catalyzed asymmetric acylation of secondary alcohols.
Topics: Acylation; Alcohols; Amines; Carboxylic Acids; Catalysis; Methane; Salts; Stereoisomerism | 2013 |
Combining NHC-Cu and Brønsted base catalysis: enantioselective allylic substitution/conjugate additions with alkynylaluminum reagents and stereospecific isomerization of the products to trisubstituted allenes.
Topics: Alkadienes; Alkynes; Allyl Compounds; Aluminum Compounds; Catalysis; Copper; Methane; Stereoisomerism | 2013 |
N-heterocyclic carbene catalyzed annulation of benzofuran-2,3-diones and enals: a concise synthesis of spiro-bis-lactone.
Topics: Aldehydes; Benzofurans; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Lactones; Methane; Models, Molecular; Molecular Structure; Spiro Compounds | 2013 |
Catalytic MBH reaction of β-substituted nitroalkenes with azodicarboxylates.
Topics: Alkenes; Azo Compounds; Catalysis; Dicarboxylic Acids; Heterocyclic Compounds; Methane; Molecular Structure; Nitro Compounds | 2013 |
Catalytic asymmetric syntheses of quinolizidines by dirhodium-catalyzed dearomatization of isoquinolinium/pyridinium methylides--the role of catalyst and carbene source.
Topics: Catalysis; Methane; Models, Molecular; Molecular Conformation; Pyridines; Quinolizidines; Rhodium; Stereoisomerism | 2013 |
Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Asymmetric Intramolecular α-Arylation of Amides: Reaction Development and Mechanistic Studies.
Topics: Alkenes; Amides; Catalysis; Indoles; Ligands; Methane; Molecular Structure; Oxindoles; Palladium; Stereoisomerism | 2013 |
Carbene transfer from triazolylidene gold complexes as a potent strategy for inducing high catalytic activity.
Topics: Catalysis; Crystallography, X-Ray; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Triazoles | 2013 |
Ruthenium-catalyzed redox-neutral and single-step amide synthesis from alcohol and nitrile with complete atom economy.
Topics: Alcohols; Amides; Methane; Nitriles; Oxidation-Reduction; Ruthenium | 2013 |
Accessible gold clusters using calix[4]arene N-heterocyclic carbene and phosphine ligands.
Topics: Calixarenes; Gold; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Phenols; Phosphines | 2013 |
Palladium-catalyzed carbenoid based N-H bond insertions: application to the synthesis of chiral α-amino esters.
Topics: Amines; Catalysis; Crystallography, X-Ray; Esters; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Palladium; Stereoisomerism | 2013 |
Oxygenation of ruthenium carbene complexes containing naphthothiophene or naphthofuran: spectroscopic and DFT studies.
Topics: Aldehydes; Coordination Complexes; Crystallography, X-Ray; Cyclization; Furans; Methane; Molecular Conformation; Oxygen; Quantum Theory; Ruthenium; Spectrophotometry, Ultraviolet; Thiophenes | 2013 |
Addition of lithium carbenoids to isocyanates: a direct access to synthetically useful N-substituted 2-haloacetamides.
Topics: Acetamides; Halogens; Isocyanates; Lithium; Methane | 2013 |
Laser-induced carbene-carbene rearrangement in solution: the diphenylcarbene-fluorene rearrangement.
Topics: Fluorenes; Lasers; Methane; Molecular Structure; Solutions | 2013 |
Experimental mechanistic studies of the tail-to-tail dimerization of methyl methacrylate catalyzed by N-heterocyclic carbene.
Topics: Catalysis; Dimerization; Heterocyclic Compounds; Methane; Methylmethacrylate; Molecular Structure | 2013 |
Correlation between functionality preference of Ru carbenes and exo/endo product selectivity for clarifying the mechanism of ring-closing enyne metathesis.
Topics: Alkenes; Alkynes; Catalysis; Cyclization; Fluorescence; Ligands; Methane; Molecular Structure; Organometallic Compounds; Ruthenium; Time Factors | 2013 |
Cu-NHC-TEMPO catalyzed aerobic oxidation of primary alcohols to aldehydes.
Topics: Alcohols; Aldehydes; Catalysis; Copper; Cyclic N-Oxides; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Oxidation-Reduction | 2013 |
Metal free catalytic hydroboration of multiple bonds in methanol using N-heterocyclic carbenes under open atmosphere.
Topics: Atmosphere; Boron; Catalysis; Heterocyclic Compounds; Methane; Methanol; Stereoisomerism; Transition Elements | 2013 |
Stereospecific asymmetric N-heterocyclic carbene (NHC)-catalyzed redox synthesis of trifluoromethyl dihydropyranones and mechanistic insights.
Topics: Catalysis; Heterocyclic Compounds; Hydrocarbons, Fluorinated; Methane; Molecular Structure; Oxidation-Reduction; Pyrones; Stereoisomerism | 2013 |
N-heterocyclic carbene-catalyzed highly enantioselective synthesis of substituted dihydropyranopyrazolones.
Topics: Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Molecular Structure; Pyrans; Pyrazolones; Stereoisomerism | 2013 |
A well-defined Pd hybrid material for the Z-selective semihydrogenation of alkynes characterized at the molecular level by DNP SENS.
Topics: Alkenes; Alkynes; Hydrogenation; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation; Palladium; Silicon Dioxide | 2013 |
N-heterocyclic carbene catalyzed regioselective oxo-acyloxylation of alkenes with aromatic aldehydes: a high yield synthesis of α-acyloxy ketones and esters.
Topics: Aldehydes; Alkenes; Catalysis; Esters; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Oxygen; Stereoisomerism | 2013 |
Synthesis of sterically-crowded olefins, gem-dihaloalkenes, butatrienes, and thioketenes through the reaction of substituted bornane-2-thiones or bornane-2-selones with conventional carbenes or metal carbenoids.
Topics: Alkenes; Camphanes; Methane | 2013 |
Facile synthesis of dibranched conjugated dienes via palladium-catalyzed oxidative coupling of N-tosylhydrazones.
Topics: Alkenes; Butadienes; Catalysis; Cycloaddition Reaction; Hydrazones; Methane; Oxidative Coupling; Palladium; Stereoisomerism | 2013 |
Preparation of pyrazine carboxamides: a reaction involving N-heterocyclic carbene (NHC) intermediates.
Topics: Amides; Amines; Aniline Compounds; Combinatorial Chemistry Techniques; Methane; Molecular Structure; Pyrazines | 2013 |
N-heterocyclic carbene-catalyzed stereoselective cascade reaction: synthesis of functionalized tetrahydroquinolines.
Topics: Amines; Catalysis; Methane; Molecular Structure; Quinolines; Stereoisomerism | 2013 |
Carbene radicals in cobalt(II)-porphyrin-catalysed carbene carbonylation reactions; a catalytic approach to ketenes.
Topics: Amines; Azo Compounds; beta-Lactams; Catalysis; Cobalt; Esters; Ethylenes; Imines; Ketones; Metalloporphyrins; Methane; Molecular Structure; Porphyrins | 2013 |
Functionalization of benzylic C(sp(3))-H bonds of heteroaryl aldehydes through N-heterocyclic carbene organocatalysis.
Topics: Aldehydes; Benzyl Compounds; Catalysis; Indoles; Methane; Molecular Structure; Spiro Compounds | 2013 |
Characterization of the key intermediates of carbene-catalyzed umpolung by NMR spectroscopy and X-ray diffraction: breslow intermediates, homoenolates, and azolium enolates.
Topics: Alcohols; Catalysis; Crystallography, X-Ray; Imidazoles; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Stereoisomerism; Vinyl Compounds | 2013 |
Carbene catalysis: An internal affair.
Topics: Carboxylic Acids; Esters; Heterocyclic Compounds; Imines; Methane | 2013 |
β-Carbon activation of saturated carboxylic esters through N-heterocyclic carbene organocatalysis.
Topics: Carboxylic Acids; Catalysis; Esters; Heterocyclic Compounds; Methane; Molecular Structure | 2013 |
Synthesis of hypervalent iodonium alkynyl triflates for the application of generating cyanocarbenes.
Topics: Alkynes; Azides; Hydrocarbons, Iodinated; Mesylates; Methane; Nitriles; Onium Compounds | 2013 |
Regioselective allene hydrosilylation catalyzed by N-heterocyclic carbene complexes of nickel and palladium.
Topics: Alkadienes; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Nickel; Organometallic Compounds; Palladium; Silanes; Stereoisomerism | 2013 |
Efficient near-UV emitters based on cationic bis-pincer iridium(III) carbene complexes.
Topics: Cations; Coordination Complexes; Crystallography, X-Ray; Iridium; Methane; Ultraviolet Rays | 2013 |
Intramolecular transannulation of alkynyl triazoles via alkyne-carbene metathesis step: access to fused pyrroles.
Topics: Alkynes; Cyclization; Methane; Molecular Structure; Organometallic Compounds; Pyrroles; Rhodium; Triazoles | 2013 |
Metal/N-heterocyclic carbene complexes: opportunities for the development of anticancer metallodrugs.
Topics: Animals; Antineoplastic Agents; Apoptosis; Cell Line, Tumor; Coordination Complexes; Female; HeLa Cells; Heterocyclic Compounds; Humans; Liver Neoplasms; Lung Neoplasms; Metals; Methane; Mice; Mice, Nude; Mitochondria; Ovarian Neoplasms; Transplantation, Heterologous | 2013 |
Enantioselective sulfonation of enones with sulfonyl imines by cooperative N-heterocyclic-carbene/thiourea/tertiary-amine multicatalysis.
Topics: Amines; Catalysis; Heterocyclic Compounds; Imines; Ketones; Methane; Stereoisomerism; Sulfones; Thiourea | 2013 |
Synthesis and in vitro antitumor activity of water soluble sulfonate- and ester-functionalized silver(I) N-heterocyclic carbene complexes.
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Heterocyclic Compounds, 1-Ring; Humans; MAP Kinase Kinase Kinase 5; Methane; Neoplasm Proteins; Neoplasms; Oxidation-Reduction; Selenoproteins; Signal Transduction; Silver; Solubility; Thioredoxin-Disulfide Reductase; Water | 2013 |
Highly enantioselective dearomatizing formal [3+3] cycloaddition reactions of N-acyliminopyridinium ylides with electrophilic enol carbene intermediates.
Topics: Acylation; Catalysis; Cycloaddition Reaction; Diazonium Compounds; Imines; Methane; Pyridazines; Pyridinium Compounds; Stereoisomerism | 2013 |
Toward organometallic (99m)Tc imaging agents: synthesis of water-stable (99)Tc-NHC complexes.
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Technetium; Water | 2013 |
Vicinal bisheterocyclizations of alkynes via nucleophilic interception of a catalytic platinum carbene.
Topics: Alkynes; Catalysis; Cyclization; Ethers; Heterocyclic Compounds; Methane; Molecular Structure; Platinum | 2013 |
[3-(Trifluoromethyl)-3H-diazirin-3-yl]coumarin as a carbene-generating photocross-linker with masked fluorogenic beacon.
Topics: Benzoquinones; Coumarins; Cross-Linking Reagents; Diazomethane; Fluorescent Dyes; HSP90 Heat-Shock Proteins; Lactams, Macrocyclic; Methane; Photolysis | 2013 |
Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2.
Topics: Carbon Dioxide; Carbon Sequestration; Heterocyclic Compounds; Methane | 2013 |
Ruthenium(II) and osmium(II) 1,2,3-triazolylidene organometallics: a preliminary investigation into the biological activity of 'click' carbene complexes.
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Survival; Click Chemistry; Coordination Complexes; Crystallography, X-Ray; HEK293 Cells; Humans; Methane; Molecular Conformation; Osmium; Ruthenium; Triazoles | 2014 |
Photoresponsive gels prepared by ring-opening metathesis polymerization.
Topics: Catalysis; Gels; Methane; Nitrobenzenes; Photolysis; Polymerization; Polymers; Ruthenium; Ultraviolet Rays | 2013 |
Asymmetric NHC-catalyzed redox α-amination of α-aroyloxyaldehydes.
Topics: Aldehydes; Amination; Catalysis; Combinatorial Chemistry Techniques; Heterocyclic Compounds; Hydrazines; Iodides; Methane; Molecular Structure; Oxidation-Reduction; Samarium; Stereoisomerism | 2013 |
Iridium(III) hydrido N-heterocyclic carbene-phosphine complexes as catalysts in magnetization transfer reactions.
Topics: Catalysis; Coordination Complexes; Iridium; Magnetic Phenomena; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Phosphines | 2013 |
Development of catalysts and ligands for enantioselective gold catalysis.
Topics: Alkadienes; Carbon; Catalysis; Gold; Ligands; Methane; Molecular Structure; Organic Chemistry Phenomena; Organogold Compounds; Organophosphorus Compounds; Phosphines; Stereoisomerism | 2014 |
A chemical-biological evaluation of rhodium(I) N-heterocyclic carbene complexes as prospective anticancer drugs.
Topics: Antineoplastic Agents; Humans; Methane; Rhodium | 2013 |
Enantioselective N-heterocyclic carbene catalyzed annulation reactions with imidazolidinones.
Topics: Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2013 |
Silica-immobilized chiral dirhodium(II) catalyst for enantioselective carbenoid reactions.
Topics: Catalysis; Methane; Molecular Conformation; Organometallic Compounds; Proline; Rhodium; Silicon Dioxide; Stereoisomerism | 2013 |
Diaminocyclopropenylidene organocatalysts: beyond N-heterocyclic carbenes.
Topics: Aldehydes; Catalysis; Cyclopropanes; Heterocyclic Compounds; Ketones; Methane; Nitrogen; Stereoisomerism | 2014 |
N-heterocyclic carbenes as effective ligands for the preparation of stabilized copper- and silver-t-butylthiolate clusters.
Topics: Copper; Drug Stability; Heterocyclic Compounds; Ligands; Methane; Organometallic Compounds; Silver; Sulfhydryl Compounds | 2014 |
New insights into small molecule activation by acyclic silylenes: a computational investigation.
Topics: Acids, Acyclic; Azides; Computer Simulation; Methane; Models, Molecular; Silanes; Transition Elements | 2014 |
N-Heterocyclic carbene catalyzed reaction of cinnamils leading to the formation of 2,3,8-triaryl vinyl fulvenes: an uncommon transformation.
Topics: Alkadienes; Catalysis; Cyclopentanes; Heterocyclic Compounds; Hexanones; Methane; Molecular Structure | 2013 |
Stereoselective 1,3-insertions of rhodium(II) azavinyl carbenes.
Topics: Amides; Aza Compounds; Carboxylic Acids; Catalysis; Crystallography, X-Ray; Methane; Molecular Structure; Rhodium; Stereoisomerism; Vinyl Compounds | 2014 |
Asymmetric homoenolate additions to acyl phosphonates through rational design of a tailored N-heterocyclic carbene catalyst.
Topics: Acylation; Alcohols; Alkenes; Catalysis; Computer Simulation; Heterocyclic Compounds; Hydroxylation; Methane; Models, Chemical; Organophosphonates | 2014 |
Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes.
Topics: Cyclization; Free Radicals; Methane; Models, Molecular | 2013 |
Modular synthesis of triarylmethanes through palladium-catalyzed sequential arylation of methyl phenyl sulfone.
Topics: Antineoplastic Agents; Boronic Acids; Carbon; Catalysis; Dimethyl Sulfoxide; Hydrogen; Methane; Palladium; Sulfones | 2014 |
Alkyne-azide cycloaddition catalyzed by silver chloride and "abnormal" silver N-heterocyclic carbene complex.
Topics: Alkynes; Azides; Catalysis; Cycloaddition Reaction; Methane; Silver Compounds; Triazoles | 2013 |
CH-π and CF-π interactions lead to structural changes of N-heterocyclic carbene palladium complexes.
Topics: Carbon; Coordination Complexes; Crystallography, X-Ray; Fluorine; Heterocyclic Compounds; Hydrogen; Hydrogen Bonding; Methane; Molecular Conformation; Palladium; Quantum Theory; Stereoisomerism | 2014 |
Metalloradical approach to 2H-chromenes.
Topics: Benzopyrans; Catalysis; Cobalt; Free Radicals; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Stereoisomerism; Substrate Specificity | 2014 |
Concomitant nitrene and carbene insertion accompanying ring expansion: spectroscopic, X-ray, and computational studies.
Topics: Crystallography, X-Ray; Imines; Magnetic Resonance Spectroscopy; Methane; Quantum Theory | 2014 |
An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenes.
Topics: Aldehydes; Carboxylic Acids; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Oxidation-Reduction | 2014 |
N-heterocyclic carbene-catalyzed [3+4] cycloaddition and kinetic resolution of azomethine imines.
Topics: Azo Compounds; Catalysis; Cyclization; Heterocyclic Compounds; Imines; Kinetics; Methane; Molecular Structure; Thiosemicarbazones | 2014 |
Pd-carbene migratory insertion: application to the synthesis of trifluoromethylated alkenes and dienes.
Topics: Alkenes; Butadienes; Halogenation; Methane; Methylation; Palladium | 2014 |
A non-diazo approach to α-oxo gold carbenes via gold-catalyzed alkyne oxidation.
Topics: Alkynes; Catalysis; Gold; Methane; Organogold Compounds; Oxidation-Reduction | 2014 |
Reactivity of gold nanoparticles towards N-heterocyclic carbenes.
Topics: Gold; Heterocyclic Compounds; Ligands; Metal Nanoparticles; Methane; Microscopy, Electron, Transmission | 2014 |
Intramolecular dearomatizing [3 + 2] annulation of α-imino carbenoids with aryl rings furnishing 3,4-fused indole skeletons.
Topics: Catalysis; Cyclization; Indoles; Methane; Molecular Structure; Rhodium | 2014 |
Pd-N-heterocyclic carbene catalyzed synthesis of piperidine alkene-alkaloids and their anti-cancer evaluation.
Topics: Alkaloids; Alkenes; Antineoplastic Agents; Catalysis; Cell Line, Tumor; Cell Proliferation; Cell Survival; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Humans; MCF-7 Cells; Methane; Molecular Conformation; Organometallic Compounds; Palladium; Piperidines; Structure-Activity Relationship | 2014 |
A broadly applicable NHC-Cu-catalyzed approach for efficient, site-, and enantioselective coupling of readily accessible (pinacolato)alkenylboron compounds to allylic phosphates and applications to natural product synthesis.
Topics: Alkenes; Biological Products; Boron Compounds; Catalysis; Copper; Heterocyclic Compounds; Methane; Molecular Structure; Phosphates; Stereoisomerism | 2014 |
Role of quantum mechanical tunneling on the γ-effect of silicon on carbenes in 3-trimethylsilylcyclobutylidene.
Topics: Cyclobutanes; Deuterium; Kinetics; Methane; Organosilicon Compounds; Quantum Theory; Silicon; Temperature | 2014 |
Synthesis of proline-based N-heterocyclic carbene ligands.
Topics: Catalysis; Imidazoles; Ligands; Methane; Molecular Structure; Proline; Rhodium; Stereoisomerism | 2014 |
Caffeine-based gold(I) N-heterocyclic carbenes as possible anticancer agents: synthesis and biological properties.
Topics: Animals; Antineoplastic Agents; Caffeine; Cell Line; Cell Line, Tumor; Cell Proliferation; Gold; Heterocyclic Compounds; Humans; Inhibitory Concentration 50; Ligands; Methane; Molecular Structure; Xanthine | 2014 |
Preparation of triazoloindoles via tandem copper catalysis and their utility as α-imino rhodium carbene precursors.
Topics: Catalysis; Copper; Indoles; Methane; Molecular Structure; Rhodium; Stereoisomerism; Sulfones; Triazoles | 2014 |
NHC-catalyzed oxidative γ-addition of α,β-unsaturated aldehydes to isatins: a high-efficiency synthesis of spirocyclic oxindole-dihydropyranones.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Indoles; Isatin; Methane; Molecular Structure; Oxidation-Reduction; Oxindoles; Pyrones; Spiro Compounds | 2014 |
Chemistry and biology of two novel gold(I) carbene complexes as prospective anticancer agents.
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Coordination Complexes; Female; Gold; Humans; Methane; Molecular Structure; Ovarian Neoplasms | 2014 |
Asymmetric hydrogenation of disubstituted furans.
Topics: Catalysis; Furans; Heterocyclic Compounds; Hydrogenation; Methane; Pressure; Ruthenium; Solvents; Stereoisomerism; Temperature | 2014 |
NHC-Cu-catalyzed addition of propargylboron reagents to phosphinoylimines. Enantioselective synthesis of trimethylsilyl-substituted homoallenylamides and application to the synthesis of S-(-)-cyclooroidin.
Topics: Alkenes; Amides; Boron Compounds; Chemistry Techniques, Synthetic; Copper; Heterocyclic Compounds; Imines; Indicators and Reagents; Methane; Pyrroles; Stereoisomerism; Substrate Specificity | 2014 |
A perspective on physical organic chemistry.
Topics: Chemistry, Physical; Methane; Molecular Structure; Organic Chemistry Phenomena | 2014 |
N-Heterocyclic carbene-catalyzed formal cross-coupling reaction of α-haloenals with thiols: organocatalytic construction of sp2 carbon-sulfur bonds.
Topics: Carbon; Catalysis; Heterocyclic Compounds; Methane; Sulfhydryl Compounds; Sulfur | 2014 |
NHC-catalyzed oxidative cyclization reaction for the synthesis of 3-substituted phthalides.
Topics: Benzofurans; Catalysis; Cyclization; Heterocyclic Compounds; Methane; Oxidation-Reduction | 2014 |
Asymmetric catalysis with N-heterocyclic carbenes as non-covalent chiral templates.
Topics: Catalysis; Chromatography, High Pressure Liquid; Heterocyclic Compounds; Hydrogen Bonding; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Molecular Structure; Organic Chemicals; Propanols; Protons; Stereoisomerism | 2014 |
A two-step reaction scheme leading to singlet carbene species that can be detected under matrix conditions for the reaction of Zr(3F) with either CH3F or CH3CN.
Topics: Acetonitriles; Free Radicals; Halogenation; Hydrocarbons, Fluorinated; Methane; Thermodynamics; Zirconium | 2014 |
Expanding the horizon of intermolecular trapping of in situ generated α-oxo gold carbenes: efficient oxidative union of allylic sulfides and terminal alkynes via C-C bond formation.
Topics: Alkynes; Allyl Compounds; Gold; Ketones; Methane; Oxidation-Reduction; Sulfides | 2014 |
Gold (I) N-heterocyclic carbene complex inhibits mouse melanoma growth by p53 upregulation.
Topics: Animals; Antineoplastic Agents; Apoptosis; Blotting, Western; Cell Line, Tumor; Disease Models, Animal; Enzyme-Linked Immunosorbent Assay; Flow Cytometry; Gold Compounds; HCT116 Cells; Hep G2 Cells; Heterocyclic Compounds; Humans; Immunohistochemistry; Melanoma; Methane; Mice; Tumor Suppressor Protein p53; Up-Regulation | 2014 |
DFT study on the mechanisms and stereoselectivities of the [4 + 2] cycloadditions of enals and chalcones catalyzed by N-heterocyclic carbene.
Topics: Aldehydes; Catalysis; Chalcones; Cycloaddition Reaction; Heterocyclic Compounds; Methane; Molecular Structure; Quantum Theory; Stereoisomerism | 2014 |
Hydrogen bonding interaction between active methylene hydrogen atoms and an anion as a binding motif for anion recognition: experimental studies and theoretical rationalization.
Topics: Anions; Hydrogen; Hydrogen Bonding; Methane; Quantum Theory | 2014 |
Gold(I) biscarbene complexes derived from vascular-disrupting combretastatin A-4 address different targets and show antimetastatic potential.
Topics: Actin Cytoskeleton; Animals; Antineoplastic Agents; Bibenzyls; Cell Line, Tumor; Cell Proliferation; Coordination Complexes; Drug Resistance, Neoplasm; G2 Phase Cell Cycle Checkpoints; Gold; HT29 Cells; Human Umbilical Vein Endothelial Cells; Humans; MCF-7 Cells; Melanoma; Methane; Mice; Mice, Inbred BALB C; Neovascularization, Physiologic; Tubulin | 2014 |
The [3 + 3]-cycloaddition alternative for heterocycle syntheses: catalytically generated metalloenolcarbenes as dipolar adducts.
Topics: Catalysis; Cycloaddition Reaction; Heterocyclic Compounds; Metals; Methane; Transition Elements | 2014 |
Zwitterionic borane adducts of N-heterocyclic carbenes from mesomeric betaines of uracil.
Topics: Anions; Betaine; Boranes; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Uracil | 2014 |
Antibacterial properties of water-soluble gold(I) N-heterocyclic carbene complexes.
Topics: Anti-Bacterial Agents; Coordination Complexes; Enterococcus faecalis; Escherichia coli; Gold; Heterocyclic Compounds; Methane; Microbial Sensitivity Tests; Micrococcus luteus; Pseudomonas aeruginosa; Solubility; Staphylococcus aureus; Yersinia ruckeri | 2014 |
Parallel and combinatorial liquid-phase synthesis of alkylbiphenyls using pentaerythritol support.
Topics: Biphenyl Compounds; Catalysis; Combinatorial Chemistry Techniques; Methane; Nickel; Propylene Glycols | 2014 |
From acetone metalation to the catalytic α-arylation of acyclic ketones with NHC-nickel(II) complexes.
Topics: Acetone; Catalysis; Coordination Complexes; Heterocyclic Compounds; Hydrocarbons, Aromatic; Ketones; Methane; Models, Molecular; Nickel | 2014 |
Gold-catalyzed cascade reactions for synthesis of carbo- and heterocycles: selectivity and diversity.
Topics: Carbon; Catalysis; Crystallography, X-Ray; Cyclization; Cycloaddition Reaction; Gold; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Stereoisomerism | 2014 |
Cytotoxic gold(I) N-heterocyclic carbene complexes with phosphane ligands as potent enzyme inhibitors.
Topics: Cell Proliferation; Cell Survival; Coordination Complexes; Enzyme Inhibitors; Gold; Heterocyclic Compounds; HT29 Cells; Humans; Ligands; MCF-7 Cells; Methane; Phosphines; Poly (ADP-Ribose) Polymerase-1; Poly(ADP-ribose) Polymerase Inhibitors; Poly(ADP-ribose) Polymerases; Quantum Theory | 2014 |
Expanded-ring N-heterocyclic carbenes efficiently stabilize gold(I) cations, leading to high activity in π-acid-catalyzed cyclizations.
