beta-nitrostyrene has been researched along with potassium-phosphate* in 1 studies
1 other study(ies) available for beta-nitrostyrene and potassium-phosphate
Article | Year |
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K3PO4-catalyzed regiospecific aminobromination of beta-nitrostyrene derivatives with N-bromoacetamide as aminobrominating agent.
A very simple, efficient, and regiospecific protocol for aminobromination of a wide scope of beta-nitrostyrene derivatives with N-bromoacetamide (NBA) as nitrogen/bromine sources has been developed by using K(3)PO(4) as catalyst. The reaction proceeded smoothly and cleanly to give the bromoamines in good to excellent yields (78-99%) within 24 h in CH(2)Cl(2) at room temperature without protection of inert gases. A possible mechanism involving a nucleophilic conjugate addition was proposed. Topics: Acetamides; Amines; Bromine; Catalysis; Crystallography, X-Ray; Methylene Chloride; Molecular Structure; Phosphates; Potassium Compounds; Stereoisomerism; Styrenes | 2010 |