betadex has been researched along with azulene* in 1 studies
1 other study(ies) available for betadex and azulene
| Article | Year |
|---|---|
A spectroscopic study of the inclusion of azulene by beta- and gamma-cyclodextrins.
The inclusion of azulene (AZ) inside the cavities of beta-cyclodextrin (beta-CD) and gamma-cyclodextrin (gamma-CD) was studied using absorption, fluorescence and induced-circular dichroism spectroscopy. The inclusion of AZ into the cavity of beta-CD has a stoichiometry of 1:1, whereas that of AZ/gamma-CD complex is 1:2. The equilibrium constants for the formation of the two complexes were calculated to be 780+/-150 M(-1) for AZ:beta-CD and (4.5+/-0.86)x10(5) M(-2) for AZ:(gamma-CD)(2). The latter is due to a stepwise equilibrium mechanism in which a 1:1 complex is formed with a binding constant of 775 M(-1), followed by the formation of a 1:2 complex with a binding constant of 580 M(-1). The difference between the two binding constant values is slight, indicating an almost equal contribution from each of the gamma-CD molecules to the overall binding in AZ:(gamma-CD)(2). From the induced-circular dichroism spectra, the inclusion of AZ was found to be axial in AZ:beta-CD and nearly axial in AZ:(gamma-CD)(2). Topics: Azulenes; beta-Cyclodextrins; Circular Dichroism; Cycloheptanes; gamma-Cyclodextrins; Kinetics; Spectrometry, Fluorescence; Spectrophotometry, Ultraviolet; Water | 2005 |