boron and phosphoric-acid

Chiral phosphoric acid-catalyzed asymmetric aldehyde prenylation has been established using an α,α-dimethyl allyl boronic ester. The transformation provides expedient access to a wide array of aryl, heteroaryl, aryl-substituted alkenyl and primary and secondary aliphatic homoprenyl alcohols with excellent asymmetric induction. The utility of this asymmetric catalysis strategy has been demonstrated through a short and efficient total synthesis of the two natural products (-)-rosiridol and (-)-bifurcadiol.

Topics: Alcohols; Aldehydes; Biological Products; Boron; Catalysis; Diterpenes; Phosphoric Acids; Prenylation; Stereoisomerism

Properties such as high optically stimulated luminescent (OSL) sensitivity, ease of preparation and dose linearity over nine decades (µGy-kGy) make LiMgPO4:Tb, B (LMP) a unique phosphor for dosimetry applications. This led to the investigation of the beta response of highly sensitive LMP-based Teflon-embedded OSL discs for personnel monitoring applications. A PTB beta secondary standard calibration setup (BSS2), which contains three beta sources viz. (147)Pm, (85)Kr and (90)Sr/(90)Y, was used. The relative response with respect to (137)Cs photons for 0.4-mm thick LMP discs was found to be ∼7.32, ∼53.5 and 100 % for (147)Pm, (85)Kr and (90)Sr/(90)Y beta energies, respectively. The response of LMP discs under various filter combinations viz. 0.18-mm thick mylar (25 mg cm(-2)), 0.625-mm thick Poly-allyl-diglycol carbonate (PADC, 81 mg cm(-2)), 1-mm thick polythene (95 mg cm(-2)), 1-mm thick Perspex (118 mg cm(-2)), 1.25-mm thick PADC (162 mg cm(-2)) and 1.6-mm thick (189 mg cm(-2)) Perspex filters was also studied and the ratio of the response of open disc to the response under filters (DOpen/DFilter) of different thicknesses (mg cm(-2)) was evaluated. Studies were also performed for the mixed field of low- ((85)Kr) and high-energy ((90)Sr/(90)Y) beta particles and the DOpen/DFilter ratio was evaluated. The angular dependence of the response of OSL discs to (85)Kr and (90)Sr/(90)Y beta sources was also studied. Studies were also carried out for (204)Tl, (32)P, natural uranium and (106)Ru/(106)Rh beta sources and the ratios of the response of open disc to that of under 1.6-mm thick Perspex (DOpen/DFilter) filter were measured. A study with various beta sources for the evaluation of the DOpen/DFilter ratio was necessary as these ratios are used to estimate the energy of beta particles and to apply the correction factor while evaluating the beta dose/design of dose estimation algorithms.

Topics: Algorithms; Beta Particles; Boron; Calibration; Equipment Design; Film Dosimetry; Humans; India; Lithium; Magnesium; Phosphoric Acids; Polytetrafluoroethylene; Radiation Dosage; Sensitivity and Specificity; Terbium; Thermoluminescent Dosimetry; Time Factors

Boron compounds are widely-used raw materials in industries. However, elevated boron concentrations in aqueous systems may be harmful to human and plants. In this study, calcium hydroxide (Ca(OH)(2)) alone and Ca(OH)(2) with phosphoric acid (H(3)PO(4)) addition (P-addition) were used to remove and recover boron from wastewater using hydrothermal methods. A microwave (MW) hydrothermal method was used and compared with the conventional heating (CH) method in batch experiments. Physicochemical properties of the precipitates obtained from both methods were analysed by XRD, SEM with EDX and BET. For the case of Ca(OH)(2) alone and the MW method, experimental results showed that boron recovery efficiency reached 90% within 10 min, and crystals of Ca(2)B(2)O(5)·H(2)O were found in the precipitates as indicated by the XRD analysis. For the case of P-addition and the MW method, boron recovery efficiency reached 99% within 10 min, and calcium phosphate species (CaHPO(4)·H(2)O, CaHPO(4) and Ca(10)(PO(4))(6)(OH)(2)) were formed. The experimental results of this study indicate that the required reaction time of the MW method was much less than that of the CH method, and the MW method is an effective and efficient method for boron removal and recovery from concentrated wastewater.

Topics: Algorithms; Boron; Calcium Hydroxide; Hot Temperature; Hydrogen-Ion Concentration; Microscopy, Electron, Scanning; Microwaves; Phosphoric Acids; Porosity; Temperature; Waste Disposal, Fluid; X-Ray Absorption Spectroscopy; X-Ray Diffraction