Page last updated: 2024-09-03

carbene and hydrogen

carbene has been researched along with hydrogen in 78 studies

Compound Research Comparison

Studies
(carbene)
Trials
(carbene)
Recent Studies (post-2010)
(carbene)
Studies
(hydrogen)
Trials
(hydrogen)
Recent Studies (post-2010) (hydrogen)
2,06701,26528,78139911,492

Research

Studies (78)

TimeframeStudies, this research(%)All Research%
pre-19900 (0.00)18.7374
1990's3 (3.85)18.2507
2000's17 (21.79)29.6817
2010's46 (58.97)24.3611
2020's12 (15.38)2.80

Authors

AuthorsStudies
Kushlan, DM; LeMaster, DM1
Campbell, N; Cory, DG; Millis, K; Singer, S; Weybright, P1
Blümich, B; Demco, DE; Schneider, M1
Abdulrahman, AM; Al-Mutabagani, LA; Al-Najjar, IM; Al-Refai, JK; Al-Shabanah, LA1
Kumar, MS; Maity, DK; Mohan, H; Naik, GH; Priyadarsini, KI; Satav, JG; Unnikrishnan, MK1
Bényei, A; Kövér, KE; Somsák, L; Tóth, M1
Binoy, J; Hubert Joe, I; Jayakumar, VS; Kartha, VB; Pradeep, B; Sajan, D; Venkata Krishna, K1
Miethchen, R; Reinke, H; Wegert, A1
Agrawal, PK1
Green, TK; Kirschner, DL1
Deselnicu, M; Fan, H; Ionescu, I; Mukarakate, C; Reid, SA; Tao, C1
Lubell, WD; Pinyol, E; Rao, MH1
Hall, MB; Yang, X1
Andersson, S; Brown, JA; Irvine, S; Kennedy, AR; Kerr, WJ; Nilsson, GN1
Afonso, CA; Candeias, NR; Gois, PM; Veiros, LF1
Hong, CS; Kim, JI; Lee, JH; Lee, SJ; Oh, CH1
Wang, LX; Zhang, YZ; Zhou, QL; Zhu, SF1
Dong, D; Huang, P; Liang, Y; Wang, K; Xiang, D; Zhou, G1
Blake, AJ; Hayes, CJ; Moody, CJ; Smith, MR; Stevens, MF1
Albrecht, M; Krüger, A; Neels, A1
Chen, Y; Panek, JS; Wu, J1
Backes, M; Plietzsch, O; Radius, U; Schaub, T1
Curran, DP; Fensterbank, L; Lacôte, E; Malacria, M; Monot, J; Solovyev, A; Ueng, SH1
Bhadbhade, M; Colbran, SB; McSkimming, A1
Bilodeau, F; Dudding, T; Gravel, M; Thai, K; Wang, L1
Mata, EG; Poeylaut-Palena, AA; Testero, SA1
He, Y; Xue, Y1
Davies, HM; Morton, D1
Che, CM; Huang, JS; Lo, VK; Zhou, CY1
Duarte, F; Toro-Labbé, A1
Hartwig, JF; Sergeev, AG1
Shen, JJ; Xie, XL; Xu, B; Zhou, QL; Zhu, SF1
Berry, JF1
Clark, PG; Keyzers, RA; Lein, M1
Che, CM; Deng, QH; Guo, Z; Wan, XL; Wang, JC; Xu, ZJ; Zhou, CY1
Achard, T; Austeri, M; Guénée, L; Lacour, J; Tortoreto, C; Zeghida, W1
Davies, HM; Dick, AR; Ghosh, D; Morton, D1
DeAngelis, A; Dmitrenko, O; Fox, JM1
González, J; López, LA; Riesgo, L; Vicente, R1
Itami, K; Yamaguchi, AD; Yamaguchi, J1
Aldridge, S; Kelly, MJ; Phillips, N; Tang, CY1
Feng, ZH; Li, QL; Song, HB; Song, LC; Sun, XJ; Xie, ZJ1
Frenking, G; Herbst-Irmer, R; Kratzert, D; Mondal, KC; Niepötter, B; Roesky, HW; Schwarzer, MC; Stalke, D; Tkach, I; Wolf, H1
Ugrinov, A; Zhang, J; Zhao, P1
Ackermann, L; Punji, B; Shevchenko, GA; Song, W1
Appelt, S; Blümich, B; de Gelder, R; Engwerda, AH; Eshuis, N; Feiters, MC; Glöggler, S; Rutjes, FP; Smits, JM; Tessari, M; van Weerdenburg, BJ; Wymenga, SS1
Crudden, CM; Nambo, M1
Hirao, H; Hong, SH; Pooi, B; Xu, X1
Agarwalla, H; Das, A; Ganguly, B; Jana, K; Kesharwani, MK; Maity, A1
Qian, D; Zhang, J1
Castarlenas, R; Di Giuseppe, A; Lahoz, FJ; Oro, LA; Pérez-Torrente, JJ1
Drewello, T; Görls, H; Guldi, DM; Heinemann, FW; Kaufhold, S; Li, J; Petermann, L; Peuntinger, K; Pilz, TD; Rau, S; Schaub, M; Staehle, R; Vos, JG; Wunderlin, M1
Fernández-Alvarez, FJ; García-Orduña, P; Iglesias, M; Lahoz, FJ; Lázaro, G; Oro, LA; Pérez-Torrente, JJ; Polo, V1
John, M; Li, Y; Weske, S; Wiegmann, S1
Hillhouse, GL; Jordan, RF; Olechnowicz, F1
Sax, AF1
Lindsay, VN; Sarpong, R; Viart, HM1
DeAngelis, A; Fox, JM; Panish, R1
Johnson, JA; Mavros, MG; Queeney, KT; Voorhis, TV; Wu, T; Zhukhovitskiy, AV1
Cokoja, M; Drees, M; Herrmann, WA; Jantke, D; Kühn, FE; Pardatscher, L1
Hoveyda, AH; Lee, J; Torker, S1
Hartwig, JF; Saper, NI1
Bacsa, J; Boyarskikh, V; Davies, HML; Liao, K; Musaev, DG; Pickel, TC1
Arnold, FH; Chen, K; Huang, X; Renata, H; Wohlschlager, L; Zhang, RK1
Deng, Z; Ding, W; Ji, X; Liu, WQ; Mo, T; Zhang, Q1
Chen, N; Huang, P; Que, C; Xu, J; Yang, Z1
Gessner, VH; Kroll, A; Schwarz, C; Steinert, H1
Evans, D; Houk, KN; Li, ML; Li, WT; Xu, B; Yang, LL; Zhou, QL; Zhu, SF1
Fettinger, JC; Franz, AK; Jagannathan, JR; Shaw, JT1
Li, Y; Ma, X; Wang, Y; Zhang, L; Zheng, Z1
Jia, CX; Qu, HJ; Xu, H; Yu, HT; Yuan, L1
Dai, L; Gao, YY; Han, YF; Ye, S; Zhang, CL1
Arnold, FH; Garcia-Borràs, M; Houk, KN; Jimenez-Osés, G; Kan, SBJ; Lewis, RD; Tang, A1
Clark, DS; Gu, Y; Hartwig, JF; Huang, J; Keasling, JD; Liu, Z; Mukhopadhyay, A1
Bacsa, J; Cammarota, RC; Davies, HML; Liu, W; Sigman, MS1
Adams, ER; Glushka, JN; Lahm, ME; Popik, VV; Ren, Z; Robinson, GH; Schaefer, HF; Tran, PM; Wang, Y; Wei, P; Xie, Y1
Annibale, VT; Chitnis, SS; Gates, DP; LaPierre, EA; Manners, I; Oldroyd, NL; Walsgrove, HTG1
Ding, ER; Tureček, F; Zhu, H; Zima, V1

