calixarenes and melamine

calixarenes has been researched along with melamine* in 7 studies

Other Studies

7 other study(ies) available for calixarenes and melamine

ArticleYear
Development and application of a new 25,27-bis(L-phenylalaninemethylester-N-carbonylmethoxy)-26,28-dihydroxy-para-tert-butylcalix[4]arene stationary phase.
    Journal of separation science, 2013, Volume: 36, Issue:3

    A 25,27-bis(L-phenylalaninemethylester-N-carbonylmethoxy)-26,28-dihydroxy- para-tert-butylcalix[4]arene-bonded silica gel stationary phase was synthesized, structurally characterized and used for LC. Its separation mechanism was studied and compared with octadecyl-bonded stationary phase, as well as our previously prepared para-tert-butylcalix[4]arene-1,2-crown-4 stationary phase. Meanwhile, the chromatographic behaviors were investigated by using polycyclic aromatic hydrocarbons, monosubstituted benzenes, anilines, phenols, Tanaka tests solutes, fluoroquinolones, and flavonoids as probes. Mechanisms involved in the chromatographic separation included hydrophobic, π-π and π-electron transfer, hydrogen bonding, and inclusion interactions. Moreover, the column was successfully employed for the analysis of the illegal additive of melamine in milk product.

    Topics: Adsorption; Animals; Calixarenes; Cattle; Chromatography, High Pressure Liquid; Food Contamination; Infant Formula; Milk; Polymers; Triazines

2013
New oxo-bridged calix[2]arene[2]triazine stationary phase for high performance liquid chromatography.
    Journal of chromatography. A, 2012, Feb-03, Volume: 1223

    A new oxo-bridged calix[2]arene[2]triazine bonded stationary phase (OCATS) for high performance liquid chromatography (HPLC) was prepared using 3-aminopropyltriethoxysilane as coupling reagent. The structure of new material was characterized by infrared spectroscopy, elemental analysis and thermogravimetric analysis. The chromatographic performance and retention mechanism of the new stationary phase were evaluated in reversed-phase mode compared with ODS using different solute probes including polycyclic aromatic hydrocarbons (PAHs), mono-substituted benzenes, disubstituted benzene isomers. The new OCATS stationary phase could provide various interactions for different solutes, such as hydrophobic, hydrogen bonding, ππ and inclusion interactions. The synergistic effects resulting from aromatic rings, bridging oxygen atoms and triazine nitrogen atoms and alkyl linkers in the new material improved the separation selectivity by multiple retention mechanisms. The retention behaviors of the analytes on OCATS column were explained with the assistance of quantum chemistry calculation results using DFT-B3LYP/STO-3G* base group. The OCATS column was successfully employed for the analysis of melamine in infant formula.

    Topics: Benzene Derivatives; Calixarenes; Chromatography, High Pressure Liquid; Humans; Infant Formula; Infant, Newborn; Models, Molecular; Polycyclic Aromatic Hydrocarbons; Triazines

2012
Selective self-organization of guest molecules in self-assembled molecular boxes.
    Journal of the American Chemical Society, 2005, Sep-14, Volume: 127, Issue:36

    This article describes the synthesis and binding properties of highly selective noncovalent molecular receptors 1(3).(DEB)6 and 3(3).(DEB)6 for different hydroxyl functionalized anthraquinones 2. These receptors are formed by the self-assembly of three calix[4]arene dimelamine derivative molecules (1 or 3) and six diethylbarbiturate (DEB) molecules to give 1(3).(DEB)6 or 3(3).(DEB)6. Encapsulation of 2 occurs in a highly organized manner; that is, a noncovalent hydrogen-bonded trimer of 2 is formed within the hydrogen-bonded receptors 1(3).(DEB)6 and 3(3).(DEB)6. Both receptors 1(3).(DEB)6 and 3(3).(DEB)6 change conformation from staggered to eclipsed upon complexation to afford a better fit for the 2(3) trimer. The receptor selectivity toward different anthraquinone derivatives 2 has been studied using 1H NMR spectroscopy, X-ray crystallography, UV spectroscopy, and isothermal microcalorimetry (ITC). The pi-pi stacking between the electron-deficient center ring of the anthraquinone derivatives 2a-c and 2e-g and the relatively electron-poor melamine units of the receptor is the driving force for the encapsulation of the guest molecules. The selectivity of the hydrogen-bonded host for the anthraquinone derivatives is the result of steric interactions between the guest molecules and the calix[4]arene aromatic rings of the host.

