beta-nitrostyrene has been researched along with diethyl-acetamidomalonic-acid* in 1 studies
1 other study(ies) available for beta-nitrostyrene and diethyl-acetamidomalonic-acid
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Synthesis of ribo-hexopyranoside- and altrose-based azacrown ethers and their application in an asymmetric Michael addition.
The synthesis of four new ribo-hexopyranoside-based chiral lariat ethers of monoaza-15-crown-5 type and two altropyranoside-based crown ethers were elaborated. Our syntheses utilized the regioselective ring opening of the oxiran moiety of the 2,3-anhydro sugars by nucleophilic reagents to afford the key intermediates. The reaction of methyl-2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranoside with ethanolamine is especially of interest to afford a 3-substituted altropyranoside. One of the ribo-hexopyranoside-based lariat ethers with a 4-methoxyphenyl substituent induced an enantioselectivity of 80% when used as catalyst in the Michael addition of diethyl acetamidomalonate to trans-β-nitrostyrene under phase transfer catalytic conditions. Topics: Borohydrides; Catalysis; Chemistry Techniques, Synthetic; Chromatography, Liquid; Crown Ethers; Hexoses; Magnetic Resonance Spectroscopy; Malonates; Molecular Structure; Phase Transition; Quaternary Ammonium Compounds; Styrenes | 2013 |