Reviews

3 review(s) available for carbene and hydrogen

ArticleYear
Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.
    Chemical Society reviews, 2011, Volume: 40, Issue:4

    Topics: Azo Compounds; Biological Products; Carbon; Catalysis; Hydrogen; Methane; Rhodium; Stereoisomerism

2011
Selective functionalisation of saturated C-H bonds with metalloporphyrin catalysts.
    Chemical Society reviews, 2011, Volume: 40, Issue:4

    Topics: Amination; Carbon; Catalysis; Hydrogen; Hydroxylation; Metalloporphyrins; Methane

2011
C-H bond functionalization: emerging synthetic tools for natural products and pharmaceuticals.
    Angewandte Chemie (International ed. in English), 2012, Sep-03, Volume: 51, Issue:36

    Topics: Alkylation; Biological Products; Carbon; Catalysis; Hydrogen; Imines; Metals; Methane; Pharmaceutical Preparations; Stereoisomerism

2012

Other Studies

75 other study(ies) available for carbene and hydrogen

ArticleYear
Resolution and sensitivity enhancement of heteronuclear correlation for methylene resonances via 2H enrichment and decoupling.
    Journal of biomolecular NMR, 1993, Volume: 3, Issue:6

    Topics: Carbon Isotopes; Escherichia coli; Free Radicals; Hydrocarbons; Hydrogen; Magnetic Resonance Spectroscopy; Methane; Protons; Sensitivity and Specificity; Thioredoxins

1993
Gradient, high-resolution, magic angle spinning 1H nuclear magnetic resonance spectroscopy of intact cells.
    Magnetic resonance in medicine, 1998, Volume: 39, Issue:3

