beta-isocupreidine has been researched along with trifluoroethylamine* in 1 studies
1 other study(ies) available for beta-isocupreidine and trifluoroethylamine
Article | Year |
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Synthesis of Chiral α-Trifluoromethylamines with 2,2,2-Trifluoroethylamine as a "Building Block".
The β-isocupreidine, a cinchonine derived alkaloid, catalyzed asymmetric SN2'-SN2' reaction between N-2,2,2-trifluoroethylisatin ketimines and MBH type carbonates was realized in a simple and efficient way. A series of chiral α-trifluoromethylamines were prepared with excellent yields and stereoselectivities. A subsequent and easy process of deprotection gave γ-trifluoromethyl-α-methylenelactam in a stereoselective manner. Topics: Carbonates; Catalysis; Cinchona Alkaloids; Ethylamines; Hydroxyquinolines; Imines; Molecular Structure; Nitriles; Quinuclidines; Stereoisomerism | 2016 |