Topics: Acids; Alkynes; Benzofurans; Catalysis; Cations; Cyclization; Gold; Heterocyclic Compounds; Indoles; Methane | 2014 |
Group 4 metal complexes with new chiral pincer NHC-ligands: synthesis, structure and catalytic activity.
Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Hafnium; Heterocyclic Compounds; Ligands; Methane; Molecular Structure; Titanium; Zirconium | 2014 |
N-Heterocyclic carbene (NHC)-modulated Pd/Cu cocatalyzed three-component synthesis of 2,6-diarylquinolines.
Topics: Catalysis; Copper; Diarylquinolines; Heterocyclic Compounds; Methane; Molecular Conformation; Palladium; Spectrometry, Fluorescence | 2014 |
Synthesis of functionalized coumarins and quinolinones by NHC-catalyzed annulation of modified enals with heterocyclic C-H acids.
Topics: Acids; Catalysis; Coumarins; Heterocyclic Compounds; Methane; Molecular Structure; Quinolones | 2014 |
Cooperative N-heterocyclic carbene (NHC)-Lewis acid-mediated regioselective umpolung formal [3 + 2] annulations of alkynyl aldehydes with isatins.
Topics: Acids, Heterocyclic; Aldehydes; Alkynes; Catalysis; Chemistry, Organic; Crystallography, X-Ray; Isatin; Lewis Acids; Methane; Stereoisomerism | 2014 |
A binuclear gold(I) complex with mixed bridging diphosphine and bis(N-heterocyclic carbene) ligands shows favorable thiol reactivity and inhibits tumor growth and angiogenesis in vivo.
Topics: Animals; Cell Line, Tumor; Cell Proliferation; Gold; HeLa Cells; Humans; Ligands; Methane; Mice; Neovascularization, Pathologic; Rabbits; Sulfhydryl Compounds; Thioredoxin-Disulfide Reductase | 2014 |
The divergent synthesis of nitrogen heterocycles by rhodium(II)-catalyzed cycloadditions of 1-sulfonyl 1,2,3-triazoles with 1,3-dienes.
Topics: Alkadienes; Azepines; Catalysis; Cycloaddition Reaction; Heterocyclic Compounds; Methane; Nitrogen; Rhodium; Triazoles | 2014 |
High-throughput screening of metal-N-heterocyclic carbene complexes against biofilm formation by pathogenic bacteria.
Topics: Anti-Bacterial Agents; Biofilms; Coordination Complexes; Copper; Gold; Gram-Negative Bacteria; Gram-Positive Bacteria; Heterocyclic Compounds; Methane; Microbial Sensitivity Tests; Silver | 2014 |
Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes.
Topics: Alkylation; Amines; Coordination Complexes; Copper; Cyclization; Electron Spin Resonance Spectroscopy; Methane; Models, Molecular; Oxidation-Reduction | 2014 |
Intermolecular hydroamination of 1,3-dienes catalyzed by bis(phosphine)carbodicarbene-rhodium complexes.
Topics: Allyl Compounds; Amination; Amines; Catalysis; Coordination Complexes; Methane; Models, Molecular; Phosphines; Polyenes; Rhodium | 2014 |
Ultra stable self-assembled monolayers of N-heterocyclic carbenes on gold.
Topics: Gold; Heterocyclic Compounds; Methane; Molecular Structure; Particle Size; Surface Properties | 2014 |
Intermolecular and regioselective access to polysubstituted benzo- and dihydrobenzo[c]azepine derivatives: modulating the reactivity of group 6 non-heteroatom-stabilized alkynyl carbene complexes.
Topics: Benzazepines; Coordination Complexes; Cycloaddition Reaction; Methane; Molecular Conformation; Stereoisomerism; Tungsten | 2014 |
Room-temperature hydrohydrazination of terminal alkynes catalyzed by saturated abnormal N-heterocyclic carbene-gold(I) complexes.
Topics: Alkynes; Catalysis; Crystallography, X-Ray; Gold; Heterocyclic Compounds; Hydrazones; Isomerism; Ligands; Methane; Molecular Conformation; Nitrogen; Organogold Compounds | 2014 |
Detailed analysis of pro-apoptotic signaling and metabolic adaptation triggered by a N-heterocyclic carbene-gold(I) complex.
Topics: Animals; Apoptosis; Cell Line, Tumor; Cell Proliferation; Enzyme-Linked Immunosorbent Assay; Gold; Heterocyclic Compounds; Humans; Intracellular Space; Methane; Mice; Mitochondria; Models, Biological; Neoplasms; Oxidative Stress; Reactive Oxygen Species; Signal Transduction; Thioredoxin-Disulfide Reductase | 2014 |
Mechanistic investigations on E-N bond-breaking and ring expansion for N-heterocyclic carbene analogues containing the group 14 elements (E).
Topics: Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Quantum Theory | 2014 |
Antitumor properties and mechanisms of mitochondria-targeted Ag(I) and Au(I) complexes containing N-heterocyclic carbenes derived from cyclophanes.
Topics: Antineoplastic Agents; Apoptosis; Cell Line; Coordination Complexes; Drug Screening Assays, Antitumor; Gold; Humans; Methane; Reactive Oxygen Species; Silver | 2014 |
Gold(I) N-heterocyclic carbene complexes with naphthalimide ligands as combined thioredoxin reductase inhibitors and DNA intercalators.
Topics: Antineoplastic Agents; Cell Proliferation; Coordination Complexes; DNA; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; HT29 Cells; Humans; Intercalating Agents; Ligands; MCF-7 Cells; Methane; Naphthalimides; Thioredoxin-Disulfide Reductase | 2014 |
Stabilization of carbenes via α-ylide substitutions: a computational quest for new divalents at DFT.
Topics: Acrylates; Computer Simulation; Cyclization; Drug Stability; Methane; Molecular Structure | 2014 |
Magnetic properties of 1:2 mixed cobalt(II) salicylaldehyde Schiff-base complexes with pyridine ligands carrying high-spin carbenes (Scar = 2/2, 4/2, 6/2, and 8/2) in dilute frozen solutions: role of organic spin in heterospin single-molecule magnets.
Topics: Cobalt; Coordination Complexes; Ligands; Methane; Molecular Structure; Pyridines; Schiff Bases | 2014 |
Targeting cytotoxicity and tubulin polymerization by metal-carbene complexes on a purine tautomer platform.
Topics: Adenine; Cell Line, Tumor; Cell Survival; Coordination Complexes; Humans; Mercury; Methane; Polymerization; Silver; Tubulin; Tubulin Modulators | 2014 |
Bifunctional N-heterocyclic carbene-catalyzed highly enantioselective synthesis of spirocyclic oxindolo-β-lactams.
Topics: beta-Lactams; Catalysis; Heterocyclic Compounds; Indoles; Methane; Molecular Structure; Spiro Compounds; Stereoisomerism | 2014 |
N-heterocyclic carbene-palladium(II)-1-methylimidazole complex-catalyzed direct C-H bond arylation of (benz)imidazoles with aryl chlorides.
Topics: Benzimidazoles; Catalysis; Heterocyclic Compounds; Hydrogen Bonding; Imidazoles; Methane; Molecular Structure; Organometallic Compounds; Palladium | 2014 |
N-Heterocyclic carbene-catalyzed chemoselective cross-aza-benzoin reaction of enals with isatin-derived ketimines: access to chiral quaternary aminooxindoles.
Topics: Aza Compounds; Benzoin; Catalysis; Imines; Indoles; Isatin; Methane; Molecular Structure; Nitriles; Stereoisomerism | 2014 |
Synthesis of the first radiolabeled 188Re N-heterocyclic carbene complex and initial studies on its potential use in radiopharmaceutical applications.
Topics: Coordination Complexes; Imidazoles; Methane; Radioisotopes; Radiopharmaceuticals; Rhenium | 2014 |
Hydride-rhodium(III)-N-heterocyclic carbene catalysts for vinyl-selective H/D exchange: a structure-activity study.
Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Deuterium; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Rhodium; Structure-Activity Relationship; Vinyl Compounds | 2014 |
A cooperative N-heterocyclic carbene/chiral phosphate catalysis system for allenolate annulations.
Topics: Catalysis; Heterocyclic Compounds; Methane; Phosphates; Stereoisomerism | 2014 |
Two Fe3(μ3-S)2(CO)8 clusters with terminal N-heterocyclic carbenes.
Topics: Crystallography, X-Ray; Ferrous Compounds; Hydrogen Bonding; Iron; Ligands; Methane; Molecular Structure | 2014 |
Iron porphyrin carbenes as catalytic intermediates: structures, Mössbauer and NMR spectroscopic properties, and bonding.
Topics: Catalysis; Iron; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Porphyrins; Spectroscopy, Mossbauer | 2014 |
DFT study on the reaction mechanisms and stereoselectivities of NHC-catalyzed [2 + 2] cycloaddition between arylalkylketenes and electron-deficient benzaldehydes.
Topics: Benzaldehydes; Catalysis; Cyclization; Electrons; Ethylenes; Heterocyclic Compounds; Ketones; Lactones; Methane; Molecular Structure; Quantum Theory; Stereoisomerism | 2014 |
Catalytic carbene transfer allows the direct customization of cyclic purine dinucleotides.
Topics: Catalysis; Dinucleoside Phosphates; Methane; Purines; Rhenium | 2014 |
Selective Kumada biaryl cross-coupling reaction enabled by an iron(III) alkoxide-N-heterocyclic carbene catalyst system.
Topics: Amides; Catalysis; Coordination Complexes; Ferric Compounds; Heterocyclic Compounds; Methane; Oxides | 2014 |
Redox and luminescent properties of robust and air-stable N-heterocyclic carbene group 4 metal complexes.
Topics: Electron Spin Resonance Spectroscopy; Heterocyclic Compounds; Luminescence; Magnetic Resonance Spectroscopy; Metals; Methane; Oxidation-Reduction | 2014 |
Synthesis of 3,3-disubstituted indoline-2-thiones catalysed by an N-heterocyclic carbene.
Topics: Aldehydes; Catalysis; Indoles; Methane; Thiones | 2014 |
A simple approach to pyrrolylimidazole derivatives by azirine ring expansion with imidazolium ylides.
Topics: Azirines; Bromides; Hydroxides; Imidazoles; Methane; Molecular Structure; Oxidation-Reduction; Potassium Compounds; Pyrroles; Quantum Theory; Stereoisomerism | 2014 |
Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts.
Topics: Catalysis; Gold; Ligands; Methane; Models, Molecular | 2014 |
Asymmetric NHC-catalyzed aza-Diels-Alder reactions: highly enantioselective route to α-amino acid derivatives and DFT calculations.
Topics: Aldehydes; Amino Acids; Aza Compounds; Catalysis; Cycloaddition Reaction; Heterocyclic Compounds, 1-Ring; Hydrocarbons, Chlorinated; Methane; Molecular Structure; Stereoisomerism | 2014 |
Palladium-catalyzed cross-coupling reaction of diazo compounds and vinyl boronic acids: an approach to 1,3-diene compounds.
Topics: Alkenes; Azo Compounds; Boronic Acids; Methane; Molecular Structure; Oxidation-Reduction; Palladium; Vinyl Compounds | 2014 |
Highly selective directed arylation reactions via back-to-back dehydrogenative C-H borylation/arylation reactions.
Topics: Boron Compounds; Catalysis; Crystallography, X-Ray; Dimerization; Heterocyclic Compounds; Hydrocarbons, Aromatic; Methane; Models, Molecular; Rhodium | 2014 |
Exploring the vinylogous reactivity of cyclohexenylidene malononitriles: switchable regioselectivity in the organocatalytic asymmetric addition to enals giving highly enantioenriched carbabicyclic structures.
Topics: Aldehydes; Bridged Bicyclo Compounds; Catalysis; Cycloaddition Reaction; Cyclohexenes; Methane; Nitriles; Spiro Compounds; Stereoisomerism; Substrate Specificity | 2014 |
Asymmetric synthesis of highly substituted β-lactones through oxidative carbene catalysis with LiCl as cooperative Lewis acid.
Topics: Catalysis; Cyclohexanes; Lactones; Lewis Acids; Lithium Chloride; Methane; Oxidants; Oxidation-Reduction; Stereoisomerism | 2014 |
N-heterocyclic-carbene-catalyzed synthesis of 2-aryl indoles.
Topics: Aza Compounds; Catalysis; Heterocyclic Compounds; Indoles; Methane; Protein Kinase Inhibitors; Stereoisomerism | 2014 |
Palladium-catalyzed amination of aryl sulfides with anilines.
Topics: Amination; Amines; Aniline Compounds; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Palladium; Sulfides | 2014 |
Methandiide as a non-innocent ligand in carbene complexes: from the electronic structure to bond activation reactions and cooperative catalysis.
Topics: Catalysis; Coordination Complexes; Electrons; Hydrogenation; Ligands; Methane; Models, Molecular; Ruthenium | 2014 |
Concerted amidation of activated esters: reaction path and origins of selectivity in the kinetic resolution of cyclic amines via N-heterocyclic carbenes and hydroxamic acid cocatalyzed acyl transfer.
Topics: Amides; Amines; Catalysis; Esters; Heterocyclic Compounds; Hydroxamic Acids; Kinetics; Methane; Molecular Structure; Quantum Theory; Stereoisomerism | 2014 |
Synthesis of isocoumarins through three-component couplings of arynes, terminal alkynes, and carbon dioxide catalyzed by an NHC-copper complex.
Topics: Alkynes; Carbon Dioxide; Catalysis; Copper; Heterocyclic Compounds; Hydrocarbons, Aromatic; Isocoumarins; Methane; Molecular Structure; Organometallic Compounds | 2014 |
Synthesis, structures, and selective toxicity to cancer cells of gold(I) complexes involving N-heterocyclic carbene ligands.
Topics: Antineoplastic Agents; Cell Line, Tumor; Chemistry Techniques, Synthetic; Gold; Heterocyclic Compounds; Humans; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds | 2014 |
Highly stereoselective synthesis of cyclopentanes bearing four stereocentres by a rhodium carbene-initiated domino sequence.
Topics: Alcohols; Catalysis; Cyclopentanes; Diazonium Compounds; Methane; Rhodium; Stereoisomerism; Vinyl Compounds | 2014 |
From furfural to fuel: synthesis of furoins by organocatalysis and their hydrodeoxygenation by cascade catalysis.
Topics: Biomass; Catalysis; Chemistry Techniques, Synthetic; Furaldehyde; Methane; Oxygen; Palladium; Petroleum | 2014 |
Divergent outcomes of carbene transfer reactions from dirhodium- and copper-based catalysts separately or in combination.
Topics: Acrolein; Catalysis; Copper; Crystallography, X-Ray; Cycloaddition Reaction; Methane; Molecular Conformation; Rhodium | 2011 |
Carbene based photochemical molecular assemblies for solar driven hydrogen generation.
Topics: Catalysis; Coordination Complexes; Electrochemical Techniques; Heterocyclic Compounds; Hydrogen; Ligands; Light; Methane; Molecular Conformation; Pyridines; Ruthenium; Silver; Spectrophotometry | 2014 |
Cobalt-catalyzed C-H arylations, benzylations, and alkylations with organic electrophiles and beyond.
Topics: Alkylation; Catalysis; Cobalt; Coordination Complexes; Methane; Molecular Structure | 2014 |
Unexpected drastic decrease in the excited-state electronic communication between porphyrin chromophores covalently linked by a palladium(II) bridge.
Topics: Electrons; Energy Transfer; Heterocyclic Compounds; Metalloporphyrins; Methane; Models, Molecular; Palladium; Quantum Theory; Zinc | 2014 |
Accesses to electronic structures and the excited states of blue luminescent copper(I) complexes containing N-heterocyclic carbene ligands: a DFT/TDDFT exploitation.
Topics: Color; Computer Simulation; Copper; Electrons; Energy Transfer; Ligands; Luminescence; Luminescent Agents; Methane; Models, Chemical; Models, Molecular; Molecular Structure; Spectrophotometry, Ultraviolet; Structure-Activity Relationship | 2014 |
Conjugate umpolung of β,β-disubstituted enals by dual catalysis with an N-heterocyclic carbene and a Brønsted acid: facile construction of contiguous quaternary stereocenters.
Topics: Acids; Aldehydes; Catalysis; Cycloaddition Reaction; Heterocyclic Compounds; Indoles; Methane; Oxindoles; Spiro Compounds; Stereoisomerism | 2014 |
Synthesis and biological evaluation of kendomycin and its analogues.
Topics: Coordination Complexes; Macrocyclic Compounds; Methane; Quinones; Rifabutin; Structure-Activity Relationship | 2014 |
Computational evaluation of tris(carbene)borate donor properties in {NiNO}(10) complexes.
Topics: Borates; Computer Simulation; Coordination Complexes; Methane; Models, Molecular; Molecular Structure; Nickel; Nitrogen; Nitrogen Oxides | 2014 |
N-heterocyclic carbene-stabilized palladium complexes as organometallic catalysts for bioorthogonal cross-coupling reactions.
Topics: Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Organometallic Compounds; Palladium | 2014 |
Rhodium-catalyzed transannulation of N-sulfonyl-1,2,3-triazoles and epoxides: regioselective synthesis of substituted 3,4-dihydro-2H-1,4-oxazines.
Topics: Catalysis; Combinatorial Chemistry Techniques; Methane; Molecular Structure; Oxazines; Rhodium; Triazoles | 2014 |
Kinetic resolution of 1,1'-biaryl-2,2'-diols and amino alcohols through NHC-catalyzed atroposelective acylation.
Topics: Acylation; Amino Alcohols; Catalysis; Heterocyclic Compounds; Kinetics; Methane; Naphthols; Nitrogen; Stereoisomerism | 2014 |
Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃].
Topics: Carbon Monoxide; Chromium; Electrochemical Techniques; Methane; Organometallic Compounds; Photochemical Processes; Quantum Theory; Temperature | 2014 |
Traditional and ion-pair halogen-bonded complexes between chlorine and bromine derivatives and a nitrogen-heterocyclic carbene.
Topics: Bromine; Chlorine; Electrons; Fluorine; Hydrogen Bonding; Methane; Models, Chemical; Static Electricity; Thermodynamics | 2014 |
Catalytic asymmetric functionalization of aromatic C-H bonds by electrophilic trapping of metal-carbene-induced zwitterionic intermediates.
Topics: Catalysis; Methane; Models, Molecular; Molecular Structure; Rhodium; Stereoisomerism | 2014 |
Proton-transfer polymerization (HTP): converting methacrylates to polyesters by an N-heterocyclic carbene.
Topics: Catalysis; Methacrylates; Methane; Molecular Structure; Polyesters; Polymerization; Protons | 2014 |
Dinuclear zinc hydride supported by an anionic bis(N-heterocyclic carbene) ligand.
Topics: Anions; Carbon Dioxide; Catalysis; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Molecular Conformation; Silanes; Zinc | 2014 |
Platinum-catalyzed synthesis of substituted phenanthrenes from biphenyl propargyl alcohols via a carbene intermediate.
Topics: Alkynes; Catalysis; Cyclization; Indoles; Methane; Molecular Structure; Phenanthrenes; Phenanthrolines; Platinum Compounds; Propanols | 2014 |
Theoretical studies on the regioselectivity of iridium-catalyzed 1,3-dipolar azide-alkyne cycloaddition reactions.
Topics: Alkynes; Azides; Catalysis; Cycloaddition Reaction; Iridium; Methane; Models, Molecular; Triazoles | 2014 |
Synthesis and biological assays on cancer cells of dinuclear gold complexes with novel functionalised di(N-heterocyclic carbene) ligands.
Topics: Antineoplastic Agents; Cell Line; Cell Line, Tumor; Cell Proliferation; Cell Survival; Cisplatin; Coordination Complexes; Copper; Cycloaddition Reaction; Humans; Imidazoles; Inhibitory Concentration 50; Ligands; Methane; Organ Specificity; Organogold Compounds; Polyethylene Glycols; Silver; Structure-Activity Relationship | 2014 |
Injection, transport, absorption and phosphorescence properties of a series of platinum (II) complexes with N-heterocyclic carbenes: a DFT and time-dependent DFT study.
Topics: Absorption, Physicochemical; Computer Simulation; Electrons; Energy Transfer; Fluorescent Dyes; Heterocyclic Compounds; Luminescent Measurements; Methane; Models, Chemical; Models, Molecular; Molecular Structure; Organoplatinum Compounds; Structure-Activity Relationship; Vibration | 2014 |
Gold-catalyzed tandem cycloisomerization/functionalization of in situ generated α-oxo gold carbenes in water.
Topics: Alkynes; Aniline Compounds; Cyclization; Gold; Isomerism; Methane; Molecular Structure; Oxidation-Reduction; Water | 2014 |
Highly stereoselective synthesis of functionalized pyrrolo[3,2-c]quinolines via N-heterocyclic carbene catalyzed cascade sequence.
Topics: Catalysis; Methane; Molecular Structure; Pyrroles; Quinolines; Stereoisomerism | 2014 |
Water-soluble NHC-Cu catalysts: applications in click chemistry, bioconjugation and mechanistic analysis.
Topics: Alkynes; Azides; Basic-Leucine Zipper Transcription Factors; Catalysis; Click Chemistry; Coordination Complexes; Copper; Cycloaddition Reaction; DNA; Drug Discovery; Heterocyclic Compounds; Methane; Models, Molecular; Peptides; Saccharomyces cerevisiae Proteins; Solubility; Thermodynamics; Triazoles; Water | 2014 |
Enantioselective all-carbon (4+2) annulation by N-heterocyclic carbene catalysis.
Topics: Carbon; Catalysis; Cyclization; Cyclohexenes; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2014 |
Direct catalytic addition of alkylnitriles to aldehydes by transition-metal/NHC complexes.
Topics: Aldehydes; Coordination Complexes; Heterocyclic Compounds; Imidazoles; Ions; Metals; Methane; Models, Molecular; Molecular Structure; Nitriles; Rhodium; Stereoisomerism; Transition Elements | 2014 |
Unexpected anion effect in the alkoxylation of alkynes catalyzed by N-heterocyclic carbene (NHC) cationic gold complexes.
Topics: Alkynes; Anions; Catalysis; Cations; Coordination Complexes; Gold; Heterocyclic Compounds; Methane; Molecular Structure | 2014 |
Regioselective allene hydroarylation via one-pot allene hydrosilylation/Pd-catalyzed cross-coupling.
Topics: Alkadienes; Catalysis; Combinatorial Chemistry Techniques; Methane; Molecular Structure; Palladium; Silanes; Stereoisomerism | 2014 |
Cyclization of η3-benzylpalladium intermediates derived from carbene insertion.
Topics: Biological Products; Cyclization; Indans; Methane; Molecular Structure; Palladium; Stereoisomerism; Tetrahydronaphthalenes | 2014 |
Rhenium and technetium tricarbonyl complexes of N-heterocyclic carbene ligands.
Topics: Carbon Monoxide; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhenium; Technetium | 2014 |
β-Functionalization of carboxylic anhydrides with β-alkyl substituents through carbene organocatalysis.
Topics: Anhydrides; Carboxylic Acids; Catalysis; Heterocyclic Compounds; Methane | 2014 |
An ylide transformation of rhodium(I) carbene: enantioselective three-component reaction through trapping of rhodium(I)-associated ammonium ylides by β-nitroacrylates.
Topics: Acrylates; Ammonium Compounds; Catalysis; Methane; Molecular Structure; Rhodium; Stereoisomerism | 2014 |
Non-natural olefin cyclopropanation catalyzed by diverse cytochrome P450s and other hemoproteins.
Topics: Alkenes; Animals; Biocatalysis; Cattle; Cyclopropanes; Cytochrome P-450 Enzyme System; Hemin; Humans; Methane; Muramidase; Serum Albumin; Styrene; Substrate Specificity | 2014 |
Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer.
Topics: Benzene; Catalysis; Electron Transport; Heterocyclic Compounds; Hydroxylation; Methane; Stereoisomerism; Substrate Specificity | 2014 |
Tuning the electronic and ligand properties of remote carbenes: a theoretical study.
Topics: Electronics; Heterocyclic Compounds; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Theoretical; Quantum Theory | 2014 |
N-heterocyclic carbene organocatalytic reductive β,β-coupling reactions of nitroalkenes via radical intermediates.
Topics: Alkenes; Anions; Electrons; Kinetics; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Nitro Compounds; Pyruvate Synthase | 2014 |
Hydroboration of arynes with N-heterocyclic carbene boranes.
Topics: Alkynes; Boranes; Electrons; Methane; Models, Molecular; Molecular Conformation | 2014 |
Oxidative enantioselective α-fluorination of aliphatic aldehydes enabled by N-heterocyclic carbene catalysis.
Topics: Aldehydes; Catalysis; Fluorine; Heterocyclic Compounds; Methane; Oxidation-Reduction; Stereoisomerism | 2015 |
Preparation and use of carbonyl-decorated carbenes in the activation of white phosphorus.
Topics: Methane; Phosphorus | 2014 |
Aryl-palladium-NHC complex: efficient phosphine-free catalyst precursors for the carbonylation of aryl iodides with amines or alkynes.
Topics: Alkynes; Amines; Catalysis; Iodides; Methane; Organometallic Compounds; Palladium | 2014 |
Stereoselective synthesis of ε-lactones or spiro-heterocycles through NHC-catalyzed annulation: divergent reactivity by catalyst control.
Topics: Catalysis; Lactones; Methane; Spiro Compounds; Stereoisomerism | 2014 |
Mechanism of Ni N-heterocyclic carbene catalyst for C-O bond hydrogenolysis of diphenyl ether: a density functional study.
Topics: Carbon; Catalysis; Heterocyclic Compounds; Hydrogenation; Methane; Molecular Conformation; Nickel; Oxidation-Reduction; Oxygen; Phenyl Ethers; Quantum Theory; Thermodynamics | 2014 |
Intramolecular annulation of aromatic rings with N-sulfonyl 1,2,3-triazoles: divergent synthesis of 3-methylene-2,3-dihydrobenzofurans and 3-methylene-2,3-dihydroindoles.
Topics: Benzofurans; Catalysis; Coordination Complexes; Cyclization; Indoles; Methane; Rhodium; Triazoles | 2015 |
N-heterocyclic carbene catalyzed enantioselective α-fluorination of aliphatic aldehydes and α-chloro aldehydes: synthesis of α-fluoro esters, amides, and thioesters.