    Topics: 3T3 Cells; Adipocytes; Animals; Cell Count; Cell Differentiation; Cell Line; Cell Membrane; Cell Survival; Choline; Coloring Agents; Diffusion; Hydrocarbons; Hydrogen; Inositol; Lipid Metabolism; Lipids; Magnetic Resonance Spectroscopy; Membrane Lipids; Methane; Mice; Phosphatidylcholines; Phospholipids; Phosphorylcholine; Triglycerides; Trypan Blue

1998
1H NMR imaging of residual dipolar couplings in cross-linked elastomers: dipolar-encoded longitudinal magnetization, double-quantum, and triple-quantum filters.
    Journal of magnetic resonance (San Diego, Calif. : 1997), 1999, Volume: 140, Issue:2

    Topics: Algorithms; Butadienes; Elastomers; Electron Spin Resonance Spectroscopy; Hemiterpenes; Humans; Hydrocarbons; Hydrogen; Magnetic Resonance Spectroscopy; Magnetics; Methane; Pentanes; Polymers; Polystyrenes

1999
Synthesis, characterization, inequivalency of methylene proton and proton lability in the amino ligand of trans-[dichloro[(N-ferrocenyl methyl)amine](eta2-ethene)platinum] complexes.
    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2003, Volume: 59, Issue:6

    Topics: Carbon; Ferrous Compounds; Hydrocarbons; Hydrogen; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Platinum; Protons; Solvents

2003
Role of phenolic O-H and methylene hydrogen on the free radical reactions and antioxidant activity of curcumin.
    Free radical biology & medicine, 2003, Sep-01, Volume: 35, Issue:5

    Topics: Animals; Antineoplastic Agents; Antioxidants; Cobalt Radioisotopes; Curcumin; Free Radicals; Gamma Rays; Hydrocarbons; Hydrogen; Hydroxides; Kinetics; Lipid Peroxidation; Male; Methane; Microsomes, Liver; Oxidation-Reduction; Phenols; Rats; Rats, Wistar; Thiobarbituric Acid Reactive Substances

2003
C-glycosylmethylene carbenes: synthesis of anhydro-aldose tosylhydrazones as precursors; generation and a new synthetic route to exo-glycals.
    Organic & biomolecular chemistry, 2003, Nov-21, Volume: 1, Issue:22

    Topics: Carbon; Cyanides; Dioxanes; Glycosides; Hot Temperature; Hydrazines; Hydrocarbons; Hydrogen; Methane; Models, Chemical; Models, Molecular; Nitrogen; Sodium

2003
NIR-FT Raman and infrared spectra and ab initio computations of glycinium oxalate.
    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2004, Volume: 60, Issue:1-2

    Topics: Carbon; Glycine; Hydrocarbons; Hydrogen; Hydrogen Bonding; Methane; Models, Chemical; Oxalates; Spectrophotometry, Infrared; Spectroscopy, Fourier Transform Infrared; Spectrum Analysis, Raman; Thermodynamics

2004
Synthesis of 2,3- or 1,2-unsaturated derivatives of 2-deoxy-2-trifluoromethylhexopyranoses.
    Carbohydrate research, 2004, Jul-12, Volume: 339, Issue:10

    Topics: Carbohydrate Conformation; Carbohydrates; Chromatography; Chromatography, Thin Layer; Cyanides; Deoxy Sugars; Fluorenes; Glycosides; Hydrocarbons; Hydrogen; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Models, Molecular; Pyrans; X-Rays

2004
Dependence of 1H NMR chemical shifts of geminal protons of glycosyloxy methylene (H2-26) on the orientation of the 27-methyl group of furostane-type steroidal saponins.
    Magnetic resonance in chemistry : MRC, 2004, Volume: 42, Issue:11

    Topics: Hydrocarbons; Hydrogen; Methane; Molecular Structure; Nuclear Magnetic Resonance, Biomolecular; Protons; Saponins; Steroids; Tribulus

2004
Nonaqueous synthesis of a selectively modified, highly anionic sulfopropyl ether derivative of cyclomaltoheptaose (beta-cyclodextrin) in the presence of 18-crown-6.
    Carbohydrate research, 2005, Aug-15, Volume: 340, Issue:11

    Topics: Anions; beta-Cyclodextrins; Carbohydrate Conformation; Carbon; Deuterium Oxide; Electrophoresis, Capillary; Hydrocarbons; Hydrogen; Magnetic Resonance Spectroscopy; Methane; Models, Chemical; Naphthalenes; Potassium; Thiophenes; Ultraviolet Rays

2005
Electronic spectroscopy of the A1A'' <-- X1A' system of CDF.
    Physical chemistry chemical physics : PCCP, 2006, Feb-14, Volume: 8, Issue:6

