asperparaline-a and 3-3-dimethylallyl-pyrophosphate

asperparaline-a has been researched along with 3-3-dimethylallyl-pyrophosphate* in 1 studies

Other Studies

1 other study(ies) available for asperparaline-a and 3-3-dimethylallyl-pyrophosphate

ArticleYear
Studies on the biosynthesis of asperparaline A: origin of the spirosuccinimde ring system.
    Journal of the American Chemical Society, 2003, Dec-03, Volume: 125, Issue:48

    The primary amino acid building blocks that constitute asperparaline A have been determined through feeding and incorporation of 13C-labeled intermediates. The beta-methyl proline residue is constituted from (S)-isoleucine, the novel spiro-succinime moiety is derived from the oxidative degradation of (S)-tryptophan, and (S)-adenosylmethionine contributes the two N-methyl residues. In addition, it was found that the incorporation of 13C-labeled acetate into the single isoprene unit clearly demonstrates that the isoprene moiety is derived from the mevalonate pathway.

    Topics: Alkaloids; Aspergillus; Carbon Isotopes; Hemiterpenes; Isoleucine; Nuclear Magnetic Resonance, Biomolecular; Organophosphorus Compounds; Piperazines; Spectrometry, Mass, Electrospray Ionization; Spiro Compounds; Succinimides; Tryptophan

2003
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