betadex and phthalic-acid

This work presents a short review of adsorptive materials proposed and tested for removing phthalates from an aqueous environment. The objective is not to present an exhaustive review of all the types of adsorbents used, but to focus on selected types of "innovative" materials. Examples include modified activated carbon, chitosan and its modifications, β-cyclodextrin, and specific types of biomass, such as activated sludge from a wastewater treatment plant, seaweed and microbial cultures. Data from the literature do not confirm the existence of a broad-spectral adsorbent with high sorption efficiency, low production costs and environmentally friendly manufacture. According to the coefficients of Freundlich's isotherm, the most promising adsorbent of those mentioned in this work appears to be the biomass of activated sludge, or extracellular polysaccharides extracted from it. This material benefits from steady production, is cheap and readily available. Nevertheless, before putting it in practice, the treatment and adaptation of this raw material has to be taken into consideration.

Topics: Adsorption; beta-Cyclodextrins; Biomass; Charcoal; Chitosan; Environmental Restoration and Remediation; Phthalic Acids; Seaweed; Sewage; Water Purification

Herein, Au@Ag@β-cyclodextrin (β-CD) nanoparticles with a relatively uniform shape and size of ∼13 nm in diameter have been successfully synthesized, and the surfaces of the synthesized nanoparticles are successful modified by β-CD. A highly efficient synthetic approach was developed for the preparation of a surface-enhanced Raman spectroscopy (SERS) substrate, which self-assembles Au@Ag@β-CD nanoparticles and analytes into a coffee ring pattern

Topics: beta-Cyclodextrins; Coffee; Esters; Gold; Metal Nanoparticles; Molecular Docking Simulation; Phthalic Acids; Silver

We demonstrate the selective detection of endocrine disruptor chemicals (EDCs) from river water using surface enhanced Raman scattering (SERS). By means of nanosphere lithography, the SERS substrate was prepared via the initial deposition of a monolayer of silica nanospheres (with diameter of ∼330 nm) on a silicon substrate as the template. Subsequently, a 180 nm thick layer of silver followed by a 20 nm layer of gold was deposited. This surface was modified with mono-6-deoxy-6-((2-mercaptoethyl)amino)-beta-cyclodextrin (β-CD) in order to produce a selective capture surface suitable for EDC capture and their detection by means of SERS. We show that EDC model compounds, including 3-amino-2-naphthoic acid (NAPH), potassium hydrogen phthalate (PHTH) and the EDC β-estradiol (ESTR), were captured by the β-CD decorated surface. This surface facilitated SERS detection with limits of detection of 3.0 μM (NAPH), 10 μM (PHTH) and 300 nM (ESTR), all 10-100 times lower than that without the surface modification with β-CD. Individual and simultaneous detection of NAPH and PHTH from their mixture was achieved as evidenced using the bianalyte Raman technique.

Topics: beta-Cyclodextrins; Endocrine Disruptors; Nanospheres; Nanostructures; Naphthalenes; Phthalic Acids; Silicon Dioxide; Spectrum Analysis, Raman; Substrate Specificity

A capillary electrophoretic method for the analysis of 12 commonly found derivatives and isomers of benzoate and phthalate, including p-toluic acid, p-acetamido and p-hydroxy derivatives of benzoic acid, salicylic acid and its acetyl ester, 2- and 4-isomers of carboxybenzaldehyde, meta-, para-, and ortho-isomers of phthalic acid, and monomethyl terephthalic acid was developed. Capillary electrophoresis (CE) was performed in the free zone electrophoresis mode. Performing CE in 10 mM phosphate buffer, pH 7.0 could separate most of the benzoic acid derivatives except the structural or positional isomers. The positional isomers of phthalic acids could be completely separated with co-addition of alpha- and beta-cyclodextrins. Addition of poly(ethylene glycol) 600 (4%) could further resolve some structural isomers. The CE method developed here is rapid, i.e. complete separation could be achieved in less than 8 min for the nine monoanionic benzoate derivatives and in less than 14 min for the three dianionic phthalate isomers. The new method has good precision and linearity and can be readily applied to real samples for quantitative analysis. It is sensitive and can detect sub-ppm (w/w) level of impurity in real terephthalic samples.

Topics: alpha-Cyclodextrins; Benzoates; beta-Cyclodextrins; Cyclodextrins; Electrophoresis, Capillary; Hydrogen-Ion Concentration; Indicators and Reagents; Isomerism; Phthalic Acids; Polyethylene Glycols; Sensitivity and Specificity