benzofurans has been researched along with 2-benzoquinone* in 1 studies
1 other study(ies) available for benzofurans and 2-benzoquinone
Article | Year |
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Synthesis of 2-substituted 7-hydroxybenzofuran-4-carboxylates via addition of silyl enol ethers to o-benzoquinone esters.
Mukaiyama Michael addition of silyl enol ethers 13 to the 1,2-quinone-4-carboxylate 6 (formed in situ by oxidation of the catechol ester 8) afforded the 2-subsituted 7-hydroxybenzofuran-4-carboxylates 14 in fair to good yields. Alkyl and aryl systems work well, but highly electron-rich silyl enol ethers could not be used because of competing oxidation. Topics: Benzofurans; Benzoquinones; Carboxylic Acids; Catalysis; Cyclization; Esters; Ethers; Molecular Structure; Oxidation-Reduction; Silanes | 2009 |