Topics: Aldehydes; Esters; Fluorine; Heterocyclic Compounds; Methane; Stereoisomerism | 2015 |
Diazo- and transition-metal-free C-H insertion: a direct synthesis of β-lactams.
Topics: Amides; Benzene Derivatives; beta-Lactams; Methane; Thermodynamics | 2015 |
Molybdenum complexes supported by mixed NHC/phosphine ligands: activation of N2 and reaction with P(OMe)3 to the first meta-phosphite complex.
Topics: Chlorides; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Methane; Molecular Conformation; Molybdenum; Nitrogen; Phosphines; Phosphites | 2015 |
Ni(NHC)]-catalyzed cycloaddition of diynes and tropone: apparent enone cycloaddition involving an 8π insertion.
Topics: Catalysis; Cyclization; Cycloaddition Reaction; Diynes; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Conformation; Stereoisomerism; Substrate Specificity; Tropolone | 2014 |
Reaction between CH2 and HCCN: a theoretical approach to acrylonitrile formation in the interstellar medium.
Topics: Acrylonitrile; Cyanides; Extraterrestrial Environment; Gases; Ice; Methane; Quantum Theory; Thermodynamics | 2014 |
Synthesis of azoimidazolium dyes with nitrous oxide.
Topics: Azo Compounds; Coloring Agents; Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Methane; Molecular Conformation; Nitrous Oxide | 2015 |
Hybrid ruthenium ROMP catalysts based on an engineered variant of β-barrel protein FhuA ΔCVF(tev) : effect of spacer length.
Topics: Bacterial Outer Membrane Proteins; Catalysis; Cysteine; Escherichia coli; Escherichia coli Proteins; Heterocyclic Compounds; Isomerism; Methane; Polymerization; Ruthenium | 2015 |
Enantioselective oxidative gold catalysis enabled by a designed chiral P,N-bidentate ligand.
Topics: Catalysis; Crystallography, X-Ray; Cyclopropanes; Gold; Ligands; Methane; Molecular Conformation; Nitrogen; Oxidation-Reduction; Phosphorus; Piperidines; Stereoisomerism | 2015 |
Intermolecular dynamic kinetic resolution cooperatively catalyzed by an N-heterocyclic carbene and a Lewis acid.
Topics: Catalysis; Heterocyclic Compounds; Kinetics; Lactones; Lewis Acids; Mesylates; Methane; Oxidation-Reduction; Stereoisomerism | 2015 |
Bis-mixed-carbene ruthenium-thiolate-alkylidene complexes: synthesis and olefin metathesis activity.
Topics: Acetates; Acrylates; Alkadienes; Alkenes; Malonates; Methane; Organometallic Compounds; Ruthenium; Sulfides | 2015 |
Controlled access to a heterometallic N-heterocyclic carbene helicate.
Topics: Heterocyclic Compounds; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Pyridines | 2015 |
Regio- and stereoselective synthesis of benzothiazolo-pyrimidinones via an NHC-catalyzed Mannich/lactamization domino reaction.
Topics: Catalysis; Imines; Lactams; Methane; Models, Molecular; Molecular Conformation; Pyrimidinones; Stereoisomerism; Substrate Specificity; Thiazoles | 2015 |
Electrochemical flow-reactor for expedient synthesis of copper-N-heterocyclic carbene complexes.
Topics: Catalysis; Copper; Electrochemistry; Feasibility Studies; Heterocyclic Compounds; Methane; Organometallic Compounds; Oxidation-Reduction; Silanes | 2015 |
Phosphorescent iridium(III)-bis-N-heterocyclic carbene complexes as mitochondria-targeted theranostic and photodynamic anticancer agents.
Topics: Antineoplastic Agents; Cell Cycle; Cell Line, Tumor; HeLa Cells; Humans; Iridium; Membrane Potential, Mitochondrial; Methane; Mitochondria; Organometallic Compounds; Photochemotherapy | 2015 |
N-heterocyclic carbene gold(I) and silver(I) complexes bearing functional groups for bio-conjugation.
Topics: Cell Line; Cell Line, Tumor; Cell Survival; Gold; Heterocyclic Compounds; Humans; Magnetic Resonance Spectroscopy; Methane; Organometallic Compounds; Silver; Spectrometry, Mass, Electrospray Ionization | 2015 |
One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay.
Topics: Catalysis; Combinatorial Chemistry Techniques; Cyclization; Lewis Acids; Mesylates; Methane; Molecular Structure; Organometallic Compounds; Rhodium; Sulfonamides; Transition Elements; Triazoles | 2015 |
N-Heterocyclic carbene-catalyzed [4 + 2] cyclization of 2-bromo-2-enal with 3-alkylenyloxindoles: efficient assembly of spirocarbocyclic oxindole.
Topics: Aldehydes; Catalysis; Cyclization; Heterocyclic Compounds; Indoles; Methane; Molecular Structure; Oxindoles; Spiro Compounds | 2015 |
Catalytic hydrodechlorination of benzyl chloride promoted by Rh-N-heterocyclic carbene catalysts.
Topics: Benzyl Compounds; Catalysis; Halogenation; Heterocyclic Compounds; Hydrogen; Methane; Models, Molecular; Molecular Conformation; Rhodium; Silanes | 2015 |
A three-dimensional microporous metal-metalloporphyrin framework.
Topics: Adsorption; Chemical Fractionation; Coordination Complexes; Manganese; Metalloporphyrins; Methane; Porosity | 2015 |
Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis.
Topics: Catalysis; Ethylenes; Methane; Models, Molecular; Ruthenium | 2015 |
Enantioconvergent synthesis of functionalized γ-butyrolactones via (3 + 2)-annulation.
Topics: 4-Butyrolactone; Cyclization; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2015 |
A Rh-catalyzed 1,2-sulfur migration/aza-Diels-Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles.
Topics: Aza Compounds; Catalysis; Methane; Rhodium; Sulfur; Triazoles | 2015 |
Confocal and fluorescence lifetime imaging sheds light on the fate of a pyrene-tagged carbon monoxide-releasing Fischer carbene chromium complex.
Topics: Biological Transport; Carbon Monoxide; Chromium; HeLa Cells; Humans; Methane; Microscopy, Confocal; Optical Imaging; Organometallic Compounds; Pyrenes | 2015 |
Functionalized cyclopentenes through a tandem NHC-catalyzed dynamic kinetic resolution and ambient temperature decarboxylation: mechanistic insight and synthetic application.
Topics: Catalysis; Cyclopentanes; Decarboxylation; Heterocyclic Compounds; Kinetics; Methane; Models, Molecular; Molecular Dynamics Simulation; Molecular Structure; Stereoisomerism; Temperature | 2015 |
Domino [4 + 1]-annulation of α,β-unsaturated δ-amino esters with Rh(II)-carbenoids – a new approach towards multi-functionalized N-aryl pyrrolidines.
Topics: Amino Acids; Cyclization; Esters; Methane; Molecular Structure; Organometallic Compounds; Pyrrolidines; Rhodium | 2015 |
Hydrogenations at room temperature and atmospheric pressure with mesoionic carbene-stabilized borenium catalysts.
Topics: Atmospheric Pressure; Boranes; Catalysis; Crystallography, X-Ray; Hydrogenation; Lewis Acids; Methane; Molecular Conformation; Temperature; Triazoles | 2015 |
Cytotoxic activity and protein binding through an unusual oxidative mechanism by an iridium(I)-NHC complex.
Topics: Cell Proliferation; Cell Survival; Coordination Complexes; Cytochromes c; HEK293 Cells; Heterocyclic Compounds; HT29 Cells; Humans; Iridium; MCF-7 Cells; Methane; Muramidase; Oxidation-Reduction | 2015 |
General and mild Ni(0)-catalyzed α-arylation of ketones using aryl chlorides.
Topics: Catalysis; Chlorides; Coordination Complexes; Hydrocarbons, Chlorinated; Ketones; Methane; Molecular Structure; Nickel | 2015 |
Methanol dehydrogenation by iridium N-heterocyclic carbene complexes.
Topics: Aniline Compounds; Catalysis; Coordination Complexes; Hydrogenation; Iridium; Methane; Methanol; Methylation | 2015 |
N-Heterocyclic carbene-catalyzed enantioselective annulations: a dual activation strategy for a formal [4+2] addition for dihydrocoumarins.
Topics: Catalysis; Coumarins; Heterocyclic Compounds; Methane; Stereoisomerism | 2015 |
1,2,4-triazole-derived carbene complexes of gold: characterization, solid-state aggregation and ligand disproportionation.
Topics: Carbon; Computer Simulation; Crystallography, X-Ray; Gold; Heterocyclic Compounds; Iodides; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Conformation; Molecular Structure; Oxygen; Reproducibility of Results; Spectrophotometry; Spectrophotometry, Ultraviolet; Stereoisomerism; Thermodynamics; Triazoles; Ultraviolet Rays; X-Ray Diffraction | 2015 |
H(C)Ag: a triple resonance NMR experiment for (109) Ag detection in labile silver-carbene complexes.
Topics: Heterocyclic Compounds; Hydrogen; Isotopes; Magnetic Resonance Spectroscopy; Methane; Organometallic Compounds; Reference Standards; Silver; Temperature | 2015 |
N-heterocyclic carbene-catalyzed radical reactions for highly enantioselective β-hydroxylation of enals.
Topics: Aldehydes; Catalysis; Free Radicals; Heterocyclic Compounds; Hydroxylation; Methane; Stereoisomerism | 2015 |
An efficient N-heterocyclic carbene-ruthenium complex: application towards the synthesis of polyesters and polyamides.
Topics: Catalysis; Methane; Molecular Structure; Nylons; Polyesters; Ruthenium | 2015 |
Novel silicone-based polymer containing active methylene designed for the removal of indoor formaldehyde.
Topics: Adsorption; Air Pollutants; Air Pollution, Indoor; Formaldehyde; Light; Methane; Paint; Polymers; Silicones | 2015 |
Theoretical investigation on the chemoselective N-heterocyclic carbene-catalyzed cross-benzoin reactions.
Topics: Benzoin; Catalysis; Heterocyclic Compounds; Methane; Models, Theoretical; Molecular Conformation; Thermodynamics | 2015 |
Rh(II)-catalyzed cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines: switchable reactivity of Rh-azavinylcarbene as [2C]- or aza-[3C]-synthon.
Topics: Aza Compounds; Azirines; Carbon; Catalysis; Cycloaddition Reaction; Methane; Rhodium; Triazoles | 2015 |
Theoretical study of stereoselectivity of the [1 + 2] cycloaddition reaction between (1S,3R,8S)-2,2-dichloro-3,7,7,10-tetramethyltricyclo[6,4,0,0(1.3)]dodec-9-ene and dibromocarbene using density functional theory (DFT) B3LYP/6-31G*(d).
Topics: Cycloaddition Reaction; Hydrocarbons, Brominated; Methane; Models, Theoretical; Molecular Structure; Polycyclic Compounds; Stereoisomerism | 2015 |
Copper(I)-catalyzed alkylation of polyfluoroarenes through Direct C-H bond functionalization.
Topics: Alkylation; Azo Compounds; Catalysis; Copper; Electrons; Fluorine; Halogenation; Hydrazones; Hydrocarbons, Aromatic; Methane; Tosyl Compounds | 2015 |
Enantioselective assembly of spirocyclic oxindole-dihydropyranones through NHC-catalyzed cascade reaction of isatins with N-hydroxybenzotriazole esters of α,β-unsaturated carboxylic acid.
Topics: Carboxylic Acids; Catalysis; Esters; Heterocyclic Compounds; Indoles; Isatin; Methane; Molecular Structure; Pyrones; Spiro Compounds; Stereoisomerism; Triazoles | 2015 |
Cycloelimination of imidazolidin-2-ylidene N-heterocyclic carbenes: mechanism and insights into the synthesis of stable "NHC-CDI" amidinates.
Topics: Amidines; Crystallography, X-Ray; Imidazoles; Methane; Models, Molecular | 2015 |
Rhodium(I)-catalyzed asymmetric carbene insertion into B-H bonds: highly enantioselective access to functionalized organoboranes.
Topics: Amination; Azo Compounds; Boranes; Catalysis; Crystallography, X-Ray; Ligands; Methane; Models, Molecular; Rhodium; Stereoisomerism | 2015 |
Aminomethylation of enals through carbene and acid cooperative catalysis: concise access to β(2)-amino acids.
Topics: Acids; Aldehydes; Amino Acids; Catalysis; Heterocyclic Compounds; Methane; Methylation; Oxidation-Reduction; Stereoisomerism | 2015 |
Synthesis and reactivity of NHC-supported Ni2(μ(2)-η(2),η(2)-S2)-bridging disulfide and Ni2(μ-S)2-bridging sulfide complexes.
Topics: Disulfides; Heterocyclic Compounds; Hydrogen; Imidazoles; Ligands; Methane; Models, Molecular; Molecular Conformation; Nickel; Organometallic Compounds | 2015 |
Exo-selective reductive macrocyclization of ynals.
Topics: Alkynes; Catalysis; Cyclization; Macrocyclic Compounds; Methane; Molecular Structure; Nickel; Stereoisomerism | 2015 |
Synthesis, characterization, and antileishmanial activities of gold(I) complexes involving quinoline functionalized N-heterocyclic carbenes.
Topics: Animals; Cell Line; Chemistry Techniques, Synthetic; Crystallography, X-Ray; Drug Evaluation, Preclinical; Gold; Heterocyclic Compounds; Leishmania infantum; Macrophages; Methane; Mice; Molecular Structure; Organogold Compounds; Quinolines; Structure-Activity Relationship; Trypanocidal Agents | 2015 |
Investigating the role of CH2 radicals in the HACA mechanism.
Topics: Methane; Models, Molecular; Polycyclic Aromatic Hydrocarbons | 2015 |
Luminescent ruthenium(II) complex bearing bipyridine and N-heterocyclic carbene-based C∧N∧C pincer ligand for live-cell imaging of endocytosis.
Topics: Cell Line; Endocytosis; Humans; Ligands; Luminescent Agents; Methane; Molecular Imaging; Organometallic Compounds; Ruthenium | 2015 |
Lipase active site covalent anchoring of Rh(NHC) catalysts: towards chemoselective artificial metalloenzymes.
Topics: Biomimetic Materials; Catalysis; Catalytic Domain; Fungal Proteins; Heterocyclic Compounds; Lipase; Methane; Organometallic Compounds; Rhodium | 2015 |
Lipophilicity-dependent ruthenium N-heterocyclic carbene complexes as potential anticancer agents.
Topics: Animals; Antineoplastic Agents; Cattle; Cell Line, Tumor; Cell Survival; Coordination Complexes; Crystallography, X-Ray; DNA; G2 Phase Cell Cycle Checkpoints; Heterocyclic Compounds; Humans; Hydrophobic and Hydrophilic Interactions; M Phase Cell Cycle Checkpoints; Methane; Molecular Conformation; Ruthenium | 2015 |
N-Heterocyclic carbene-catalyzed annulation of cyclic β-enamino esters with enals: access to functionalized indolo[2,3-a]quinolizidines.
Topics: Aldehydes; Carbon; Catalysis; Chemistry, Pharmaceutical; Chromatography, Thin Layer; Esters; Heterocyclic Compounds; Indoles; Light; Magnetic Resonance Spectroscopy; Mass Spectrometry; Methane; Molecular Structure; Quinolizidines; Solvents; Stereoisomerism | 2015 |
Synthesis and anticancer activity of silver(I)-N-heterocyclic carbene complexes derived from the natural xanthine products caffeine, theophylline and theobromine.
Topics: Antineoplastic Agents; Biological Products; Caffeine; Cell Line, Tumor; Cell Survival; Coordination Complexes; Crystallography, X-Ray; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Humans; Hydrophobic and Hydrophilic Interactions; Methane; Molecular Conformation; Silver; Theobromine; Theophylline; Xanthine | 2015 |
An efficient approach to 1,2,3-trisubstituted indole via rhodium catalyzed carbene C(sp(3))-H bond insertion.
Topics: Catalysis; Indoles; Methane; Molecular Structure; Organometallic Compounds; Rhodium | 2015 |
Synthesis of β-Carboline-Based N-Heterocyclic Carbenes and Their Antiproliferative and Antimetastatic Activities against Human Breast Cancer Cells.
Topics: Animals; Antineoplastic Agents; Apoptosis; Breast Neoplasms; Carbolines; Caspases; Cell Line, Tumor; Cell Proliferation; Female; Humans; Lung Neoplasms; M Phase Cell Cycle Checkpoints; Membrane Potential, Mitochondrial; Methane; Mice; Neoplasm Metastasis | 2015 |
Intramolecular Insertions into Unactivated C(sp³)-H Bonds by Oxidatively Generated β-Diketone-α-Gold Carbenes: Synthesis of Cyclopentanones.
Topics: Cyclopentanes; Gold; Hydrogen Bonding; Ketones; Methane; Oxidation-Reduction | 2015 |
Synthesis and characterization of an iron complex bearing a cyclic tetra-N-heterocyclic carbene ligand: an artifical heme analogue?
Topics: Crystallography, X-Ray; Ferrous Compounds; Heterocyclic Compounds; Ligands; Methane; Models, Molecular; Molecular Structure | 2015 |
Oxidative N-heterocyclic carbene catalyzed stereoselective annulation of simple aldehydes and 5-alkenyl thiazolones.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Oxidation-Reduction; Pyrones; Stereoisomerism; Thiazoles | 2015 |
Cooperative catalysis of N-heterocyclic carbene and Brønsted acid for a highly enantioselective route to unprotected spiro-indoline-pyrans.
Topics: Indoles; Methane; Pentanoic Acids; Pyrans; Spiro Compounds; Stereoisomerism | 2015 |
A modular, air-stable nickel precatalyst.
Topics: Catalysis; Combinatorial Chemistry Techniques; Crystallography, X-Ray; Ligands; Methane; Molecular Conformation; Molecular Structure; Nickel; Organometallic Compounds; Phosphines | 2015 |
The fluxional amine gold(III) complex as an excellent catalyst and precursor of biologically active acyclic carbenes.
Topics: Amines; Antineoplastic Agents; Catalysis; Cell Proliferation; Cell Survival; Cisplatin; Cyanides; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Gold; Humans; Ligands; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Structure-Activity Relationship; Tumor Cells, Cultured | 2015 |
Experimental and computational mechanistic investigation of chlorocarbene additions to bridgehead carbene-anti-Bredt systems: noradamantylcarbene-adamantene and adamantylcarbene-homoadamantene.
Topics: Adamantane; Alkenes; Ethylenes; Methane; Photolysis; Solvents | 2015 |
Chemical bonding: the orthogonal valence-bond view.
Topics: Hydrogen; Methane; Models, Chemical; Molecular Structure; Quantum Theory; Thermodynamics | 2015 |
N-Heterocyclic Carbene-Catalyzed δ-Carbon LUMO Activation of Unsaturated Aldehydes.
Topics: Aldehydes; Benzene Derivatives; Benzofurans; Carbon; Catalysis; Cyclization; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2015 |
Copper(I) complexes of mesoionic carbene: structural characterization and catalytic hydrosilylation reactions.
Topics: Catalysis; Copper; Crystallography, X-Ray; Methane; Models, Molecular; Molecular Conformation; Molecular Structure; Organometallic Compounds | 2015 |
Interfacing microbial styrene production with a biocompatible cyclopropanation reaction.
Topics: Catalysis; Cyclopropanes; Escherichia coli; Ferric Compounds; Glucose; Indoles; Isoindoles; Methane; Styrene | 2015 |
Nickel N-heterocyclic carbene catalyzed C-C bond formation: a new route to aryl ketones.
Topics: Catalysis; Ketones; Methane; Molecular Structure; Nickel | 2015 |
Enantioselective β-Protonation by a Cooperative Catalysis Strategy.
Topics: Acrolein; Catalysis; Esters; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Conformation; Protons; Quantum Theory; Stereoisomerism | 2015 |
Rapid access to spirocylic oxindoles: application of asymmetric N-heterocyclic carbene-catalyzed [3 + 3] cycloaddition of imines to oxindole-derived enals.
Topics: Aldehydes; Catalysis; Cycloaddition Reaction; Heterocyclic Compounds; Imines; Indoles; Methane; Molecular Structure; Oxindoles; Spiro Compounds; Stereoisomerism | 2015 |
Titanium carbenoid-mediated cyclopropanation of allylic alcohols: selectivity and mechanism.
Topics: Cyclopropanes; Methane; Molecular Structure; Propanols; Titanium | 2015 |
N-Heterocyclic carbene-catalyzed diastereoselective synthesis of β-lactone-fused cyclopentanes using homoenolate annulation reaction.
Topics: Catalysis; Cyclopentanes; Lactones; Methane; Oxides; Pyridines | 2015 |
Synthesis of Alkenylphosphonates through Palladium-Catalyzed Coupling of α-Diazo Phosphonates with Benzyl or Allyl Halides.
Topics: Benzyl Compounds; Catalysis; Halogenation; Hydrocarbons, Halogenated; Methane; Molecular Structure; Organophosphonates; Palladium | 2015 |
Enantioselective N-heterocyclic carbene-catalyzed synthesis of indenopyrones.
Topics: Aldehydes; Catalysis; Cyclization; Halogenation; Heterocyclic Compounds; Indenes; Methane; Pyrones; Stereoisomerism | 2015 |
A Versatile Room-Temperature Route to Di- and Trisubstituted Allenes Using Flow-Generated Diazo Compounds.
Topics: Alkadienes; Alkynes; Catalysis; Copper; Diazonium Compounds; Methane; Temperature | 2015 |
N-Heterocyclic Carbene-Catalyzed Oxidative Annulations of α,β-Unsaturated Aldehydes with Hydrazones: Selective Synthesis of Optically Active 4,5-Dihydropyridazin-3-ones and Pyridazin-3-ones.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Hydrazones; Methane; Molecular Structure; Oxidation-Reduction; Pyridazines | 2015 |
Oxidative N-Heterocyclic Carbene-Catalyzed γ-Carbon Addition of Enals to Imines: Mechanistic Studies and Access to Antimicrobial Compounds.
Topics: Aldehydes; Anti-Infective Agents; Heterocyclic Compounds; Imines; Methane; Molecular Structure; Oryza; Oxidation-Reduction; Stereoisomerism; Sulfonamides | 2015 |
Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand.
Topics: Biocatalysis; Catalysis; Cytochrome P-450 Enzyme System; Hemeproteins; Iron Compounds; Ligands; Metalloporphyrins; Methane; Models, Molecular; Thermodynamics | 2015 |
Stereoselective Synthesis of Highly Substituted Tetrahydrofurans through Diverted Carbene O-H Insertion Reaction.
Topics: Catalysis; Copper; Furans; Methane; Rhodium; Stereoisomerism | 2015 |
Probing the Diastereoselectivity of Staudinger Reactions Catalyzed by N-Heterocyclic Carbenes.
Topics: beta-Lactams; Catalysis; Crystallography, X-Ray; Cycloaddition Reaction; Ethylenes; Imidazoles; Imines; Ketones; Methane; Models, Molecular; Molecular Structure; Stereoisomerism | 2015 |
Pd-catalyzed cross-coupling of terminal alkynes with ene-yne-ketones: access to conjugated enynes via metal carbene migratory insertion.
Topics: Alkynes; Catalysis; Ketones; Methane; Molecular Structure; Palladium | 2015 |
PEGylated N-Heterocyclic Carbene Anchors Designed To Stabilize Gold Nanoparticles in Biologically Relevant Media.
Topics: Buffers; Crystallography, X-Ray; Culture Media; Gold; Hydrogen Peroxide; Ligands; Metal Nanoparticles; Methane; Models, Molecular; Polyethylene Glycols; Solubility; Surface Properties | 2015 |
The interception of a copper-based carbene radical with an α-carbonyl diazomethane radical: C1/C1N2 copolymerization.
Topics: Animals; Chlorocebus aethiops; Copper; COS Cells; Diazomethane; HeLa Cells; Humans; Imidazoles; Luminescent Agents; Methane; Models, Molecular; Optical Imaging; Polymerization | 2015 |
Stretch Out or Fold Back? Conformations of Dinuclear Gold(I) N-Heterocyclic Carbene Macrocycles.
Topics: Coordination Complexes; Gold; Heterocyclic Compounds; Macrocyclic Compounds; Magnetic Resonance Spectroscopy; Methane; Molecular Conformation | 2015 |
Carbon-Supported Copper Nanomaterials: Recyclable Catalysts for Huisgen [3+2] Cycloaddition Reactions.
Topics: Alkynes; Azides; Carbon; Catalysis; Click Chemistry; Copper; Cycloaddition Reaction; Methane; Models, Molecular; Nanostructures; Nanotubes, Carbon; Triazoles | 2015 |
Stereodivergent Intramolecular C(sp(3))-H Functionalization of Azavinyl Carbenes: Synthesis of Saturated Heterocycles and Fused N-Heterotricycles.
Topics: Amination; Carbon; Catalysis; Cyclization; Furans; Hydrogen; Magnetic Resonance Spectroscopy; Metals; Methane; Models, Chemical; Molecular Structure; Stereoisomerism; Triazoles | 2015 |
Microwave-Assisted Condensation Reactions of Acetophenone Derivatives and Activated Methylene Compounds with Aldehydes Catalyzed by Boric Acid under Solvent-Free Conditions.
Topics: Acetophenones; Aldehydes; Boric Acids; Catalysis; Green Chemistry Technology; Methane; Microwaves; Solvents | 2015 |
Hydroboration of Arynes Formed by Hexadehydro-Diels-Alder Cyclizations with N-Heterocyclic Carbene Boranes.
Topics: Boranes; Catalysis; Cyclization; Cycloaddition Reaction; Heterocyclic Compounds; Hydrocarbons, Cyclic; Methane; Molecular Structure | 2015 |
N-Heterocyclic carbene-catalyzed [3+3] cyclocondensation of bromoenals with aldimines: highly enantioselective synthesis of dihydropyridinones.
Topics: Bromine; Catalysis; Crystallography, X-Ray; Cycloaddition Reaction; Imines; Methane; Models, Molecular; Pyridones; Stereoisomerism | 2015 |
Synthesis and Suzuki Reactions of N-Heterocyclic Carbene Difluoro(aryl)-boranes.
