Compounds > bis(8-quinolinolato)copper(ii)

bis(8-quinolinolato)copper(ii) and mordenite

bis(8-quinolinolato)copper(ii) has been researched along with mordenite* in 1 studies

Other Studies

1 other study(ies) available for bis(8-quinolinolato)copper(ii) and mordenite

Article	Year
Selective oxidation of methane by the bis(mu-oxo)dicopper core stabilized on ZSM-5 and mordenite zeolites. Journal of the American Chemical Society, 2005, Feb-09, Volume: 127, Issue:5 This work reports on the capability of the O2-activated Cu-ZSM-5 and Cu-MOR zeolites to selectively convert methane into methanol at a temperature of 398 K. A strong correlation between (i) the activity and (ii) the intensity of the 22 700 cm-1 UV-vis band, assigned to the bis(mu-oxo)dicopper core, is found (i) as a function of the reaction temperature, (ii) as a function of the Cu loading of the zeolite, and (iii) in comparison to other Cu materials. These three lines of evidence firmly support the key role of the bis(mu-oxo)dicopper core in this selective, low-temperature hydroxylation of methane. Topics: Aluminum Silicates; Biomimetic Materials; Copper; Kinetics; Methane; Monophenol Monooxygenase; Organometallic Compounds; Oxidation-Reduction; Oxygen; Oxygenases; Oxyquinoline; Zeolites	2005

Article

Year

Selective oxidation of methane by the bis(mu-oxo)dicopper core stabilized on ZSM-5 and mordenite zeolites.

Journal of the American Chemical Society, 2005, Feb-09, Volume: 127, Issue:5

This work reports on the capability of the O2-activated Cu-ZSM-5 and Cu-MOR zeolites to selectively convert methane into methanol at a temperature of 398 K. A strong correlation between (i) the activity and (ii) the intensity of the 22 700 cm-1 UV-vis band, assigned to the bis(mu-oxo)dicopper core, is found (i) as a function of the reaction temperature, (ii) as a function of the Cu loading of the zeolite, and (iii) in comparison to other Cu materials. These three lines of evidence firmly support the key role of the bis(mu-oxo)dicopper core in this selective, low-temperature hydroxylation of methane.

Topics: Aluminum Silicates; Biomimetic Materials; Copper; Kinetics; Methane; Monophenol Monooxygenase; Organometallic Compounds; Oxidation-Reduction; Oxygen; Oxygenases; Oxyquinoline; Zeolites

2005