    Topics: Deuterium; Fluorides; Hydrocarbons; Hydrogen; Methane; Models, Chemical; Quantum Theory; Rotation; Spectrometry, Fluorescence; Vibration

2006
Rigid dipeptide mimics: synthesis of enantiopure C6-functionalized pyrrolizidinone amino acids.
    The Journal of organic chemistry, 2007, Feb-02, Volume: 72, Issue:3

    Topics: Alkylation; Amino Acids; Carbon; Carboxylic Acids; Catalysis; Crystallography, X-Ray; Dimethyl Sulfoxide; Diminazene; Dipeptides; Hydrocarbons; Hydrogen; Hydrogen Bonding; Methane; Models, Chemical; Molecular Mimicry; Molecular Structure; Pyrroles; Pyrrolidinones; Stereoisomerism; Temperature

2007
The catalytic dehydrogenation of ammonia-borane involving an unexpected hydrogen transfer to ligated carbene and subsequent carbon-hydrogen activation.
    Journal of the American Chemical Society, 2008, Feb-13, Volume: 130, Issue:6

    Topics: Ammonia; Boranes; Catalysis; Computer Simulation; Hydrocarbons; Hydrogen; Hydrogenation; Ligands; Methane; Models, Chemical; Nickel; Organometallic Compounds; Quantum Theory

2008
Highly active iridium(I) complexes for catalytic hydrogen isotope exchange.
    Chemical communications (Cambridge, England), 2008, Mar-07, Issue:9

    Topics: Catalysis; Deuterium; Heterocyclic Compounds; Hydrocarbons; Hydrogen; Iridium; Isotope Labeling; Ligands; Magnetic Resonance Spectroscopy; Methane; Models, Molecular; Molecular Structure; Organometallic Compounds; Phosphines

2008
C-H carbene insertion of alpha-diazo acetamides by photolysis in non-conventional media.
    The Journal of organic chemistry, 2008, Aug-01, Volume: 73, Issue:15

    Topics: Carbon; Diazonium Compounds; Hydrogen; Methane; Molecular Structure; Photolysis; Solvents

2008
Intramolecular Huisgen-type cyclization of platinum-bound pyrylium ions with alkenes and subsequent insertion into a benzylic C-H bond.
    Angewandte Chemie (International ed. in English), 2008, Volume: 47, Issue:39

    Topics: Alkenes; Benzene; Carbon; Catalysis; Crystallography, X-Ray; Cyclization; Hydrogen; Ions; Methane; Models, Molecular; Molecular Structure; Platinum Compounds

2008
Copper-catalyzed highly enantioselective carbenoid insertion into Si-H bonds.
    Angewandte Chemie (International ed. in English), 2008, Volume: 47, Issue:44

    Topics: Catalysis; Copper; Hydrogen; Methane; Silanes; Silicon; Stereoisomerism

2008
Efficient and divergent synthesis of cyclophosphamide analogues from 2-arylamino-3-acetyl-5,6-dihydro-4H-pyrans.
    Chemical communications (Cambridge, England), 2008, Dec-14, Issue:46

    Topics: Acetylation; Amines; Cyclophosphamide; Hydrogen; Methane; Models, Molecular; Molecular Structure; Pyrans

2008
Carbene reactivity of 4-diazo-4H-imidazoles toward nucleophiles and aromatic compounds.
    The Journal of organic chemistry, 2009, Dec-18, Volume: 74, Issue:24

    Topics: Alcohols; Amines; Antineoplastic Agents; Azo Compounds; Cyclization; Fluorocarbons; Hydrocarbons, Aromatic; Hydrogen; Imidazoles; Methane; Nitrogen; Oxygen; Photochemistry; Pyridines; Solvents; Temperature

2009
Rhodium-mediated activation of an alkane-type C-H bond.
    Chemical communications (Cambridge, England), 2010, Jan-14, Volume: 46, Issue:2

    Topics: Alkanes; Carbon; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Rhodium

2010
Vinylogous aldol products from chiral crotylsilanes obtained by enantioselective Rh(II) and Cu(I) carbenoid Si-H insertion.
    Organic letters, 2010, May-07, Volume: 12, Issue:9

    Topics: Aldehydes; Copper; Hydrogen; Methane; Rhenium; Silanes; Silicones; Stereoisomerism

2010
Facile C-S, S-H, and S-S bond cleavage using a nickel(0) NHC complex.
    Dalton transactions (Cambridge, England : 2003), 2009, Sep-21, Issue:35

    Topics: Carbon; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogen; Ligands; Methane; Models, Molecular; Molecular Structure; Nickel; Organometallic Compounds; Stereoisomerism; Sulfhydryl Compounds; Sulfur

