calix(4)arene and tetrathiafulvalene

calix(4)arene has been researched along with tetrathiafulvalene* in 3 studies

Other Studies

3 other study(ies) available for calix(4)arene and tetrathiafulvalene

ArticleYear
Rationally designed calix[4]arene-pyrrolotetrathiafulvalene receptors for electron-deficient neutral guests.
    The Journal of organic chemistry, 2013, May-17, Volume: 78, Issue:10

    Four upper rim bis-monopyrrolotetrathiafulvalene-calix[4]arene conjugates 2a,b and 3a,b have been efficiently synthesized using a modular construction approach. The new compounds feature a molecular tweezer architecture with a quasi-parallel arrangement of redox-active tetrathiafulvalene (TTF) arms, which serve as the guest binding centers. Complexation studies using UV/vis binding titrations revealed a high affinity of the calixarene-TTF receptors for planar electron-deficient guests, leading to formation of deeply colored charge-transfer complexes in solution. The binding efficiency of the receptors depends on the flexibility of the calixarene scaffolds and the electronic nature of the TTF arms: the highest binding efficiency is shown by receptor 2b, featuring a highly preorganized molecular structure and an electron-rich TTF moiety.

    Topics: Calixarenes; Electrons; Heterocyclic Compounds; Models, Molecular; Molecular Structure; Phenols

2013
Metal-ion-promoted electron transfer between tetrathiafulvalene and quinone units within a calix[4]arene framework and tuning through coordination of the neighboring crown ether with a sodium cation.
    Chemistry, an Asian journal, 2012, Jan-02, Volume: 7, Issue:1

    A new calix[4]arene 1 with tetrathiafulvalene (TTF), quinone, and crown ether units in the lower rim was designed and synthesized with the aim to investigate the possibility to tune the metal-ion promoted electron transfer by coordination of the crown ether unit with additional metal ions. Both absorption and electron spin resonance (ESR) spectroscopic studies clearly indicate that electron transfer occurs efficiently from TTF to the quinone units in the presence of Sc(3+)/Pb(2+)/Zn(2+). Moreover, the intramolecular electron transfer within 1 induced by Zn(2+) can be switched off by addition of Na(+) and further turned on by addition of either Sc(3+) or Pb(2+).

    Topics: Calixarenes; Cations; Crown Ethers; Electron Transport; Heterocyclic Compounds; Ions; Metals, Heavy; Molecular Structure; Phenols; Quinones; Sodium

2012
Anion responsive TTF-appended calix[4]arenes. Synthesis and study of two different conformers.
    The Journal of organic chemistry, 2011, Feb-04, Volume: 76, Issue:3

    Two new cone- and 1,3-alternate-calix[4]arenes (cone-1 and 1,3-alt-1), bearing four modified TTF (tetrathiafulvalene) substituents on the upper rim, have been synthesized. The binding ability of these two sets of conformers for various anions, including F(-), Cl(-), Br(-), I(-), PF6(-), ClO4(-), HSO4(-), CH3COO(-), H2PO4(-), and HP2O7(3-), was tested in organic media by monitoring the changes in their UV/vis and (1)H NMR spectra as a function of added anion, as well as via cyclovoltammetry (CV) (all anions studied as their respective TBA salts). On the basis of the present findings, we propose that incorporation of four TTF units within an overall calix[4]arene-based recognition framework produces a preorganized receptor system that displays a modest preference for the pyrophosphate (HP2O7(3-)) anion.

    Topics: Anions; Calixarenes; Heterocyclic Compounds; Magnetic Resonance Spectroscopy; Molecular Conformation; Molecular Structure; Phenols

2011