calyciphylline-a and 3-hydroxybutanal

calyciphylline-a has been researched along with 3-hydroxybutanal* in 1 studies

Other Studies

1 other study(ies) available for calyciphylline-a and 3-hydroxybutanal

ArticleYear
Synthesis of the ABC Ring of Calyciphylline A-Type Alkaloids by a Stereocontrolled Aldol Cyclization: Formal Synthesis of (±)-Himalensine A.
    The Journal of organic chemistry, 2022, 08-05, Volume: 87, Issue:15

    A synthetic approach to a functionalized ABC-tricyclic framework of calyciphilline A-type alkaloids, a building block toward this class of alkaloids, is reported. The key synthetic steps involve a radical cyclization to form the hydroindole system and piperidine ring closure through a stereocontrolled aldol cyclization. The resulting alcohol allows the methyl group to be installed in the bowl-shaped azatricyclic structure; this crucial reaction takes place with configuration retention. The synthesis of azatricyclic compound

    Topics: Aldehydes; Alkaloids; Cyclization; Molecular Structure; Polycyclic Compounds; Stereoisomerism

2022