Topics: Boranes; Catalysis; Diazonium Compounds; Heterocyclic Compounds; Methane; Molecular Structure; Palladium | 2015 |
Chemoselective N-Heterocyclic Carbene-Catalyzed Cascade of Enals with Nitroalkenes.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Methane; Molecular Structure; Nitro Compounds | 2015 |
Quantitative assessment of the carbocation/carbene character of the gold-carbene bond.
Topics: Carbon; Gold; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Quantum Theory | 2015 |
Enantioselective Synthesis of Chromanones Bearing Quaternary Substituted Stereocenters Catalyzed by (1R)-Camphor-Derived N-Heterocyclic Carbenes.
Topics: Camphor; Catalysis; Chromones; Heterocyclic Compounds; Methane; Molecular Structure; Stereoisomerism | 2015 |
Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes.
Topics: Catalysis; Hydrogenation; Ketones; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Phenols; Rhodium; Stereoisomerism | 2015 |
N-Heterocyclic Carbene-Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes.
Topics: Alkenes; Alkynes; Allyl Compounds; Boron; Boron Compounds; Catalysis; Copper; Indicators and Reagents; Methane; Molecular Weight; Organophosphates; Stereoisomerism | 2015 |
Cascade bicyclizations of o-alkynyl aldehydes with thiazolium salts: a new access toward poly-functionalized indeno[2,1-b]pyrroles.
Topics: Aldehydes; Catalysis; Indenes; Methane; Models, Molecular; Pyrroles; Salts; Thiazoles | 2015 |
Adjusting the DNA Interaction and Anticancer Activity of Pt(II) N-Heterocyclic Carbene Complexes by Steric Shielding of the Trans Leaving Group.
Topics: Antineoplastic Agents; Cell Line, Tumor; DNA; Heterocyclic Compounds; Humans; Methane; Platinum Compounds | 2015 |
N-heterocyclic carbenes (NHC) with 1,2,4-oxadiazole-substituents related to natural products: synthesis, structure and potential antitumor activity of some corresponding gold(I) and silver(I) complexes.
Topics: Animals; Antineoplastic Agents; Biological Products; Cell Line, Tumor; Cell Proliferation; Crystallography, X-Ray; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; Methane; Mice; Mice, Nude; Models, Molecular; Molecular Structure; Neoplasms, Experimental; Organometallic Compounds; Oxadiazoles; Silver; Structure-Activity Relationship | 2015 |
Dinitrogen extrusion from enoldiazo compounds under thermal conditions: synthesis of donor-acceptor cyclopropenes.
Topics: Acetamides; Acetates; Cyclopropanes; Diazonium Compounds; Methane; Nitrogen; Temperature | 2015 |
Stereospecific nickel-catalyzed cross-coupling reactions of benzylic ethers and esters.
Topics: Antineoplastic Agents; Catalysis; Esters; Ethers; Furans; Methane; Naphthalenes; Nickel; Oxidation-Reduction; Stereoisomerism; Thiophenes | 2015 |
Advances in nickel-catalyzed cycloaddition reactions to construct carbocycles and heterocycles.
Topics: Carbon Dioxide; Catalysis; Cycloaddition Reaction; Cyclopropanes; Diynes; Heterocyclic Compounds; Isocyanates; Ketones; Methane; Nickel; Nitriles; Pyridones; Pyrones; Tropolone | 2015 |
γ-Carbon Activation through N-Heterocyclic Carbene/Brønsted Acids Cooperative Catalysis: A Highly Enantioselective Route to δ-Lactams.
Topics: Carbon; Catalysis; Lactams; Methane; Molecular Structure; Stereoisomerism; Sulfones | 2015 |
Influence of Electronic Effects on the Reactivity of Triazolylidene-Boryl Radicals: Consequences for the use of N-Heterocyclic Carbene Boranes in Organic and Polymer Synthesis.
Topics: Boranes; Free Radicals; Heterocyclic Compounds; Methane; Molecular Structure; Photochemical Processes; Polymerization; Stereoisomerism; Triazoles | 2015 |
Rh(II)-Catalyzed Reactions of Diazoesters with Organozinc Reagents.
Topics: Azo Compounds; Catalysis; Hydrazones; Indicators and Reagents; Ketones; Methane; Molecular Structure; Organometallic Compounds; Rhodium; Zinc | 2015 |
Application of the π-accepting ability parameter of N-heterocyclic carbene ligands in iridium complexes for signal amplification by reversible exchange (SABRE).
Topics: Coordination Complexes; Electrons; Heterocyclic Compounds; Iridium; Ligands; Methane; Models, Molecular; Pyridines | 2015 |
4-Alkylated Silver-N-Heterocyclic Carbene (NHC) Complexes with Cytotoxic Effects in Leukemia Cells.
Topics: Antineoplastic Agents; Cell Line, Tumor; Chemistry Techniques, Synthetic; Drug Screening Assays, Antitumor; Heterocyclic Compounds; HL-60 Cells; Humans; Imidazoles; Inhibitory Concentration 50; Leukemia; Methane; Silver; Structure-Activity Relationship | 2015 |
Stereolability of chiral ruthenium catalysts with frozen NHC ligand conformations investigated by dynamic-HPLC.
Topics: Catalysis; Chromatography, High Pressure Liquid; Drug Stability; Heterocyclic Compounds; Kinetics; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Ruthenium; Stereoisomerism | 2015 |
Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals.
Topics: Catalysis; Chemistry Techniques, Synthetic; Cyclopentanes; Heterocyclic Compounds; Methane; Stereoisomerism | 2015 |
Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds.
Topics: Boron; Catalysis; Free Radicals; Heterocyclic Compounds; Hydroxides; Ketones; Kinetics; Methane; Methanol; Models, Molecular; Molecular Conformation; Permeability; Silanes; Stereoisomerism; Water | 2015 |
Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization.
Topics: Heterocyclic Compounds; Iron Compounds; Ligands; Methane; Models, Molecular; Molecular Conformation | 2015 |
Hg(OTf)2 Catalyzed Intramolecular 1,4-Addition of Donor-Acceptor Cyclopropenes to Arenes.
Topics: Catalysis; Combinatorial Chemistry Techniques; Cyclopropanes; Hydrocarbons; Mercury; Mesylates; Methane; Molecular Structure | 2015 |
Catalytic Asymmetric Four-Component Reaction for the Rapid Construction of 3,3-Disubstituted 3-Indol-3'-yloxindoles.
Topics: Catalysis; Glyoxylates; Indoles; Methane; Models, Molecular; Molecular Structure; Phosphoric Acids; Rhodium; Stereoisomerism | 2015 |
Catalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights.
Topics: Acylation; Amines; Catalysis; Heterocyclic Compounds; Hydroxamic Acids; Kinetics; Methane; Models, Molecular; Molecular Conformation; Stereoisomerism | 2015 |
Anti-Markovnikov hydroheteroarylation of unactivated alkenes with indoles, pyrroles, benzofurans, and furans catalyzed by a nickel-N-heterocyclic carbene system.
Topics: Alkenes; Benzofurans; Catalysis; Furans; Indoles; Methane; Molecular Structure; Nickel; Organometallic Compounds; Pyrroles | 2015 |
Synthesis and application of a dual chiral [2.2]paracyclophane-based N-heterocyclic carbene in enantioselective β-boration of acyclic enones.
Topics: Boron; Boron Compounds; Catalysis; Copper; Heterocyclic Compounds; Ketones; Methane; Polycyclic Compounds; Stereoisomerism | 2015 |
Solvent mimicry with methylene carbene to probe protein topography.
Topics: Amino Acid Sequence; Animals; Bees; Binding Sites; Calmodulin; Cattle; Diazomethane; Indicators and Reagents; Melitten; Methane; Methylation; Models, Molecular; Molecular Sequence Data; Protein Conformation; Protein Folding; Solvents; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; Tandem Mass Spectrometry | 2015 |
Rh-Catalyzed Reactions of 3-Diazoindolin-2-imines: Synthesis of Pyridoindoles and Tetrahydrofuropyrroloindoles.
Topics: Catalysis; Furans; Heterocyclic Compounds, 4 or More Rings; Imines; Indoles; Methane; Molecular Structure; Rhodium | 2015 |
Surface Characterization and in situ Protein Adsorption Studies on Carbene-Modified Polymers.
Topics: Adsorption; Methane; Photoelectron Spectroscopy; Polymers; Proteins; Quartz Crystal Microbalance Techniques; Surface Properties | 2015 |
Hydrazone-initiated carbene/alkyne cascades to form polycyclic products: ring-fused cyclopropenes as mechanistic intermediates.
Topics: Alkynes; Cyclopropanes; Hydrazones; Methane; Molecular Structure; Polycyclic Compounds | 2015 |
Elucidation of Pyranonigrin Biosynthetic Pathway Reveals a Mode of Tetramic Acid, Fused γ-Pyrone, and exo-Methylene Formation.
Topics: Alkenes; Aspergillus niger; Biosynthetic Pathways; Methane; Molecular Structure; Multigene Family; Pyrones; Pyrroles; Pyrrolidinones | 2015 |
Enantioselective palladium-catalyzed C-H functionalization of indoles using an axially chiral 2,2'-bipyridine ligand.
Topics: 2,2'-Dipyridyl; Acetates; Catalysis; Indoles; Ligands; Methane; Palladium; Phenols; Stereoisomerism | 2015 |
Copper N-Heterocyclic Carbene Complexes As Active Catalysts for the Synthesis of 2-Substituted Oxazolines from Nitriles and Aminoalcohols.
Topics: Amino Alcohols; Catalysis; Copper; Heterocyclic Compounds; Methane; Molecular Structure; Nitriles; Organometallic Compounds; Oxazoles | 2015 |
Total Synthesis of the Posttranslationally Modified Polyazole Peptide Antibiotic Plantazolicin A.
Topics: Anti-Bacterial Agents; Azoles; Catalysis; Dose-Response Relationship, Drug; Methane; Methicillin-Resistant Staphylococcus aureus; Microbial Sensitivity Tests; Molecular Structure; Oligopeptides; Polymers; Rhodium; Structure-Activity Relationship | 2015 |
Rhenium complexes of bidentate, bis-bidentate and tridentate N-heterocyclic carbene ligands.
Topics: Chlorides; Cysteine; Heterocyclic Compounds, 2-Ring; Heterocyclic Compounds, 3-Ring; Histidine; Indicators and Reagents; Isotope Labeling; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Oxides; Radiopharmaceuticals; Rhenium; Silver Compounds; X-Ray Diffraction | 2015 |
Divergent Reactivity of Rhodium(I) Carbenes Derived from Indole Annulations.
Topics: Indoles; Methane; Molecular Structure; Organometallic Compounds; Rhodium | 2015 |
Synthesis of novel polysubstituted N-benzyl-1H-pyrroles via a cascade reaction of alkynyl Fischer carbenes with α-imino glycine methyl esters.
Topics: Glycine; Imines; Methane; Molecular Structure; Pyrroles | 2015 |
Biological Screening of Newly Synthesized BIAN N-Heterocyclic Gold Carbene Complexes in Zebrafish Embryos.
Topics: Animals; Embryo, Nonmammalian; Gold; Heterocyclic Compounds; Methane; Molecular Structure; Oxidative Stress; Zebrafish | 2015 |
BIAN N-Heterocyclic Gold Carbene Complexes induced cytotoxicity in human cancer cells via upregulating oxidative stress.
Topics: Acenaphthenes; Antineoplastic Agents; Cell Survival; Coordination Complexes; Fluorouracil; Glutathione; Gold; HEK293 Cells; Hep G2 Cells; Heterocyclic Compounds; Humans; Inhibitory Concentration 50; MCF-7 Cells; Methane; Nanofibers; Oxidative Stress | 2015 |
Superior Oxygen Stability of N-Heterocyclic Carbene-Coated Au Nanocrystals: Comparison with Dodecanethiol.
Topics: Gold; Methane; Nanoparticles; Oxygen; Stereoisomerism | 2015 |
Fighting Fenton Chemistry: A Highly Active Iron(III) Tetracarbene Complex in Epoxidation Catalysis.
Topics: Catalysis; Epoxy Compounds; Heterocyclic Compounds; Hydroxylation; Iron; Methane; Organometallic Compounds | 2015 |
Novel triazolium based 11(th) group NHCs: synthesis, characterization and cellular response mechanisms.
Topics: Apoptosis; Cell Line, Tumor; Cell Proliferation; Coordination Complexes; Copper; Gold; Heterocyclic Compounds; Humans; Ligands; Methane; Microscopy, Electron, Transmission; Oxidation-Reduction; Proteasome Endopeptidase Complex; Reactive Oxygen Species; Silver; Thioredoxin-Disulfide Reductase; Triazoles | 2015 |
Pyridazine N-Oxides as Precursors of Metallocarbenes: Rhodium-Catalyzed Transannulation with Pyrroles.
Topics: Antineoplastic Agents; Catalysis; Cyclic N-Oxides; Indoles; Methane; Molecular Structure; Nitrogen; Pyridazines; Pyrroles; Rhodium | 2015 |
An N-Heterocyclic Carbene-Catalyzed Oxidative γ-Aminoalkylation of Saturated Carboxylic Acids through in Situ Activation Strategy: Access to δ-Lactam.
Topics: Carboxylic Acids; Catalysis; Lactams; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2015 |
Lewis Acid Mediated Vinylogous Additions of Enol Nucleophiles into an α,β-Unsaturated Platinum Carbene.
Topics: Benzofurans; Catalysis; Indoles; Lewis Acids; Methane; Molecular Structure; Platinum | 2016 |
Protein Footprinting by Carbenes on a Fast Photochemical Oxidation of Proteins (FPOP) Platform.
Topics: Animals; Calmodulin; Cattle; Chromatography, Reverse-Phase; Leucine; Mass Spectrometry; Methane; Models, Molecular; Oxidation-Reduction; Photochemical Processes; Protein Footprinting | 2016 |
Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration.
Topics: Alkenes; Catalysis; Cyclization; Diazonium Compounds; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2016 |
N-Heterocyclic carbene-catalyzed [4 + 2] cyclization of α,β-unsaturated carboxylic acids bearing γ-H with isatins: an enantioselective synthesis of spirocyclic oxindole-dihydropyranones.
Topics: Carboxylic Acids; Catalysis; Crystallography, X-Ray; Cyclization; Heterocyclic Compounds; Indoles; Isatin; Methane; Models, Molecular; Molecular Structure; Spiro Compounds; Stereoisomerism | 2016 |
Chiral Diarylmethanes via Copper-Catalyzed Asymmetric Allylic Arylation with Organolithium Compounds.
Topics: Allyl Compounds; Catalysis; Copper; Indicators and Reagents; Lithium; Methane; Molecular Structure; Organometallic Compounds; Stereoisomerism; Tolterodine Tartrate | 2016 |
Synthesis, characterization and antimicrobial activities of novel silver(I) complexes with coumarin substituted N-heterocyclic carbene ligands.
Topics: Anti-Bacterial Agents; Antifungal Agents; Candida albicans; Candida tropicalis; Coumarins; Dose-Response Relationship, Drug; Escherichia coli; Heterocyclic Compounds; Ligands; Methane; Microbial Sensitivity Tests; Molecular Structure; Organometallic Compounds; Pseudomonas aeruginosa; Silver; Staphylococcus aureus; Structure-Activity Relationship | 2016 |
In vitro antimicrobial studies of new benzimidazolium salts and silver N-heterocyclic carbene complexes.
Topics: Anti-Infective Agents; Benzimidazoles; Carbon-13 Magnetic Resonance Spectroscopy; Heterocyclic Compounds; In Vitro Techniques; Methane; Microbial Sensitivity Tests; Proton Magnetic Resonance Spectroscopy; Silver; Spectrophotometry, Infrared | 2016 |
N-Heterocyclic carbene-catalyzed [3 + 2] annulation of bromoenals with 3-aminooxindoles: highly enantioselective synthesis of spirocyclic oxindolo-γ-lactams.
Topics: Catalysis; Heterocyclic Compounds; Hydrocarbons, Brominated; Indoles; Lactams; Methane; Molecular Structure; Spiro Compounds | 2016 |
Bone Marrow Lipid Profiles from Peripheral Skeleton as Potential Biomarkers for Osteoporosis: A 1H-MR Spectroscopy Study.
Topics: Absorptiometry, Photon; Adipose Tissue; Aged; Aged, 80 and over; Biomarkers; Bone Density; Bone Diseases, Metabolic; Bone Marrow; Calcaneus; Female; Femur Neck; Glycerol; Humans; Image Processing, Computer-Assisted; Lipids; Methane; Middle Aged; Osteoporosis; Postmenopause; Proton Magnetic Resonance Spectroscopy; Reproducibility of Results | 2016 |
Stereoelectronic Model To Explain Highly Stereoselective Reactions of Seven-Membered-Ring Oxocarbenium-Ion Intermediates.
Topics: Methane; Stereoisomerism | 2016 |
Versatile synthesis of cationic N-heterocyclic carbene-gold(i) complexes containing a second ancillary ligand. Design of heterobimetallic ruthenium-gold anticancer agents.
Topics: Cations; Gold; Heterocyclic Compounds; Ligands; Methane; Ruthenium | 2016 |
Moving from Classical Ru-NHC to Neutral or Charged Rh-NHC Based Catalysts in Olefin Metathesis.
Topics: Alkenes; Catalysis; Heterocyclic Compounds; Methane; Molecular Conformation; Organometallic Compounds; Rhodium; Ruthenium | 2016 |
N-Heterocyclic Carbene Ligand-Enabled C(sp(3))-H Arylation of Piperidine and Tetrahydropyran Derivatives.
Topics: Catalysis; Ligands; Methane; Molecular Structure; Piperidines; Pyrans | 2016 |
Chemoselective and stereoselective lithium carbenoid mediated cyclopropanation of acyclic allylic alcohols.
Topics: Cyclopropanes; Lithium; Methane; Molecular Structure; Propanols; Stereoisomerism | 2016 |
Organocatalytic Kinetic Resolution of Sulfoximines.
Topics: Heterocyclic Compounds; Imines; Kinetics; Methane; Molecular Structure; Stereoisomerism | 2016 |
An Enantioselective Assembly of Dihydropyranones through an NHC/LiCl-Mediated in situ Activation of α,β-Unsaturated Carboxylic Acids.
Topics: Carboxylic Acids; Catalysis; Heterocyclic Compounds; Lithium Chloride; Methane; Pyrones; Stereoisomerism | 2016 |
Bond Activation by Metal-Carbene Complexes in the Gas Phase.
Topics: Coordination Complexes; Gases; Methane | 2016 |
Luminescent platinum(II) complexes with functionalized N-heterocyclic carbene or diphosphine selectively probe mismatched and abasic DNA.
Topics: Base Pair Mismatch; Biosensing Techniques; DNA; Humans; Luminescence; Methane; Neoplasms; Platinum | 2016 |
Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature.
Topics: Coordination Complexes; Electron Spin Resonance Spectroscopy; Methane; Models, Molecular | 2016 |
Accessing a Biologically Relevant Benzofuran Skeleton by a One-Pot Tandem Heck Alkynylation/Cyclization Reaction Using Well-Defined Palladium N-Heterocyclic Carbene Complexes.
Topics: Alkynes; Benzofurans; Cyclization; Heterocyclic Compounds; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Palladium; Spectrometry, Mass, Electrospray Ionization | 2016 |
Binding of molecular oxygen by an artificial heme analogue: investigation on the formation of an Fe-tetracarbene superoxo complex.
Topics: Biomimetic Materials; Heme; Iron; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds; Oxygen | 2016 |
Facile Syntheses of N-Heterocyclic Carbene Precursors through I2 - or NIS-Promoted Amidiniumation of N-Alkenyl Formamidines.
Topics: Amidines; Heterocyclic Compounds; Iodine; Methane; Molecular Structure; Succinimides | 2016 |
Benzimidazolium-based novel silver N-heterocyclic carbene complexes: synthesis, characterisation and in vitro antimicrobial activity.
Topics: Anti-Infective Agents; Benzimidazoles; Carbon-13 Magnetic Resonance Spectroscopy; Methane; Microbial Sensitivity Tests; Proton Magnetic Resonance Spectroscopy; Silver | 2016 |
Imidazolium-Based Poly(Ionic Liquid)s Featuring Acetate Counter Anions: Thermally Latent and Recyclable Precursors of Polymer-Supported N-Heterocyclic Carbenes for Organocatalysis.
Topics: Acetates; Anions; Catalysis; Heterocyclic Compounds; Imidazoles; Ionic Liquids; Methane; Molecular Structure; Polymers; Temperature | 2016 |
Ligand Exchange Reaction of Au(I) R-N-Heterocyclic Carbene Complexes with Cysteine.
Topics: Cysteine; Gold; Heterocyclic Compounds; Ligands; Methane; Molecular Structure; Organogold Compounds | 2016 |
Enantioselective Assembly of Spirolactones through NHC-Catalyzed Remote γ-Carbon Addition of Enals with Isatins.
Topics: Aldehydes; Catalysis; Isatin; Methane; Spironolactone; Stereoisomerism | 2016 |
Exploring Cooperative Effects in Oxidative NHC Catalysis: Regioselective Acylation of Carbohydrates.
Topics: Acylation; Carbohydrates; Catalysis; Disaccharides; Methane; Molecular Structure; Oxidation-Reduction | 2016 |
Highly photoluminescent copper carbene complexes based on prompt rather than delayed fluorescence.
Topics: Copper; Luminescence; Methane; Molecular Structure; Photochemical Processes; Temperature; Time Factors | 2016 |
Enantioselective, Stereodivergent Hydroazidation and Hydroamination of Allenes Catalyzed by Acyclic Diaminocarbene (ADC) Gold(I) Complexes.
Topics: Alkadienes; Amines; Catalysis; Coordination Complexes; Gold; Methane; Stereoisomerism | 2016 |
N-Heterocyclic Carbene Capture by Cytochrome P450 3A4.
Topics: Cytochrome P-450 CYP3A; Cytochrome P-450 CYP3A Inhibitors; Heterocyclic Compounds; Humans; Hydrogen-Ion Concentration; Ligands; Methane; Models, Molecular; Protons; Quantum Theory; Ritonavir; Spectrophotometry, Ultraviolet; Spectrum Analysis, Raman; Titrimetry | 2016 |
Tri(1-adamantyl)phosphine: Expanding the Boundary of Electron-Releasing Character Available to Organophosphorus Compounds.
Topics: Catalysis; Electrons; Heterocyclic Compounds; Methane; Organophosphorus Compounds; Phosphines | 2016 |
Antiplasmodial activities of gold(I) complexes involving functionalized N-heterocyclic carbenes.
Topics: Animals; Antimalarials; Cell Survival; Chlorocebus aethiops; Chloroquine; Crystallography, X-Ray; Gold; Inhibitory Concentration 50; Methane; Molecular Structure; Organometallic Compounds; Plasmodium falciparum; Structure-Activity Relationship; Vero Cells | 2016 |
Auranofin and N-heterocyclic carbene gold-analogs are potent inhibitors of the bacteria Helicobacter pylori.
Topics: Anti-Bacterial Agents; Auranofin; Cell Line, Transformed; Dose-Response Relationship, Drug; Drug Synergism; Helicobacter pylori; Heterocyclic Compounds; Humans; Inhibitory Concentration 50; Methane; Microbial Sensitivity Tests; Molecular Structure; Organogold Compounds | 2016 |
N-Heterocyclic Carbene-Gold(I) Complexes Conjugated to a Leukemia-Specific DNA Aptamer for Targeted Drug Delivery.
Topics: Antineoplastic Agents; Aptamers, Nucleotide; Cell Survival; Coordination Complexes; Drug Delivery Systems; Flow Cytometry; Gold; Heterocyclic Compounds; Humans; Leukemia; Methane; Microscopy, Confocal; Molecular Structure | 2016 |
Enantioselective N-heterocyclic carbene-catalyzed synthesis of saccharine-derived dihydropyridinones with cis-selectivity.
Topics: Catalysis; Cyclization; Dihydropyridines; Methane; Saccharin; Stereoisomerism | 2016 |
Platinum(iv) N-heterocyclic carbene complexes: their synthesis, characterisation and cytotoxic activity.
Topics: Cell Line, Tumor; Cell Proliferation; Heterocyclic Compounds; Humans; Methane; Mitochondria; Platinum Compounds | 2016 |
A multi-target caffeine derived rhodium(i) N-heterocyclic carbene complex: evaluation of the mechanism of action.
Topics: Animals; Apoptosis; Bacteria; Caffeine; Cell Cycle; Cell Line, Tumor; Cell Survival; Chick Embryo; Chorioallantoic Membrane; Coordination Complexes; DNA Damage; Humans; Membrane Potential, Mitochondrial; Methane; Reactive Oxygen Species; Rhodium; Wound Healing | 2016 |
Synthesis of C₂-Symmetric Benzimidazolium Salts and Their Application in Palladium-Catalyzed Enantioselective Intramolecular α-Arylation of Amides.
Topics: Amides; Anesthetics, Local; Bromobenzenes; Catalysis; Indoles; Methane; Palladium; Salts; Stereoisomerism | 2016 |
First Crystal Structure for a Gold Carbene-Protein Adduct.
Topics: Crystallography, X-Ray; Gold; Methane; Models, Molecular; Organometallic Compounds; Plant Proteins; Protein Conformation | 2016 |
Reactions of Persistent Carbenes with Hydrogen-Terminated Silicon Surfaces.
Topics: Hydrogen; Methane; Models, Molecular; Molecular Conformation; Silicon; Surface Properties | 2016 |
Dinuclear Au(i) N-heterocyclic carbene complexes derived from unsymmetrical azolium cyclophane salts: potential probes for live cell imaging applications.
Topics: Azoles; Cell Line, Tumor; Coordination Complexes; Crystallography, X-Ray; Gold; Heterocyclic Compounds; Humans; Luminescence; Methane; Models, Molecular; Molecular Probes; Proton Magnetic Resonance Spectroscopy | 2016 |
New gold carbene complexes as candidate anticancer agents.
Topics: Animals; Antineoplastic Agents; Cell Line; Cell Proliferation; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Filaggrin Proteins; Gold; HCT116 Cells; Humans; Methane; Mice; Molecular Structure; Structure-Activity Relationship | 2016 |
Masked N-Heterocyclic Carbene-Catalyzed Alkylation of Phenols with Organic Carbonates.
