arisugacin has been researched along with cyclohexanone* in 1 studies
1 other study(ies) available for arisugacin and cyclohexanone
| Article | Year |
|---|---|
Stereoselective trans- and cis-dihydroxylations of 2H-pyranyl and dihydropyridinyl heterocycles synthesized from formal [3 + 3]-cycloaddition reactions of alpha,beta-unsaturated iminium ions with 1,3-dicarbonyl equivalents.
[reaction: see text]We describe here an inherent problem in direct epoxidation of the endocyclic olefin in 2H-pyrans fused to 2-pyrones. Such difficulties led to the development of highly stereoselective trans- and cis-dihydroxylations of these olefinic systems in both 2H-pyrans and dihydropyridines fused to a 2-pyrones or a 2-cyclohexenone. Protocols for the removal of the activated allylic hydroxyl group are also reported. Topics: Alkaloids; Alkenes; Catalysis; Cyclohexanones; Heterocyclic Compounds, 2-Ring; Hydroxylation; Imines; Molecular Structure; Pyrans; Pyridines; Pyrones; Quinolines; Stereoisomerism; Structure-Activity Relationship | 2001 |