bis(8-quinolinolato)copper(ii) has been researched along with mordenite* in 1 studies
1 other study(ies) available for bis(8-quinolinolato)copper(ii) and mordenite
Article | Year |
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Selective oxidation of methane by the bis(mu-oxo)dicopper core stabilized on ZSM-5 and mordenite zeolites.
This work reports on the capability of the O2-activated Cu-ZSM-5 and Cu-MOR zeolites to selectively convert methane into methanol at a temperature of 398 K. A strong correlation between (i) the activity and (ii) the intensity of the 22 700 cm-1 UV-vis band, assigned to the bis(mu-oxo)dicopper core, is found (i) as a function of the reaction temperature, (ii) as a function of the Cu loading of the zeolite, and (iii) in comparison to other Cu materials. These three lines of evidence firmly support the key role of the bis(mu-oxo)dicopper core in this selective, low-temperature hydroxylation of methane. Topics: Aluminum Silicates; Biomimetic Materials; Copper; Kinetics; Methane; Monophenol Monooxygenase; Organometallic Compounds; Oxidation-Reduction; Oxygen; Oxygenases; Oxyquinoline; Zeolites | 2005 |