Topics: Alkylation; Carbonates; Catalysis; Green Chemistry Technology; Imidazoles; Methane; Phenols | 2016 |
Self-Supported N-Heterocyclic Carbenes and Their Use as Organocatalysts.
Topics: Benzimidazoles; Catalysis; Esterification; Methane; Molecular Structure; Oxidation-Reduction; Polymers; Stereoisomerism | 2016 |
Cytotoxicity and biodistribution studies of luminescent Au(i) and Ag(i) N-heterocyclic carbenes. Searching for new biological targets.
Topics: A549 Cells; Acridines; Antineoplastic Agents; Apoptosis; Cell Nucleus; Cell Survival; Coordination Complexes; DNA; Drug Screening Assays, Antitumor; Gold; Humans; Ligands; Luminescence; Lysosomes; Methane; Microscopy, Fluorescence; Silver; Structure-Activity Relationship; Tissue Distribution | 2016 |
Cyclometalated Palladium(II) N-Heterocyclic Carbene Complexes: Anticancer Agents for Potent In Vitro Cytotoxicity and In Vivo Tumor Growth Suppression.
Topics: Animals; Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Cell Survival; Coordination Complexes; Humans; Methane; Mice, Nude; Neoplasms; Palladium | 2016 |
Synthesis and Structures of [LCu(I)(SSi(i)Pr3)] (L = triphos, carbene) and Related Compounds.
Topics: Aldehyde Oxidoreductases; Coordination Complexes; Copper; Crystallography, X-Ray; Ligands; Methane; Models, Molecular; Multienzyme Complexes; Organophosphorus Compounds | 2016 |
Novel cis-[(NHC)
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Survival; Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Humans; Inhibitory Concentration 50; Ligands; Methane; Molecular Structure; Platinum | 2016 |
Hydrogen Production and Storage on a Formic Acid/Bicarbonate Platform using Water-Soluble N-Heterocyclic Carbene Complexes of Late Transition Metals.
Topics: Bicarbonates; Catalysis; Formates; Heterocyclic Compounds; Hot Temperature; Hydrogen; Indium; Kinetics; Methane; Rhodium; Solubility; Water | 2016 |
Carbon-Nitrogen Bond Cleavage by a Thorium-NHC-bpy Complex.
Topics: 2,2'-Dipyridyl; Carbon; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Nitrogen; Organometallic Compounds; Thorium | 2016 |
Synthesis of a 1-Aryl-2,2-chlorosilyl(phospha)silene Coordinated by an N-Heterocyclic Carbene.
Topics: Heterocyclic Compounds, 1-Ring; Methane; Silene | 2016 |
Influence of the Headgroup of Azolium-Based Lipids on Their Biophysical Properties and Cytotoxicity.
Topics: 1,2-Dipalmitoylphosphatidylcholine; Animals; Antineoplastic Agents; Calorimetry, Differential Scanning; Cell Line; Cell Survival; Heterocyclic Compounds; Humans; Lipids; Liposomes; Methane; Microscopy, Fluorescence | 2017 |
DNA-Accelerated Catalysis of Carbene-Transfer Reactions by a DNA/Cationic Iron Porphyrin Hybrid.
Topics: Animals; Catalysis; Cations; DNA; Iron; Male; Metalloporphyrins; Methane; Molecular Structure; Salmon; Testis | 2016 |
Catalytic activation of carbon-carbon bonds in cyclopentanones.
Topics: Biological Products; Carbon; Catalysis; Chemistry Techniques, Synthetic; Cyclohexanones; Cyclopentanes; Hydrogen Bonding; Methane; Molecular Structure; Pyridines; Quantum Theory; Rhodium; Terpenes; Tetralones | 2016 |
An artificial metalloenzyme with the kinetics of native enzymes.
Topics: Biocatalysis; Cytochrome P450 Family 19; Iridium; Kinetics; Metalloproteins; Methane; Mutation; Porphyrins; Protein Conformation; Stereoisomerism | 2016 |
Carbene footprinting accurately maps binding sites in protein-ligand and protein-protein interactions.
Topics: Animals; Binding Sites; Chickens; Glucosides; Horses; Ligands; Methane; Models, Molecular; Molecular Probes; Muramidase; Oligosaccharides; Protein Footprinting; Protein Interaction Mapping; Proteins; Staining and Labeling; Ubiquitin | 2016 |
Diphenylcarbene Protected by Four ortho-Iodine Groups: An Unusually Persistent Triplet Carbene.
Topics: Biphenyl Compounds; Iodine; Lasers; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Photolysis; Spectrum Analysis; Temperature | 2016 |
Gold(I) NHC Complexes: Antiproliferative Activity, Cellular Uptake, Inhibition of Mammalian and Bacterial Thioredoxin Reductases, and Gram-Positive Directed Antibacterial Effects.
Topics: Anti-Bacterial Agents; Antineoplastic Agents; Apoptosis; Bacterial Proteins; Cell Line, Tumor; Cell Proliferation; Coordination Complexes; Drug Resistance, Neoplasm; Drug Screening Assays, Antitumor; Gold; Gram-Positive Bacteria; Heterocyclic Compounds; Humans; Methane; Microbial Sensitivity Tests; Thioredoxin-Disulfide Reductase | 2017 |
Palladium(ii)-Acetylacetonato Complexes with Mesoionic Carbenes: Synthesis, Structures and Their Application in the Suzuki-Miyaura Cross Coupling Reaction.
Topics: Catalysis; Click Chemistry; Coordination Complexes; Crystallography, X-Ray; Hydroxybutyrates; Methane; Molecular Conformation; Palladium; Pentanones | 2016 |
N-heterocyclic carbene complexes of silver and gold as novel tools against breast cancer progression.
Topics: Antineoplastic Agents; Apoptosis; Breast Neoplasms; Cell Proliferation; Cell Survival; Disease Progression; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; MCF-7 Cells; Methane; Molecular Structure; Organometallic Compounds; Silver; Structure-Activity Relationship | 2016 |
Directed evolution of cytochrome c for carbon-silicon bond formation: Bringing silicon to life.
Topics: Bacterial Proteins; Biocatalysis; Carbon; Cytochromes c; Directed Molecular Evolution; Hydrogen Bonding; Methane; Organosilicon Compounds; Rhodothermus; Silicon; Substrate Specificity | 2016 |
Taming Metal/Fluorine Carbenoids.
Topics: Fluorine; Lithium; Magnetic Resonance Spectroscopy; Metals; Methane; Molecular Conformation; Potassium; Sodium | 2017 |
A linear hydroxymethyl tetramate undergoes an acetylation-elimination process for exocyclic methylene formation in the biosynthetic pathway of pyrroindomycins.
Topics: Acetylation; Biological Products; Biosynthetic Pathways; Macrolides; Methane; Methylation; Streptomyces | 2016 |
Arrested α-hydride migration activates a phosphido ligand for C-H insertion.
Topics: Borates; Ferrous Compounds; Ligands; Methane; Molecular Conformation; Quantum Theory | 2016 |
Versatile Homoallylic Boronates by Chemo-, S
Topics: Alcohols; Allyl Compounds; Boronic Acids; Catalysis; Copper; Heterocyclic Compounds; Hydrogen; Methane; Molecular Structure; Quantum Theory; Stereoisomerism | 2017 |
Platinum-Catalyzed α,β-Unsaturated Carbene Formation in the Formal Syntheses of Frondosin B and Liphagal.
Topics: Catalysis; Cycloaddition Reaction; Heterocyclic Compounds, 4 or More Rings; Methane; Molecular Structure; Oxidation-Reduction; Phenols; Platinum; Stereoisomerism; Terpenes | 2017 |
Metal NHC Complexes with Naphthalimide Ligands as DNA-Interacting Antiproliferative Agents.
Topics: Apoptosis; Cell Proliferation; Circular Dichroism; Coordination Complexes; Crystallography, X-Ray; Cymenes; DNA; Drug Stability; HT29 Cells; Humans; Intercalating Agents; Ligands; MCF-7 Cells; Methane; Molecular Conformation; Monoterpenes; Naphthalimides; Rhodium; Ruthenium; Spectrophotometry, Ultraviolet | 2017 |
Formation of cellulose-carbene complex via depolymerization in ILs: Dependence of IL types on kinetics, conformation and dispersity.
Topics: Cellulose; Hydrolysis; Imidazoles; Ionic Liquids; Kinetics; Methane; Molecular Conformation; Polymerization | 2017 |
NHC-catalyzed [4 + 2] annulation of 2-bromo-2-enals with acylhydrazones: enantioselective synthesis of δ-lactams.
Topics: Aldehydes; Catalysis; Heterocyclic Compounds; Hydrazones; Lactams; Methane; Molecular Structure | 2017 |
Rhenium(i) complexes of N-heterocyclic carbene ligands that bind to amyloid plaques of Alzheimer's disease.
Topics: Alzheimer Disease; Coordination Complexes; Frontal Lobe; Humans; Ligands; Methane; Microscopy, Fluorescence; Models, Molecular; Optical Imaging; Plaque, Amyloid; Rhenium | 2017 |
N-formylation and N-methylation of amines using metal-free N-heterocyclic carbene catalysts and CO
Topics: Amines; Carbon; Carbon Dioxide; Catalysis; Heterocyclic Compounds; Methane; Methylation; Nitrogen | 2017 |
How the extra methylene group affects the ligation properties of Glu vs. Asp and Gln vs. Asn amino acids: a DFT/PCM study.
Topics: Amino Acid Sequence; Aspartic Acid; Binding Sites; Computer Simulation; Glutamic Acid; Glutamine; Ligands; Methane; Models, Chemical; Protein Binding; Proteins; Thermodynamics | 2017 |
Cyclometalated Gold(III) Complexes Containing N-Heterocyclic Carbene Ligands Engage Multiple Anti-Cancer Molecular Targets.
Topics: Animals; Antineoplastic Agents; Body Weight; Cell Line, Tumor; Cell Proliferation; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Humans; Ligands; Methane; Mice; Molecular Structure; Neoplasms, Experimental; Organogold Compounds; Structure-Activity Relationship | 2017 |
Defining the Anti-Cancer Activity of Tricarbonyl Rhenium Complexes: Induction of G2/M Cell Cycle Arrest and Blockade of Aurora-A Kinase Phosphorylation.
Topics: Antineoplastic Agents; Aurora Kinase A; Cell Line, Tumor; Cell Survival; Coordination Complexes; Crystallography, X-Ray; G2 Phase Cell Cycle Checkpoints; HEK293 Cells; Humans; Ligands; M Phase Cell Cycle Checkpoints; Methane; Molecular Conformation; Phosphorylation; Ruthenium; Structure-Activity Relationship | 2017 |
Highly Diastereo- and Enantioselective Synthesis of Trifluoromethyl-Substituted Cyclopropanes via Myoglobin-Catalyzed Transfer of Trifluoromethylcarbene.
Topics: Catalysis; Cyclopropanes; Hydrocarbons, Fluorinated; Methane; Molecular Structure; Myoglobin; Stereoisomerism | 2017 |
Stereochemical Complexity in Oxocarbenium-Ion-Initiated Cascade Annulations for the Synthesis of the ABCD Core of Mattogrossine.
Topics: Cyclization; Indole Alkaloids; Methane; Stereoisomerism | 2017 |
Is Carbene Formation Necessary for Dissolving Cellulose in Ionic Liquids?
Topics: Cellulose; Ionic Liquids; Methane; Molecular Dynamics Simulation; Molecular Structure | 2017 |
Cytotoxicity of Pyrazine-Based Cyclometalated (C^N
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Crystallography, X-Ray; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Fluorescence Polarization; Humans; Ligands; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Pyrazines; Structure-Activity Relationship | 2017 |
Engineering of RuMb: Toward a Green Catalyst for Carbene Insertion Reactions.
Topics: Catalysis; Coordination Complexes; Methane; Molecular Structure; Myoglobin; Protein Engineering | 2017 |
Steroid-Au
Topics: Animals; Anti-Bacterial Agents; Coordination Complexes; Drug Discovery; Escherichia coli; Gold; Heterocyclic Compounds; Larva; Methane; Microbial Sensitivity Tests; Moths; Staphylococcus aureus; Steroids; Structure-Activity Relationship | 2017 |
Novel NHC Precursors: Synthesis, Characterization, and Carbonic Anhydrase and Acetylcholinesterase Inhibitory Properties.
Topics: Acetylcholinesterase; Carbonic Anhydrase I; Carbonic Anhydrase II; Carbonic Anhydrase Inhibitors; Cholinesterase Inhibitors; Dose-Response Relationship, Drug; Heterocyclic Compounds; Humans; Imidazolidines; Ligands; Methane; Molecular Structure; Structure-Activity Relationship | 2017 |
Anti-trypanosomal activity of cationic N-heterocyclic carbene gold(I) complexes.
Topics: Antiprotozoal Agents; Cell Survival; Coordination Complexes; Epithelial Cells; Flagella; Gold; HeLa Cells; Humans; Inhibitory Concentration 50; Methane; Parasitic Sensitivity Tests; Trypanosoma brucei brucei | 2017 |
NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings.
Topics: Aldehydes; Alkynes; Catalysis; Heterocyclic Compounds; Ligands; Methane; Molecular Conformation; Nickel; Oxidation-Reduction; Quantum Theory; Stereoisomerism | 2017 |
A new method to reduce false positive results in breast MRI by evaluation of multiple spectral regions in proton MR-spectroscopy.
Topics: Algorithms; Area Under Curve; Breast Neoplasms; Choline; Female; Humans; Magnetic Resonance Imaging; Methane; Prospective Studies; Protons; Radiography; Sensitivity and Specificity; Signal-To-Noise Ratio; Water | 2017 |
A Carbene Catalysis Strategy for the Synthesis of Protoilludane Natural Products.
Topics: Biological Products; Catalysis; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Polycyclic Sesquiterpenes; Sesquiterpenes | 2017 |
α-Unsubstituted Pyrroles by NHC-Catalyzed Three-Component Coupling: Direct Synthesis of a Versatile Atorvastatin Derivative.
Topics: Atorvastatin; Catalysis; Chalcone; Heterocyclic Compounds; Methane; Pyrroles | 2017 |
Coinage Metal Complexes of the Carbenic Tautomer of a Conjugated Mesomeric Betaine Akin to Nitron.
Topics: Betaine; Coordination Complexes; Copper; Crystallography, X-Ray; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Structure-Activity Relationship; Triazoles | 2017 |
Anticancer Gold N-Heterocyclic Carbene Complexes: A Comparative in vitro and ex vivo Study.
Topics: Animals; Antineoplastic Agents; Cell Line, Tumor; Heterocyclic Compounds; Humans; Kidney; Male; Methane; Neoplasms; Organogold Compounds; Rats, Wistar | 2017 |
N-Heterocyclic Carbene Coinage Metal Complexes of the Germanium-Rich Metalloid Clusters [Ge₉R₃]
Topics: Coordination Complexes; Crystallography, X-Ray; Germanium; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Stereoisomerism; X-Ray Diffraction | 2017 |
N-Heterocyclic Carbene Catalyzed [3+2] Cycloaddition of Enals with Masked Cinnamates for the Asymmetric One-Pot Synthesis of Adipic Acid Derivatives.
Topics: Adipates; Catalysis; Cinnamates; Cycloaddition Reaction; Cyclopentanes; Methane; Molecular Structure; Stereoisomerism | 2017 |
Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions.
Topics: Benzimidazoles; Carbon; Catalysis; Coordination Complexes; Methane; Nitrogen; Palladium; Salts; Video Recording | 2017 |
Amino Acid Insertion Frequencies Arising from Photoproducts Generated Using Aliphatic Diazirines.
Topics: Amino Acid Sequence; Amino Acids; Chromatography, Liquid; Diazomethane; Indicators and Reagents; Isomerism; Methane; Photolysis; Proteins; Tandem Mass Spectrometry | 2017 |
Kinetic and high-throughput profiling of epigenetic interactions by 3D-carbene chip-based surface plasmon resonance imaging technology.
Topics: Crystallography, X-Ray; DNA; DNA Repair; DNA-Binding Proteins; Epigenesis, Genetic; Epigenomics; Histones; Humans; Kinetics; Methane; Oligonucleotide Array Sequence Analysis; Structure-Activity Relationship; Surface Plasmon Resonance | 2017 |
Cyclometalated iridium(iii) N-heterocyclic carbene complexes as potential mitochondrial anticancer and photodynamic agents.
Topics: Antineoplastic Agents; Apoptosis; Biological Transport; Cell Line, Tumor; Heterocyclic Compounds; Humans; Intracellular Space; Iridium; Membrane Potential, Mitochondrial; Methane; Mitochondria; Organometallic Compounds; Photosensitizing Agents; Reactive Oxygen Species | 2017 |
Organocatalytic Asymmetric Synthesis of trans-γ-Lactams.
Topics: Benzoquinones; Catalysis; Cycloaddition Reaction; Heterocyclic Compounds; Hydrogen Bonding; Lactams; Methane; Oxidation-Reduction; Phosphoric Acids; Stereoisomerism | 2017 |
Catalytic C(sp
Topics: Alkylation; Catalysis; Iron; Methane; Molecular Structure; Stereoisomerism | 2017 |
(C^N
Topics: Antineoplastic Agents; Carbon; Cell Line; Cell Proliferation; Cell Survival; Coordination Complexes; Crystallography, X-Ray; Drug Screening Assays, Antitumor; Glutathione; Gold; Humans; Ligands; MCF-7 Cells; Methane; Molecular Conformation; Nitrogen; Pyrazines; Reactive Oxygen Species | 2017 |
Carbene Footprinting Reveals Binding Interfaces of a Multimeric Membrane-Spanning Protein.
Topics: Amino Acid Sequence; Binding Sites; Chromatography, Liquid; Detergents; Diazomethane; Membrane Proteins; Methane; Micelles; Oxidation-Reduction; Protein Multimerization; Spectrometry, Mass, Electrospray Ionization; Tandem Mass Spectrometry | 2017 |
Experimental and Computational Gas Phase Acidities of Conjugate Acids of Triazolylidene Carbenes: Rationalizing Subtle Electronic Effects.
Topics: Acids; Catalysis; Cations; Electrons; Gases; Methane; Pyrrolidines; Triazoles | 2017 |
Carboxymethylated Dextran-Modified N-Heterocyclic Carbene Self-Assembled Monolayers on Gold for Use in Surface Plasmon Resonance Biosensing.
Topics: Biosensing Techniques; Dextrans; Gold; Methane; Reproducibility of Results; Surface Plasmon Resonance | 2017 |
Benzannulated Re(i)-NHC complexes: synthesis, photophysical properties and antimicrobial activity.
Topics: Anti-Infective Agents; Coordination Complexes; Crystallography, X-Ray; Gram-Negative Bacteria; Gram-Positive Bacteria; Heterocyclic Compounds; Ligands; Methane; Microbial Sensitivity Tests; Molecular Conformation; Rhenium | 2017 |
Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands.
Topics: Catalysis; Ethers; Hydrogen; Kinetics; Ligands; Lignin; Methane; Nickel | 2017 |
Novel Gold and Silver Carbene Complexes Exert Antitumor Effects Triggering the Reactive Oxygen Species Dependent Intrinsic Apoptotic Pathway.
Topics: Antineoplastic Agents; Apoptosis; Cell Proliferation; Cell Survival; Cells, Cultured; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Gold; Humans; Methane; Mitochondria; Reactive Oxygen Species; Silver; Structure-Activity Relationship | 2017 |
Synthesis, characterization, and antileishmanial activity of neutral N-heterocyclic carbenes gold(I) complexes.
Topics: Animals; Antiprotozoal Agents; Cell Line; Dose-Response Relationship, Drug; Heterocyclic Compounds; Leishmania infantum; Macrophages; Methane; Mice; Molecular Structure; Organogold Compounds; Parasitic Sensitivity Tests; Structure-Activity Relationship | 2018 |
Antibacterial effect and DNA delivery using a combination of an arsonium-containing lipophosphoramide with an N-heterocyclic carbene-silver complex - Potential benefits for cystic fibrosis lung gene therapy.
Topics: Anti-Bacterial Agents; Cell Line; Cystic Fibrosis; DNA; Drug Carriers; Gene Transfer Techniques; Genetic Therapy; Gram-Positive Bacteria; Humans; Lung; Methane; Microbial Sensitivity Tests; Nanoparticles; Phosphoramides; Pseudomonas aeruginosa; Silver | 2018 |
N-Heterocyclic Carbene Self-Assembled Monolayers on Gold as Surface Plasmon Resonance Biosensors.
Topics: Biosensing Techniques; Gold; Methane; Reproducibility of Results; Surface Plasmon Resonance | 2017 |
Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds.
Topics: Biological Products; Carbon; Catalysis; Cytochrome P-450 Enzyme System; Hydrogen; Hydrogen Bonding; Methane; Models, Molecular; Molecular Structure; Rhodium; Steroids; Vitamin E | 2017 |
Aptamer-mediated selective delivery of a cytotoxic cationic NHC-Au(i) complex to cancer cells.
Topics: Antineoplastic Agents; Aptamers, Nucleotide; Base Sequence; Cell Line, Tumor; Cell Survival; Gold; Humans; Methane; Organometallic Compounds | 2017 |
Migratory Insertion of Carbenes into Au(III)-C Bonds.
Topics: Carbon; Catalysis; Gold; Kinetics; Ligands; Methane; Molecular Structure; Thermodynamics | 2018 |
N-Heterocyclic Carbene Boranes as Reactive Oxygen Species-Responsive Materials: Application to the Two-Photon Imaging of Hypochlorous Acid in Living Cells and Tissues.
Topics: Animals; Boranes; HeLa Cells; Hippocampus; Humans; Hypochlorous Acid; Methane; Mice; Microscopy, Fluorescence, Multiphoton; Oxidation-Reduction; RAW 264.7 Cells; Reactive Oxygen Species | 2018 |
Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution.
Topics: Alkenes; Catalysis; Cyclopropanes; Hemeproteins; Ligands; Methane; Porphyrins; Quantum Theory | 2018 |
Mechanism of intersubunit ketosynthase-dehydratase interaction in polyketide synthases.
Topics: Acyl Carrier Protein; Acyltransferases; Bacteria; Cross-Linking Reagents; Hydro-Lyases; Lyases; Magnetic Resonance Spectroscopy; Markov Chains; Methane; Mutagenesis; Phylogeny; Polyketide Synthases; Protein Binding; Protein Domains; Protein Structure, Secondary | 2018 |
An organocatalyzed Stetter reaction as a bio-inspired tool for the synthesis of nucleic acid-based bioconjugates.
Topics: Biomimetics; Catalysis; Chemistry Techniques, Synthetic; Glycoconjugates; Glycosylation; Heterocyclic Compounds; Methane; Nucleic Acids; Nucleosides; Pyrroles; Surface-Active Agents; Thymidine | 2018 |
Asymmetric Induction via a Helically Chiral Anion: Enantioselective Pentacarboxycyclopentadiene Brønsted Acid-Catalyzed Inverse-Electron-Demand Diels-Alder Cycloaddition of Oxocarbenium Ions.
Topics: Catalysis; Chromans; Crystallography, X-Ray; Cycloaddition Reaction; Cyclopentanes; Electrons; Ions; Methane; Models, Molecular; Molecular Structure; Stereoisomerism | 2018 |
Supported Au Nanoparticles with N-Heterocyclic Carbene Ligands as Active and Stable Heterogeneous Catalysts for Lactonization.
Topics: Catalysis; Dendrimers; Gold; Heterocyclic Compounds; Lactones; Ligands; Metal Nanoparticles; Methane; Molecular Structure; Particle Size; Surface Properties | 2018 |
Harnessing the β-Silicon Effect for Regioselective and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization by Donor/Acceptor Carbenes Derived from 1-Sulfonyl-1,2,3-triazoles.
Topics: Catalysis; Methane; Molecular Structure; Rhodium; Silicon; Stereoisomerism; Triazoles | 2018 |
Polycyclic Indoline-Benzodiazepines through Electrophilic Additions of α-Imino Carbenes to Tröger Bases.
Topics: Benzodiazepines; Catalysis; Imines; Indoles; Methane; Models, Molecular; Polycyclic Compounds; Rhodium; Stereoisomerism; Triazoles | 2018 |
Self-Assembled N-Heterocyclic Carbene-Based Carboxymethylated Dextran Monolayers on Gold as a Tunable Platform for Designing Affinity-Capture Biosensor Surfaces.
Topics: Biosensing Techniques; Dextrans; Gold; Methane | 2018 |
Iodine-catalyzed diazo activation to access radical reactivity.
Topics: Alkenes; Catalysis; Chemistry, Organic; Iodine; Light; Methane; Pyrroles; Temperature | 2018 |
Catalytic iron-carbene intermediate revealed in a cytochrome
Topics: Bacterial Proteins; Crystallography, X-Ray; Directed Molecular Evolution; Methane; Porphyrins; Rhodothermus; Transferases | 2018 |
Carbene in Cupredoxin Protein Scaffolds: Replacement of a Histidine Ligand in the Active Site Substantially Alters Copper Redox Properties.
Topics: Azurin; Catalytic Domain; Copper; Electrochemical Techniques; Electron Spin Resonance Spectroscopy; Heterocyclic Compounds; Histidine; Ligands; Methane; Mutagenesis, Site-Directed; Oxidation-Reduction; Spectrophotometry | 2018 |
Exploring diversity in platinum(iv) N-heterocyclic carbene complexes: synthesis, characterization, reactivity and biological evaluation.
Topics: Antineoplastic Agents; Cell Line, Tumor; Chemistry Techniques, Synthetic; Dimethyl Sulfoxide; Drug Resistance, Neoplasm; Drug Stability; Glutathione; Heterocyclic Compounds; Humans; Methane; Models, Molecular; Molecular Conformation; Organoplatinum Compounds; Oxidation-Reduction; Water | 2018 |
Pharmacomodulation on Gold-NHC complexes for anticancer applications - is lipophilicity the key point?
Topics: Antineoplastic Agents; Cell Line; Cell Proliferation; Cell Survival; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; Hydrophobic and Hydrophilic Interactions; Methane; Models, Molecular; Molecular Structure; Structure-Activity Relationship | 2018 |
Mechanochemical Activation of Fluorogenic CuAAC "Click" Reactions for Stress-Sensing Applications.
Topics: Alkynes; Azides; Catalysis; Copper; Cycloaddition Reaction; Fluorescent Dyes; Methane; Molecular Structure; Organometallic Compounds; Polymers | 2018 |
Synthesis and Cytotoxicity Studies of Novel NHC*-Gold(I) Complexes Derived from Lepidiline A.
