betadex and 2-4-dichlorophenol

A novel composite consisting reduced graphene oxide-functionalized beta-cyclodextrin epichlorohydrin polymer (RGO-βCD-ECH) was synthesized for the treatment of phenolic wastewater. Batch study of phenolic pollutants (2,4-dichlorophenol, 2-chlorophenol, and phenol) was analyzed using the synthesized composite as an adsorbent from an aqueous solution. The optimized parameters were temperature 25 °C, adsorption time 60 min, solution pH 7, and dosage 0.25 g/L. The isotherm data were more suitably fitted by the Langmuir isotherm model. The maximum uptake for 2,4-dichlorophenol, phenol, and 2-chlorophenol was 702.853, 659.475, and 674.155 mg/g, respectively, at 25 ± 1 °C. The kinetic data for all the phenolic pollutants follow the pseudo-second-order model, and the rate was controlled by film diffusion. Thermodynamic data revealed that the process of removing phenolic pollutants is spontaneous and endothermic. The composite can be used up to five cycles with a small reduction in the removal. Adsorption performance of the synthesized composite for synthetic industrial effluents shows that up to 78% removal occurred in 60 min adsorption time. Based on the remarkably rapid adsorption and high adsorption capacity, the synthesized composite can be considered an efficient adsorbent for treating phenolic pollutants from wastewater.

Topics: Adsorption; beta-Cyclodextrins; Chlorophenols; Epichlorohydrin; Graphite; Kinetics; Phenol; Phenols; Polymers; Wastewater; Water Pollutants, Chemical

This work describes methacrylic acid functionalized β-cyclodextrin (MAA-βCD) as a novel functional monomer in the preparation of molecular imprinted polymer (MIP MAA-βCD) for the selective removal of 2,4-dichlorophenol (2,4-DCP). The polymer was characterized using Fourier Transform Infrared (FTIR) spectroscopy, Brunauer-Emmett-Teller (BET) and Field Emission Scanning Electron Microscopy (FESEM) techniques. The influence of parameters such as solution pH, contact time, temperature and initial concentrations towards removal of 2,4-DCP using MIP MAA-βCD have been evaluated. The imprinted material shows fast kinetics and the optimum pH for removal of 2,4-DCP is pH 7. Compared with the corresponding non-imprinted polymer (NIP MAA-βCD), the MIP MAA-βCD exhibited higher adsorption capacity and outstanding selectivity towards 2,4-DCP. Freundlich isotherm best fitted the adsorption equilibrium data of MIP MAA-βCD and the kinetics followed a pseudo-second-order model. The calculated thermodynamic parameters showed that adsorption of 2,4-DCP was spontaneous and exothermic under the examined conditions.

Topics: Adsorption; beta-Cyclodextrins; Chlorophenols; Hydrogen-Ion Concentration; Kinetics; Molecular Imprinting; Particle Size; Polymethacrylic Acids; Temperature; Thermodynamics; Water Pollutants, Chemical

Numerous reports have indicated that hydrophobic organic compound bioaccessibility in sediment and soil can be determined by extraction using aqueous hydroxypropyl-beta-cyclodextrin (HPCD) solutions. This study establishes the compatibility of HPCD with Selenastrum capricornutum and assesses whether its presence influences the toxicity of reference toxicants. Algal growth inhibition (72 h) showed no significant (P>0.05) difference at HPCD concentrations up to and including 20 mM. HPCD presence did not influence the toxicity of the inorganic reference toxicant (ZnSO(4)), with IC50 values of 0.82 microM and 0.85 microM, in the presence and absence of HPCD (20 mM), respectively. However, HPCD presence (20 mM) reduced the toxicity of 2,4-dichlorophenol and the herbicides diuron and isoproturon. These reductions were attributed to inclusion complex formation between the toxicants and the HPCD cavity. Liberation of complexed toxicants, by sample manipulation prior to toxicity assessment, is proposed to provide a sensitive, high throughput, bioassay that reflects compound bioaccessibility.

Topics: 2-Hydroxypropyl-beta-cyclodextrin; beta-Cyclodextrins; Chlorophenols; Diuron; Dose-Response Relationship, Drug; Ecology; Eukaryota; Herbicides; Phenylurea Compounds; Soil Pollutants; Toxicity Tests