2009
Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical.
    Organic letters, 2010, Jul-02, Volume: 12, Issue:13

    Topics: Boranes; Free Radicals; Heterocyclic Compounds; Hydrogen; Kinetics; Methane; Molecular Structure; Stereoisomerism

2010
Hydride ion-carrier ability in Rh(I) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand.
    Dalton transactions (Cambridge, England : 2003), 2010, Nov-28, Volume: 39, Issue:44

    Topics: Crystallography, X-Ray; Electrochemistry; Heterocyclic Compounds; Hydrogen; Ions; Ligands; Methane; Niacinamide; Organometallic Compounds; Rhodium; Spectrometry, Mass, Electrospray Ionization; Spectrophotometry, Ultraviolet

2010
NHC-catalyzed intramolecular redox amidation for the synthesis of functionalized lactams.
    Organic letters, 2010, Dec-17, Volume: 12, Issue:24

    Topics: Amination; Catalysis; Heterocyclic Compounds; Hydrogen; Lactams; Methane; Molecular Structure; Oxidation-Reduction

2010
The non-metathetic role of Grubbs' carbene complexes: from hydrogen-free reduction of α,β-unsaturated alkenes to solid-supported sequential cross-metathesis/reduction.
    Chemical communications (Cambridge, England), 2011, Feb-07, Volume: 47, Issue:5

    Topics: Alkenes; Catalysis; Hydrogen; Methane; Microwaves; Molecular Conformation; Molecular Structure

2011
Theoretical investigations on the mechanism of benzoin condensation catalyzed by pyrido[1,2-a]-2-ethyl[1,2,4]triazol-3-ylidene.
    The journal of physical chemistry. A, 2011, Mar-03, Volume: 115, Issue:8

    Topics: Benzaldehydes; Benzoin; Catalysis; Furans; Hydrogen; Methane; Models, Chemical; Molecular Structure; Protons; Pyridines; Quantum Theory; tert-Butyl Alcohol; Triazoles

2011
The mechanism of H2 activation by (amino)carbenes.
    The journal of physical chemistry. A, 2011, Apr-14, Volume: 115, Issue:14

    Topics: Hydrogen; Methane; Quantum Theory

2011
Selective, nickel-catalyzed hydrogenolysis of aryl ethers.
    Science (New York, N.Y.), 2011, Apr-22, Volume: 332, Issue:6028

    Topics: Alcohols; Biomass; Carbon; Catalysis; Chemical Phenomena; Ethers; Hydrocarbons, Aromatic; Hydrogen; Hydrogenation; Ligands; Lignin; Methane; Nickel; Oxygen; Phenyl Ethers; Temperature

2011
Asymmetric N-H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids.
    Angewandte Chemie (International ed. in English), 2011, Nov-25, Volume: 50, Issue:48

    Topics: Amines; Amino Acids; Catalysis; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Phosphoric Acids; Rhodium; Spiro Compounds; Stereoisomerism

2011
The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates.
    Dalton transactions (Cambridge, England : 2003), 2012, Jan-21, Volume: 41, Issue:3

    Topics: Catalysis; Electrons; Hydrogen; Imines; Methane; Models, Theoretical; Molecular Structure; Rhodium

2012
Studies of the H-D exchange mechanism of malonganenone B.
    Organic & biomolecular chemistry, 2012, Mar-07, Volume: 10, Issue:9

    Topics: Deuterium; Diterpenes; Hydrogen; Imidazoles; Kinetics; Methane; Molecular Structure

2012
Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(III) complex of a D4-symmetric Halterman porphyrin ligand.
    Chemical communications (Cambridge, England), 2012, May-07, Volume: 48, Issue:36

    Topics: Carbon; Catalysis; Hydrogen; Iridium; Ligands; Metalloporphyrins; Methane; Silicon; Stereoisomerism; Substrate Specificity

2012
Enol acetal synthesis through carbenoid C-H insertion into tetrahydrofuran catalyzed by CpRu complexes.
    Angewandte Chemie (International ed. in English), 2012, Jun-11, Volume: 51, Issue:24

    Topics: Acetals; Azo Compounds; Carbon; Catalysis; Coordination Complexes; Furans; Hydrogen; Methane; Ruthenium

2012
Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton.
    Chemical communications (Cambridge, England), 2012, Jun-14, Volume: 48, Issue:47

    Topics: Androgens; Androstadienes; Catalysis; Hydrogen; Methane; Oxygen; Rhodium; Silver

2012
Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration.
    Journal of the American Chemical Society, 2012, Jul-04, Volume: 134, Issue:26

    Topics: Azo Compounds; Catalysis; Computer Simulation; Cyclopropanes; Hydrogen; Methane; Molecular Conformation; Rhodium; Stereoisomerism