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Survival; Gold; Heterocyclic Compounds; Humans; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Structure-Activity Relationship; X-Ray Diffraction | 2018 |
Novel and Versatile Imine-N-Heterocyclic Carbene Half-Sandwich Iridium(III) Complexes as Lysosome-Targeted Anticancer Agents.
Topics: A549 Cells; Antineoplastic Agents; Apoptosis; Cell Cycle; Cell Survival; Coordination Complexes; Crystallography, X-Ray; Flow Cytometry; Heterocyclic Compounds; Humans; Imines; Iridium; Ligands; Lysosomes; Magnetic Resonance Spectroscopy; Methane; Microscopy, Confocal; Models, Molecular | 2018 |
Self-assembling Properties of an N-Heterocyclic Carbene-based Metallosurfactant: Pd-Coordination Induced Formation of Reactive Interfaces in Water.
Topics: Bromides; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Imidazoles; Iodides; Ligands; Liquid Crystals; Methane; Micelles; Molecular Conformation; Organic Chemistry Phenomena; Palladium; Scattering, Radiation; Styrene; Surface Tension; Surface-Active Agents; Water | 2018 |
Enantioselective Synthesis of Indolines, Benzodihydrothiophenes, and Indanes by C-H Insertion of Donor/Donor Carbenes.
Topics: Catalysis; Indans; Indoles; Methane; Oxidation-Reduction; Rhodium; Stereoisomerism; Thiophenes | 2018 |
Synthesis of new allyl palladium complexes bearing purine-based NHC ligands with antiproliferative and proapoptotic activities on human ovarian cancer cell lines.
Topics: Alkenes; Antineoplastic Agents; Apoptosis; Cell Line, Tumor; Cell Proliferation; Chemistry Techniques, Synthetic; Female; Heterocyclic Compounds; Humans; Inhibitory Concentration 50; Ligands; Methane; Organometallic Compounds; Ovarian Neoplasms; Palladium; Purines | 2018 |
A novel mesoionic carbene based highly fluorescent Pd(ii) complex as an endoplasmic reticulum tracker in live cells.
Topics: Cell Survival; Coordination Complexes; Endoplasmic Reticulum; Fluorescent Dyes; HeLa Cells; Humans; Methane; Microscopy, Confocal; Molecular Structure; Palladium; Spectrometry, Fluorescence | 2018 |
Phenoxide chelated Ir(iii) N-heterocyclic carbene complexes: synthesis, characterization, and evaluation of their in vitro anticancer activity.
Topics: A549 Cells; Antineoplastic Agents; Apoptosis; Cell Line, Tumor; Chemistry Techniques, Synthetic; Coordination Complexes; DNA; HeLa Cells; Heterocyclic Compounds; Humans; Hydrolysis; Iridium; Lysosomes; Methane; Mitochondria; Models, Molecular; Molecular Conformation; Structure-Activity Relationship | 2018 |
N-Heterocyclic Carbene-Modified Au-Pd Alloy Nanoparticles and Their Application as Biomimetic and Heterogeneous Catalysts.
Topics: Alloys; Catalysis; Glucose; Gold; Hydrogenation; Methane; Nanoparticles; Oxidation-Reduction; Palladium; Particle Size; Stereoisomerism; Stilbenes; Titanium | 2018 |
Voltaglue Bioadhesives Energized with Interdigitated 3D-Graphene Electrodes.
Topics: Electrodes; Graphite; Kinetics; Methane; Polyesters; Printing, Three-Dimensional | 2018 |
Half-sandwich Iridium
Topics: A549 Cells; Antineoplastic Agents; Drug Screening Assays, Antitumor; Humans; Iridium; Membrane Potential, Mitochondrial; Methane; Molecular Structure | 2018 |
Highly Diastereo- and Enantioselective Synthesis of Nitrile-Substituted Cyclopropanes by Myoglobin-Mediated Carbene Transfer Catalysis.
Topics: Catalysis; Cyclopropanes; Methane; Molecular Structure; Myoglobin; Nitriles; Stereoisomerism | 2018 |
Interaction of a gold(i) dicarbene anticancer drug with human telomeric DNA G-quadruplex: solution and computationally aided X-ray diffraction analysis.
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Crystallography, X-Ray; G-Quadruplexes; Humans; Methane; Models, Molecular; Molecular Structure; Organogold Compounds; Quantum Theory; Solutions; Telomere | 2018 |
Urea Insertion Reaction of Rhodium-Carbenoid.
Topics: Catalysis; Methane; Molecular Structure; Rhodium; Urea | 2018 |
In vitro Anti-atherogenic Properties of N-Heterocyclic Carbene Aurate(I) Compounds.
Topics: Anti-Inflammatory Agents; Blood Platelets; Humans; Methane; Models, Molecular; Organogold Compounds; Platelet Activating Factor; Platelet Aggregation; Platelet Aggregation Inhibitors | 2018 |
BF
Topics: Benzene Derivatives; Boranes; Catalysis; Methane; Molecular Structure | 2018 |
Catalyst-Substrate Effects on Biocompatible SABRE Hyperpolarization.
Topics: Antitubercular Agents; Biocompatible Materials; Catalysis; Cell Line, Tumor; Cell Survival; Coordination Complexes; Deuterium; Humans; Iridium; Isoniazid; Methane; Pyrazinamide; Substrate Specificity | 2019 |
Binding silver to chitooligosaccharides through N-heterocyclic carbenes: Synthesis and antimicrobial activity.
Topics: Anti-Bacterial Agents; Antifungal Agents; Binding Sites; Candida albicans; Chitin; Chitosan; Escherichia coli; Heterocyclic Compounds; Methane; Microbial Sensitivity Tests; Molecular Structure; Oligosaccharides; Pseudomonas aeruginosa; Silver; Staphylococcus aureus | 2019 |
Robust gold nanorods stabilized by bidentate N-heterocyclic-carbene-thiolate ligands.
Topics: Density Functional Theory; Gold; Methane; Microscopy, Electron, Transmission; Nanotubes; Spectrophotometry, Ultraviolet; Sulfhydryl Compounds | 2019 |
NHC-Catalyzed Formal [2+2] Annulations of Allenoates for the Synthesis of Substituted Oxetanes.
Topics: Catalysis; Ethers, Cyclic; Methane; Molecular Structure | 2018 |
A Fluorescent Silver(I) Carbene Complex with Anticancer Properties: Synthesis, Characterization, and Biological Studies.
Topics: Antineoplastic Agents; Cell Proliferation; Cell Survival; Crystallography, X-Ray; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Fluorescent Dyes; Humans; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Silver Compounds; Structure-Activity Relationship; Tumor Cells, Cultured | 2019 |
Physicochemical characteristics and pyrolysis performance of corn stalk torrefied in aqueous ammonia by microwave heating.
Topics: Ammonia; Gas Chromatography-Mass Spectrometry; Hot Temperature; Methane; Microwaves; Polysaccharides; Pyrolysis; Water; Zea mays | 2019 |
A gold(i) biscarbene complex with improved activity as a TrxR inhibitor and cytotoxic drug: comparative studies with different gold metallodrugs.
Topics: Antineoplastic Agents; Apoptosis; Cell Line, Tumor; Enzyme Inhibitors; Gold; Heterocyclic Compounds; Humans; Methane; Models, Molecular; Protein Binding; Thioredoxin-Disulfide Reductase | 2019 |
Total Synthesis of the Reported Structure of Stresgenin B Enabled by the Diastereoselective Cyanation of an Oxocarbenium.
Topics: Density Functional Theory; Dioxoles; Methane; Molecular Conformation; Nitriles; Stereoisomerism | 2018 |
A Ruthenium(II) N-Heterocyclic Carbene (NHC) Complex with Naphthalimide Ligand Triggers Apoptosis in Colorectal Cancer Cells via Activating the ROS-p38 MAPK Pathway.
Topics: Apoptosis; Cell Cycle; Cell Cycle Checkpoints; Cell Line, Tumor; Cell Proliferation; Colorectal Neoplasms; Heterocyclic Compounds; Humans; Ligands; Membrane Potential, Mitochondrial; Methane; Mitochondria; Naphthalimides; p38 Mitogen-Activated Protein Kinases; Reactive Oxygen Species; Ruthenium; Signal Transduction | 2018 |
Fluorescent functionalised naphthalimides and their Au(i)-NHC complexes for potential use in cellular bioimaging.
Topics: Cell Proliferation; Coordination Complexes; Crystallography, X-Ray; Fluorescent Dyes; Gold; Heterocyclic Compounds; Humans; Ligands; Methane; Models, Molecular; Molecular Structure; Naphthalimides; Neoplasms; Tumor Cells, Cultured | 2019 |
Enzymatic assembly of carbon-carbon bonds via iron-catalysed sp
Topics: Alkylation; Animals; Biocatalysis; Carbon; Coenzymes; Cysteine; Cytochrome P-450 Enzyme System; Directed Molecular Evolution; Heme; Hydrogen; Iron; Male; Methane; Serine; Substrate Specificity; Vitamin B 12 | 2019 |
Schisandrin B elicits the Keap1-Nrf2 defense system via carbene reactive metabolite which is less harmful to mice liver.
Topics: Activation, Metabolic; Animals; Cell Survival; Chemical and Drug Induced Liver Injury; Cyclooctanes; Cytochrome P-450 Enzyme System; Hep G2 Cells; Humans; Kelch-Like ECH-Associated Protein 1; Lignans; Liver; Male; Methane; Mice; Microsomes, Liver; NF-E2-Related Factor 2; Polycyclic Compounds; Signal Transduction | 2018 |
Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization.
Topics: Methane; Photochemistry; Photolysis; Polymerization | 2018 |
Novel half-sandwich iridium OˆC (carbene)-Complexes: In vitro and in vivo tumor growth suppression and pro-apoptosis via ROS-mediated cross-talk between mitochondria and lysosomes.
Topics: A549 Cells; Animals; Antineoplastic Agents; Apoptosis; Cell Line, Tumor; Cell Proliferation; Coordination Complexes; Female; HCT116 Cells; HeLa Cells; Hep G2 Cells; HT29 Cells; Humans; Iridium; Ligands; Lysosomes; Methane; Mice; Mice, Inbred BALB C; Mitochondria; Reactive Oxygen Species | 2019 |
Efficient Synthesis of Furfural from Biomass Using SnCl₄ as Catalyst in Ionic Liquid.
Topics: Biomass; Catalysis; Furaldehyde; Ionic Liquids; Methane; Spectrum Analysis; Tin Compounds | 2019 |
Reactivity of Gold(I) Monocarbene Complexes with Protein Targets: A Theoretical Study.
Topics: Arginine; Aspartic Acid; Binding Sites; Catalysis; Coordination Complexes; Cysteine; Glutamine; Gold; Methane; Models, Theoretical; Protein Binding; Proteins; Thermodynamics | 2019 |
Superelectrophilicity of 1,2-Azaborine: Formation of Xenon and Carbon Monoxide Adducts.
Topics: Benzene Derivatives; Boron Compounds; Carbon Monoxide; Cycloaddition Reaction; Lewis Bases; Methane; Quantum Theory; Xenon | 2019 |
Carbene-Catalyzed Enantioselective Decarboxylative Annulations to Access Dihydrobenzoxazinones and Quinolones.
Topics: Catalysis; Methane; Molecular Structure; Quinolones; Stereoisomerism | 2019 |
Revisiting the Mechanism of the Anaerobic Coproporphyrinogen III Oxidase HemN.
Topics: Bacterial Proteins; Biocatalysis; Catalytic Domain; Coproporphyrinogen Oxidase; Coproporphyrinogens; Escherichia coli; Hydrogen; Methane; Protein Binding; Protoporphyrins; S-Adenosylmethionine | 2019 |
Preparation of Titanocene-Gold Compounds Based on Highly Active Gold(I)-N-Heterocyclic Carbene Anticancer Agents: Preliminary in vitro Studies in Renal and Prostate Cancer Cell Lines.
Topics: Antineoplastic Agents; Cell Movement; Cell Proliferation; Cell Survival; Cells, Cultured; Coordination Complexes; Density Functional Theory; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; Methane; Molecular Structure; Organometallic Compounds; Structure-Activity Relationship | 2019 |
Non-aqueous, tissue compliant carbene-crosslinking bioadhesives.
Topics: Adhesives; Animals; Biocompatible Materials; Cross-Linking Reagents; Humans; Methane; Platelet Activation; Platelet-Rich Plasma; Polyamines; Polyethylene Glycols; Porosity; Stress, Mechanical; Swine; Ultraviolet Rays; Viscosity | 2019 |
Glucose oxidase mimicking half-sandwich nickel(II) complexes of coumarin substituted N-heterocyclic carbenes as novel molecular electrocatalysts for ultrasensitive and selective determination of glucose.
Topics: Biomimetic Materials; Biosensing Techniques; Blood Glucose; Coordination Complexes; Coumarins; Electrochemical Techniques; Electrodes; Glucose Oxidase; Humans; Methane; Models, Molecular; Nickel; Oxidation-Reduction | 2019 |
A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization.
Topics: Density Functional Theory; Methane; Molecular Structure; Polymerization | 2019 |
Selective biocatalytic hydroxylation of unactivated methylene C-H bonds in cyclic alkyl substrates.
Topics: Biocatalysis; Cycloparaffins; Cytochrome P-450 Enzyme System; Hydroxylation; Methane; Molecular Structure; Sphingomonadaceae; Substrate Specificity | 2019 |
Topics: Boron Compounds; Esters; Methane; Molecular Structure; Oxygen; Spectrum Analysis | 2019 |
Isolating Free Carbenes, their Mixed Dimers and Organic Radicals.
Topics: Catalysis; Magnetic Resonance Spectroscopy; Methane | 2019 |
Room temperature N-heterocyclic carbene manganese catalyzed selective N-alkylation of anilines with alcohols.
Topics: Alcohols; Alkylation; Aniline Compounds; Catalysis; Heterocyclic Compounds; Manganese; Methane; Temperature | 2019 |
Solid-phase synthesis of biocompatible N-heterocyclic carbene-Pd catalysts using a sub-monomer approach.
Topics: Biocompatible Materials; Catalysis; Cell Survival; Heterocyclic Compounds; Humans; Ligands; MCF-7 Cells; Methane; Molecular Structure; Palladium; Solid-Phase Synthesis Techniques | 2019 |
PepFoot: A Software Package for Semiautomated Processing of Protein Footprinting Data.
Topics: Automation, Laboratory; Binding Sites; Hydroxyl Radical; Information Storage and Retrieval; Mass Spectrometry; Methane; Protein Footprinting; Software | 2019 |
Catalytically Active N-Heterocyclic Carbene Release from Single-Chain Nanoparticles Following a Thermolysis-Driven Unfolding Strategy.
Topics: Catalysis; Cross-Linking Reagents; Heterocyclic Compounds; Methane; Molecular Structure; Nanoparticles; Silver; Temperature | 2019 |
Chemical tuning for potential antitumor fluoroquinolones.
Topics: 3T3 Cells; Animals; Antineoplastic Agents; Dermatitis, Phototoxic; Drug Design; Fluoroquinolones; Halogens; Lasers; Methane; Mice; Mice, Inbred BALB C; Microscopy, Confocal; Photochemistry; Quinolones; Singlet Oxygen | 2019 |
Synthesis of podophyllotoxin-glycosyl triazoles
Topics: Antineoplastic Agents; Cell Line, Tumor; Click Chemistry; Cycloaddition Reaction; Drug Screening Assays, Antitumor; Humans; Methane; Molecular Docking Simulation; Podophyllotoxin; Silver; Structure-Activity Relationship; Topoisomerase II Inhibitors; Triazoles | 2021 |
Synthesis and in-depth studies on the anticancer activity of novel palladacyclopentadienyl complexes stabilized by N-Heterocyclic carbene ligands.
Topics: Antineoplastic Agents; Cell Line; Cell Proliferation; Cell Survival; Coordination Complexes; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Humans; Ligands; Methane; Models, Molecular; Molecular Structure; Structure-Activity Relationship | 2019 |
Tumor vasodilation by N-Heterocyclic carbene-based nitric oxide delivery triggered by high-intensity focused ultrasound and enhanced drug homing to tumor sites for anti-cancer therapy.
Topics: Animals; Cell Line, Tumor; Cell Proliferation; Chickens; Doxorubicin; Drug Delivery Systems; Drug Liberation; Female; Heterocyclic Compounds; High-Intensity Focused Ultrasound Ablation; Methane; Mice, Inbred BALB C; Mice, Nude; Micelles; Neoplasms; Nitric Oxide; Temperature; Tissue Distribution; Vasodilation | 2019 |
Antibacterial and transfection activities of nebulized formulations incorporating long n-alkyl chain silver N-heterocyclic carbene complexes.
Topics: Aerosols; Anti-Bacterial Agents; Bronchi; Cell Line; Cell Survival; DNA; Epithelial Cells; Escherichia coli; Humans; Luciferases; Methane; Plasmids; Pseudomonas aeruginosa; Silver; Staphylococcus aureus; Transfection | 2019 |
Copper-Hydride-Catalyzed Enantioselective Processes with Allenyl Boronates. Mechanistic Nuances, Scope, and Utility in Target-Oriented Synthesis.
Topics: Alkadienes; Alkaloids; Boronic Acids; Catalysis; Copper; Cycloaddition Reaction; Heterocyclic Compounds; Indolizines; Methane; Molecular Structure; Piperidines; Stereoisomerism | 2019 |
Intramolecular Carbene C-H Insertion Reactions of 2-Diazo-2-sulfamoylacetamides.
Topics: Acetamides; Carbon; Catalysis; Diazonium Compounds; Hydrogen; Methane; Sulfonamides | 2019 |
Neutral iridium(iii) complexes bearing BODIPY-substituted N-heterocyclic carbene (NHC) ligands: synthesis, photophysics, in vitro theranostic photodynamic therapy, and antimicrobial activity.
Topics: Anti-Infective Agents; Boron Compounds; Cell Line, Tumor; Cell Survival; Coordination Complexes; Humans; Iridium; Ligands; Light; Methane; Neoplasms; Photochemotherapy; Photosensitizing Agents; Quantum Theory; Reactive Oxygen Species; Staphylococcus aureus; Theranostic Nanomedicine | 2019 |
Pd Nanocatalyst Adorned on Magnetic Chitosan@
Topics: Catalysis; Chitosan; Imidazoles; Magnetic Phenomena; Methane; Nanotubes, Carbon; Palladium; Spectroscopy, Fourier Transform Infrared; Thermogravimetry | 2019 |
DFT based engineering of N-heterocyclic carbenes to exacerbate its activity for SO
Topics: Density Functional Theory; Heterocyclic Compounds; Methane; Molecular Structure; Sulfamerazine; Sulfur Dioxide | 2019 |
Ruthenium-Catalyzed (
Topics: Alkynes; Antineoplastic Agents, Phytogenic; Boron; Isomerism; Methane; Molecular Structure; Naphthalenes; Ruthenium; Stilbenes | 2019 |
Regio- and Stereospecific Cyclopolymerization of α,ω-Diynes by Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.
Topics: Cations; Coordination Complexes; Diynes; Heterocyclic Compounds; Imidazoles; Methane; Molybdenum; Polymerization; Polymers; Stereoisomerism | 2020 |
Caspase-3 mediated programmed cell death by a gold-stabilised peptide carbene.
Topics: A549 Cells; Amino Acids; Apoptosis; Caspase 3; Coordination Complexes; Density Functional Theory; Fluorescent Dyes; Gold; Humans; Ligands; MCF-7 Cells; Methane; Models, Molecular; Molecular Structure; Optical Imaging; Peptides | 2019 |
New morpholine-liganded palladium(II) N-heterocyclic carbene complexes: Synthesis, characterization, crystal structure, and DNA-binding studies.
Topics: Binding Sites; Coordination Complexes; Crystallography, X-Ray; DNA, Circular; Ligands; Methane; Morpholines; Nitriles; Palladium; Plasmids | 2019 |
Light-Activated, Bioadhesive, Poly(2-hydroxyethyl methacrylate) Brush Coatings.
Topics: Animals; Azirines; Benzoates; Cattle; Meniscus; Methacrylates; Methane; Photochemical Processes; Polymerization; Silicon Dioxide; Surface Properties; Tissue Adhesives; Ultraviolet Rays | 2020 |
Photochemical Reactions in the Synthesis of Protein-Drug Conjugates.
Topics: Animals; Antibodies; Cell Line, Tumor; Copper Radioisotopes; Cycloaddition Reaction; Humans; Isotope Labeling; Ligands; Methane; Mice; Mice, Nude; Neoplasms; Pharmaceutical Preparations; Proteins; Tomography, Emission-Computed, Single-Photon; Transplantation, Heterologous; Ultraviolet Rays | 2020 |
Direct and Chemoselective Synthesis of Tertiary Difluoroketones via Weinreb Amide Homologation with a CHF
Topics: Amides; Hydrocarbons, Fluorinated; Ketones; Methane; Molecular Structure; Stereoisomerism | 2019 |
Pd(NHC)(cinnamyl)Cl-catalyzed Suzuki cross-coupling reaction of aryl sulfonates with arylboronic acids.
Topics: Aminobutyrates; Antihypertensive Agents; Arylsulfonates; Biphenyl Compounds; Catalysis; Drug Combinations; Heterocyclic Compounds; Mesylates; Methane; Palladium; Phosphates; Potassium Compounds; Valsartan | 2020 |
Carbene-Catalyzed Enantioselective Aromatic N-Nucleophilic Addition of Heteroarenes to Ketones.
Topics: Catalysis; Ketones; Methane; Molecular Structure; Stereoisomerism | 2020 |
Synthesis, characterization, and biological studies of multidentate gold(i) and gold(iii) NHC complexes.
Topics: Antineoplastic Agents; Benzimidazoles; Cell Line, Tumor; Coordination Complexes; Drug Stability; Gold; Heterocyclic Compounds; Humans; Methane; Silver | 2019 |
Functionalization of GlucoPyranosides at position 5 by 1,5 C-H insertion of Rh(II)-Carbenes: Dramatic influence of the anomeric configuration.
Topics: Catalysis; Electron Transport; Glycosides; Methane; Rhodium; Stereoisomerism | 2019 |
Cross-linking polyethylene through carbenes.
Topics: Methane; Polyethylene; Polymers | 2019 |
Comparative biological evaluation and G-quadruplex interaction studies of two new families of organometallic gold(I) complexes featuring N-heterocyclic carbene and alkynyl ligands.
Topics: Antineoplastic Agents; Drug Screening Assays, Antitumor; G-Quadruplexes; Humans; Ligands; MCF-7 Cells; Methane; Neoplasms; Organogold Compounds | 2020 |
Highly enantioselective carbene insertion into N-H bonds of aliphatic amines.
Topics: Amines; Amino Acids; Catalysis; Chemistry Techniques, Synthetic; Copper; Hydrogen Bonding; Kinetics; Methane; Molecular Structure; Stereoisomerism; Thiourea | 2019 |
Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy.
Topics: Carbon Dioxide; Catalysis; Methane; Stereoisomerism | 2019 |
Subresidue-Resolution Footprinting of Ligand-Protein Interactions by Carbene Chemistry and Ion Mobility-Mass Spectrometry.
Topics: Amyloid beta-Peptides; Animals; Binding Sites; Chickens; ERRalpha Estrogen-Related Receptor; Humans; Ion Mobility Spectrometry; Ligands; Mass Spectrometry; Methane; Muramidase; Protein Binding; Receptors, Estrogen | 2020 |
Origin of the Breakthrough Productivity of Ruthenium-Cyclic Alkyl Amino Carbene Catalysts in Olefin Metathesis.
Topics: Alkenes; Amines; Catalysis; Coordination Complexes; Heterocyclic Compounds; Methane; Molecular Structure; Ruthenium | 2019 |
Synthesis of Bis-Glyoxylamide Peptidomimetics Derived from Bis-
Topics: Alcohols; Amines; Amino Acids; Esters; Indoles; Isatin; Methane; Models, Molecular; Molecular Structure; Oxygen; Peptidomimetics; X-Rays | 2019 |
A de novo peroxidase is also a promiscuous yet stereoselective carbene transferase.
Topics: Aldehydes; Alkenes; Amines; Biocatalysis; Escherichia coli; Escherichia coli Proteins; Methane; Peroxidases; Substrate Specificity | 2020 |
Synthesis, photophysical and anticancer properties of mitochondria-targeted phosphorescent cyclometalated iridium(III) N-heterocyclic carbene complexes.
Topics: A549 Cells; Animals; Antineoplastic Agents; Coordination Complexes; Humans; Iridium; Methane; Mice; Mice, Nude; Neoplasms, Experimental; Photochemotherapy; Photosensitizing Agents; Xenograft Model Antitumor Assays | 2020 |
N-Heterocyclic Carbenes as Reversible Exciton-Delocalizing Ligands for Photoluminescent Quantum Dots.
Topics: Heterocyclic Compounds; Ligands; Luminescence; Methane; Quantum Dots | 2020 |
Can We Safely Obtain Formal Oxidation States from Centroids of Localized Orbitals?
Topics: Methane; Models, Molecular; Models, Theoretical; Oxidation-Reduction; Protons; Quantum Theory | 2020 |
Cytotoxic Ag(I) and Au(I) NHC-carbenes bind DNA and show TrxR inhibition.
Topics: A549 Cells; Animals; Cattle; Coordination Complexes; Cytotoxins; DNA, Neoplasm; Enzyme Inhibitors; Gold; Hep G2 Cells; Humans; Methane; Rats; Silver; Thioredoxin-Disulfide Reductase | 2020 |
Synthesis, Structure, and Anticancer Activity of Symmetrical and Non-symmetrical Silver(I)-N-Heterocyclic Carbene Complexes.
Topics: Animals; Antineoplastic Agents; Benzimidazoles; Drug Screening Assays, Antitumor; Female; HCT116 Cells; Humans; Inhibitory Concentration 50; K562 Cells; Ligands; Magnetic Resonance Spectroscopy; Male; MCF-7 Cells; Methane; Molecular Structure; Rats; Silver; Spectroscopy, Fourier Transform Infrared; Structure-Activity Relationship; X-Ray Diffraction | 2020 |
Novel fast-acting pyrazole/pyridine-functionalized N-heterocyclic carbene silver complexes assembled with nanoparticles show enhanced safety and efficacy as anticancer therapeutics.
