boron-oxide and sodium-oxide

This study investigates a novel approach to controlling biofilms of the most frequent pathogens implicated in the etiology of biomaterials-associated infections. New bactericidal filler based on a non-toxic glass, belonging to B

Topics: Aluminum Oxide; Biocompatible Materials; Biofilms; Boron Compounds; Dimethylpolysiloxanes; Erythrocytes; Glass; Gram-Negative Bacteria; Gram-Positive Bacteria; Hemolysis; Humans; Microbial Sensitivity Tests; Oxides; Polyurethanes; Silicon Dioxide; Sodium Compounds; Staphylococcus epidermidis; Surface Properties; Tensile Strength; Zinc Oxide

Low-fusing bonding agents have been widely applied in Ti-ceramics restorations. As an important category, borate bonding agents have great potentials in increasing Ti-porcelain bonding. The purpose of this study is to evaluate the effect of borate bonding agent with addition of Na2O and Al2O3 on Ti6Al4V-porcelain bonding. The thermal properties of borate bonding agent, such as glass transition temperature (Tg) and crystallization peak temperature (Tp), were investigated to establish the sintering process. And the coefficient of thermal expansion (CTE) was to evaluate the matching effect of porcelain to Ti6Al4V. The bond strength was analyzed by the three point bending test. The microscopic morphology of the borate bonding agent surface after sintering, the interface of Ti-borate bonding agent-porcelain, and the fracture mode after porcelains fracture, were studied to assess the influence of borate bonding agent on Ti6Al4V-ceramics. With the addition of Na2O and Al2O3, the porcelain residues were observed increased indication on the Ti6Al4V surface after porcelain fracture and the bond strength was acquired the maximum (49.45MPa) in the bonding agent composition of 75.70B2O3-5.92La2O3-11.84SrO-4.67Na2O-1.87Al2O3. Those results suggest that borate bonding agent is an effective way to improve the Ti6Al4V-ceramics bond strength. And the addition of Na2O and Al2O3 strengthen this effect.

Topics: Alloys; Aluminum Oxide; Boron Compounds; Dental Bonding; Dental Porcelain; Lanthanum; Materials Testing; Microscopy, Electron, Scanning; Oxides; Sodium Compounds; Surface Properties; Titanium

Electron paramagnetic resonance (EPR), optical absorption, and FT-IR spectra of vanadyl ions in the sodium-lead borophosphate (Na(2)O-PbO-B(2)O(3)-P(2)O(5)) (SLBP) glass system have been studied. EPR spectra of all the glass samples exhibit resonance signals characteristic of VO(2+) ions. The spin Hamiltonian parameters g and A are found to be independent of the V(2)O(5) content and temperature. The values of the spin Hamiltonian parameters indicate that the VO(2+) ions in SLBP glasses are present in octahedral sites with tetragonal compression. The population difference between Zeeman levels (N) is calculated as a function of temperature for an SLBP glass sample containing 1.0 mol % VO(2+) ions. From the EPR data, the paramagnetic susceptibility (χ) is calculated at different temperatures, and the Curie constant (C) is calculated from the 1/χ versus T graph. The optical absorption spectra of the glass samples show two absorption bands, and they are attributed to V(3+) and V(4+) ions. The optical band gap energy (E(opt)) and Urbach energy (ΔE) are calculated from their ultraviolet absorption edges. It is observed that, as the vanadium ion concentration increases, E(opt) decreases and ΔE increases. The study of the IR absorption spectrum depicts the presence of BO(3), BO(4), PO(3), PO(4), and VO(5) structural units.

Topics: Biocompatible Materials; Boron Compounds; Electron Spin Resonance Spectroscopy; Glass; Ions; Lead; Optical Devices; Oxides; Phosphorus Compounds; Sodium Compounds; Spectroscopy, Fourier Transform Infrared; Temperature; Thermodynamics; Vanadates

Optical and physical properties of Ni2+ doped 20ZnO+xLi2O+(30-x)Na2O+50B2O3 (5≤x≤25) glasses are carried out at room temperature. Powder XRD pattern of all the glass samples confirms the amorphous nature. Several physical parameters are evaluated for all the glasses with respect to the composition. The optical absorption spectra confirm the site symmetry of the Ni2+ doped glasses are near octahedral. Crystal field and inter-electronic repulsion parameters are also evaluated. It is interesting to observe that the optical band gap and Urbach energies exhibit the mixed alkali effect. The FT-IR spectral investigations of Ni2+ doped glasses exhibit characteristic vibrations of BO3 and BO4 units.