2012
Catalytic generation of zinc carbenes from alkynes: zinc-catalyzed cyclopropanation and Si-H bond insertion reactions.
    Angewandte Chemie (International ed. in English), 2012, Aug-06, Volume: 51, Issue:32

    Topics: Alkynes; Catalysis; Cyclopropanes; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Silicon; Stereoisomerism; Zinc

2012
Hydrogen shuttling: synthesis and reactivity of a 14-electron iridium complex featuring a bis(alkyl) tethered N-heterocyclic carbene ligand.
    Chemical communications (Cambridge, England), 2012, Dec-21, Volume: 48, Issue:98

    Topics: Electrons; Heterocyclic Compounds; Hydrogen; Iridium; Ligands; Methane; Models, Molecular; Molecular Conformation; Organometallic Compounds

2012
Synthesis, characterization, and electrochemical properties of diiron propaneditellurolate (PDTe) complexes as active site models of [FeFe]-hydrogenases.
    Dalton transactions (Cambridge, England : 2003), 2013, Feb-07, Volume: 42, Issue:5

    Topics: Catalysis; Catalytic Domain; Coordination Complexes; Crystallography, X-Ray; Electrochemical Techniques; Hydrogen; Hydrogenase; Iron; Iron Compounds; Iron-Sulfur Proteins; Methane; Molecular Conformation; Phosphines; Tellurium

2013
Conversion of a singlet silylene to a stable biradical.
    Angewandte Chemie (International ed. in English), 2013, Feb-04, Volume: 52, Issue:6

    Topics: Carbon; Crystallography, X-Ray; Free Radicals; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Quantum Theory; Silicon Compounds; Thermodynamics

2013
Ruthenium(II)/N-heterocyclic carbene catalyzed [3+2] carbocyclization with aromatic N-H ketimines and internal alkynes.
    Angewandte Chemie (International ed. in English), 2013, Jun-24, Volume: 52, Issue:26

    Topics: Alkynes; Amines; Carbon; Catalysis; Hydrogen; Hydrogen Bonding; Imines; Ligands; Metals; Methane; Nitriles; Nitrogen; Protons; Ruthenium; Temperature

2013
Cobalt-catalyzed C-H bond functionalizations with aryl and alkyl chlorides.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2013, Aug-05, Volume: 19, Issue:32

    Topics: Alkylation; Carbon; Catalysis; Chlorides; Cobalt; Heterocyclic Compounds; Hydrogen; Indoles; Methane

2013
Ligand effects of NHC-iridium catalysts for signal amplification by reversible exchange (SABRE).
    Chemical communications (Cambridge, England), 2013, Aug-28, Volume: 49, Issue:67

    Topics: Catalysis; Coordination Complexes; Hydrogen; Iridium; Ligands; Methane; Pyridines

2013
Modular synthesis of triarylmethanes through palladium-catalyzed sequential arylation of methyl phenyl sulfone.
    Angewandte Chemie (International ed. in English), 2014, Jan-13, Volume: 53, Issue:3

    Topics: Antineoplastic Agents; Boronic Acids; Carbon; Catalysis; Dimethyl Sulfoxide; Hydrogen; Methane; Palladium; Sulfones

2014
CH-π and CF-π interactions lead to structural changes of N-heterocyclic carbene palladium complexes.
    Angewandte Chemie (International ed. in English), 2014, Jan-27, Volume: 53, Issue:5

    Topics: Carbon; Coordination Complexes; Crystallography, X-Ray; Fluorine; Heterocyclic Compounds; Hydrogen; Hydrogen Bonding; Methane; Molecular Conformation; Palladium; Quantum Theory; Stereoisomerism

2014
Hydrogen bonding interaction between active methylene hydrogen atoms and an anion as a binding motif for anion recognition: experimental studies and theoretical rationalization.
    The journal of physical chemistry. A, 2014, Apr-10, Volume: 118, Issue:14

    Topics: Anions; Hydrogen; Hydrogen Bonding; Methane; Quantum Theory

2014
Gold-catalyzed cascade reactions for synthesis of carbo- and heterocycles: selectivity and diversity.
    Chemical record (New York, N.Y.), 2014, Volume: 14, Issue:2

    Topics: Carbon; Catalysis; Crystallography, X-Ray; Cyclization; Cycloaddition Reaction; Gold; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Stereoisomerism

2014
Hydride-rhodium(III)-N-heterocyclic carbene catalysts for vinyl-selective H/D exchange: a structure-activity study.
    Chemistry (Weinheim an der Bergstrasse, Germany), 2014, Jul-01, Volume: 20, Issue:27

    Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Deuterium; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Rhodium; Structure-Activity Relationship; Vinyl Compounds

