brevipolide-h and cyclopropane

brevipolide-h has been researched along with cyclopropane* in 1 studies

Other Studies

1 other study(ies) available for brevipolide-h and cyclopropane

Article	Year
Enantioselective synthesis of (+)-brevipolide H. Organic & biomolecular chemistry, 2016, Jul-12, Volume: 14, Issue:28 The enantioselective synthesis of natural brevipolide H is reported for the first time. By way of Sharpless epoxidation of penta-1,4-dien-3-ol, both enantiomerically pure epoxides were converted to the corresponding olefins for cross metathesis. Subsequent transformations, including epoxide ring opening, esterifications, cyclopropanation, oxidation and ring-closing metathesis, provided the target molecule. This synthesis successfully addresses previous shortcomings in preparing brevipolides. Topics: Cyclization; Cyclopropanes; Epoxy Compounds; Esterification; Hyptis; Oxidation-Reduction; Pyrones; Stereoisomerism	2016

Article

Year

Enantioselective synthesis of (+)-brevipolide H.

Organic & biomolecular chemistry, 2016, Jul-12, Volume: 14, Issue:28

The enantioselective synthesis of natural brevipolide H is reported for the first time. By way of Sharpless epoxidation of penta-1,4-dien-3-ol, both enantiomerically pure epoxides were converted to the corresponding olefins for cross metathesis. Subsequent transformations, including epoxide ring opening, esterifications, cyclopropanation, oxidation and ring-closing metathesis, provided the target molecule. This synthesis successfully addresses previous shortcomings in preparing brevipolides.

Topics: Cyclization; Cyclopropanes; Epoxy Compounds; Esterification; Hyptis; Oxidation-Reduction; Pyrones; Stereoisomerism

2016