ascladiol and furan

ascladiol has been researched along with furan* in 1 studies

Other Studies

1 other study(ies) available for ascladiol and furan

Article	Year
Divergent synthesis of the co-isolated mycotoxins longianone, isopatulin, and (Z)-ascladiol via furan oxidation. The Journal of organic chemistry, 2009, Aug-21, Volume: 74, Issue:16 Longianone and the biosynthetically related mycotoxins isopatulin and (Z)-ascladiol were prepared following a divergent route from a readily available furan diol. The route toward longianone features an unprecedented TBAF-promoted intramolecular oxa-Michael reaction to a conjugated keto enoate, and the oxidation of dihydrolongianone to longianone with stabilized IBX. The route to isopatulin features a chemoenzymatic synthesis of (Z)-ascladiol, and the regioselective oxidation of (Z)-ascladiol to isopatulin with MnO(2). Topics: Furans; Heterocyclic Compounds, 2-Ring; Lactones; Mycotoxins; Oxidation-Reduction; Spiro Compounds; Stereoisomerism	2009

Article

Year

Divergent synthesis of the co-isolated mycotoxins longianone, isopatulin, and (Z)-ascladiol via furan oxidation.

The Journal of organic chemistry, 2009, Aug-21, Volume: 74, Issue:16

Longianone and the biosynthetically related mycotoxins isopatulin and (Z)-ascladiol were prepared following a divergent route from a readily available furan diol. The route toward longianone features an unprecedented TBAF-promoted intramolecular oxa-Michael reaction to a conjugated keto enoate, and the oxidation of dihydrolongianone to longianone with stabilized IBX. The route to isopatulin features a chemoenzymatic synthesis of (Z)-ascladiol, and the regioselective oxidation of (Z)-ascladiol to isopatulin with MnO(2).

Topics: Furans; Heterocyclic Compounds, 2-Ring; Lactones; Mycotoxins; Oxidation-Reduction; Spiro Compounds; Stereoisomerism

2009