2014
Carbene based photochemical molecular assemblies for solar driven hydrogen generation.
    Dalton transactions (Cambridge, England : 2003), 2014, Sep-28, Volume: 43, Issue:36

    Topics: Catalysis; Coordination Complexes; Electrochemical Techniques; Heterocyclic Compounds; Hydrogen; Ligands; Light; Methane; Molecular Conformation; Pyridines; Ruthenium; Silver; Spectrophotometry

2014
Catalytic hydrodechlorination of benzyl chloride promoted by Rh-N-heterocyclic carbene catalysts.
    ChemSusChem, 2015, Volume: 8, Issue:3

    Topics: Benzyl Compounds; Catalysis; Halogenation; Heterocyclic Compounds; Hydrogen; Methane; Models, Molecular; Molecular Conformation; Rhodium; Silanes

2015
H(C)Ag: a triple resonance NMR experiment for (109) Ag detection in labile silver-carbene complexes.
    Magnetic resonance in chemistry : MRC, 2015, Volume: 53, Issue:4

    Topics: Heterocyclic Compounds; Hydrogen; Isotopes; Magnetic Resonance Spectroscopy; Methane; Organometallic Compounds; Reference Standards; Silver; Temperature

2015
Synthesis and reactivity of NHC-supported Ni2(μ(2)-η(2),η(2)-S2)-bridging disulfide and Ni2(μ-S)2-bridging sulfide complexes.
    Inorganic chemistry, 2015, Mar-16, Volume: 54, Issue:6

    Topics: Disulfides; Heterocyclic Compounds; Hydrogen; Imidazoles; Ligands; Methane; Models, Molecular; Molecular Conformation; Nickel; Organometallic Compounds

2015
Chemical bonding: the orthogonal valence-bond view.
    International journal of molecular sciences, 2015, Apr-21, Volume: 16, Issue:4

    Topics: Hydrogen; Methane; Models, Chemical; Molecular Structure; Quantum Theory; Thermodynamics

2015
Stereodivergent Intramolecular C(sp(3))-H Functionalization of Azavinyl Carbenes: Synthesis of Saturated Heterocycles and Fused N-Heterotricycles.
    Journal of the American Chemical Society, 2015, Jul-08, Volume: 137, Issue:26

    Topics: Amination; Carbon; Catalysis; Cyclization; Furans; Hydrogen; Magnetic Resonance Spectroscopy; Metals; Methane; Models, Chemical; Molecular Structure; Stereoisomerism; Triazoles

2015
Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration.
    Accounts of chemical research, 2016, Jan-19, Volume: 49, Issue:1

    Topics: Alkenes; Catalysis; Cyclization; Diazonium Compounds; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism

2016
Reactions of Persistent Carbenes with Hydrogen-Terminated Silicon Surfaces.
    Journal of the American Chemical Society, 2016, 07-13, Volume: 138, Issue:27

    Topics: Hydrogen; Methane; Models, Molecular; Molecular Conformation; Silicon; Surface Properties

2016
Hydrogen Production and Storage on a Formic Acid/Bicarbonate Platform using Water-Soluble N-Heterocyclic Carbene Complexes of Late Transition Metals.
    ChemSusChem, 2016, Oct-06, Volume: 9, Issue:19

    Topics: Bicarbonates; Catalysis; Formates; Heterocyclic Compounds; Hot Temperature; Hydrogen; Indium; Kinetics; Methane; Rhodium; Solubility; Water

2016
Versatile Homoallylic Boronates by Chemo-, S
    Angewandte Chemie (International ed. in English), 2017, 01-16, Volume: 56, Issue:3

    Topics: Alcohols; Allyl Compounds; Boronic Acids; Catalysis; Copper; Heterocyclic Compounds; Hydrogen; Methane; Molecular Structure; Quantum Theory; Stereoisomerism

2017
Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands.
    Journal of the American Chemical Society, 2017, 12-06, Volume: 139, Issue:48

    Topics: Catalysis; Ethers; Hydrogen; Kinetics; Ligands; Lignin; Methane; Nickel

2017
Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds.
    Nature, 2017, 11-30, Volume: 551, Issue:7682

    Topics: Biological Products; Carbon; Catalysis; Cytochrome P-450 Enzyme System; Hydrogen; Hydrogen Bonding; Methane; Models, Molecular; Molecular Structure; Rhodium; Steroids; Vitamin E

2017
Enzymatic assembly of carbon-carbon bonds via iron-catalysed sp
    Nature, 2019, Volume: 565, Issue:7737

    Topics: Alkylation; Animals; Biocatalysis; Carbon; Coenzymes; Cysteine; Cytochrome P-450 Enzyme System; Directed Molecular Evolution; Heme; Hydrogen; Iron; Male; Methane; Serine; Substrate Specificity; Vitamin B 12