    Topics: Anthraquinones; Barbiturates; Calixarenes; Crystallography, X-Ray; Models, Molecular; Molecular Structure; Phenols; Triazines

2005
Self-assembly and stability of double rosette nanostructures with biological functionalities.
    Organic & biomolecular chemistry, 2005, Oct-21, Volume: 3, Issue:20

    The syntheses of calix[4]arene dimelamines that are functionalized with alkyl, aminoalkyl, ureido, pyridyl, carbohydrate, amino acid and peptide functionalities, and their self-assembly with barbituric acid or cyanuric acid derivatives into well-defined hydrogen-bonded nanostructures are described. The thermodynamic stability of these hydrogen-bonded assemblies was studied by CD spectroscopy in mixtures of CHCl3 and MeOH. The stability of the assemblies depends on several steric factors and the polarity of the functional groups connected to the assembly components.

    Topics: Amines; Amino Acids; Barbiturates; Calixarenes; Carbohydrates; Circular Dichroism; Hydrogen Bonding; Molecular Conformation; Nanostructures; Peptides; Phenols; Stereoisomerism; Thermodynamics; Triazines

2005
Formation of a hydrogen-bonded receptor assembly in niosomal membranes.
    Journal of the American Chemical Society, 2004, Sep-08, Volume: 126, Issue:35

    The formation of a hydrogen-bonded receptor in niosomal membranes is reported in this communication. The niosomes prepared from non-ionic surfactants C12EO3 and C14EO3 provide a stable system that allows the self-assembly of hydrogen-bonded receptors to occur in contact with aqueous environments. We demonstrate here by CD, TEM and Confocal Microscopy that the incorporation of the building blocks, calix[4]dimelamine 1 and PerBAR, within the niosomal membranes led to the formation of well-defined hydrogen-bonded assembly 13.(PerBAR)6 within these membranes.

    Topics: Barbiturates; Biomimetic Materials; Calixarenes; Circular Dichroism; Hydrogen Bonding; Liposomes; Membranes, Artificial; Perylene; Phenols; Receptors, Cell Surface; Surface-Active Agents; Triazines

2004
Complexation of phenolic guests by endo- and exo-hydrogen-bonded receptors.
    Organic & biomolecular chemistry, 2003, Jul-21, Volume: 1, Issue:14

    This article describes the complexation of phenol derivatives by hydrogen-bonded receptors. These phenol receptors are formed by self-assembly of calix[4]arene dimelamine or tetramelamine derivatives with 5,5-diethylbarbiturate (DEB) or cyanurate derivatives (CYA). The double rosette assemblies 3(3).(DEB)6/(CYA)6 have their phenol-binding functionalities (ureido groups) at the top and at the bottom of the double rosette (exo-receptors). The tetrarosette assemblies 4(3).(DEB)12/(CYA)12 form a cavity with binding sites between the two double rosettes for guest encapsulation (endo-receptors). An intrinsic binding constant Ka of 202 M-1 and 286 M-1 for the binding of 4-nitrophenol to the ureido functionalized exo- and endo-receptors, respectively, was observed. For the exo-receptor a 1:6 stoichiometry was observed while for the endo-receptor 1:4 binding stoichiometry was determined by Job plot and MALDI-TOF MS. The important role that the hydroxy group's acidity plays in the complexation of 4-nitrophenol is clarified by binding studies with different phenol derivatives. The hydrogen-bonded receptors showed a much smaller response towards less acidic phenol derivatives.

    Topics: Barbiturates; Binding Sites; Calixarenes; Hydrogen Bonding; Kinetics; Magnetic Resonance Spectroscopy; Models, Molecular; Molecular Conformation; Phenols; Receptors, Drug; Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; Triazines

2003
Amplification of chirality: the "sergeants and soldiers" principle applied to dynamic hydrogen-bonded assemblies.
    Journal of the American Chemical Society, 2001, Oct-24, Volume: 123, Issue:42

    The amplification of supramolecular chirality has been studied in dynamic chiral hydrogen-bonded assemblies 1(3).(CA)(6) using "Sergeants and Soldiers" experiments. Previously, we have shown that chiral centers present in either the dimelamine component 1 or the cyanurate component CA quantitatively induce one handedness (M or P) in the assembly. This offers the possibility to study the amplification of chirality under two different kinetic regimes. When chiral dimelamines 1 are used, the exchange of chiral components and (M/P)-interconversion, i.e., interconversion between the (M)- and (P)-isomers of assembly 1(3).(CA)(6), take place via identical pathways (condition A). When chiral cyanurates CA are used, the exchange of chiral components occurs much faster than (M/P)-interconversion (condition B). Experimentally, a much stronger chiral amplification is observed under condition B. For example, the observed chiral amplification for a mixture of chiral and achiral components (40:60) is 46% under condition B and 32% under condition A. Kinetic models were developed to fit the experimental data and to simulate chiral amplification in dynamic systems in general. These simulations show that it is theoretically possible that the diastereomeric excess in a dynamic system is more than 99% with less than 1% chiral component present!

    Topics: Barbiturates; Calixarenes; Hydrogen Bonding; Kinetics; Models, Chemical; Phenols; Stereoisomerism; Thermodynamics; Triazines

2001