australifungin and decalin

australifungin has been researched along with decalin* in 1 studies

Other Studies

1 other study(ies) available for australifungin and decalin

Article	Year
Intramolecular Diels-Alder (IMDA) Studies toward the Synthesis of Australifungin. Stereocontrol in the Acetate Aldol Reaction of β,β'-Branched Aldehydes. Organic letters, 2016, Feb-05, Volume: 18, Issue:3 Studies of australifungin illustrate an enantiocontrolled synthesis of the trans-decalin core 28 via an intramolecular [4π + 2π] cycloaddition. This strategy utilizes the nitroalkene dienophile of 27 as a surrogate ketene equivalent. Stereocontrol at C-2 is critically important for an effective intramolecular Diels-Alder (IMDA) process. Our studies report high asymmetric induction using a nonracemic Duthaler titanium enolate in the acetate aldol reaction with β,β'-branched aldehyde 13 to introduce the required C-2 chirality. Topics: Acetates; Aldehydes; Cycloaddition Reaction; Molecular Structure; Naphthalenes; Stereoisomerism; Tetrahydronaphthalenes	2016

Article

Year

Intramolecular Diels-Alder (IMDA) Studies toward the Synthesis of Australifungin. Stereocontrol in the Acetate Aldol Reaction of β,β'-Branched Aldehydes.

Organic letters, 2016, Feb-05, Volume: 18, Issue:3

Studies of australifungin illustrate an enantiocontrolled synthesis of the trans-decalin core 28 via an intramolecular [4π + 2π] cycloaddition. This strategy utilizes the nitroalkene dienophile of 27 as a surrogate ketene equivalent. Stereocontrol at C-2 is critically important for an effective intramolecular Diels-Alder (IMDA) process. Our studies report high asymmetric induction using a nonracemic Duthaler titanium enolate in the acetate aldol reaction with β,β'-branched aldehyde 13 to introduce the required C-2 chirality.

Topics: Acetates; Aldehydes; Cycloaddition Reaction; Molecular Structure; Naphthalenes; Stereoisomerism; Tetrahydronaphthalenes

2016