Topics: A549 Cells; Animals; Antineoplastic Agents; Apoptosis; Cell Proliferation; Colonic Neoplasms; Heterocyclic Compounds; Humans; Methane; Mice; Molecular Structure; Nanoparticles; Pyrazoles; Pyridines; Silver; Structure-Activity Relationship; Tumor Cells, Cultured; Xenograft Model Antitumor Assays | 2020 |
Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions.
Topics: Alkenes; Alkylation; Catalysis; Coordination Complexes; Hot Temperature; Hydrocarbons, Aromatic; Methane; Molecular Structure; Nickel; Oxidation-Reduction; Stereoisomerism; Thermodynamics | 2020 |
Multifunctional Au
Topics: Antineoplastic Agents; Cell Line; Cell Proliferation; Cell Survival; Coordination Complexes; Drug Design; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; Methane; Molecular Structure; Optical Imaging; Photochemotherapy; Precision Medicine; Theranostic Nanomedicine | 2020 |
Insight into the Substitution Mechanism of Antitumor Au(I) N-Heterocyclic Carbene Complexes by Cysteine and Selenocysteine.
Topics: Antineoplastic Agents; Cysteine; Density Functional Theory; Gold; Heterocyclic Compounds; Methane; Molecular Structure | 2020 |
Towards the Preparation of Stable Cyclic Amino(ylide)Carbenes.
Topics: Catalysis; Hydrogen; Methane; Molecular Structure; Stereoisomerism; Sulfides | 2020 |
Regioselective Arene C-H Alkylation Enabled by Organic Photoredox Catalysis.
Topics: Alkylation; Catalysis; Cations; Diazonium Compounds; Drug Development; Free Radicals; Hydrocarbons, Aromatic; Metals; Methane; Photochemistry | 2020 |
Potent Inhibition of Thioredoxin Reductase by the Rh Derivatives of Anticancer M(arene/Cp*)(NHC)Cl
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Coordination Complexes; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Enzyme Inhibitors; Heterocyclic Compounds; Humans; Ligands; Metals, Heavy; Methane; Molecular Conformation; Structure-Activity Relationship; Thioredoxin-Disulfide Reductase | 2020 |
Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids.
Topics: Carboxylic Acids; Catalysis; Chemistry Techniques, Synthetic; Heterocyclic Compounds; Ketones; Methane; Oxidation-Reduction; Photochemical Processes | 2020 |
Microenvironment mapping via Dexter energy transfer on immune cells.
Topics: B7-H1 Antigen; Catalysis; Cell Membrane; Cellular Microenvironment; Energy Transfer; Humans; Jurkat Cells; Lymphocytes; Methane; Photochemical Processes; Protein Interaction Mapping; Protein Interaction Maps; Ultraviolet Rays | 2020 |
A luminescent lipid mimetic iridium(III) N-heterocyclic carbene complex for membrane labelling.
Topics: Biomimetics; Heterocyclic Compounds; Iridium; Liposomes; Luminescence; Methane; Molecular Structure; Phospholipids | 2020 |
Lysosome-targeted chemotherapeutics: Anticancer mechanism of N-heterocyclic carbene iridium(III) complex.
Topics: A549 Cells; Antineoplastic Agents; Apoptosis; Carcinoma, Non-Small-Cell Lung; Cell Line, Tumor; Cell Proliferation; Coordination Complexes; Cytochromes c; Drug Screening Assays, Antitumor; HeLa Cells; Heterocyclic Compounds; Humans; Iridium; Lung Neoplasms; Lysosomes; Methane; Microscopy, Confocal; Mitochondria; Organometallic Compounds | 2020 |
Cp
Topics: Humans; Methane; Molecular Structure; Organometallic Compounds; Titanium | 2020 |
Chemoselective N-H insertion catalyzed by a de novo carbene transferase.
Topics: Biocatalysis; Methane; Transferases | 2020 |
Access to Optically Enriched α-Aryloxycarboxylic Esters via Carbene-Catalyzed Dynamic Kinetic Resolution and Transesterification.
Topics: Catalysis; Esterification; Esters; Methane; Stereoisomerism | 2020 |
Modular Chiral
Topics: Catalysis; Heterocyclic Compounds; Ligands; Methane; Nickel; Stereoisomerism | 2020 |
Synthesis, Electrochemical and Spectroscopic Characterization of Selected Quinolinecarbaldehydes and Their Schiff Base Derivatives.
Topics: Acetonitriles; Aldehydes; Chemistry, Organic; Electrochemistry; Gas Chromatography-Mass Spectrometry; Magnetic Resonance Spectroscopy; Mass Spectrometry; Methane; Molecular Conformation; Oxygen; Quinolines; Schiff Bases; Software; Spectrophotometry, Infrared; Spectroscopy, Fourier Transform Infrared; X-Ray Diffraction | 2020 |
The Influence of Various
Topics: Alkenes; Catalysis; Heterocyclic Compounds; Ligands; Methane | 2020 |
The roles of extracellular polymeric substances of Pandoraea sp. XY-2 in the removal of tetracycline.
Topics: Adsorption; Anti-Bacterial Agents; Biotechnology; Burkholderiaceae; Extracellular Polymeric Substance Matrix; Methane; Polymers; Polyproteins; Polysaccharides; Sewage; Spectrometry, Fluorescence; Spectroscopy, Fourier Transform Infrared; Tetracycline; Time Factors; Water Pollutants, Chemical; Water Purification | 2020 |
Toward multifunctional anticancer therapeutics: post-synthetic carbonate functionalisation of asymmetric Au(i) bis-N-heterocyclic carbenes.
Topics: A549 Cells; Antineoplastic Agents; Cell Proliferation; Coordination Complexes; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; Methane; Molecular Structure; Optical Imaging | 2020 |
Enantioselective Diarylcarbene Insertion into Si-H Bonds Induced by Electronic Properties of the Carbenes.
Topics: Electronics; Hydrogen; Methane; Molecular Structure; Silanes; Silicon; Stereoisomerism | 2020 |
Enantioselective Si-H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes.
Topics: Catalysis; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Silanes; Silicon; Stereoisomerism | 2020 |
Organic solvent stability and long-term storage of myoglobin-based carbene transfer biocatalysts.
Topics: Biocatalysis; Methane; Myoglobin; Protein Stability; Solvents | 2020 |
Carbene-Induced Rescue of Catalytic Activity in Deactivated Nitrite Reductase Mutant.
Topics: Catalysis; Copper; Ligands; Methane; Nitrite Reductases | 2020 |
Non-Diazo C-H Insertion Approach to Cyclobutanones through Oxidative Gold Catalysis.
Topics: Carbon; Catalysis; Cyclobutanes; Gold; Hydrogen; Ketones; Methane; Molecular Conformation; Oxidation-Reduction; Quantum Theory | 2020 |
Antiproliferative Activity of Functionalized Histidine-derived Au(I) bis-NHC Complexes for Bioconjugation.
Topics: Antineoplastic Agents; Cell Line; Cell Proliferation; Coordination Complexes; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Histidine; Humans; Methane; Molecular Structure; Optical Imaging; Structure-Activity Relationship | 2020 |
Synthesis of Iron(II)-N-Heterocyclic Carbene Complexes: Paving the Way for a New Class of Antibiotics.
Topics: Anti-Bacterial Agents; Electron Spin Resonance Spectroscopy; Escherichia coli; Heterocyclic Compounds; Hydroxyl Radical; Imidazoles; Iron; Methane; Microbial Sensitivity Tests; Spectrophotometry, Ultraviolet; Staphylococcus aureus; Structure-Activity Relationship | 2020 |
Topics: Animals; Antineoplastic Agents; Cell Proliferation; Drug Screening Assays, Antitumor; Gold; Heterocyclic Compounds; Humans; Iodine Radioisotopes; Ligands; Methane; Mice; Molecular Structure; Positron-Emission Tomography; Tissue Distribution; Tumor Cells, Cultured | 2020 |
Topics: Antineoplastic Agents; Drug Screening Assays, Antitumor; HCT116 Cells; Humans; Methane; Neoplasms; Nuclear Magnetic Resonance, Biomolecular; Organoplatinum Compounds; PC-3 Cells | 2020 |
Alternating Cascade Metathesis Polymerization of Enynes and Cyclic Enol Ethers with Active Ruthenium Fischer Carbenes.
Topics: Alkynes; Ethers, Cyclic; Methane; Molecular Structure; Organometallic Compounds; Polymerization; Ruthenium | 2020 |
Bio- and Medicinally Compatible α-Amino-Acid Modification via Merging Photoredox and N-Heterocyclic Carbene Catalysis.
Topics: Amino Acids; Catalysis; Heterocyclic Compounds; Ketones; Methane; Molecular Structure; Oxidation-Reduction; Stereoisomerism | 2020 |
Mercury(II) Complexes of Anionic
Topics: Crystallography, X-Ray; Heterocyclic Compounds; Ligands; Mercury; Methane; Models, Molecular; Molecular Structure; Stereoisomerism | 2020 |
Synthesis, conformational analysis and antibacterial activity of Au(I)-Ag(I) and Au(I)-Hg(II) heterobimetallic N-heterocyclic carbene complexes.
Topics: Anti-Bacterial Agents; Chemistry Techniques, Synthetic; Coordination Complexes; Copper; Gold; Mercury; Metals, Heavy; Methane; Microbial Sensitivity Tests; Models, Molecular; Molecular Conformation; Silver | 2020 |
An Organometallic Gold(I) Bis-N-Heterocyclic Carbene Complex with Multimodal Activity in Ovarian Cancer Cells.
Topics: Antineoplastic Agents; Caffeine; Cell Line, Tumor; Female; Gold; Humans; Methane; Organometallic Compounds; Ovarian Neoplasms; Proteomics | 2020 |
A Spirocyclic Parabanic Acid Masked N-Heterocyclic Carbene as Thermally Latent Pre-Catalyst for Polyamide 6 Synthesis and Epoxide Curing.
Topics: Caprolactam; Epoxy Compounds; Hydantoins; Methane; Polymers | 2020 |
Carbene modification and reversible crosslinking of silver nanoparticles for controlled antibacterial activity.
Topics: Anti-Bacterial Agents; Escherichia coli; Metal Nanoparticles; Methane; Microbial Sensitivity Tests; Particle Size; Silver; Staphylococcus aureus | 2020 |
The anticancer activity of an air-stable Pd(I)-NHC (NHC = N-heterocyclic carbene) dimer.
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Cell Survival; Coordination Complexes; Dimerization; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Humans; Methane; Molecular Structure; Palladium; Structure-Activity Relationship | 2020 |
Strategies for the expression and characterization of artificial myoglobin-based carbene transferases.
Topics: Metalloproteins; Methane; Myoglobin; Transferases | 2020 |
Unsaturated and Benzannulated
Topics: Carbon Dioxide; Catalysis; Coordination Complexes; Cyclohexenes; Hafnium; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Conformation; Polymerization; Titanium | 2020 |
DFT Investigation of Hydrogen Atom Abstraction from NHC-Boranes by Methyl, Ethyl and Cyanomethyl Radicals-Composition and Correlation Analysis of Kinetic Barriers.
Topics: Boranes; Density Functional Theory; Heterocyclic Compounds; Hydrogen; Kinetics; Methane; Models, Molecular; Temperature | 2020 |
On the reactivity of mRNA Cap0: C-H oxidative addition of 7-methylguanosine to Pt
Topics: Base Pairing; DNA; Guanosine; Hydrogen Bonding; Methane; Platinum; RNA, Messenger | 2020 |
Cyclic (Alkyl)(Amino)Carbene (CAAC) Gold(I) Complexes as Chemotherapeutic Agents.
Topics: Antineoplastic Agents; Auranofin; Cell Line, Tumor; Gold; Humans; Methane | 2021 |
Kinetic Resolution of Aziridines Enabled by N-Heterocyclic Carbene/Copper Cooperative Catalysis: Carbene Dose-Controlled Chemo-Switchability.
Topics: Aziridines; Catalysis; Copper; Cycloaddition Reaction; Heterocyclic Compounds; Isatin; Kinetics; Methane; Oxindoles; Spiro Compounds; Stereoisomerism | 2021 |
In Cellulo Evaluation of the Therapeutic Potential of NHC Platinum Compounds in Metastatic Cutaneous Melanoma.
Topics: Antineoplastic Agents; bcl-X Protein; Cell Death; Cell Line, Tumor; Cell Survival; DNA Breaks, Double-Stranded; DNA Damage; Drug Resistance, Neoplasm; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Humans; Melanoma; Melanoma, Cutaneous Malignant; Methane; Organoplatinum Compounds; Proto-Oncogene Proteins B-raf; Skin Neoplasms | 2020 |
Bioorthogonal Activation of Dual Catalytic and Anti-Cancer Activities of Organogold(I) Complexes in Living Systems.
Topics: Alkynes; Animals; Antineoplastic Agents; Catalysis; Cell Line, Tumor; Cell Survival; Coordination Complexes; Density Functional Theory; Embryo, Nonmammalian; Gold; Humans; Methane; Optical Imaging; Palladium; Zebrafish | 2021 |
Influence of Fluorine Substituents on the Electronic Properties of Selenium-
Topics: Fluorine; Heterocyclic Compounds; Isotopes; Ligands; Magnetic Resonance Spectroscopy; Methane; Selenium; Selenium Compounds | 2020 |
A Combined Spectroscopic and Protein Crystallography Study Reveals Protein Interactions of Rh
Topics: Coordination Complexes; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Models, Molecular; Molecular Structure; Muramidase; Rhodium | 2020 |
Large-Scale Synthesis of a Niche Olefin Metathesis Catalyst Bearing an Unsymmetrical N-Heterocyclic Carbene (NHC) Ligand and its Application in a Green Pharmaceutical Context.
Topics: Alkenes; Green Chemistry Technology; Ligands; Methane; Organometallic Compounds; Ruthenium | 2020 |
On the Different Mode of Action of Au(I)/Ag(I)-NHC Bis-Anthracenyl Complexes Towards Selected Target Biomolecules.
Topics: Algorithms; DNA; Gold; Heterocyclic Compounds; Macromolecular Substances; Methane; Models, Theoretical; Molecular Structure; Nucleic Acid Denaturation; RNA; Serum Albumin, Bovine; Silver; Spectrum Analysis; Structure-Activity Relationship; Thermodynamics | 2020 |
Rationally Designed Redox-Active Au(I) N-Heterocyclic Carbene: An Immunogenic Cell Death Inducer.
Topics: Animals; Antineoplastic Agents; Cell Line, Tumor; Coordination Complexes; Endoplasmic Reticulum Stress; Gold; Heterocyclic Compounds; Humans; Immunogenic Cell Death; Methane; Mice; Neoplasms; Oxidation-Reduction; Reactive Oxygen Species; Transplantation, Heterologous | 2020 |
Probing the Mechanism of Photoaffinity Labeling by Dialkyldiazirines through Bioorthogonal Capture of Diazoalkanes.
Topics: Catalysis; Diazomethane; Diazonium Compounds; Indicators and Reagents; Methane; Molecular Structure | 2020 |
Targeting Telomeres: Molecular Dynamics and Free Energy Simulation of Gold-Carbene Binding to DNA.
Topics: DNA; G-Quadruplexes; Gold; Ligands; Methane; Molecular Dynamics Simulation; Telomere | 2021 |
Rhenium N-heterocyclic carbene complexes block growth of aggressive cancers by inhibiting FGFR- and SRC-mediated signalling.
Topics: Animals; Cell Line, Tumor; Coordination Complexes; Humans; Methane; Mice; Mice, Inbred NOD; Mice, SCID; Reactive Oxygen Species; Receptor, Fibroblast Growth Factor, Type 1; Rhenium; Signal Transduction; src-Family Kinases; Xenograft Model Antitumor Assays; Zebrafish | 2020 |
Transamidation of Amides and Amidation of Esters by Selective N-C(O)/O-C(O) Cleavage Mediated by Air- and Moisture-Stable Half-Sandwich Nickel(II)-NHC Complexes.
Topics: Air; Amides; Aniline Compounds; Catalysis; Chemistry Techniques, Synthetic; Esters; Kinetics; Methane; Nickel; Nitrogen; Organometallic Compounds | 2021 |
Improved Antiproliferative Activity and Fluorescence of a Dinuclear Gold(I) Bisimidazolylidene Complex via Anthracene-Modification.
Topics: Anthracenes; Cell Line; Cell Proliferation; Coordination Complexes; Gold; HeLa Cells; Humans; Imidazolidines; MCF-7 Cells; Methane; Molecular Conformation; Spectrophotometry, Ultraviolet | 2020 |
Luminescent Quantum Dots Stabilized by N-Heterocyclic Carbene Polymer Ligands.
Topics: Carbon-13 Magnetic Resonance Spectroscopy; Heterocyclic Compounds; Ligands; Luminescence; Methane; Microscopy, Electron, Transmission; Polymers; Proton Magnetic Resonance Spectroscopy; Quantum Dots | 2021 |
Synthesis of N-heterocyclic carbene gold(I) complexes.
Topics: Catalysis; Gold; Heterocyclic Compounds; Imidazoles; Imidazolidines; Ligands; Methane; Models, Molecular | 2021 |
Dynamic Kinetic Resolution of α-Trifluoromethyl Hemiaminals without α-Hydrogen via NHC-Catalyzed
Topics: Acylation; Catalysis; Esters; Hydrocarbons, Fluorinated; Hydrogen; Kinetics; Lipase; Methane; Molecular Structure; Stereoisomerism | 2021 |
Total Synthesis of (+)-Hyacinthacine A
Topics: Amines; Benzoin; Catalysis; Cyclization; Furans; Methane; Molecular Structure; Stereoisomerism | 2021 |
Continuous flow synthesis and antimicrobial evaluation of NHC* silver carboxylate derivatives of SBC3 in vitro and in vivo.
Topics: Anti-Bacterial Agents; Coordination Complexes; Fatty Acids; Gram-Negative Bacteria; Gram-Negative Bacterial Infections; Heterocyclic Compounds; Humans; Methane; Models, Molecular; Silver | 2021 |
Probing d- and l-Adrenaline Binding to β
Topics: Amino Acid Motifs; Cross-Linking Reagents; Density Functional Theory; Epinephrine; Gases; Humans; Ion Mobility Spectrometry; Methane; Molecular Structure; Peptide Fragments; Photochemistry; Protein Binding; Receptors, Adrenergic, beta-2; Stereoisomerism; Temperature | 2021 |
Alcohol Dehydrogenases and N-Heterocyclic Carbene Gold(I) Catalysts: Design of a Chemoenzymatic Cascade towards Optically Active β,β-Disubstituted Allylic Alcohols.
Topics: Alcohol Dehydrogenase; Catalysis; Gold; Heterocyclic Compounds; Methane; Molecular Structure; Propanols | 2021 |
Programmable site-selective labeling of oligonucleotides based on carbene catalysis.
Topics: Base Sequence; Carbon-13 Magnetic Resonance Spectroscopy; Catalysis; Cross-Linking Reagents; DNA; DNA-Directed RNA Polymerases; Methane; Oligonucleotides; Promoter Regions, Genetic; Proton Magnetic Resonance Spectroscopy; Rhodium; Staining and Labeling; Substrate Specificity; Viral Proteins | 2021 |
Unveiling Luminescent Ir
Topics: Endoplasmic Reticulum; Iridium; Luminescence; Methane; Molecular Structure; Organometallic Compounds | 2021 |
Insertion of metal carbenes into the anilinic N-H bond of unprotected aminobenzenesulfonamides delivers low nanomolar inhibitors of human carbonic anhydrase IX and XII isoforms.
Topics: Aminobenzoates; Antigens, Neoplasm; Antineoplastic Agents; Carbonic Anhydrase Inhibitors; Carbonic Anhydrase IX; Carbonic Anhydrases; Cell Proliferation; Coordination Complexes; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Humans; Isoenzymes; Methane; Molecular Structure; Structure-Activity Relationship; Sulfonamides; Tumor Cells, Cultured | 2021 |
PEPPSI complexes as potential prodrugs: enzyme inhibition, antioxidant activity, electrochemical characterization, molecular docking analysis.
Topics: Acetylcholinesterase; Binding Sites; Butyrylcholinesterase; Catalysis; Coordination Complexes; Density Functional Theory; Electrochemical Techniques; Enzyme Inhibitors; Ligands; Methane; Molecular Docking Simulation; Palladium; Prodrugs; Pyridines | 2021 |
Silver (I)
Topics: Anti-Bacterial Agents; Bacteria; Catalysis; HEK293 Cells; Heterocyclic Compounds; Humans; Methane; Molecular Structure; Silver | 2021 |
[2+2] Cycloadditions with an Iron Carbene: A Critical Step in Enyne Metathesis.
Topics: Alkynes; Catalysis; Coordination Complexes; Crystallography, X-Ray; Cycloaddition Reaction; Iron; Methane; Molecular Conformation; Quantum Theory | 2021 |
Noncanonical Heme Ligands Steer Carbene Transfer Reactivity in an Artificial Metalloenzyme*.
Topics: Heme; Ligands; Metalloproteins; Methane | 2021 |
Biomimetic Carbene Cascades Enabled Imine Derivative Migration from Carbene
Topics: Biomimetics; Imines; Methane; Molecular Structure; Thiocarbamates; Triazoles | 2021 |
Origin and Control of Chemoselectivity in Cytochrome
Topics: Biocatalysis; Cytochromes c; Hydrogen; Methane; Molecular Structure; Nitrogen; Silicon | 2021 |
Mapping the interaction between eukaryotic initiation factor 4A (eIF4A) and the inhibitor hippuristanol using carbene footprinting and mass spectrometry.
Topics: Eukaryotic Initiation Factor-4A; Mass Spectrometry; Methane; Protein Biosynthesis; Sterols | 2021 |
Synthesis and in vitro anticancer activities of selenium N-heterocyclic carbene compounds.
Topics: Antineoplastic Agents; Apoptosis; Cell Line, Tumor; Cell Survival; Coordination Complexes; Drug Screening Assays, Antitumor; G1 Phase Cell Cycle Checkpoints; Heterocyclic Compounds; Humans; Methane; Reactive Oxygen Species; Selenium; Structure-Activity Relationship | 2021 |
Light-Driven Carbene Catalysis for the Synthesis of Aliphatic and α-Amino Ketones.
Topics: Catalysis; Electrons; Heterocyclic Compounds; Ketones; Light; Methane; Molecular Structure; Stereoisomerism | 2021 |
Mimicking reactive high-valent diiron-
Topics: Biomimetic Materials; Coordination Complexes; Enzymes; Iron; Kinetics; Methane; Models, Molecular; Molecular Conformation | 2021 |
Silver-N-heterocyclic carbene complexes-catalyzed multicomponent reactions: Synthesis, spectroscopic characterization, density functional theory calculations, and antibacterial study.
Topics: Anti-Bacterial Agents; Antifungal Agents; Bacteria; Density Functional Theory; Drug Stability; Fungi; Heterocyclic Compounds; Methane; Microbial Sensitivity Tests; Silver Compounds; Static Electricity; Structure-Activity Relationship; Time Factors | 2021 |
Cyclic (Alkyl)(amino)carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes*.
Topics: Alkenes; Alkynes; Catalysis; Copper; Ligands; Methane; Molecular Structure | 2021 |
Annulation of Enals with Carbamoylpropiolates via NHC-Catalyzed Enolate Pathway: Access to Functionalized Maleimides/Iso-maleimides and Synthesis of Aspergillus FH-X-213.
Topics: Aspergillus; Catalysis; Maleimides; Methane; Stereoisomerism | 2021 |
Novel Ag(I)-NHC complex: synthesis,
Topics: Heterocyclic Compounds; Humans; Male; Methane; Molecular Docking Simulation; Molecular Structure; Spectroscopy, Fourier Transform Infrared | 2022 |
Gold(I) and Gold(III) N-Heterocyclic Carbene Complexes as Antibacterial Agents and Inhibitors of Bacterial Thioredoxin Reductase.
Topics: Anti-Bacterial Agents; Antineoplastic Agents; Cell Line, Tumor; Cell Proliferation; Cell Survival; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Enzyme Inhibitors; Gold; Gram-Negative Bacteria; Gram-Positive Bacteria; Heterocyclic Compounds; Humans; Methane; Microbial Sensitivity Tests; Molecular Structure; Structure-Activity Relationship; Thioredoxin-Disulfide Reductase | 2021 |
Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium-Carbene Catalysts.
Topics: Alkenes; Catalysis; Coordination Complexes; Methane; Molecular Conformation; Ruthenium | 2021 |
Evaluation of Ruthenium(II)
Topics: Anti-Bacterial Agents; Bacteria; Bacterial Infections; Bacterial Proteins; Coordination Complexes; Heterocyclic Compounds; Humans; Methane; Models, Molecular; Ruthenium; Thioredoxin-Disulfide Reductase | 2021 |
N-Heterocyclic Carbene-Catalyzed Formal [3+3] Annulation of Alkynyl Acylazoliums for the Synthesis of Benzofuro[3,2-
Topics: Catalysis; Esters; Methane | 2021 |
Topics: Coordination Complexes; Heterocyclic Compounds; Humans; Methane; Patents as Topic | 2022 |
Exporting Metal-Carbene Chemistry to Live Mammalian Cells: Copper-Catalyzed Intracellular Synthesis of Quinoxalines Enabled by N-H Carbene Insertions.
Topics: Catalysis; Copper; HeLa Cells; Humans; Methane; Molecular Structure; Quinoxalines | 2021 |
Metallaphotoredox-enabled deoxygenative arylation of alcohols.
Topics: Alcohols; Bromides; Carbon; Catalysis; Chlorides; Metals; Methane; Nitrogen; Oxidation-Reduction; Oxygen; Paclitaxel; Photochemistry; Simvastatin | 2021 |
A Tandem Nucleophilic Aminopalladation and Carbene Insertion Sequence for Indole Fused Polycycles.
Topics: Cyclization; Indoles; Methane; Molecular Structure; Polycyclic Compounds | 2021 |
Minimalistic peptidic scaffolds harbouring an artificial carbene-containing amino acid modulate reductase activity.
Topics: Amino Acids; Methane; Molecular Structure; Oxidoreductases; Peptides | 2021 |
Green synthesis of selenium based N-heterocyclic carbene compounds; structural, in-vitro anticancer and molecular docking studies.
