betadex and cypermethrin

betadex has been researched along with cypermethrin* in 6 studies

Other Studies

6 other study(ies) available for betadex and cypermethrin

ArticleYear
Molecular dynamics simulation and TDDFT study of the structures and UV-vis absorption spectra of MCT-β-CD and its inclusion complexes.
    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2015, Volume: 149

    In this research, the inclusion ratios and inclusion constants of MCT-β-CD/PERM and MCT-β-CD/CYPERM inclusion complexes were measured by UV-vis and fluorescence spectroscopy. The inclusion ratios are both 1:1, and the inclusion constants are 60 and 342.5 for MCT-β-CD/PERM and MCT-β-CD/CYPERM, respectively. The stabilities of inclusion complexes were investigated by MD simulation. MD shows that VDW energy plays a vital role in the stability of inclusion complex, and the destruction of inclusion complex is due to the increasing temperature. The UV-vis absorption spectra of MCT-β-CD and its inclusion complexes were studied by time-dependent density functional theory (TDDFT) method employing BLYP-D3, B3LYP-D3 and M06-2X-D3 functionals. BLYP-D3 well reproduces the UV-vis absorption spectrum and reveals that the absorption bands of MCT-β-CD mainly arise from n→π(∗) and n→σ(∗) transition, and those of inclusion complexes mainly arise from intramolecular charge transfer (ICT). ICT results in the shift of main absorption bands of MCT-β-CD.

    Topics: beta-Cyclodextrins; Molecular Conformation; Molecular Dynamics Simulation; Permethrin; Pyrethrins; Quantum Theory; Spectrophotometry, Ultraviolet; Thermodynamics

2015
Effects of Two Surfactants and Beta-Cyclodextrin on Beta-Cypermethrin Degradation by Bacillus licheniformis B-1.
    Journal of agricultural and food chemistry, 2015, Dec-23, Volume: 63, Issue:50

    The biodegradation efficiency of beta-cypermethrin (β-CY) is low especially at high concentrations mainly due to poor contact between this hydrophobic pesticide and microbial cells. In this study, the effects of two biodegradable surfactants (Tween-80 and Brij-35) and β-cyclodextrin (β-CD) on the growth and cell surface hydrophobicity (CSH) of Bacillus licheniformis B-1 were studied. Furthermore, their effects on the solubility, biosorption, and degradation of β-CY were investigated. The results showed that Tween-80 could slightly promote the growth of the strain while Brij-35 and β-CD exhibited little effect on its growth. The CSH of strain B-1 and the solubility of β-CY were obviously changed by using Tween-80 and Brij-35. The surfactants and β-CD could enhance β-CY biosorption and degradation by the strain, and the highest degradation was obtained in the presence of Brij-35. When the surfactant or β-CD concentration was 2.4 g/L, the degradation rate of β-CY in Brij-35, Tween-80, and β-CD treatments was 89.4%, 50.5%, and 48.1%, respectively. The half-life of β-CY by using Brij-35 was shortened by 69.1 h. Beta-CY content in the soil with both strain B-1 and Brij-35 decreased from 22.29 mg/kg to 4.41 mg/kg after incubation for 22 d. This work can provide a promising approach for the efficient degradation of pyrethroid pesticides by microorganisms.

    Topics: Bacillus; beta-Cyclodextrins; Biodegradation, Environmental; Half-Life; Hydrophobic and Hydrophilic Interactions; Insecticides; Kinetics; Polyethylene Glycols; Polysorbates; Pyrethrins; Soil; Soil Pollutants; Solubility; Surface-Active Agents

2015
Inclusion complexes of cypermethrin and permethrin with monochlorotriazinyl-beta-cyclodextrin: a combined spectroscopy, TG/DSC and DFT study.
    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2014, Jan-03, Volume: 117

    The suitable size hydrophobic cavity and monochlorotriazinyl group as a reactive anchor make MCT-β-CD to be widely used in fabric finishing. In this paper, the inclusion complexes of monochlorotriazinyl-beta-cyclodextrin (MCT-β-CD) with cypermethrin (CYPERM) and permethrin (PERM) are synthesized and analyzed by TG/DSC, FT-IR and Raman spectroscopy. TG/DSC reveals that the decomposed temperatures of inclusion complexes are lower by 25-30 °C than that of physical mixtures. DFT calculations in conjunction with FT-IR and Raman spectral analyses are used to study the structures of MCT-β-CD and their inclusion complexes. Four isomers of trisubstituted MCT-β-CD are designed and DFT calculations reveal that 1,3,5-trisubstituted MCT-β-CD has the lowest energy and can be considered as main component of MCT-β-CD. The ground-state geometries, vibrational wavenumbers, IR and Raman intensities of MCT-β-CD and their inclusion complexes were calculated at B3LYP/6-31G (d) level of theory. Upon examining the optimized geometry of inclusion complex, we find that the CYPERM and PERM are inserted into the toroid of MCT-β-CD from the larger opening. The band at 1646 cm(-1) in IR and at 1668 cm(-1) in Raman spectrum reveals that monochloroazinyl group of MCT-β-CD exists in ketone form but not in anion form. The noticeable IR and Raman shift of phenyl reveals that these two benzene rings of CYPERM and PERM stays inside the cavity of MCT-β-CD and has weak interaction with MCT-β-CD. This spectroscopy conclusion is consistent with theoretical predicted structure.

