calix(4)arene and phenyldiazene

calix(4)arene has been researched along with phenyldiazene* in 1 studies

Other Studies

1 other study(ies) available for calix(4)arene and phenyldiazene

ArticleYear
Phenylene-diimine-capped conjugate of lower rim 1,3-calix[4]arene as molecular receptor for Mg2+ via arm conformational changes followed by aggregation and mimicking the species by molecular mechanics.
    The Journal of organic chemistry, 2014, Jun-20, Volume: 79, Issue:12

    A phenylene-diimine-capped conjugate of lower rim 1,3-calix[4]arene (L) was synthesized, characterized, and shown to selectively bind to Mg(2+) using its capped arms. This results in a selective recognition of Mg(2+) through eliciting fluorescence enhancement of ∼70 fold with a detection limit of 40 ± 5 ppb. However, in the presence of blood serum, the lowest detection limit is 209 ± 10 ppb (0.2 μM). The binding of Mg(2+) to L is authenticated by absorption and (1)H NMR data. The Job's plot derived on the basis of the absorption data showed 1:1 stoichiometry between the receptor and Mg(2+). The 1:1 species was further confirmed through ESI MS, that is, being supported by the isotope peak pattern authenticating the presence of Mg(2+) in the complex. The L binds Mg(2+) octahedrally using the tetradentate L(2-) and two additional acetic acid moieties by bringing conformational changes as studied on the basis of MM computations. The conformational changes that occur in the capped arms upon Mg(2+) binding were supported experimentally by NOESY. AFM and SEM studies showed that spherical particles of L are modified into flower and chain type aggregates upon complexation with Mg(2+), confirming the supramolecular behavior of the species formed.

    Topics: Calixarenes; Imines; Magnesium; Magnetic Resonance Spectroscopy; Phenols; Spectrometry, Fluorescence

2014