Topics: Antineoplastic Agents; Cell Proliferation; Chemistry Techniques, Synthetic; Drug Screening Assays, Antitumor; Heterocyclic Compounds; Humans; Ligands; Methane; Molecular Docking Simulation; Selenium; Tumor Cells, Cultured | 2021 |
Synthesis of Platinum(II) N-Heterocyclic Carbenes Based on Adenosine.
Topics: Adenosine; Methane; Organoplatinum Compounds | 2021 |
Dinuclear gold(I) complexes with
Topics: Antineoplastic Agents; Cell Line, Tumor; Cell Survival; Coordination Complexes; Crystallography, X-Ray; Gold; Humans; Ligands; Methane; Molecular Conformation | 2021 |
Exploring the stability of the NHC-metal bond using thiones as probes.
Topics: Coordination Complexes; Heterocyclic Compounds; Metals, Heavy; Methane; Molecular Structure; Thiones | 2021 |
Topics: Animals; Antineoplastic Agents; Cell Line, Tumor; Cell Survival; Cisplatin; Drug Screening Assays, Antitumor; Fibroblasts; Heterocyclic Compounds; Humans; Inhibitory Concentration 50; Iron Compounds; Methane; Neoplasms; Xenograft Model Antitumor Assays; Zebrafish | 2021 |
Probing N-Heterocyclic Carbene Surfaces with Laser Desorption Ionization Mass Spectrometry.
Topics: Gold; Lasers; Mass Spectrometry; Metal Nanoparticles; Methane | 2021 |
Chelating Phosphine-N-Heterocyclic Carbene Platinum Complexes via Catalytic Asymmetric Hydrophosphination and Their Cytotoxicity Toward MKN74 and MCF7 Cancer Cell Lines.
Topics: Antineoplastic Agents; Chelating Agents; Dose-Response Relationship, Drug; Drug Screening Assays, Antitumor; Humans; Methane; Molecular Structure; Organoplatinum Compounds; Phosphines; Tumor Cells, Cultured | 2021 |
Gold N-Heterocyclic Carbene Catalysts for the Hydrofluorination of Alkynes Using Hydrofluoric Acid: Reaction Scope, Mechanistic Studies and the Tracking of Elusive Intermediates.
Topics: Alkynes; Gold; Heterocyclic Compounds; Hydrofluoric Acid; Methane | 2022 |
Transition metal complexes bearing atropisomeric saturated NHC ligands.
Topics: Catalysis; Coordination Complexes; Ligands; Methane; Stereoisomerism | 2022 |
α-Amino-iso-Butyric Acid Foldamers Terminated with Rhodium(I) N-Heterocyclic Carbene Catalysts.
Topics: Butyric Acid; Catalysis; Heterocyclic Compounds; Iridium; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2022 |
A Chemoenzymatic Cascade Combining a Hydration Catalyst with an Amine Dehydrogenase: Synthesis of Chiral Amines.
Topics: Amination; Amines; Bacillaceae; Gold; Methane; Models, Molecular; Molecular Conformation; Oxidoreductases; Water | 2022 |
Fibrillated bacterial cellulose liquid carbene bioadhesives for mimicking and bonding oral cavity surfaces.
Topics: Cellulose; Humans; Hydrogels; Methane; Mouth | 2022 |
Assembly and Evolution of Artificial Metalloenzymes within
Topics: Carbon; Catalysis; Cytochrome P-450 Enzyme System; Escherichia coli; Evolution, Molecular; Hydrogen; Iridium; Metalloproteins; Methane; Mutagenesis, Site-Directed; Porphyrins; Stereoisomerism | 2022 |
Raman spectroscopic characterization of selenium N-heterocyclic carbene compounds.
Topics: Heterocyclic Compounds; Methane; Selenium; Selenium Compounds; Spectrum Analysis, Raman | 2022 |
N-Heterocyclic Carbene-Promoted [4+2] Annulation of α-Chloro Hydrazones with α-Chloro Aliphatic Aldehydes to Access Enantioenriched Dihydropyridazinones.
Topics: Aldehydes; Heterocyclic Compounds; Hydrazones; Methane; Stereoisomerism | 2022 |
Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions.
Topics: Carbon; Catalysis; Coordination Complexes; Hydrogen; Kinetics; Methane; Rhodium; Stereoisomerism; Thermodynamics | 2022 |
C(sp
Topics: Catalysis; Cyclization; Methane; Palladium | 2022 |
NHC Catalysis for Umpolung Pyridinium Alkylation via Deoxy-Breslow Intermediates.
Topics: Alkylation; Catalysis; Heterocyclic Compounds; Methane | 2022 |
Remote C(sp
Topics: Acylation; Amides; Cyclization; Methane | 2022 |
Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties.
Topics: Ligands; Methane | 2022 |
Carbohydrate-substituted N-heterocyclic carbenes Palladium complexes: High efficiency catalysts for aqueous Suzuki-Miyaura reaction.
Topics: Carbohydrates; Catalysis; Methane; Palladium; Water | 2022 |
Arylopeptoid oligomers functionalised by combinatorial or sequential on-resin click chemistry using a copper(I)-N-heterocyclic carbene catalyst.
Topics: Catalysis; Click Chemistry; Copper; Methane | 2022 |
Carbene-Catalyzed Enantioselective Sulfonylation of Enone Aryl Aldehydes: A New Mode of Breslow Intermediate Oxidation.
Topics: Aldehydes; Catalysis; Methane; Stereoisomerism; Sulfones | 2022 |
β-Lactam and penicillin substituted mesoionic metal carbene complexes.
Topics: beta-Lactams; Coordination Complexes; Methane; Penicillins; Triazoles | 2022 |
Intense Photoinduced Intervalence Charge Transfer in High-Valent Iron Mixed Phenolate/Carbene Complexes.
Topics: Crystallography, X-Ray; Iron; Ligands; Methane; Phenols | 2022 |
A Green Synthesis of Carbene-Metal-Amides (CMAs) and Carboline-Derived CMAs with Potent in vitro and ex vivo Anticancer Activity.
Topics: Amides; Carbolines; Heterocyclic Compounds; Humans; Ligands; Metals; Methane; Molecular Structure; Neoplasms | 2022 |
Enantioselective Seleno-Michael Addition Reactions Catalyzed by a Chiral Bifunctional N-Heterocyclic Carbene with Noncovalent Activation.
Topics: Carbon; Catalysis; Methane; Stereoisomerism | 2022 |
Cobalt(II)-tetraphenylporphyrin-catalysed carbene transfer from acceptor-acceptor iodonium ylides via N-enolate-carbene radicals.
Topics: Catalysis; Cobalt; Methane; Porphyrins | 2022 |
Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N-Heterocyclic Carbene Ligand: Improved Stability and Activity.
Topics: Alkenes; Catalysis; Ligands; Methane; Ruthenium | 2022 |
Radical Acylalkylation of 1,3-Enynes To Access Allenic Ketones via
Topics: Catalysis; Ketones; Methane | 2022 |
Cyanopropyl functionalized benzimidazolium salts and their silver N-heterocyclic carbene complexes: Synthesis, antimicrobial activity, and theoretical analysis.
Topics: Anti-Bacterial Agents; Escherichia coli; Methane; Methicillin-Resistant Staphylococcus aureus; Microbial Sensitivity Tests; Salts; Silver; Structure-Activity Relationship | 2022 |
Dichotomy of platinum(II) and gold(III) carbene intermediates switching from N- to O-selectivity.
Topics: Cyclization; Gold; Methane; Platinum | 2022 |
Hydroxy Mercapto Methylene: The Missing H
Topics: Isomerism; Methane | 2022 |
Divergent Asymmetric Synthesis of Panowamycins, TM-135, and Veramycin F Using C-H Insertion with Donor/Donor Carbenes.
Topics: Biological Products; Catalysis; Humans; Methane; Oxidation-Reduction | 2022 |
Efficient Nicotinamide Adenine Dinucleotide Regeneration with a Rhodium-Carbene Catalyst and Isolation of a Hydride Intermediate.
Topics: Methane; NAD; Oxidation-Reduction; Regeneration; Rhodium | 2022 |
Non-Stabilized Vinyl Anion Equivalents from Styrenes by N-Heterocyclic Carbene Catalysis and Its Use in Catalytic Nucleophilic Aromatic Substitution.
Topics: Anions; Catalysis; Methane; Styrenes | 2022 |
Synthesis and Vibrational Circular Dichroism Analysis of
Topics: Circular Dichroism; Methane; Stereoisomerism | 2022 |
Radical borylation of vinyl azides with NHC-boranes: divergent synthesis of α-boryl ketones and borylated triazoles.
Topics: Azides; Boranes; Ketones; Methane; Triazoles | 2022 |
Synthesis of α-Amino Cyclobutanones via Formal 1,3-Hydroxy Migration Triggered by Formation of α-Imino Rhodium Carbene.
Topics: Catalysis; Methane; Rhodium | 2022 |
Iridium(III)-Catalyzed Asymmetric Site-Selective Carbene C-H Insertion during Late-Stage Transformation.
Topics: Catalysis; Iridium; Methane; Molecular Structure | 2022 |
Cytotoxic properties of rhenium(I) tricarbonyl complexes of N-heterocyclic carbene ligands.
Topics: Antineoplastic Agents; Ligands; Methane; Rhenium | 2022 |
The effects of two gold-N-heterocyclic carbene (NHC) complexes in ovarian cancer cells: a redox proteomic study.
Topics: Antineoplastic Agents; Carcinoma, Ovarian Epithelial; Cell Line, Tumor; Coordination Complexes; Female; Gold; Gold Compounds; Humans; Methane; Ovarian Neoplasms; Oxidation-Reduction; Proteomics | 2022 |
N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of Carbocycle-Fused Uracils via Formal [4 + 2] Annulation/Lactone Formation/Decarboxylation Cascade.
Topics: Catalysis; Decarboxylation; Lactones; Methane; Stereoisomerism | 2022 |
Biocatalytic Carbene Transfer Using Diazirines.
Topics: Azo Compounds; Biocatalysis; Catalysis; Diazomethane; Methane | 2022 |
Unsaturated Copolyesters from Macrolactone/Norbornene: Toward Reaction Kinetics of Metathesis Copolymerization Using Ruthenium Carbene Catalysts.
Topics: Kinetics; Ligands; Methane; Norbornanes; Polymers; Ruthenium | 2022 |
Bis[cyclic (alkyl)(amino)carbene] isomers: Stable
Topics: Alkenes; Ligands; Methane; Rhodium | 2022 |
Carbene and photocatalyst-catalyzed decarboxylative radical coupling of carboxylic acids and acyl imidazoles to form ketones.
Topics: Carboxylic Acids; Catalysis; Imidazoles; Ketones; Methane | 2022 |
Therapeutic
Topics: Antineoplastic Agents; Biological Products; Catalysis; Humans; Methane | 2022 |
Synthesis of Carbene-Metal-Amido (CMA) Complexes and Their Use as Precatalysts for the Activator-Free, Gold-Catalyzed Addition of Carboxylic Acids to Alkynes.
Topics: Alkynes; Carboxylic Acids; Catalysis; Coordination Complexes; Gold; Heterocyclic Compounds; Ligands; Methane | 2022 |
Topics: Alkenes; Alkynes; Humans; Methane; Salts | 2022 |
Carbene-Catalyzed Activation of C-Si Bonds for Chemo- and Enantioselective Cross Brook-Benzoin Reaction.
Topics: Benzoin; Catalysis; Ketones; Methane; Stereoisomerism | 2022 |
Cyclic (amino)(barrelene)carbenes: an original family of CAACs through a novel synthetic pathway.
Topics: Alkynes; Catalysis; Cyclization; Methane | 2022 |
Synthesis of α-Ketoamides via Gold(I) Carbene Intermediates.
Topics: Catalysis; Gold; Methane | 2022 |
Rhodium(I) Carbene-Promoted Enantioselective C-H Functionalization of Simple Unprotected Indoles, Pyrroles and Heteroanalogues: New Mechanistic Insights.
Topics: Catalysis; Indoles; Methane; Pyrroles; Rhodium; Stereoisomerism | 2022 |
Weakly Coordinating
Topics: Amides; Catalysis; Coumarins; Cyclization; Heterocyclic Compounds, 4 or More Rings; Methane | 2022 |
Synthesis of tetrasubstituted allenes
Topics: Alkadienes; Catalysis; Methane; Palladium | 2022 |
An Artificial Metalloenzyme Based on a Copper Heteroscorpionate Enables sp
Topics: Catalysis; Copper; Metalloproteins; Methane | 2022 |
Organocatalytic Three-Component Acyldifluoromethylation of Vinylarenes via
Topics: Aldehydes; Catalysis; Ketones; Methane; Molecular Structure | 2022 |
Catalytic (3 + 2) umpolung annulations of α-thioacyl carbenes with aryl isothiocyanates.
Topics: Catalysis; Imines; Isothiocyanates; Methane; Rhodium | 2022 |
Halo complexes of gold(I) containing glycoconjugate carbene ligands: synthesis, characterization, cytotoxicity and interaction with proteins and DNA model systems.
Topics: Animals; Cattle; DNA; Glycoconjugates; Gold; Ligands; Methane; Models, Molecular | 2022 |
Electroredox carbene organocatalysis with iodide as promoter.
Topics: Aldehydes; Iodides; Methane; Promoter Regions, Genetic | 2022 |
β-Aminosulfonyl Fluorides via Water-Accelerated N-Heterocyclic Carbene Catalysis.
Topics: Catalysis; Fluorides; Methane; Solvents; Sulfur; Water | 2022 |
Bottom-up Synthesis of Water-Soluble Gold Nanoparticles Stabilized by N-Heterocyclic Carbenes: From Structural Characterization to Applications.
Topics: Colloids; Gold; Humans; Ligands; Metal Nanoparticles; Methane; Nitrophenols; Wastewater; Water | 2022 |
Porphyrins and Metalloporphyrins Combined with N-Heterocyclic Carbene (NHC) Gold(I) Complexes for Photodynamic Therapy Application: What Is the Weight of the Heavy Atom Effect?
Topics: Gold; Metalloporphyrins; Methane; Photochemotherapy; Porphyrins; Singlet Oxygen | 2022 |
Enantioselective Synthesis of δ-Carbolinones via N-Heterocyclic Carbene Catalysis.
Topics: Catalysis; Heterocyclic Compounds; Methane; Stereoisomerism | 2022 |
Topics: Alkenes; Catalysis; Cycloaddition Reaction; Methane | 2022 |
Chirality influence on the cytotoxic properties of anionic chiral bis(N-heterocyclic carbene)silver complexes.
Topics: Antineoplastic Agents; Crystallography, X-Ray; Heterocyclic Compounds; Methane; Molecular Structure | 2022 |
Ru(II)-Catalyzed regioselective carbene insertion into β-carbolines and isoquinolines.
Topics: Carbolines; Catalysis; Isoquinolines; Methane; Molecular Structure | 2022 |
Persistent Radicals Derived from N-Heterocyclic Carbenes for Material Applications.
Topics: Animals; Boranes; Cations; Methane; Mice; Nitric Oxide | 2022 |
Synthesis of β-Thiolated-α-arylated Ketones Enabled by Photoredox and
Topics: Aldehydes; Alkenes; Catalysis; Disulfides; Ketones; Methane; Molecular Structure | 2022 |
Antibacterial silver and gold complexes of imidazole and 1,2,4-triazole derived N-heterocyclic carbenes.
Topics: Anti-Bacterial Agents; Coordination Complexes; Gold; Imidazoles; Methane; Microbial Sensitivity Tests; Silver; Staphylococcus aureus; Triazoles | 2022 |
Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy.
Topics: Alcohols; Ketones; Methane; Silver | 2022 |
N-Heterocyclic Carbene (NHC) Silver Complexes as Versatile Chemotherapeutic Agents Targeting Human Topoisomerases and Actin.
Topics: Acetates; Actins; Anti-Infective Agents; Antineoplastic Agents; Coordination Complexes; Gram-Negative Bacteria; Gram-Positive Bacteria; Heterocyclic Compounds; Humans; Iodides; Methane; Silver | 2022 |
Efficient Synthesis of Orphaned Cyclopropanes Using Sulfones as Carbene Equivalents.
Topics: Carbon; Catalysis; Cyclopropanes; Methane; Molecular Structure; Styrenes; Sulfones | 2022 |
Free Aluminylenes: An Emerging Class of Compounds.
Topics: Aluminum; Methane; Oxidation-Reduction; Transition Elements | 2022 |
Chemo- and Regioselective Multiple C(sp
Topics: Malonates; Methane; Molecular Structure; Rhodium | 2022 |
N-Heterocyclic Carbene-Catalyzed [3 + 2] Annulation of 3,3'-Bisoxindoles with α-Bromoenals: Enantioselective Construction of Contiguous Quaternary Stereocenters.
Topics: Catalysis; Indoles; Methane; Stereoisomerism | 2022 |
YfeX - A New Platform for Carbene Transferase Development with High Intrinsic Reactivity.
Topics: Biocatalysis; Catalytic Domain; Methane; Peroxidases; Transferases | 2022 |
N-Heterocyclic carbene-based C-centered Au(I)-Ag(I) clusters with intense phosphorescence and organelle-selective translocation in cells.
Topics: Gold; Ligands; Methane; Organelles | 2022 |
N-Heterocyclic Carbene Modified Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide.
Topics: Catalysis; Heterocyclic Compounds; Hydrogen Peroxide; Methane; Palladium | 2022 |
Ir and NHC Dual Chiral Synergetic Catalysis: Mechanism and Stereoselectivity in γ-Butyrolactone Formation.
Topics: 4-Butyrolactone; Aldehydes; Catalysis; Heterocyclic Compounds; Iridium; Ligands; Methane | 2022 |
Activation of Ammonia by a Carbene-Stabilized Dithiolene Zwitterion.
Topics: Ammonia; Electron Transport; Hydrogen; Methane | 2022 |
Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone.
Topics: Carbon Dioxide; Carbon Monoxide; Methane; Organometallic Compounds | 2022 |
A crystalline cyclic (alkyl)(amino)carbene with a 1,1'-ferrocenylene backbone.
Topics: Methane | 2022 |
Reaching High Stereoselectivity and Activity in Organocatalyzed Ring-Opening Polymerization of Racemic Lactide by the Combined Use of a Chiral (Thio)Urea and a
Topics: Dioxanes; Methane; Plastics; Polyesters; Polymerization; Stereoisomerism; Thiourea; Toluene; Urea | 2022 |
Electronic, geometrical and photophysical facets of five coordinated porphyrin N-heterocyclic carbene transition metals complexes: A theoretical study.
Topics: Carbon; Cobalt; Electronics; Ligands; Manganese; Metalloporphyrins; Metals; Methane; Models, Theoretical; Photosensitizing Agents; Porphyrins | 2023 |
Atroposelective Access to 1,3-Oxazepine-Containing Bridged Biaryls via Carbene-Catalyzed Desymmetrization of Imines.
Topics: Imines; Methane; Oxazepines | 2023 |
An N-heterocyclic carbene iridium(III) complex as a potent anti-cancer stem cell therapeutic.
Topics: Antineoplastic Agents; Caspases; Cytostatic Agents; Iridium; Methane; Neoplastic Stem Cells; Superoxides | 2022 |
BF
Topics: Alkanes; Carbon; Cyclization; Fluorine; Methane | 2022 |
Visible-Light-Promoted Carbene Insertion and Decarbonylation for the Synthesis of α-Substituted γ-Ketoesters.
Topics: Light; Methane | 2022 |
Enantioselective Cyclopropanation Catalyzed by Gold(I)-Carbene Complexes.
Topics: Alkenes; Alkynes; Catalysis; Cyclopropanes; Esters; Gold; Methane; Stereoisomerism | 2022 |
Divergent Pd-catalyzed Functionalization of 4-Oxazolin-2-ones and 4-Methylene-2-oxazolidinones and Synthesis of Heterocyclic-Fused Indoles.
Topics: Catalysis; Ellipticines; Indoles; Methane; Methanol; Oxazolidinones; Palladium | 2022 |
Helicenic N-heterocyclic carbene copper(I) complex displaying circularly polarized blue fluorescence.
Topics: Benzimidazoles; Copper; Ligands; Methane | 2022 |
Three-Electron Nickel(I)/Nickel(0) Half-Bond.
Topics: Bromides; Electrons; Methane; Molecular Structure; Nickel | 2022 |
N-Heterocyclic carbene-catalysed homoenolate addition reaction to 3-cyano-2-imino-2
Topics: Benzopyrans; Catalysis; Methane | 2022 |
Impact of Coordination Mode and Ferrocene Functionalization on the Anticancer Activity of N-Heterocyclic Carbene Half-Sandwich Complexes.
Topics: Antineoplastic Agents; Coordination Complexes; Ligands; Metallocenes; Methane; Reactive Oxygen Species | 2022 |
One-Pot Sequential Synthesis of 3,3'- or 2,3'-Bis(indolyl)methanes by Using 1,3-Dithiane as the Methylene Source.
Topics: Methane | 2022 |
How to Stabilize Carbenes in Enzyme Active Sites without Metal Ions.
Topics: Arginine; Catalytic Domain; Ions; Metals; Methane | 2022 |
Synthesis of 2-Aminofurans and 2-Aminothiophenes through Elemental Sulfur-Promoted Switchable Redox Condensation Reaction of Enaminones with Methylene Nitriles.
Topics: Methane; Nitriles; Oxidation-Reduction; Sulfur | 2022 |
Speciation and Structures in Pt Surface Sites Stabilized by N-Heterocyclic Carbene Ligands Revealed by Dynamic Nuclear Polarization Enhanced Indirectly Detected
Topics: Coordination Complexes; Ligands; Magnetic Resonance Spectroscopy; Methane; Platinum; Transition Elements | 2022 |
A General C-N Cross-Coupling to Synthesize Heteroaryl Amines Using a Palladacyclic N-Heterocyclic Carbene Precatalyst.
Topics: Amines; Chlorides; Methane; Protein Kinase Inhibitors | 2022 |
Nickel Carbene-Mediated One-Carbon Homologative γ-Butyrolactonization.
Topics: 4-Butyrolactone; Methane; Molecular Structure; Nickel; Stereoisomerism | 2022 |
Ambient Temperature Carbene-Mediated Depolymerization: Stoichiometric and Catalytic Reactions of
Topics: Catalysis; Hydrogen; Methane; Temperature | 2022 |
Chemoselective carbene insertion into the N-H bonds of NH
Topics: Amines; Ammonia; Methane; Protons; Silver; Water | 2022 |
Protoglobin-Catalyzed Formation of cis-Trifluoromethyl-Substituted Cyclopropanes by Carbene Transfer.
Topics: Catalysis; Cyclopropanes; Methane; Stereoisomerism | 2023 |
Catalyst Controlled Site- and Stereoselective Rhodium(II) Carbene C(sp
Topics: Catalysis; Methane; Rhodium; Stereoisomerism | 2023 |
Photoinduced Halogen-Atom Transfer by
Topics: Electron Transport; Halogens; Methane | 2023 |
Cu-Catalyzed Methylenation of Alcohols with
Topics: Alcohols; Catalysis; Indicators and Reagents; Methane | 2023 |
N-Heterocyclic Carbene-Catalyzed Aza-Michael-Mannich-Lactamization Cascade for the Enantioselective Synthesis of Pyrazoloquinolin-3-ones.
Topics: Amines; Catalysis; Methane; Stereoisomerism | 2023 |
Theoretical Investigation of Chemoselectivity between C-H Insertion and Amide Insertion in Intramolecular Rhodium-Carbene Reactions.
Topics: Catalysis; Methane; Nitrogen; Rhodium | 2023 |
Residue-Level Characterization of Antibody Binding Epitopes Using Carbene Chemical Footprinting.
Topics: Antibodies; Epitope Mapping; Epitopes; Methane | 2023 |
MicroED Structure of a Protoglobin Reactive Carbene Intermediate.
Topics: Electrons; Methane; Peptides; Proteins | 2023 |
Remote Electronic Effect of Chiral N-Heterocyclic Carbene Catalyst on an Asymmetric Benzoin Reaction.
Topics: Benzoin; Catalysis; Methane; Stereoisomerism | 2023 |
Four-Membered Bimetallic Carbon Complex [(M(η
Topics: Methane; Models, Molecular; Protons; Transition Elements | 2023 |
Discovery of the Azaserine Biosynthetic Pathway Uncovers a Biological Route for α-Diazoester Production.
Topics: Azaserine; Biosynthetic Pathways; Methane; Multigene Family; Oxidation-Reduction | 2023 |
Rh(II)-Catalyzed Chemoselective Oxy-alkynylation of Acceptor-Acceptor Carbenes: Synthesis of C2-Quaternary Alkyne-Substituted 3(2
Topics: Alkynes; Azo Compounds; Catalysis; Methane | 2023 |
Reversing the Enantioselectivity of Enzymatic Carbene N-H Insertion Through Mechanism-Guided Protein Engineering.
Topics: Amines; Catalytic Domain; Methane; Protein Engineering | 2023 |
Formation of Highly Stable 1,2-Dicarbonyl Organic Radicals from Cyclic (Alkyl)(amino)carbenes.
Topics: Electrons; Methane; Propiolactone | 2023 |
Carbene-catalyzed chemoselective reaction of unsymmetric enedials for access to Furo[2,3-b]pyrroles.
Topics: Catalysis; Methane; Molecular Structure; Pyrroles | 2023 |
Amphiphilic polymeric nanoparticles enable homogenous rhodium-catalysed NH insertion reactions in living cells.
Topics: Catalysis; HeLa Cells; Humans; Methane; Nanoparticles; Rhodium | 2023 |
Heteroleptic Silver(I) and Gold(I) N-Heterocyclic Carbene Complexes: Structural Characterization, Computational Analysis, Tyrosinase Inhibitory, and Biological Effects.
Topics: Anti-Bacterial Agents; Gold; Humans; Methane; Monophenol Monooxygenase; Silver | 2023 |
Binding Interactions and Inhibition Mechanisms of Gold Complexes in Thiamine Diphosphate-Dependent Enzymes.
Topics: Catalytic Domain; Methane; Protein Binding; Thiamine; Thiamine Pyrophosphate | 2023 |
Mechanistic manifold in a hemoprotein-catalyzed cyclopropanation reaction with diazoketone.
Topics: Catalysis; Heme; Methane; Myoglobin | 2023 |