2019
Revisiting the Mechanism of the Anaerobic Coproporphyrinogen III Oxidase HemN.
    Angewandte Chemie (International ed. in English), 2019, 05-06, Volume: 58, Issue:19

    Topics: Bacterial Proteins; Biocatalysis; Catalytic Domain; Coproporphyrinogen Oxidase; Coproporphyrinogens; Escherichia coli; Hydrogen; Methane; Protein Binding; Protoporphyrins; S-Adenosylmethionine

2019
Intramolecular Carbene C-H Insertion Reactions of 2-Diazo-2-sulfamoylacetamides.
    Molecules (Basel, Switzerland), 2019, Jul-19, Volume: 24, Issue:14

    Topics: Acetamides; Carbon; Catalysis; Diazonium Compounds; Hydrogen; Methane; Sulfonamides

2019
Towards the Preparation of Stable Cyclic Amino(ylide)Carbenes.
    Molecules (Basel, Switzerland), 2020, Feb-12, Volume: 25, Issue:4

    Topics: Catalysis; Hydrogen; Methane; Molecular Structure; Stereoisomerism; Sulfides

2020
Enantioselective Diarylcarbene Insertion into Si-H Bonds Induced by Electronic Properties of the Carbenes.
    Journal of the American Chemical Society, 2020, 07-15, Volume: 142, Issue:28

    Topics: Electronics; Hydrogen; Methane; Molecular Structure; Silanes; Silicon; Stereoisomerism

2020
Enantioselective Si-H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes.
    Journal of the American Chemical Society, 2020, 07-08, Volume: 142, Issue:27

    Topics: Catalysis; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Silanes; Silicon; Stereoisomerism

2020
Non-Diazo C-H Insertion Approach to Cyclobutanones through Oxidative Gold Catalysis.
    Angewandte Chemie (International ed. in English), 2020, 09-28, Volume: 59, Issue:40

    Topics: Carbon; Catalysis; Cyclobutanes; Gold; Hydrogen; Ketones; Methane; Molecular Conformation; Oxidation-Reduction; Quantum Theory

2020
DFT Investigation of Hydrogen Atom Abstraction from NHC-Boranes by Methyl, Ethyl and Cyanomethyl Radicals-Composition and Correlation Analysis of Kinetic Barriers.
    Molecules (Basel, Switzerland), 2020, Oct-01, Volume: 25, Issue:19

    Topics: Boranes; Density Functional Theory; Heterocyclic Compounds; Hydrogen; Kinetics; Methane; Models, Molecular; Temperature

2020
Dynamic Kinetic Resolution of α-Trifluoromethyl Hemiaminals without α-Hydrogen via NHC-Catalyzed
    Organic letters, 2021, 02-19, Volume: 23, Issue:4

    Topics: Acylation; Catalysis; Esters; Hydrocarbons, Fluorinated; Hydrogen; Kinetics; Lipase; Methane; Molecular Structure; Stereoisomerism

2021
Origin and Control of Chemoselectivity in Cytochrome
    Journal of the American Chemical Society, 2021, 05-12, Volume: 143, Issue:18

    Topics: Biocatalysis; Cytochromes c; Hydrogen; Methane; Molecular Structure; Nitrogen; Silicon

2021
Assembly and Evolution of Artificial Metalloenzymes within
    Journal of the American Chemical Society, 2022, 01-19, Volume: 144, Issue:2

    Topics: Carbon; Catalysis; Cytochrome P-450 Enzyme System; Escherichia coli; Evolution, Molecular; Hydrogen; Iridium; Metalloproteins; Methane; Mutagenesis, Site-Directed; Porphyrins; Stereoisomerism

2022
Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions.
    Journal of the American Chemical Society, 2022, 02-02, Volume: 144, Issue:4

    Topics: Carbon; Catalysis; Coordination Complexes; Hydrogen; Kinetics; Methane; Rhodium; Stereoisomerism; Thermodynamics

2022
Activation of Ammonia by a Carbene-Stabilized Dithiolene Zwitterion.
    Journal of the American Chemical Society, 2022, 09-14, Volume: 144, Issue:36

    Topics: Ammonia; Electron Transport; Hydrogen; Methane

2022
Ambient Temperature Carbene-Mediated Depolymerization: Stoichiometric and Catalytic Reactions of
    Journal of the American Chemical Society, 2022, 12-21, Volume: 144, Issue:50

    Topics: Catalysis; Hydrogen; Methane; Temperature

2022
Carbene Cross-Linking in Gas-Phase Peptide Ion Scaffolds.
    Journal of the American Society for Mass Spectrometry, 2023, Apr-05, Volume: 34, Issue:4

    Topics: Cations; Diazomethane; Hydrogen; Molecular Dynamics Simulation; Peptides

2023