brine and 2-2-2-trifluorodiazoethane

brine has been researched along with 2-2-2-trifluorodiazoethane* in 1 studies

Other Studies

1 other study(ies) available for brine and 2-2-2-trifluorodiazoethane

ArticleYear
Brine-Stabilized 2,2,2-Trifluorodiazoethane and Its Application in the Synthesis of CF3-Substituted Cyclopropane α-Amino Acids.
    Organic letters, 2015, Jul-17, Volume: 17, Issue:14

    A facile thermodynamic cyclopropanation of trisubstituted olefinic azlactones with a stock solution of CF3CHN2 in CH3CN is realized. This method shows excellent generality, affording a wide range of trifluoromethyl-substituted cyclopropanes bearing azlactone rings in good to high yields and diastereoselectivities. With the products in hand, the trifluoromethyl-substituted cyclopropane α-amino acids and relative peptide derivatives could be readily obtained.

    Topics: Amino Acids; Azo Compounds; Cyclopropanes; Hydrocarbons, Fluorinated; Molecular Structure; Salts

2015