Topics: Alkalies; Boron Compounds; Glass; Lithium Compounds; Models, Theoretical; Nickel; Oxides; Sodium Compounds; Spectroscopy, Fourier Transform Infrared; Zinc Oxide

The structural properties of the glass matrix 40SiO(2)·30Na(2)O·1Al(2)O(3)·(29-x)B(2)O(3)·xFe(2)O(3) (mol%), 0.0≤x≤29.0 were studied by X-ray diffraction (XRD), differential thermal analysis (DTA) and Raman and infrared spectroscopy (FT-IR). XRD demonstrated Fe(3)O(4) crystal formation for Fe(2)O(3) concentrations of 29.0 mol%. DTA showed that glass transition and crystallization temperatures changed as a function of Fe(2)O(3) concentration and that these alterations were related to structural change in the glass system. Interesting aspects of Raman and FT-IR spectra were found, and this gives information about of the structure changes in Si-O-Si units of these glasses as a function of Fe(2)O(3) concentration.

Topics: Aluminum Oxide; Boron Compounds; Crystallization; Differential Thermal Analysis; Ferric Compounds; Glass; Molecular Structure; Osmolar Concentration; Oxides; Silicon Dioxide; Sodium Compounds; Spectroscopy, Fourier Transform Infrared; Spectrum Analysis, Raman

New bioactive glasses with compositions based on the CaO-MgO-SiO(2) system and additives of B(2)O(3), P(2)O(5), Na(2)O, and CaF(2) were prepared. The in vitro mineralization behaviour was tested by immersion of powders or bulk glasses in simulated body fluid (SBF). Monitoring of ionic concentrations in SBF and scanning electron microscopy (SEM) observations at the surface of the glasses were conducted over immersion time. Raman and infrared (IR) spectroscopy shed light on the structural evolution occurring at the surface of the glasses that leads to formation of hydroxyapatite.

Topics: Biocompatible Materials; Boron Compounds; Calcium Fluoride; Durapatite; Glass; Infrared Rays; Oxides; Phosphorus Compounds; Sodium Compounds; Spectrum Analysis, Raman

The bioactivity, i.e., bone-bonding ability, of 26 glasses in the system Na2O-K2O-MgO-CaO-B2O3-P2O5-SiO2 was studied in vivo. This investigation of bioactivity was performed to establish the compositional dependence of bioactivity, and enabled a model to be developed that describes the relation between reactions in vivo and glass composition. Reactions in vivo were investigated by inserting glass implants into rabbit tibia for 8 weeks. The glasses and the surrounding tissue were examined using scanning electron microscopy (SEM), light microscopy, and energy-dispersive X-ray analysis (EDXA). For most of the glasses containing < 59 mol % SiO2, SEM and EDXA showed two distinct layers at the glass surface after implantation, one silica-rich and another containing calcium phosphate. The build-up of these layers in vivo was taken as a sign of bioactivity. The in vivo experiments showed that glasses in the investigated system are bioactive when they contain 14-30 mol % alkali oxides, 14-30 mol % alkaline earth oxides, and < 59 mol % SiO2. Glasses containing potassium and magnesium bonded to bone in a similar way as bioactive glasses developed so far.

Topics: Animals; Biocompatible Materials; Bone Cements; Boron Compounds; Calcium Compounds; Electron Probe Microanalysis; Female; Glass; Implants, Experimental; Magnesium Oxide; Male; Materials Testing; Microscopy, Electron, Scanning; Osseointegration; Oxides; Phosphorus Compounds; Potassium Compounds; Rabbits; Silicon Dioxide; Sodium Compounds; Tibia

The magic-angle spinning sidebands of the satellite transition (ST, m = +/- 3/2 <==> +/- 1/2) for 11B nuclear magnetic resonance (11B ST spectroscopy) have been used to detect multiple boron sites in Na2O-B2O3-SiO2 glasses. The experimental details and data analysis are described, how multiple BO4 and BO3 units can be distinguished using standard magic-angle spinning. For a 16Na2O-30B2O3-53.9SiO2 glass (0.1 MnO) two BO4 units with chemical shifts of -2.5 and 0 ppm were found which differ considerably in their quadrupole interaction. Besides this we found three different BO3 units with approximate chemical shifts of 17, 15, and 19 ppm. The results are compared with earlier measurements.

Topics: Boron; Boron Compounds; Glass; Magnetic Resonance Spectroscopy; Oxides; Silicon Dioxide; Sodium Compounds