    Topics: beta-Cyclodextrins; Differential Thermal Analysis; Models, Molecular; Molecular Structure; Permethrin; Pyrethrins; Quantum Theory; Spectroscopy, Fourier Transform Infrared; Spectrum Analysis, Raman; Vibration

2014
TDDFT study of UV-vis spectra of permethrin, cypermethrin and their beta-cyclodextrin inclusion complexes: a comparison of dispersion correction DFT (DFT-D3) and DFT.
    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 2014, Jul-15, Volume: 128

    A comparative study of DFT and DFT-D3 has been carried out on the UV-vis absorption of permethrin, cypermethrin and their β-cyclodextrin inclusion complexes. The TDDFT method with PCM (or COSMO) model was adopted and B3LYP, BLYP and BLYP-D3 functionals were selected. Comparing the simulated spectra with experimental one, we can notice that pure BLYP functional can better reproduce the UV-vis spectra than hybrid B3LYP, but empirical dispersion corrections BLYP-D3 has better performance than BLYP. BLYP-D3 calculations reveal that the main absorption bands of permethrin and cypermethrin arise from the π→π(*) transition, after encapsulated by β-CD to form inclusion complexes, the host-guest intermolecular charge transfer (ICT) makes the main absorption bands to be changed significantly in wavelength and intensity.

    Topics: beta-Cyclodextrins; Permethrin; Pyrethrins

2014
Usefulness of cyclodextrin media for the determination of alpha-cypermethrin by photochemically induced fluorescence: analytical applications to natural waters.
    Analytical and bioanalytical chemistry, 2009, Volume: 394, Issue:4

    The photochemically induced fluorescence (PIF) spectral properties of alpha-cypermethrin in organic solvents (hexane, dichloromethane, acetonitrile, ethanol) and in cyclodextrin aqueous solutions (beta-CD and 2-hydroxypropyl-beta-CD, 2-HP-beta-CD) were investigated. The photolysis kinetics of alpha-cypermethrin were evaluated in the various media. The PIF signal was found to be significantly enhanced in the CD media relative to the organic solvents. The stoichiometry and the formation constants of the alpha-cypermethrin inclusion complexes formed with the CDs were determined. The analytical performances of the PIF method were improved in the presence of HP-beta-CD relative to the other media, and a CD-enhanced PIF analytical method was developed. The limits of detection and limits of quantification ranged, respectively, between 6 and 98 ng/mL and between 24 and 343 ng/mL, depending on the medium. Application to the analysis of tap water and Senegal natural water samples collected close to agricultural areas and spiked with alpha-cypermethrin yielded satisfactory recoveries going from about 77% to 98%. An interference study of foreign species, including pesticides and inorganic ions likely to be present in natural waters, was also carried out.

    Topics: Acetonitriles; beta-Cyclodextrins; Ethanol; Fluorescence; Fresh Water; Hexanes; Kinetics; Methylene Chloride; Photochemical Processes; Photolysis; Pyrethrins; Solvents; Spectrometry, Fluorescence; Spectrophotometry, Ultraviolet; Time Factors

2009
Nonexhaustive beta-cyclodextrin extraction as a chemical tool to estimate bioavailability of hydrophobic pesticides for earthworms.
    Environmental science & technology, 2008, Nov-15, Volume: 42, Issue:22

    Chemical methods to assess bioavailability in soil and sediment often use synthetic polymers that mimic uptake of organic compounds in organisms or microbial degradation. In this paper we have assessed a biomimetic extraction method using hydroxyl-beta-cyclodextrin (HP-beta-CD) to estimate uptake of the two insecticides alpha-cypermethrin (alpha-CYP) and chlorfenvinphos (CFVP) in the earthworm Eisenia fetida. Additionally, a novel approach was developed to estimate the efficiency of biomimetic extractions. The study revealed that HP-beta-CD is a suitable surrogate for estimating the bioaccessibility of hydrophobic chemicals in soil. If one uses a 3.5 times higher amount of HP-beta-CD than soil, effective and reproducible extractions can be achieved within 48 h. Atthese conditions, inclusion of dissolved chemicals by HP-beta-CD mimics uptake of a given compound into earthworms and takes into account sorption-related aspects that control biological uptake. The data indicate that, with increasing hydrophobicity, the affinity of organic chemicals to HP-beta-CD does not increase to the same degree as to soil organic matter. Therefore, a high surplus of HP-beta-CD is necessaryto provide a sufficient extraction capacity in biomimetic extractions.

    Topics: Adsorption; Animals; beta-Cyclodextrins; Biological Availability; Chlorfenvinphos; Hydrophobic and Hydrophilic Interactions; Insecticides; Oligochaeta; Pyrethrins; Soil; Soil Pollutants

2008